CN106479046A - A kind of PPM environment-friendly materials and preparation method thereof - Google Patents
A kind of PPM environment-friendly materials and preparation method thereof Download PDFInfo
- Publication number
- CN106479046A CN106479046A CN201610866573.1A CN201610866573A CN106479046A CN 106479046 A CN106479046 A CN 106479046A CN 201610866573 A CN201610866573 A CN 201610866573A CN 106479046 A CN106479046 A CN 106479046A
- Authority
- CN
- China
- Prior art keywords
- friendly materials
- ethylene
- ppm
- environment
- ppm environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of PPM environment-friendly materials and preparation method thereof, and the PPM environment-friendly materials include the composition of following percentage by weight：80% 85% calcium carbonate, 15% 20% vector resin, 0.5 10% dispersant, 0.5% 10% lubricant, 0.5% 10% coupling agent and 0.1 3% antioxidant.The preparation method of the PPM environment-friendly materials is comprised the following steps：Calcium carbonate coating modification, modified mix with vector resin, lubricant, antioxidant banburying again, carry out extruding pelletization and air-cooled, screening, packaging is completed, until complete whole preparation process.The preparing raw material of the PPM environment-friendly materials is easy to get, low cost, quality height, technical maturity, be easy to promote, effect is significant.Plastic products manufacture field is can be widely applied to, especially in plastics package industry and agripast industry and materials for construction industry.
Description
Technical field
The present invention relates to a kind of PPM environment-friendly materials and preparation method thereof.
Background technology
China is one of limestone deposit resource-rich country in the world.In addition to Shanghai, Hong Kong, Macao, in each province, it is directly under the jurisdiction of
City, autonomous region are all distributed.Count according to former State Bureau of Building Materials Industry's geology center, national limestone distribution area reaches 43.8 ten thousand Km2 (not
Including Tibet and Taiwan), account for the 1/20 of area.
Part oil plastics are substituted using inorganic filling materials such as calcium carbonate, reduce material while saving petroleum resources and become
This, it has also become the trend of plastic industry development.Calcium carbonate can be widely applied to the fields such as rubber, coating, papermaking, plastics, ink.
But China and in the world the efficient technique of rainwater utilization slower development to calcium carbonate, for a long time, application calcium carbonate in the plastic is all
Be to fill based on 20% or so, and useless really play improve the processability of plastics, improve plastic products stability and reduce modeling
Material products cost etc. is acted on.
Content of the invention
For problems of the prior art, the present invention provides a kind of PPM environment-friendly materials and preparation method thereof, its preparation
Raw material is easy to get, low cost, quality height, technical maturity, be easy to promote, effect is significant.Can be widely applied to plastic products processing neck
Domain, especially in plastics package industry and agripast industry and materials for construction industry.
The present invention provides a kind of PPM environment-friendly materials, including the composition of following percentage by weight：The calcium carbonate of 80%-85%,
The vector resin of 15%-20%, the dispersant of 0.5-10%, the lubricant of 0.5%-10%, the coupling agent of 0.5%-10% and 0.1-3%
Antioxidant.
The present invention also provides a kind of preparation method of PPM environment-friendly materials, comprises the following steps：
Step one：First the calcium carbonate of inorganic particle, dispersant and coupling agent are simultaneously introduced split according to parts by weight proportioning
Coating modification is carried out in coating machine；
Step 2：Modified again with vector resin, lubricant, antioxidant while being put into banburying in banbury and mixing；
Step 3：The material that banburying is mixed is put in comminutor carries out extruding pelletization；
Step 4：Air-cooled, screening, packaging, complete preparation process.
Present invention has the advantage that：
In the production process of plastic products, can play improves the processability of plastics, improves plastic products stability and reduction
Plastic products cost etc. is acted on, and the features such as with environmental protection, inexpensive, reusable edible.
Green Sheng PPM environment-friendly materials compared to biological plastics and starch-based material have low price, stability higher, processing
The advantage such as difficulty is easier, practicality is higher.And compared to common filling master batch, green Sheng PPM environment-friendly materials possess light specific gravity, add
Plus the performance advantage such as ratio height, product strength height, environmental protection.
Make the method for vector resin using polypropylene and polyethylene blend, effect is more preferable.Product had both maintained PPM masterbatch
Characteristic and range, production efficiency can be improve, reduces the cost of raw material using the fervent air-cooled technique of die face again.
The utilization ratio of calcium carbonate is improved, increases adding proportion.
Calcium carbonate and the fusion agent of fusion, the auxiliary agents such as polypropylene are developed in innovation, and the surface that improve calcium carbonate powder is lived
Change effect.
The production process equipment of independent research, reduces production cost, improves product competitiveness.
Industrialization is achieved, product applications are extensive.
Specific embodiment
With reference to specific embodiment, the invention will be further described, so that those skilled in the art can be more preferable
Understand the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.
The present invention provides a kind of PPM environment-friendly materials, is white plates body, no substantially mechanical admixture and stain, it include with
The composition of lower percentage by weight：The calcium carbonate of 80%-85%（Preferably 80%, 85%）, 10%-30% vector resin（Preferably
20%）, 0.5-10% dispersant（Preferably 5%）, 0.5%-10% lubricant（Preferably 5%）, 0.5%-10% coupling agent（Excellent
Elect 5% as）And 0.1-3% antioxidant（Preferably 2%）.Proportion is 1.55-1.65 g/cm3, flow index MFR, (MI) is
4-5 g/10 min, pH value are 6.9-7, moisture≤0.3%（The moisture condensed containing a small amount of in the air after the completion of preparation, one
As between 0-0.3%, being 0）.
For guaranteeing the stability of product quality and facilitating follow-up PROCESS FOR TREATMENT, thus the calcium carbonate in its composition is fineness
It is 6 for -3000 mesh of 1000 mesh, draw ratio：1-13：The transparent calcite calcium carbonate of 1 needle-like.
The vector resin is polypropylene, polyethylene or the mixture of the two, and during the two mixing, percentage by weight is poly- third
Alkene is 20-50%, and polyethylene is 50%-80%.
The vector resin can also be constituted with ethylene-octene copolymer and/or ethylene-acrylic acid copolymer for polypropylene
Mixture, wherein mix when percentage by weight be polypropylene be 90-95%, ethylene-octene copolymer be 5-10%, ethene-the third
Olefin(e) acid copolymer is 5-10%.
The vector resin can also be polyethylene and ethylene-vinyl acetate copolymer and/or ethylene-octene copolymer
And/or the mixture that ethylene-acrylic acid copolymer is constituted, when wherein mixing, percentage by weight is 80-95% for polyethylene, described
Ethylene-vinyl acetate copolymer is 5-20%, and ethylene-octene copolymer is 5-10%, and ethylene-acrylic acid copolymer is 5-20%.
The vector resin can also for polypropylene, the mixture of both polyethylene and ethylene-vinyl acetate copolymer and/
Or the mixture that ethylene-octene copolymer and/or ethylene-acrylic acid copolymer are constituted, when wherein mixing, percentage by weight is poly-
Propylene is 40-45%, and polyethylene is 40-45%, and ethylene-vinyl acetate copolymer is 5-10%, and ethylene-octene copolymer is 5-
10%, ethylene-acrylic acid copolymer is 5-10%.
The dispersant is Stearyl Amine, in vinyl double Stearyl Amine, barium stearate, calcium stearate and zinc stearate
One or more, when select multiple when, zero gravity ratio requirement between each composition.The lubricant be paraffin, Tissuemat E,
One or more in OPE and low-molecular-weight polypropylene wax, when selecting multiple, zero gravity between each composition
Ratio requirement.The coupling agent is aluminate coupling agent, titanate coupling agent, silane coupler, Aluminate-titanate esters are compound even
One or more in connection agent and zirconium aluminate coupling agent, when selecting multiple, zero gravity ratio requirement between each composition.
The present invention provides a kind of preparation method of PPM environment-friendly materials, comprises the following steps：
Step one：First the calcium carbonate of inorganic particle, dispersant and coupling agent are simultaneously introduced split according to parts by weight proportioning
Coating modification is carried out in coating machine, and modified temperature is 90-130 DEG C, and the time is 5-15 minute, preferably 5-10 minute, enters one
Step is preferably 10 minutes, obtains the good inorganic particle of coating modification；
Step 2：By the good inorganic particle of coating modification with vector resin, lubricant, antioxidant while being put into close in banbury
Refining mixing, can adopt the kneader with S type blade（Patent No. ZL.201520870644.6）Banburying mixing is carried out, close
The temperature of refining mixing is 90-150 DEG C, and the time is 10-20 minute, and preferably 10-15 more preferably 10 minutes, is mixed
Material afterwards；
Step 3：The material that banburying is mixed is by the extruder with S type blade（Patent No.
ZL.201520870597.5）It is delivered to into air-cooling pelletizer（Patent No. ZL.201520870458.2）In carry out extrusion and make
Grain, time are 15-20 minute, preferably 15 minutes；
Step 4：Using a kind of water-cooled feed system（Patent No. ZL.201520870525.0）In type particle is carried out
Air-cooled, screening, packaging, air-cooled, screening, the time of packaging are 20-30 minute, preferably 30 minutes, that is, obtain PPM environmental protection material
Material.
PPM environment-friendly materials can be produced by process above engineering, with yield is big, good dispersion, addition
Greatly, for different applications, shared percentage in the formula components of PPM environment-friendly materials specifically can be adjusted, meanwhile, its
The temperature and time needed in links in technological process also can be accordingly different.
Calcium carbonate as a kind of aboundresources, cheap inorganic mineral powder, 300～600 yuan of ordinary calcium carbonate/
Ton, and vistanex price is at 9000～15000 yuan/ton, at 7000～8500 yuan/ton, resin compares carbon to polyvinyl chloride price
The price of sour calcium powder is higher by 20～30 times, and the price of modified master also only has the 1/5～1/2 of resin.If in plastic products
Add 10%～50% masterbatch, deduct density factor, plastic products per ton can also the hundreds of unit of reduces cost to thousands of units, enterprise
Productivity effect is clearly.
Appropriate Paris white is added in plastic products, can also be improved the printing of plastic products, is touched sense, reduces note
The shrinkage factor of the products such as modeling, while production cost is reduced, improves properties of product, improves the competitiveness of product in market, produce
Obvious economic benefit and social benefit.
Generally powder body material is used as filler in granular form.The shape of particle is not very regular, but to plastics
For performance, the geometry of filler particles has important impact to the physical and mechanical property for filling system, therefore powder material
The grain shape of material be when using firstly the need of being paid close attention to.For sheet-like particle, often using concept, the i.e. piece of radius-thickness ratio
The planar dimension (vertical or horizontal) of shape particle and the ratio of thickness;For fibrous particle, often using the general of draw ratio
Read, i.e. the length-to-diameter of fibrous particle.The grain shape of calcium carbonate mostly in tetragonal body, hexahedron, many cubes and
Irregular square graininess, physical property impact of its shape on mobility and product in plastic processing are extremely important.This
By precisely screening, we are 6 from draw ratio for invention:1-13:The transparent calcite calcium carbonate of 1 needle-like, fibrous particle
Structure can improve material property further with certain orientation in the plastic deformation of plastics macromolecular structure, while
Again will not be because of the mobile performance of too big draw ratio impact material.
Filling-modified technology it is important that, powder granule is singly distributed to plastics equably, as far as possible
In matrix, it is, in general, that the particle diameter of filler particles is less, if can be uniformly dispersed, then the mechanical property of filling system is better;
But particle diameter is less, processing cost is higher, realizes which dispersed more difficult.Require that the particle diameter distribution of calcium powder is got in plastic products
Narrow better, that is, minimum grain size and maximum particle diameter is classified out, according to use requirement, for different product, present invention collection particle diameter exists
Product in the range of 1000 mesh to 3000 mesh, it is ensured that dispersed, the transparent, mechanical property of product and oil absorbency.
Filler particles surface roughness is different.The particle of i.e. same volume, its surface area geometric form not only with particle
Shape relevant (spherical watch area is minimum), also relevant with the degree of roughness on its surface.Specific surface area is the surface of unit mass filler
Product, its size have direct relation to the compatibility between filler and resin, the difficulty or ease of filler surface activation process and cost.
Filler particles surface free energy magnitude relationship scattered difficulty or ease in matrix resin to filler.When one timing of specific surface area, surface
Free energy is big, particle easier cohesion each other, is more difficult dispersion.When filler is surface-treated, reduce its surface free energy
It is one of main target.By the present invention in that with the dispersant of independent development, choosing multiple efficient couplings effectively for calcium powder
Agent, allows they and inorganic particle mixed at high speed at a certain temperature, in the presence of heat in ambient temperature and friction, reduces powder
The surface free energy of body particle, the polar group of coupling agent is connected to powder granule surface, and non-polar group outwardly, makes powder
Between powder, all there is non-polar group segment to intercept, be difficult to reunite between powder granule, while activation effect is improved, strengthen powder
Compatibility between body and resin macromolecule.
It is relevant that the density of filler piles up state with filler particles.As the particle of precipitated calcium carbonate assumes spindle, and weigh
There is space in broken stone shape when piling up between particle in the particle of matter calcium carbonate, and after the former volume is significantly greater than
Person, thus the apparent density of precipitated calcium carbonate is less than powdered whiting, but this is not intended to fine particle calcium carbonate " light ", coarse whiting " weight ", because
It is that difference for its individual particle between them is very little, the former is 2.4～2.7g/cm3, the latter is 2.7～2.9g/
cm3.In filling plastic modification field, real impact filling system global density be the density of filler individual particle and they
Whether the existence form in plastic substrate is agglomerated together, and has tight etc. and matrix plastic molecule between.This
Weight calcium powder is used in mixed way by invention, is effectively reduced the sedimentation phenomenon in product activation process, is improved activation efficiency.After activation with
Vector resin（According to different product needed）Polypropylene, polyethylene, ethylene-vinyl acetate copolymer, POE,
Ethylene acrylic acid co polymer, lubricant, antioxidant etc. are put in the kneader with S type blade simultaneously and carry out banburying mixing,
Temperature control is at 90-150 DEG C.Under temperature, pressure collective effect, the auxiliary agent such as dispersant, lubricant, coupling agent fully reacts,
The resin carrier allowed under powder granule and elastomeric state uniformly mixed be incorporated in Van der Waals force in the presence of make activation powder surface another
The lipophilic group at end adsorbs on the side chain of resin carrier, as the fibrous rigid structural support of inorganic particle itself lives to set
The long-chain of fat, forms certain space so that PPM environment-friendly materials can't substantially increase the density of product.Reduce becoming for product
This, improves the market competitiveness.
The hardness of filler particles itself has duality, and the high filler of one side hardness can make the resistance to of filled plastics material
Mill property is improved, and on the other hand due to adding filler, the especially high filler of hardness, obturator system are easily right in process
Heavy wear is caused on the surface of the process equipment contacted by material and mould, and during this serious wear, the economic loss that brings
Considerably beyond the interests that brings using filler, the application in the plastic of this powder body material will be affected.Certainly, hardness level is not
Same filler is different to the abrasion of process equipment, on the other hand for the filler of certain hardness, the metal watch of process equipment
The tear strength in face rises with the increase of packing material size, and to after certain particle diameter, its tear strength tends towards stability.Additionally, relative grind
The difference of the hardness of the bi-material of mill is also relevant with tear strength size.When metal strength is higher than 1.25 times of abrasive hardness, category
In low abrasion situation;When metal strength is 0.8～1.25 times of abrasive hardness, belong to middle abrasion condition;Metal strength is less than
During 0.8 times of abrasive hardness, belong to high abrasion condition.For example, it is generally used for the barrel of plastic extruder and the metal material of screw rod
Expect for 38CrMoAl steel alloy, via nitride is processed, its Vickers hardness is 800～900, and the Vickers hardness of coarse whiting is 140 or so.
Therefore the extrusion machining of calcium carbonate filled plastics, despite abrasion, but not particularly significant, can receive at least;And flyash
Glass microballoon or quartz sand, more than 1000, these material filled plastics are extremely serious to the abrasion of nitrated steel for its Vickers hardness,
After tens tons of materials of processing, just there is no (nitration case about 0.4mm is thick) in the nitration case of its screw rod.The present invention is by activation
The calcium carbonate powder of changed handling, reduces the reunion of calcium carbonate granule, improves mobility, reduces pressure when processing,
While plus the parcel of resin carrier, reducing directly contact of the inorganic particle to equipment, product hardness, wearability is being improved
While effectively reducing the abrasion of the equipment of material.
The whiteness height of filler has vital impact to the color and luster or even outward appearance of filled plastics material and product.Logical
Chang Baidu is higher, and the impact to filled plastics coloring is less, only affects the bright-coloured degree of color.Due to there is presently no completely
Transparent filler, therefore filled plastics are often opaque, if the Color whiteness of filler is not high or be in other color and lusters, only
The plastic products of black or dark color can be done.Plastic material itself has very big difference, the folding of most general-purpose plastics to the refractive index of light
Rate is penetrated 1.50～1.60.When the refractive index of powder stuffing and the refractive index of plastic substrate same or like when, they are added to
Covering impact after in matrix plastic on light is less, otherwise filled plastics are just strong to the covering effect of light.The present invention chooses high
Calcite is originated as calcium carbonate powder thoroughly, and whiteness is high.While calcite crystal has two equal short axles and perpendicular to the 3rd
Axle (major axis).Light along major axis propagate when, its spread speed is indeclinable, and when light is propagated along other directions, is divided
The light for two kinds of friction speeds is solved, produces two refractive indexes.Two refractive indexes of calcite be respectively 1.658 and 1.486 with
The refractive index 1.50～1.60 of general-purpose plastics is close to, and the product transparency for doing green Sheng PPM environment-friendly materials is high, and color and luster is affected
Little.
Calcium carbonate itself is not hygroscopic, without constitution water and the crystallization water, but in the collection of usual ore, storage, processing and storehouse
During storage, because powder granule is minimum, moisture is easily absorbed.Requirement of the plastics in use to moisture is high, powder standard
≤ 0.5%, during practical application is required, powder water content answers≤0.3%, and the less impact to plastic products of water content is less.This
Heat in equipment heating and friction during the bright activation modification by us, effectively excludes the moisture carried in powder, activation
Later there is the surface protection of lipophilic group again so that powder is difficult moisture is absorbed, while also back segment banburying and extruding pelletization
Process heats abundant cladding while excluding moisture further with vector resin, reduces the directly contact with moisture in air,
So that the moisture of product is controlled in 0.2% level below, impact will not be produced on plastic products.
The present invention provides PPM environment-friendly materials, and under temperature, pressure collective effect, dispersant, lubricant, coupling agent etc. are helped
Agent is fully reacted, and the resin carrier under allowing powder granule and elastomeric state is uniformly mixed in the presence of being incorporated in Van der Waals force and makes activation powder
The lipophilic group of the body surface face other end adsorbs on the side chain of resin carrier, due to stretching and inflation to resin macromolecular it
Between, bring space between resin macromolecular and the fibrous rigid structure of inorganic particle itself, effectively reduce the density of product.Survey
Test result shows that the HDPE density of film for adding 30% PPM environment-friendly materials is 0.958%, and horizontal and vertical tensile strength is respectively
26.04MPa and 28.64MPa, contrasts conventional HDPE films, and combination property is dramatically increased；The similar interpolation inserts in contrast market
Product, than increasing by 32% and 62% respectively, density reduces 8% to tensile property.In the partially thin industry of this profit of plastic processing, density
Reduction by cause product competitiveness greatly improve.
Table 1：The PPM environment-friendly materials that the present invention is provided and common inserts add same ratio performance comparison
According to being shown with the test result of upper table 1, under equal addition, the product mechanical property that green Sheng PPM environment-friendly materials are obtained
Ordinary calcium carbonate inserts can be substantially better than, in density, also has significantly reduction.
The application of the PPM environment-friendly materials of the present invention, can reduce the usage amount of conventional resins in a large number, so as to save oil money
Source.Dirt will not be caused to human body, empty gas and water and soil in processing procedure after raw material are chosen, produce, using and be discarded
Dye, the PPM environment-friendly materials and its product repeatedly can be recycled, and even lose using function, and the waste residue after burning can also
For other purposes such as construction material, if not burning after discarded, also can be disintegrated naturally not in natural environment and causing vision dirty
Dye（Show through SGS mechanism detection data, PPM product refuse bag time of about 200 hours in natural light oxygen environment just may be used
Start disintegration）.The production cost of the PPM environment-friendly materials is 50% of conventional resins or so, greatlys save the production of down-stream enterprise
Cost.Using the product of PPM environment-friendly materials have high texture, shock resistance, circumnutate, hardness and high rigidity, and gas permeability, extension
Property, resistance to marring and anti-slip effect etc., it is higher to compare general biodegradable plastic stability, will not be mould because of improper storage
Become, there is low price compared to biological plastics and starch-based material, the higher advantage of practicality.
The PPM environment-friendly materials that the present invention is provided possess the advantages such as environmental protection, superior performance compared with common filling master batch,
Which can adding proportion be high, product surface product is big, production capacity is high, this is because which employs Polymer Technology, molecule is in network structure
And be evenly distributed, material has structural void, the fast factor of the effect of fretting map, discharging speed, therefore can improve making for product
With performance, identical in adding proportion, in the case that products thickness is consistent, the surface area of PPM environmental protection material product will have more 10%-
30%.When under equal conditions, using PPM environment-friendly materials blown film, production capacity will be higher by 10%-20%, save the electricity charge, artificial, studio rent
Deng cost.Simultaneously as product discharge speed is fast, the infringement to film blowing machine screw is reduced.The PPM environment-friendly materials are by calcium carbonate
Efficient utilization, PE, PP and calcium carbonate copolymerization are truly realized the function of substituting conventional resins, solve powder activation, multiple
The problems such as polymer blending is compatible, calcium carbonate-filled proportion increases serious, improves adding proportion and the mechanical property of product, with
When it also avoid that biological plastics insufficient raw material, production capacity are low, price is high, inconvenient preservation and transport etc. are touched in actual application
The difficult problem for arriving.In plastic industry, there is provided a kind of material solution of new energy-saving and emission-reduction.
The PPM environment-friendly materials that the present invention is provided can be applicable to film blowing（Such as shopping bag, refuse bag, agricultural film, mulch film etc.）、
It is applied to wire drawing（Such as non-woven fabrics, woven bag etc.）, be applied to injection（Such as tubing, sheet material etc.）, be applied to each side skill such as papermaking
Art field.
Embodiment described above is only the preferred embodiment that is lifted for absolutely proving the present invention, the protection model of the present invention
Enclose not limited to this.Equivalent substitute or conversion that those skilled in the art are made on the basis of the present invention, all in the present invention
Protection domain within.Protection scope of the present invention is defined by claims.
Claims (9)
1. a kind of PPM environment-friendly materials, it is characterised in that including the composition of following percentage by weight：The calcium carbonate of 80%-85%,
The vector resin of 15%-20%, the dispersant of 0.5-10%, the lubricant of 0.5%-10%, the coupling agent of 0.5%-10% and 0.1-3%
Antioxidant.
2. PPM environment-friendly materials according to claim 1, it is characterised in that the proportion of the PPM environment-friendly materials is 1.55-
1.65 g/cm3, flow index is 4-5g/10 min, and pH value is 6.9-7.
3. PPM environment-friendly materials according to claim 1, it is characterised in that the calcium carbonate is the transparent calcite carbon of needle-like
Sour calcium, its fineness are -3000 mesh of 1000 mesh, and draw ratio is 6：1-13：1.
4. PPM environment-friendly materials according to claim 1, it is characterised in that the vector resin is polypropylene, polyethylene or
The mixture of the two, during the two mixing, percentage by weight is 20-50% for polypropylene, and polyethylene is 50%-80%, or
The vector resin is the mixture that polypropylene is constituted with ethylene-octene copolymer and/or ethylene-acrylic acid copolymer,
When wherein mixing, percentage by weight is 90-95% for polypropylene, and ethylene-octene copolymer is 5-10%, ethylene-acrylic acid copolymer
For 5-10%, or
The vector resin is polyethylene and ethylene-vinyl acetate copolymer and/or ethylene-octene copolymer and/or ethene-the third
The mixture that olefin(e) acid copolymer is constituted, when wherein mixing, percentage by weight is 80-95% for polyethylene, the ethene-vinyl acetate
Copolymer is 5-20%, and ethylene-octene copolymer is 5-10%, and ethylene-acrylic acid copolymer is 5-20%, or
The vector resin is polypropylene, the mixture of both polyethylene and ethylene-vinyl acetate copolymer and/or ethene-pungent
The mixture that alkene copolymer and/or ethylene-acrylic acid copolymer are constituted, when wherein mixing, percentage by weight is 40- for polypropylene
45%, polyethylene is 40-45%, and ethylene-vinyl acetate copolymer is 5-10%, and ethylene-octene copolymer is 5-10%, ethene-the third
Olefin(e) acid copolymer is 5-10%.
5. PPM environment-friendly materials according to claim 1, it is characterised in that the dispersant is Stearyl Amine, vinyl is double
One or more in Stearyl Amine, barium stearate, calcium stearate and zinc stearate, when selecting multiple, between each composition
Zero gravity ratio requirement.
6. PPM environment-friendly materials according to claim 1, it is characterised in that the lubricant is paraffin, Tissuemat E, oxygen
One or more in change Tissuemat E and low-molecular-weight polypropylene wax, when selecting multiple, between each composition, zero gravity is joined
Than requiring.
7. PPM environment-friendly materials according to claim 1, it is characterised in that the coupling agent is aluminate coupling agent, metatitanic acid
One or more in ester coupling agent, silane coupler, Aluminate-titanate esters composite coupler and zirconium aluminate coupling agent,
When selecting multiple, zero gravity ratio requirement between each composition.
8. a kind of preparation method of PPM environment-friendly materials, it is characterised in that comprise the following steps：
Step one：First the calcium carbonate of inorganic particle, dispersant and coupling agent are simultaneously introduced split according to parts by weight proportioning
Coating modification is carried out in coating machine；
Step 2：Modified again with vector resin, lubricant, antioxidant while being put into banburying in banbury and mixing；
Step 3：The material that banburying is mixed is put in comminutor carries out extruding pelletization；
Step 4：Air-cooled, screening, packaging, complete preparation process.
9. the preparation method of PPM environment-friendly materials according to claim 8, it is characterised in that modified temperature in the step 1
Spend for 90-130 DEG C, the time is 5-15 minute；In the step 2, the temperature of banburying mixing is 90-150 DEG C, and the time is 10-20
Minute；In the step 3, the time of extruding pelletization is 15-20 minute；The step 4 apoplexy cool time is 20-30 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610866573.1A CN106479046A (en) | 2016-09-28 | 2016-09-28 | A kind of PPM environment-friendly materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610866573.1A CN106479046A (en) | 2016-09-28 | 2016-09-28 | A kind of PPM environment-friendly materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106479046A true CN106479046A (en) | 2017-03-08 |
Family
ID=58267978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610866573.1A Pending CN106479046A (en) | 2016-09-28 | 2016-09-28 | A kind of PPM environment-friendly materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106479046A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033437A (en) * | 2017-05-18 | 2017-08-11 | 聂超 | A kind of PPM environmental friendly materials and preparation method thereof |
| CN108102189A (en) * | 2017-12-15 | 2018-06-01 | 广东昱升个人护理用品股份有限公司 | A kind of polyolefin micropore ventilated membrane of the high grade of transparency and its preparation method and application |
| CN108317305A (en) * | 2018-01-31 | 2018-07-24 | 淄博洁林塑料制管有限公司 | A kind of polystyrene continuously multi-layer co-extruded foaming heat-insulating composite pipe material and its manufacturing method |
| CN109111153A (en) * | 2018-08-22 | 2019-01-01 | 河南东贵电子科技有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
| CN109135053A (en) * | 2018-07-17 | 2019-01-04 | 徐州益康环保科技有限公司 | A kind of PPM environmental friendly material and preparation method thereof |
| CN111019218A (en) * | 2019-12-23 | 2020-04-17 | 田勇 | Preparation method of easily-degradable and easily-incineratable composite material |
| CN114957830A (en) * | 2022-04-19 | 2022-08-30 | 财纳福诺木业(中国)有限公司 | Panel substrate |
| CN117447125A (en) * | 2023-10-27 | 2024-01-26 | 浙江晶引电子科技有限公司 | Environment-friendly material for ultrathin flexible film packaging substrate and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400064A (en) * | 2015-11-11 | 2016-03-16 | 广东碧盛环球环保材料有限公司 | Filling masterbatch and preparation method thereof |
-
2016
- 2016-09-28 CN CN201610866573.1A patent/CN106479046A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400064A (en) * | 2015-11-11 | 2016-03-16 | 广东碧盛环球环保材料有限公司 | Filling masterbatch and preparation method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033437A (en) * | 2017-05-18 | 2017-08-11 | 聂超 | A kind of PPM environmental friendly materials and preparation method thereof |
| CN108102189A (en) * | 2017-12-15 | 2018-06-01 | 广东昱升个人护理用品股份有限公司 | A kind of polyolefin micropore ventilated membrane of the high grade of transparency and its preparation method and application |
| CN108102189B (en) * | 2017-12-15 | 2021-03-26 | 广东昱升个人护理用品股份有限公司 | High-transparency polyolefin microporous breathable film and preparation method and application thereof |
| CN108317305A (en) * | 2018-01-31 | 2018-07-24 | 淄博洁林塑料制管有限公司 | A kind of polystyrene continuously multi-layer co-extruded foaming heat-insulating composite pipe material and its manufacturing method |
| CN109135053A (en) * | 2018-07-17 | 2019-01-04 | 徐州益康环保科技有限公司 | A kind of PPM environmental friendly material and preparation method thereof |
| CN109111153A (en) * | 2018-08-22 | 2019-01-01 | 河南东贵电子科技有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
| CN111019218A (en) * | 2019-12-23 | 2020-04-17 | 田勇 | Preparation method of easily-degradable and easily-incineratable composite material |
| CN114957830A (en) * | 2022-04-19 | 2022-08-30 | 财纳福诺木业(中国)有限公司 | Panel substrate |
| CN117447125A (en) * | 2023-10-27 | 2024-01-26 | 浙江晶引电子科技有限公司 | Environment-friendly material for ultrathin flexible film packaging substrate and preparation method thereof |
| CN117447125B (en) * | 2023-10-27 | 2024-04-05 | 浙江晶引电子科技有限公司 | Environment-friendly material for ultrathin flexible film packaging substrate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106479046A (en) | A kind of PPM environment-friendly materials and preparation method thereof | |
| CN100432132C (en) | Transparent film mother material and its preparation process | |
| CN100429266C (en) | Synthetic paper made of environmental protection plastic and its preparation method | |
| CN102120843B (en) | Subnanometer enhanced and toughened transparent master batch and preparation method thereof | |
| CN102675918B (en) | Preparation method of low-yellowness antibacterial calcium carbonate functional composite powder for ventilated membrane | |
| CN105400154A (en) | Biodegradable plastic color masterbatch and preparation method thereof | |
| CN102585369A (en) | Composite modification filling master batch | |
| CN106750780A (en) | A kind of transparent filling master batch of barium sulfate and preparation method thereof | |
| CN102863697B (en) | Stress whitening resistant modified polypropylene material and preparation method thereof | |
| CN104497406B (en) | Filling master batch for transparent film and preparation method of filling master batch | |
| CN102432985A (en) | Method for preparing PET-organic intercalated montmorillonite composite material | |
| CN102604227A (en) | Flame-retardant filling master batch for polypropylene and preparation method thereof | |
| CN105218925A (en) | A kind of stone of controlled degradation moulds Environmental protection bag and preparation technology thereof | |
| CN110527141B (en) | Modified wollastonite powder and preparation method and application thereof | |
| CN102964815B (en) | Microscopically well-dispersed high performance nano reinforced nylon composite and preparation method thereof | |
| CN104974426A (en) | Sodium sulfate plastic filling modified transparent masterbatch | |
| CN104479214A (en) | Highly-filled modified HDPE/LDPE/LLDPE/EVA/PP blended blown film and preparation method thereof | |
| CN102020786A (en) | New material special for transparent plastics and preparation method thereof | |
| CN1858119A (en) | Technology for producing super fine talc powder master batch | |
| CN109651685A (en) | A kind of fluorescence rotational moulding PP Pipe Compound and preparation method thereof | |
| CN101293967A (en) | Method for preparing anhydrous sodium sulfate plastic modified master batch | |
| CN1951994A (en) | Transparent film masterbatch and its preparing method | |
| CN105440621B (en) | PLA noctilucence master batch and preparation method thereof | |
| CN105419086A (en) | Preparing method for compound whitening polyolefin material for plastic woven bags | |
| CN109971036B (en) | Preparation method of monodisperse ultra-narrow distributed calcium carbonate for PET transparent film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170308 |