CN106460136A - Equipment and process for the pickling and metallic coating of a metal strip - Google Patents

Equipment and process for the pickling and metallic coating of a metal strip Download PDF

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Publication number
CN106460136A
CN106460136A CN201580017944.2A CN201580017944A CN106460136A CN 106460136 A CN106460136 A CN 106460136A CN 201580017944 A CN201580017944 A CN 201580017944A CN 106460136 A CN106460136 A CN 106460136A
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CN
China
Prior art keywords
band
temperature
pickling
stove
unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201580017944.2A
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Chinese (zh)
Inventor
A.查拉耶
S.迈拉德
P.波德达
J-P.罗比内特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clecim France SAS
Original Assignee
Primetals Technologies Austria GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority claimed from EP14290086.9A external-priority patent/EP2927343A1/en
Application filed by Primetals Technologies Austria GmbH filed Critical Primetals Technologies Austria GmbH
Priority to CN202111184286.XA priority Critical patent/CN113846281A/en
Publication of CN106460136A publication Critical patent/CN106460136A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0278Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224Two or more thermal pretreatments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/024Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Abstract

The present invention describes equipment for the pickling and metallic coating, such as galvanizing, of a continuously running metal strip, successively comprising along the run direction at least a pickling unit, a furnace and a coating unit, and for which the metal strip entering the pickling unit is by default a hot-rolled product. The equipment according to the invention is characterized in that: a rolling mill for elongation/limited reduction of strip thickness, referred to as a skin-pass rolling mill, is positioned between the pickling unit and the furnace; the furnace imposes a heat cycle on the strip that makes it possible to control a restoration of strip structure (that is to say free of strip recrystallization) and imposes, at the outlet of the furnace, a heating of the strip to the temperature that is required at the inlet of the metallic coating unit. A pickling and metallic coating process is also proposed.

Description

The equipment of the pickling for metal tape and metal coating and method
Technical field
The present invention relates to the pickling of metal tape as described in the preamble according to claim 1 and metal coating equipment, and And further relate to correlation technique as described in the preamble according to claim 14.
Background technology
So far, steel heat rolling line enables the metal tape providing thickness to be typically larger than close to 1.2 mm.These lines are general Need to combine continuous casting, the thickness of its product paid is about 200 to 250 mm, thus needing by means of hot-rolling mill housing group Part, to obtain being obviously reduced of thickness, especially when needing to realize close to the minimum thickness of 1 mm.For realizing this knot The energy balance of this kind equipment of fruit and size are quite heavy.In recent years, new ESP(Strip steel without a head produces)Type Metal continuous cast method enables to obtain, using the more widgets of hot-rolling mill housing, the steel gold that minimum thickness is of about 0.7 mm at present Belong to band.Very possible within the coming years or decades, by such method of the example with regard to ESP type, technically The less thickness of such as about 0.5 mm will be enabled.It should also be noted that such method also allows for continuously producing metal Band, and therefore highly effective in terms of productivity ratio.Additionally, for from continuous casting until the rolling of relatively small thickness terminates, these methods Make product change the required energy balance to reduce with respect to existing method.Generally, such band(Strip steel, strip)Manufacturer Therefore there is at least one continuous casting line being attached to hot-rolling mill housing unit, and it is attached in outlet and reels machine system. Therefore, these bands are to be paid that is to say, that with rolling without pickling to have oxidized surface " hot " coil form The form of band.
Therefore if it is necessary to " hot " the metal coating operation with execution such as plating, then pass through " hot " explained above The band that technique is obtained must be acid washed further, is then finally electroplated.In the case of conventional hot preparation route, its The output thickness of produced band then generally will be at least above 1.2 mm.Additionally, in order to obtain thinner and also have good The coated metal tape of punching press property(For example through plating)It is necessary to these bands cold rolling make its thickness be obviously reduced.Therefore, phase For the processing hardening of initial reduced levels, the cold rolling processing that can cause steel is hardened.However, the advantage of this method contributes to Realize final good punching press property, but need first to make rolled metal band before plating at the downstream of mill operation Annealing, so that be possible to finally obtain especially good punching press property.US 4 436 292 A describes to the band entering Carry out cold rolling, annealing and the example electroplating route of then plating.
From for producing little thickness(A few tenths of mm, such as 0.7 mm)Band thermal process(Such as ESP type method) Start, the little thickness of the band of these " hot " technique productions gradually returns to the area of the larger thickness via cold rolling production explained above Between.
For the minimum thickness entering close to the band of 1.2 mm, in US 6 761 936 B1 of calendar year 2001, describe one kind The just traveling that continuously pickling obtains from thermal process with plating(Or winding)And the method for the product without pickling.This Method mainly provides and carries out pickling by the method impregnating the metal tape being continuously traveling in bathing in liquid alloy and electroplate coating The embodiment of the form of equipment, this equipment includes successively along direct of travel:At least pickling unit(Include cleaning in its exit And drying), Yi Jilu, the temperature for making the band after pickling reaches for final plating stage needed for liquid zinc bath porch Temperature.Constantly require on market to reduce production cost and improve quality, this especially to be produced by reducing the following:Produce The size and number of equipment, operation team's resource and energy expenditure, and also process time.Plating has thickness in input Still also there is the hot product of the larger thickness of good punching press property close to the thickness of the relative thin of 0.5 mm, completely in output Meet the demand of steelmaker and its client.Thus, the method described by US 6 761 936 B1 does not obviously meet such difficulty Topic.Finally, even if the hot product of today and tomorrow entering the pickling described in US 6 761 936 B1 and electroplating device Mouth presents such as 0.7 mm or less thickness, and the input of band body and output thickness will be almost unchanged all the time.Additionally, for example The electroplated coating quality of the dipping in heating bath according to US 6 761 936 B1 and dewatering cannot be in surface roughness and band Flatness aspect optimized.Finally, most of bands in exit therefore will must not have good punching press property.Due to Lack cold rolling manipulation, this equipment therefore has as a drawback that:The electroplated product of thickness reduction can not be paid(For example from In the range of 0.5 mm to 5 mm), keep the mechanical intensive property of output products so as to machinery substantially with input product simultaneously Intensity property is identical.
With need not cold rolling and and then anneal in the case of reduce through pickling and electroplated product(In upstream from without pickling Hot product produced by)Thickness be target, the explanation of Patents US 8 163 348 B2 or EP 1 861 517 B1 Book proposes such solution, and based on the equipment described in US 6 761 936 B1, this solution proposes will be cold rolling Unit(The thickness causing 6.5% to 10% reduces)It is positioned the downstream of electroplating unit that is to say, that passing through cold rolling electroplating(Coating) Product.Metal tape stands the operation by cold rolling reduce thickness, and described thickness reduces or even is limited to 10% all the time, and rolls it There is no the annealing in downstream afterwards, described thickness reduces and is not suitable for being obtained in that the best in quality for plating tape is:On the one hand, Due to the different power of the rolling between substrate and adding layers and the effect of elongation, the intensity of coat has by the wind of apparent damage Danger;On the other hand, because downstream does not have annealing operation, there is the not good enough risk of the punching press property of band, especially for very great Cheng The thickness of degree reduces.
Content of the invention
Therefore, an object of the invention is to provide a solution to be used for expanding from the output of continuous metal painting method Product thickness range, give tacit consent to this continuous metal painting method supply be from thermal process preparation band roll up obtained The steel band without pickling advanced.The program being provided should also ensure that the band of coating unit porch has adding of minimum degree Work is hardened, even if implement tape thickness reducing so that it is also such for expanding described scope.Finally, this scheme should make it possible to Need not pass through cold rolling(Anneal including making band(Recrystallization)Stage)Reduce the stage of big thickness, also will can keep final product simultaneously The good press quality of product.
Equally, the present invention also should can ensure that combination with the continuous combined method of next stage:Pickling, thickness reduce, coarse The holding of the optimal properties of material after the improvement of degree and flatness, thickness reduction, and the deposition of metal coating.Metal coats Plating mainly on tape, for example, pass through the hot tempering process in the liquid metals bath include various types of metal alloys, So that steel is carried out with plating protection, then it is for ensuring that the relevant treatment of the market quality of product after coating.Can also carry For any other plating method, the such as plating in suitable electrobath.
Therefore, the scheme of apparatus-form is provided by the feature of claim 1.Finally, by the feature of claim 14 Correlation technique is provided.
Pickling and metal coating from the metal tape for being continuously traveling(For example electroplate)Equipment start, along traveling side To including successively:At least one pickling unit, stove and coating unit(For example the liquid metals as coating agent is bathed, or electrolysis Bath), and the metal tape that wherein acquiescence enters pickling unit is hot-rolled product,
It is characterised by according to the equipment of the present invention:
- for tape thickness limited elongation/reduction rolling device, referred to as skin pass rolling device, described skin pass rolling device It is positioned between pickling unit and stove;
- stove applies thermal cycle to band, and this enables control over the recovery of band structure(I.e., it has no band recrystallization), and The temperature needed for the porch of metal coating unit will be heated in the outlet of stove with temperature(Machine is heated or cooled by suitable Structure).
Therefore, produced it is ensured that producing such plating with combining of the temperature controlled continuous processing in downstream by limited reduction Product(Band, bande), wherein, the product of access arrangement can be derived from a series of metal tapes without pickling of hot preparation technique Volume, it can be more than the final thickness after coating in the thickness of entrance.Therefore, the combination of these methods, enabling maintain Or improve the property of the band of input, it is known even if skin pass rolling device is slightly applied with reduction, and stove also can be in recovery mode Apply temperature range on tape, and need not apply(For example)The recrystallization mould of the metal grain needed for annealing stage after cold rolling Formula, the practically even long large model of crystal grain.
This is because, different from conventional cold rolling(Being obviously reduced of thickness)It is desirable to very high temperature(Such as 750 ° or Higher)Annealing(Recrystallize at least one times), according to stove under generally non-oxidizing atmosphere for the present invention, in band flat After standing the slight reduction of thickness in whole rolling device, in lower temperature(Between 300 DEG C and 700 DEG C, less than two minutes)Under Maintenance level under apply single tape recover.Therefore, this equipment advantageously enables to balance on wider(Limited)Thickness The effect the reducing band possible with ensureing control recovers, to ensure the high press quality of output band(By recovering to make processing hard The impact changed minimizes).Finally, roughness and flatness are made it possible to ensure that by the limited reduction that skin pass rolling device is realized It is suitable for downstream applicator and downstream is preferably dehydrated required more preferable wettability.It is arranged on the cleaning in skin pass rolling device downstream Unit will make it possible to extraly discharge possible Emulsion/detergent or other basic products, and also dust(Iron powder)With By the action of skin pass rolling device issuable other metal fragment, to improve coating quality.
It is known to implement the reduction of the product entering the equipment according to the present invention, it is therefore possible to producing thinner output Band, and therefore increase with reference to pickling and metal coating(For example pass through plating)Tinuous production on production capacity and(Can Minimize)Thickness range.The press quality of output band is also improved.For example, relatively small for especially thickness(Particularly thick Degree is between 2.5 mm and at least 5 mm)Some input products, skin pass rolling device only executes slight elongation(Or it is thick Degree reduces), and make to obtain the plating tape with particularly excellent punching press property.
Meanwhile, in conjunction with the equipment according to the present invention provided above and relative all aspects and enforcement herein Example, a kind of method that the present invention provides pickling of the metal tape being continuously traveling and metal coating, it wraps successively along direct of travel Include:At least one pickling stages(2), heat treatment and simultaneously control the stage with temperature(4)And the coating stage of such as plating(5) (For example by being immersed in liquid metals bath or in electrobath), and wherein, the metal tape of the upstream of acquiescence pickling stages is Hot-rolled product,
Methods described is characterised by:
- can in pickling stages and with temperature controlling stages between activate the limited reduction of thickness and band roughness and flat The finishing stage of degree;
- in the limited reduction of activation thickness and in the case of the finishing stage with roughness and flatness, carry temperature control rank Section applies thermal cycle to band, and this enables control over the recovery of band structure and does not have the recrystallization carrying, and applies on tape The temperature needed for metal coating unit entrance will be heated to output temperature.
The single or joint operation being possible also by other skin pass rolling device and seven-roll Abramsen machine carries place after coating In the reason stage, be the other coating stage after described operation(For example it is passivated the stage).
The combination of dependent claims also present advantages of the present invention.
Brief description
Execution and application example is provided using described accompanying drawing:
Fig. 1 according to the exemplary embodiment of the equipment of the present invention,
The principle of the recovery according to the band in the stove of the equipment of the present invention for the Fig. 2,
The selection of control parameter of Fig. 3 Restoration stage.
Specific embodiment
Fig. 1 presents the exemplary embodiment of the equipment according to the present invention.This exemplary embodiment relates generally to continuous row The pickling of the metal tape entering and metal coating equipment, it includes successively along direct of travel:At least pickling unit(2), stove(4)With Metal coating unit(5)(It is coated in liquid metals bath or in other electrolysis-type bath by hot dipping), and wherein give tacit consent to The metal tape entering pickling unit is hot-rolled product,
Described equipment is characterised by:
- for tape thickness limited elongation/reduction rolling device(3), referred to as skin pass rolling device, described rolling device (3)It is positioned between pickling unit and stove;
-- stove has available heat engine structure, and it can apply thermal cycle to band, and this makes it possible at least control the recovery of band structure, Without the recrystallization of band, and at outlet of still, band is heated to the temperature needed for metal coating unit porch.
Thermal cycle has the effect realizing the following:
- band is heated to controllable temperature scope as wide as possible(Such as 300-700 DEG C)Under recovery scope.
- during the shortest recovery time of band(This depends on said temperature and thickness reduction condition, and additionally depends on grade The necessary chemical composition of metallurgical property)Maintained.
- by the final regulation being heated or cooled to into trip temperature during loop ends, to realize the required temperature of coating.
In pickling unit(2)Upstream, entrance zone, threshold zone(1)Make it possible to by two uncoilers(1a, 1b)Introduce the tape into To in described unit, this uncoiler makes band roll up successively towards band cutter and bonding machine(11)Debatching, so that two continuous bands of welding Head and afterbody, and also accumulator(Not shown), for adjustment band gait of march during welding operation, and it is used for Then the band after welding is incorporated into pickling unit(2)In.De-scaling(" peroxide breaks down ")Mechanism is also positioned band and enters pickling Unit(2)Entrance before.
Pickling unit(2)Juxtaposed acid bath successively can be included and also have cleaning and dewatering device.It can be alternative Ground includes the system for spraying pickling compound on product, such as by means of solid abrasive, and(If necessary)By In liquid abrasive.Solid abrasive includes such as solid particle and/or crystal grain, and liquid(If necessary)At least include water.? Afterwards it should be noted that the metal tape that acquiescence enters pickling unit is hot-rolled product, it has the minimum thick of a few tenths of millimeter Degree.Alternately, the metal tape of pickling unit upstream can also be the cold-rolled products replacing hot-rolled product, in this case, Band does not carry out pickling in pickling unit(Or transfer to skin pass rolling unit from pickling unit), and stove provides other heating And cooling body, to guarantee the annealing carrying.However, no longer describing this alternative scheme in the context of the present invention, because i.e. The switching making it embody between " hot " band treating surface-coated or " cold " band is flexible(For example in order that band is electroplated)But, It requires:Or stove can be annealed again;Or continuing holding by the high hardness value that cold rolling processing hardening causes is energy Enough acceptance.
According in the equipment of the present invention, it is positioned pickling unit(2)Exit skin pass rolling device(3)Make thickness 0.1% at least 30% can be reduced.The outlet of skin pass rolling device is attached to the unit for cleaning band(31), it include following in Cleaning device at least one:Defat(If reducing degree to be more than close to 10%, this will require in skin pass rolling device The operation of rolling in using oil-water type emulsion), scrub, spray, being dehydrated or be dried.Finally, skin pass rolling device uses work gas Cylinder, it has the definite roughness being suitable for desired on tape roughness after the operation of cylinder, to guarantee to the greatest extent may be used Many ground subsequent coating can be adhered to this band.The skin pass rolling type of device installed can be mono-hull formula, actually Even two juxtaposed housings can be included.
In the exit of cleaning unit, band is hence into stove(4)In, stove(4)Include successively:Induction apparatuss or other heater At least one of structure heating arrangements, radial canal or other temperature maintaining body, quick heating and/or rapid cooling machine structure are extremely A few extra region.These heating arrangements can present different the adding of band with the requirement of the heat treatment according to the present invention Heat or cooling dynamic.It is desirable that stove is placed under non-oxidizing atmosphere.In order to ensure the recovery of band, a section bag of stove Include the mechanism for heating tape, it guarantees the recrystallization at least part of band, the temperature of band kept at a threshold temperature, It is desirable that under the fixing level of temperature-controllable being maintained at during less than two minutes between 300 DEG C and 700 DEG C.
If recovery temperature maintenance level(palier)Less than the temperature needed for the porch of coating unit, then stove can lead to Cross for the hot dipping near 500 DEG C of conventional plating, so that band was finally raised before entering the unit for metal coating required Band output temperature, and and then so that it is dropped back to less than this value, it is desirable that for liquid electroplating bath, it drops back to 465 DEG C (There is a possibility that this temperature according to the types of alloys being used significant changes), or for electrobath, it drops back to close to ring The temperature of border temperature.Therefore, the with good grounds a kind of heating and cooling mechanism of arrangement distribution of stove, so that it is guaranteed that the recovery for band Some fixing level(Scope or circulation)And temperature treatment(Property according to it and steel grade)And to coating unit(5) The temperature required regulation in porch.
Subsequently, band enters coating unit(5)In, for example by hot liquid metals as the heat in the bath of coating agent Leaching.Mechanism for being dehydrated, heating, cool down and impregnated in bucket is positioned the downstream of metal bath, and and then is transmitted to band Second accumulator, referred to as middle accumulator, to be adjusted to finishing section(6)Gait of march, finishing section can wrap successively Include the second skin pass rolling device, seven-roll Abramsen machine, the mechanism for monitoring the property of plating tape(By thickness measure/surface inspection Look into etc.), and for being finally passivated optional second mechanism of coating at surface using irradiation modules(7).
Finally, leave finishing section(6)With final coating section(7)Bring inlet/outlet section into(8), it includes module group Part(81), such as outlet accumulator, optionally with the cutter of belt edge, the final mechanism for surface inspection, optional Oiling module and band cutter, enabling be cut laterally band, so as band to be divided and be directed at least one band volume, And ideally two bands are rolled up(8a、8b).
This exemplary embodiment of equipment according to the present invention therefore enables pickling and the gold of the metal tape being continuously traveling Belong to the favorable method of coating, it includes successively along direct of travel:At least one pickling stages(2), band temperature controlling stages(4)With Metal coats the stage(5), and wherein, the metal tape in pickling stages upstream for the acquiescence is hot-rolled product,
Methods described is characterised by:
- activation tape thickness can reduce and carry roughness and flatness to repair between pickling stages and band temperature controlling stages The whole stage;
- in the case that tape thickness reduces and carries roughness and the flatness finishing stage is activated, carry temperature controlling stages pair Band applies thermal cycle, and this makes it possible to control the recovery of band structure and does not have the recrystallization carrying, and applies heating to band Reach entrance band output temperature needed in porch for the metal coating unit.
Fig. 2 as simply as possible graphic extension be directed to Fig. 1 shown in the equipment according to the present invention stove(4)In band extensive Multiple principle.On the vertical coordinate of figure, hardness will be carried(D)(Hardness increase is defined as processing hardening)It is expressed as according to abscissa On temperature T(℃)Function.Assume to reach skin pass rolling device(3)Porch by " hot " technique obtain then through acid The band washed presents initial work-hardened condition(Ei), skin pass rolling device itself by processing hardening to apply harden, and And give it in skin pass rolling device(3)Exit there is the new work-hardened condition of bigger hardness(Ee).Then, this Bright target is to pass through stove(4)Heating/cooling arrange to reduce the hardness of the band leaving skin pass rolling device, this can Band is made to stand in the thermal cycle in temperature range and at least in the temperature stabilization level in the dash area of Fig. 2(REST) Under, this dash area represents the possible scope with recovery temperature.Therefore, shown curve very schematically show from extensive Work-hardened condition in multiple scope(Ee)Temperature rise make bring back to it close to initial manufacture hardening state(Ei)'s State, but temperature need not be made to rise above described scope(REST)In included temperature that is to say, that need not rise to It is related to the higher temperature with recrystallization(By including the part of cross-hatched(RECR)Represent), wherein recrystallize and commonly referred to move back Fire, it actually even relates to crystal grain and grows up(Be exclusively used in being obviously reduced thickness cold rolling after annealing required).By this It can be ensured that the band leaving stove and then being coated will keep very good property, especially very good rushes the mode of kind Pressure property.
Fig. 3 presents temperature T of three possible selection of control parameters of the Restoration stage targeted for Fig. 2(℃)With The time(s)The curve chart of change, these three parameters select e.g. to be directed to the Three Estate of band or band reduces in stove(4)Enter Three conditions at mouthful.Stove(4)At least one section guarantee for every in controlling the possible parameter of Restoration stage to select One is provided with the thermal cycle with heating followed by temperature stabilization horizontal versions, and in this example, temperature stabilization level is located respectively Three required temperature when recovering(Trest1, Trest2, Trest3)One of place, and and then at outlet of still, be heated to gold Belong to the entrance of coating unit(Bath)The required band temperature in place(For example for the hot dipping in conventional electroplating baths, T=465 DEG C).Thus control The thermal conditioning path of stove processed, to optimize temperature cycles, this temperature cycles is applied to travel across at least one chamber of stove Carry, target is to execute the Restoration stage of carrying material according to the external of described band and internal condition, and and then adds at the end of recovering The torrid zone, minimized especially for the persistent period making the active of recovery band heat/cool down(Energy requirement minimizes).Should Point out, recover the persistent period(Dt_Rest)End can be extended beyond towards bath heating tape stage that is to say, that Outside stove, therefore potentially and advantageously the active energy without stove is contributed.
Finally it is pointed out that according to the pickling of the metal tape being continuously traveling of the present invention and plating method, energy Enough make initially to be exclusively used in controlling the single thermocycle stage with recovering achieving at least part of band recrystallization(It is practically even Crystal grain is grown up)In the sense that be extend.
This is because, initially it is exclusively used in controlling the single thermocycle stage with recovering can extend at the heat of such as annealing In the reason stage, it requires to be provided with has the suitable stove heating and cooling down thermal power.Annealing is passed through to include at least first Restoration stage, Followed by part or complete recrystallization stage and last optional crystal grain long megastage.The rolling of this especially suitable stove upstream The reduction of the relatively large degree of device processed, such as more than 5%, practically even reach at least 40%.This is because, even if stampability Verify in through overpickling then rolling and under " substantially " Restoration stage heating the torrid zone for be good it is also possible to For desired optimal thermal cycle by the boundary alignment of temperature aspect between Restoration stage and recrystallization stage, or even with master Between the recrystallization stage wanted, until even and the crystal grain long megastage between.In other words in this case it is still possible to " recovery " band in one Portion of material, and under given interval, make this part experience the beginning of recrystallization, even if recovery process not yet completes Other partly the going up when continuing of the carrying material of Restoration stage is also such.Recrystallization stage and the crystal grain long megastage it Between it is observed that the border of same type.In document " Traitements thermiques des alliages ferreux (The heat treatment of ferroalloy)" in, the 68-71 page, extract " les pr é cis AFNOR/NATHAN-METALLURGIE(é laboration, structures-propriétés, normalisation)", 2005 editions, ISBN AFNOR: 978-2- 12-260131-0, clearly illustrates for cold rolling these heat effects in the case of annealing(At least include the recovery rank carrying Section and partially or completely recrystallize stage, practically even also crystal grain long megastage).
The change of resume speed also depends on the thermokineticss of process, depends on:
The work-hardening capacity that the mill operation implemented in stove upstream produces.The degree that known rolling thickness reduces is bigger, The discontinuous defect then being caused by the thickness reduction rolling in the crystal structure tissue of handled carrying material is more, corresponds to More or less of energy accumulation in the structural material of handled band.This energy is in during annealing and especially in recovery Period discharges;It should be noted that the dynamic work-hardening capacity depending on rolling generation that this of crystal structure changes;
Furnace temperature;
The duration of heat.
After these last aspects of potential annealing, the present invention proposes therefore to be likely to be of according to the equipment of the present invention At least one section of stove is included for heating(And/or be used for cooling down)The mechanism of band, it guaranteed typically less than two minute phase Between will become minimum temperature higher than at least part of recrystallization in the structural material of handled band with temperature control(Ideally Higher than 500 DEG C), rolling device presents(Band)More than 5%, practically even up at least 40% significantly(Thickness) Reduce.
Similarly, the equipment according to the present invention includes at least being used for heating therefore, it is possible to a section with stove(And/or For cooling down)The mechanism of band, its guarantee during typically less than two minutes by with temperature control become higher than band at least partly again Crystallization and/or the minimum temperature grown up until crystal grain(Ideally it is higher than 500 DEG C), rolling device embodies(Band)More than 5%, Practically even up at least 40% significantly(Thickness)Reduce.
For reference, recrystallization temperature value is typically located between 500 DEG C and 850 DEG C, and related to crystal grain temperature of growing up The value of connection is higher, can reach and more than 900 DEG C.
It should be pointed out that realizing temperature control according to being directed to(For example control at least one thermal cycle(Restoration stage, Yi Jiran Afterwards if necessary, recrystallization the stage, the crystal grain long megastage))The heating recommended of purpose(And/or cooling)Mechanism, in stove Dispose radiating element(For example manage)And/or induction apparatuss.Generally more expensive than using radiating element using induction apparatuss, especially in energy consumption Aspect.Therefore, it is noted that the rolling device in pickling unit exit in the case of setting radiating element in stove(Example As skin pass rolling device)So that being especially possible to repair(Increase)The surface roughness of the band through rolling, i.e. surface roughness changes The emission ratio of variable speed is not that is to say, that being in is that the band of very coarse apparent condition is easier to pass back by radiation heat emission The heat radiation that device is launched, and contrary, and if surface is coarse, band is preferably absorbed radiated heat.Former for this Cause, the rolling device of therefore stove upstream makes it possible to optimize(Practically even shorten)The desired thermal cycle of the present invention.

Claims (15)

1. the equipment of a kind of pickling of metal tape for being continuously traveling and metal coating, its along direct of travel include successively to Few pickling unit(2), stove(4)With metal coating unit(5), and wherein, the metal tape that acquiescence enters described pickling unit is Hot-rolled product,
It is characterized in that:
- for tape thickness limited elongation/reduction rolling device, referred to as skin pass rolling device, described skin pass rolling device It is positioned between described pickling unit and described stove;
- described stove applies thermal cycle to described band, and this enables control over the recovery of band structure, and the outlet in described stove Place, described band is heated to the temperature needed for the porch of described metal coating unit.
2. equipment according to claim 1, wherein, described stove is included in induction apparatuss or other heating arrangements at least successively At least one of one heating arrangements, radial canal or other temperature maintaining body, quick heating and/or rapid cooling machine structure is extra Region.
3. equipment according to claim 1, wherein, described stove is placed under non-oxidizing atmosphere.
4. equipment according to claim 1, wherein, the described metal tape entering described pickling unit is to assume a few milli of zero point The hot-rolled product of the minimum thickness of rice.
5. equipment according to claim 1, wherein, described skin pass rolling device embodies 0.1% at least 30% thickness Reduce the factor.
6. equipment according to claim 1, the described skin pass rolling device wherein installed can be mono-hull formula, real On border, it even can include two juxtaposed housings.
7. equipment according to claim 1, wherein, described skin pass rolling device has working cylinder, in described cylinder After operation, described working cylinder has the definite roughness being suitable for the upper desired degree of roughness of described band.
8. equipment according to claim 1, wherein, the outlet of described skin pass rolling device couples the cleaning unit of described band (31), described cleaning unit includes at least one in following cleaning mode:Defat, scrub, spray, being dehydrated or be dried.
9. equipment according to claim 1, wherein, a section of described stove includes the mechanism for heating described band, It guarantees the temperature of described band was maintained within the time less than two minutes the threshold value of at least part of recrystallization of described band At a temperature of, it is desirably maintained under the temperature stabilization level between 300 DEG C and 700 DEG C.
10. equipment according to claim 1, wherein, a section of described stove is at least included for heating described band Mechanism, it guarantees to become to tie higher than at least part of of described band by the temperature control of band within the time of typically less than two minutes again Brilliant minimum temperature, is ideally higher than 500 DEG C, described rolling device embodies more than 5%, is practically even up at least 40% Significantly reduce.
11. equipment according to claim 1, wherein, a section of described stove is at least included for heating described band Mechanism, it guarantees to become with temperature control at least part of recrystallization higher than described band within the time of typically less than two minutes And/or the minimum temperature grown up until crystal grain, ideally it is higher than 500 DEG C, described rolling device embodies more than 5%, actually very Up at least 40% significantly reduction.
12. equipment according to claim 1, wherein, described stove passes through the hot dipping near 500 DEG C, the output of elevated band Temperature reaches required temperature when entering metal coating unit, so that its temperature is dropped back to less than this value, ideally right Drop back to 465 DEG C in liquid electroplating bath, this temperature can the significant change according to the types of alloys being used, or for electricity Solution bath drops back to the temperature close to ambient temperature.
13. equipment according to claim 1, wherein, the metal tape of described pickling unit upstream is not hot-rolled product, but Cold-rolled products, in this case, described band does not carry out pickling in described pickling unit, for example, shift from described pickling unit To described skin pass rolling device, and described stove provides other heating and cooling mechanism to provide the annealing of band.
A kind of 14. pickling of metal tape for being continuously traveling and the method for metal coating, it includes successively along direct of travel: At least one pickling stages(2), carry temperature controlled heat treatment stages(4)Coat the stage with metal(5), and wherein, acquiescence exists The metal tape of described pickling stages upstream is hot-rolled product,
It is characterized in that:
- can in described pickling stages and with temperature controlling stages between activate the limited reduction of thickness and band roughness and The finishing stage of flatness;
- reducing and carry roughness and in the case of the flatness finishing stage in activation, described band temperature controlling stages are to described Band applies thermal cycle, and this enables control over the recovery of band structure, and applies heating on tape so that band output temperature reaches Enter the temperature needed for described metal coating unit porch.
15. methods according to claim 14 are wherein, in the sense that at least part of recrystallization realizing band, actual Above even in the sense that crystal grain is grown up, described thermocycle stage is extended.
CN201580017944.2A 2014-03-31 2015-01-26 Equipment and process for the pickling and metallic coating of a metal strip Pending CN106460136A (en)

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EP14290086.9A EP2927343A1 (en) 2014-03-31 2014-03-31 Installation and method for pickling and metal coating of a metal strip
EP14290086.9 2014-03-31
EP14290104.0 2014-04-11
EP14290104 2014-04-11
PCT/EP2015/051427 WO2015149960A1 (en) 2014-03-31 2015-01-26 Equipment and process for the pickling and metallic coating of a metal strip

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CN113463001A (en) * 2021-07-01 2021-10-01 范安辉 Metal plating device suitable for steel strips with different thicknesses

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JPH07126747A (en) * 1993-11-05 1995-05-16 Sumitomo Metal Ind Ltd Production of si-containing steel plate excellent in hot dip galvanizing suitability
JPH08325689A (en) * 1995-05-30 1996-12-10 Nippon Steel Corp Equipment for manufacturing hot dip galvanized hot rolled steel sheet excellent in lubricity and chemical conversion
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WO2015149960A1 (en) 2015-10-08
MX2016012711A (en) 2017-03-31
PL3126539T3 (en) 2021-06-14
EP3126539B1 (en) 2020-11-25
CN113846281A (en) 2021-12-28
ES2856229T3 (en) 2021-09-27
RU2016138425A3 (en) 2018-10-04
RU2016138425A (en) 2018-05-04

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