CN106436350A - Micro-suspension dyeing system, and dyeing method and application thereof - Google Patents

Micro-suspension dyeing system, and dyeing method and application thereof Download PDF

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Publication number
CN106436350A
CN106436350A CN201610382825.3A CN201610382825A CN106436350A CN 106436350 A CN106436350 A CN 106436350A CN 201610382825 A CN201610382825 A CN 201610382825A CN 106436350 A CN106436350 A CN 106436350A
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China
Prior art keywords
dyeing
fine suspension
fabric
dispersion
micro
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Pending
Application number
CN201610382825.3A
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Chinese (zh)
Inventor
温明华
陶建玉
尹寿虎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Hengxin Knitting Printing & Dyeing Co Ltd
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Suzhou Hengxin Knitting Printing & Dyeing Co Ltd
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Application filed by Suzhou Hengxin Knitting Printing & Dyeing Co Ltd filed Critical Suzhou Hengxin Knitting Printing & Dyeing Co Ltd
Priority to CN201610382825.3A priority Critical patent/CN106436350A/en
Publication of CN106436350A publication Critical patent/CN106436350A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67375Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341 with sulfur-containing anions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters
    • D06P3/54Polyesters using dispersed dyestuffs

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a micro-suspension dyeing system, and a dyeing method and application thereof. The method comprises the following steps: dispersing into a micro-suspension dyeing and dispersing system by adopting disperse dyes for high-strength microfibers, a micro-suspension dispersing agent, a cosolvent, a thickening agent, a penetrating agent and an antifoaming agent, dyeing fabrics by using a dyeing process comprising the steps of padding to color, drying, baking to color, reducing and cleaning, lustering and finally dewatering and drying, and applying to dyeing of a knitted polyester fabric. Compared with the prior art, the method has the following advantages that with the adoption of the fabrics dyed on the micro-suspension system, the water usage of high-bath-ratio dyeing in the conventional overflow jar dyeing is reduced, and the water amount is saved by over 30%; the time of dyeing the knitted polyester fabric is short, the time of dyeing fabrics per tonnage is saved by one half at least, and the efficiency and the yield are improved.

Description

A kind of fine suspension dyeing system and colouring method and application
Technical field
The invention belongs to staining technique field, more particularly, to a kind of fine suspension dyeing system and colouring method and application.
Background technology
Micro-suspension stain technology refers to add fine suspension auxiliary agent, this auxiliary agent and dyestuff structure in dye bath in dye bath Become to have the stable fine suspension compared with strong-hydrophobicity, because dyestuff micro suspension particle is tiny, have very strong permeability to fabric tissue, Dyestuff fine suspension particle can equably adsorb in fabric face and yarn gap, raises with temperature, micro suspension system Gradually disintegrate, the dye molecule discharging spreads to fibrous inside, carries out being bonded to fibrous inside, completes dyeing course.This skill Art solves the phenomenon of uneven dyeing, shortens dyeing time, and can improve dye uptake, thus reducing the negative of later process Load, reduces sewage discharge, has the effect of energy-conserving and environment-protective.
Micro-suspension stain technology is studied relatively at present in protein fibre and cotton, the Colour Difference of corduroy fabric Many, mainly for acid dyes and reactive dye;Hair/nitrile staple in bulk also there is application, mainly for the dye of positive ion.For Report is had no at present using disperse dyes micro-suspension stain technology, the yield of dacron is high, dyeing adopts high temperature to overflow mostly Stream staining technique, disperse dyes enters at 130 DEG C in the space of fiber thus on contaminate, removing loose colour, biography through reduction cleaning The staining method of system is highly water intensive, highly energy-consuming.
The dyeing that micro-suspension stain technology is applied to polyster fibre presently, there are following problem:Disperse dyes Water-insoluble characteristic, needs to screen suitable disperse dyes and dispersant or suspension stabilizer makes stable system;Dyestuff is non-aqueous Molten, little to the absorption affinity of fiber, needing releasing high pressure to pad makes it adsorb in fiber surface;High temperature is needed during contaminating on dyestuff Make it into fibrous inside to realize contaminating.
Accordingly, it would be desirable to a kind of new technical scheme solves the above problems.
Content of the invention
Goal of the invention:In order to overcome, disperse dyes present in prior art are improper, dyeing process is loaded down with trivial details, performance is unstable Fixed problem, the present invention proposes a kind of fine suspension dyeing reducing dyeing water consumption, dyeing time, raising efficiency and yield System and colouring method and application.
Technical scheme:In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:A kind of fine suspension dye Colour system, forms fine suspension dispersion by following component by weight, and dispersion viscosity is 1600pa.s-2200pa s:High-tensile strength part woven fabric disperse dyes 0.5%-8%, fine suspension dispersant 5%-15%, cosolvent 1%-2%, thickener 15-35%, bleeding agent 1.5%, defoamer 1%, the water of surplus.
It is more highly preferred to, described high-tensile strength part woven fabric high-tensile strength part disperse dyes are high-tensile strength part woven fabric high-tensile strength part disperse dyes FBL or the high-tensile strength part woven fabric grand liquid of slips black high-tensile strength part disperse dyes.
Further, described cosolvent is water in the micro suspension system that thickener forms for the disperse dyes for cosolvent Property cosolvent.
It is more highly preferred to, described fine suspension dispersant is a kind of lignin sulfonic acid increasing fine suspension system stability Salt chemical dispersant.
The invention allows for a kind of colouring method of above-mentioned fine suspension dyeing system, comprise the steps:
(1) configuration of fine suspension dispersion:Get out following raw material first in the desired amount, choose high-tensile strength part woven fabric and use High-tensile strength part disperse dyes, fine suspension dispersant, cosolvent, thickener, the water composition of bleeding agent, defoamer and surplus are stablized Fine suspension dispersion;
(2) pad colouring:Fine suspension dispersion is put into and pads in groove, adjust liquid carrying rate 60%-95%, speed 15-30m/min, three leachings three are rolled, and make fine suspension dispersion uniformly be attached to the fiber surface of fabric;
(3) dry:Heat drying cylinder by multigroup steam to be dried the fine suspension dispersion on fabric, uniformly Moisture content is the degree of drying of 3.5%-5%;
(4) bake colouring:Three layer of 8 section after improving amounts to 72 meters of long conduction oil dryers, and temperature setting exists Between 175-185 DEG C, the fabric after drying is carried out high temperature color development, make dyestuff well into the inside of fiber, form colouring;
(5) reduction cleaning and upper soft:Using caustic soda 2g/L, sodium hydrosulfite 4g/L, under conditions of 90-95 DEG C, carry out rope form 9 groove Overflow is washed, and fabric is carried out sufficient reduction cleaning, removes loose colour and is fully peeled off the thickener in dispersion, And add, in last two grooves, the overall feel that softening agent improves fabric;
(6) it is dehydrated and dry.
Further, the pressure carrying out roll in described step (2) is 0.5-4.5 atmospheric pressure.
Further, the consumption of described softening agent is 1.5%-2.5%.
The invention allows for a kind of application of above-mentioned fine suspension dyeing system, it is applied particularly to the dye of polyester knitted fabric Color.
Beneficial effect:A kind of fine suspension dyeing system and its colouring method and application that the present invention provides, using high-tensile strength part Woven fabric disperse dyes, fine suspension dispersant, cosolvent, thickener, bleeding agent and defoamer are dispersed into fine suspension dye Color dispersion, through padding colouring, drying, bakeing colouring, reduction cleaning and upper soft, last dewatered drying dyeing flow process Fabric is dyeed, and is applied in the dyeing of polyester knitted fabric, compared with prior art there is advantages below:Using Fine suspension fastens dye fabric, decreases the water consumption of high bath ratio dyeing in conventional overflow cylinder dyeing, has saved more than 50% Water consumption;Dyeing time for polyester knitted fabric is shorter, and the dyeing time of more than half saved by fabric per ton, improves effect Rate and yield.
Specific embodiment
With reference to embodiment, the present invention is described in further detail:
Embodiment 1:
Select the redness flannel fabric of the 280G containing 100% polyster fibre to carry out fine suspension dyeing system to be dyeed:
(1) configuration of red fine suspension dispersion:Get out following raw material first in the desired amount, choose high-tensile strength part and surpass Fibre high-tensile strength part disperse dyes FBL0.5%, fine suspension dispersant 5%, cosolvent 1%, thickener 15%, bleeding agent 1.5%th, the water of defoamer 1% and surplus forms stable fine suspension dispersion, and the viscosity of dispersion is after measured 1600pa·s;
(2) pad colouring:Fine suspension dispersion is put into and pads in groove, adjust liquid carrying rate 60%, speed 30m/ Min, three leachings three are rolled, and make fine suspension dispersion uniformly be attached to the fiber surface of fabric, the wherein pressure of roll is 0.5 Atmospheric pressure;
(3) dry:Heat drying cylinder by 20 groups of 120 DEG C of steam to be dried the fine suspension dispersion on fabric, The degree of drying being 3.5% to uniform moisture content;
(4) bake colouring:Three layer of 8 section after improving amounts to 72 meters of long conduction oil dryers, and temperature setting is 175 DEG C, the fabric after drying is carried out high temperature color development, makes dyestuff well into the inside of polyster fibre, form colouring;
(5) reduction cleaning and upper soft:Using caustic soda 2g/L, sodium hydrosulfite 4g/L, under conditions of 90 DEG C, carry out rope form 9 groove overflow Washing, fabric is carried out sufficient reduction cleaning, removes loose colour and is fully peeled off the thickener in dispersion, and Last two grooves add the overall feel that softening agent improves fabric;The consumption of the highly concentrated softening agent of block is 1.5%;
(6) it is dehydrated and dry.
After measured, present invention micro-suspension stain technology produces water consumption used by fabric per ton is 3 tons of water, the used time 1.5 Individual hour, and traditional overflow dye vat dyes fabric water consumption per ton and is 5 tons, takes 3.5 hours, to sum up, the present invention has Excellent energy-conservation and the effect that saves time.Washing fastness after dyeing is more than 3.5 grades, and color fastness to light is more than 3 grades, colourless flower and frost flower Phenomenon, customers' responsiveness is good.
Embodiment 2:
Select the super soft fabric of 220G black crystal containing 100% polyster fibre to carry out fine suspension dyeing system to be contaminated Color:
(1) configuration of black fine suspension dispersion:Get out following raw material first in the desired amount, choose high-tensile strength part and surpass The grand liquid of fibre slips black high-tensile strength part disperse dyes 8%, fine suspension dispersant 15%, cosolvent 2%, thickener 35%, ooze The stable fine suspension dispersion of the water composition of agent 1.5%, defoamer 1% and surplus thoroughly, dispersion is viscous after measured Spend for 2200pa s;
(2) pad colouring:Fine suspension dispersion is put into and pads in groove, adjust liquid carrying rate 95%, speed 15m/ Min, three leachings three are rolled, and make fine suspension dispersion uniformly be attached to the fiber surface of fabric, the wherein pressure of roll is 4.5 Atmospheric pressure;
(3) dry:Heat drying cylinder by 40 groups of 120 DEG C of steam to be dried the fine suspension dispersion on fabric, The degree of drying being 5% to uniform moisture content;
(4) bake colouring:Three layer of 8 section after improving amounts to 72 meters of long conduction oil dryers, and temperature setting is 185 DEG C, the fabric after drying is carried out high temperature color development, makes dyestuff well into the inside of polyster fibre, form colouring;
(5) reduction cleaning and upper soft:Using caustic soda 2g/L, sodium hydrosulfite 4g/L, under conditions of 90 DEG C, carry out rope form 9 groove overflow Washing, fabric is carried out sufficient reduction cleaning, removes loose colour and is fully peeled off the thickener in dispersion, and Last two grooves add the overall feel that softening agent improves fabric;The consumption of the highly concentrated softening agent of block is 2.5%;
(6) it is dehydrated and dry.
After measured, present invention micro-suspension stain technology produces water consumption used by fabric per ton is 3 tons of water, the used time 1.5 Individual hour, and traditional overflow dye vat dyes fabric water consumption per ton and is 5 tons, takes 3.5 hours, to sum up, the present invention has Excellent energy-conservation and the effect that saves time.Washing fastness after dyeing is more than 3.5 grades, and color fastness to light is more than 3 grades, colourless flower and frost flower Phenomenon, customers' responsiveness is good.
It should be pointed out that above specific embodiment is only illustrative of the invention and is not intended to limit the scope of the invention, After having read the present invention, the modification of the various equivalent form of values to the present invention for the those skilled in the art all falls within power appended by the application Profit requires limited range.

Claims (8)

1. a kind of fine suspension dyeing is it is characterised in that forming fine suspension dispersion by following component by weight, Dispersion viscosity is 1600pa.s-2200pa s:High-tensile strength part woven fabric disperse dyes 0.5%-8%, fine suspension dispersant 5%-15%, cosolvent 1%-2%, thickener 15-35%, bleeding agent 1.5%, defoamer 1%, the water of surplus.
2. fine suspension according to claim 1 dyeing system it is characterised in that:Described woven fabric high-tensile strength part disperse dyes are High-tensile strength part woven fabric high-tensile strength part disperse dyes FBL or the black disperse dyes of the grand liquid of high-tensile strength part woven fabric slips.
3. fine suspension according to claim 1 dyeing system it is characterised in that:Described cosolvent is disperse dyes in thickening Aqueous cosolvent in the micro suspension system of agent composition.
4. fine suspension according to claim 1 dyeing system it is characterised in that:Described fine suspension dispersant is that increase is micro- A kind of lignin sulfonate chemical dispersant of suspended substance system stability.
5. the colouring method of fine suspension dyeing system as claimed in claim 1 is it is characterised in that comprise the steps:
(1) configuration of fine suspension dispersion:Get out following raw material first in the desired amount, choose the dispersion of high-tensile strength part woven fabric Dyestuff, fine suspension dispersant, cosolvent, thickener, the water of bleeding agent, defoamer and surplus form stable fine suspension Dispersion;
(2) pad colouring:Fine suspension dispersion is put into and pads in groove, adjust liquid carrying rate 60%-95%, speed 15- 30m/min, three leachings three are rolled, and make fine suspension dispersion uniformly be attached to the fiber surface of fabric;
(3) dry:Heat drying cylinder by multigroup steam to be dried the fine suspension dispersion on fabric, to uniformly containing Water rate is the degree of drying of 3.5%-5%;
(4) bake colouring:Three layer of 8 section after improving amounts to 72 meters of long conduction oil dryers, and temperature setting is in 175-185 Between DEG C, the fabric after drying is carried out high temperature color development, make dyestuff well into the inside of fiber, form colouring;
(5) reduction cleaning and upper soft:Using caustic soda 2g/L, sodium hydrosulfite 4g/L, under conditions of 90-95 DEG C, carry out rope form 9 groove overflow Washing, fabric is carried out sufficient reduction cleaning, removes loose colour and is fully peeled off the thickener in dispersion, and Last two grooves add the overall feel that softening agent improves fabric;
(6) it is dehydrated and dry.
6. fine suspension according to claim 5 dyeing system colouring method it is characterised in that:Enter in described step (2) The pressure of row roll is 0.5-4.5 atmospheric pressure.
7. fine suspension according to claim 5 dyeing system colouring method it is characterised in that:The consumption of described softening agent For 1.5%-2.5%.
8. the application of fine suspension dyeing system as claimed in claim 1 is it is characterised in that be applied to the dye of polyester knitted fabric Color.
CN201610382825.3A 2016-06-01 2016-06-01 Micro-suspension dyeing system, and dyeing method and application thereof Pending CN106436350A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107740293A (en) * 2017-10-30 2018-02-27 江苏波波熊纺织品有限公司 A kind of polyester fabric new dyeing method
CN109267385A (en) * 2018-08-22 2019-01-25 新乡市新星特种织物有限公司 It is knitted intellectual circle's dyeing
CN109355834A (en) * 2018-10-11 2019-02-19 江苏康尼纺织品有限公司 A kind of environment-friendly type lint cloth colouring method and its residual mill base treatment process

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CN1059920A (en) * 1990-08-15 1992-04-01 阿尔布赖特-威尔逊公司 Dye suspensions
JP2002363869A (en) * 2001-06-04 2002-12-18 Asahi Kasei Corp Method of dyeing textile product
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CN204608380U (en) * 2015-04-16 2015-09-02 苏州市恒信针织印染有限责任公司 A kind of fine suspension is coloured to complete equipment

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JP2002363869A (en) * 2001-06-04 2002-12-18 Asahi Kasei Corp Method of dyeing textile product
CN104153212A (en) * 2014-08-06 2014-11-19 浙江理工大学 Pad dyeing method for full-shade polyester fabric
CN204608380U (en) * 2015-04-16 2015-09-02 苏州市恒信针织印染有限责任公司 A kind of fine suspension is coloured to complete equipment

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107740293A (en) * 2017-10-30 2018-02-27 江苏波波熊纺织品有限公司 A kind of polyester fabric new dyeing method
CN109267385A (en) * 2018-08-22 2019-01-25 新乡市新星特种织物有限公司 It is knitted intellectual circle's dyeing
CN109267385B (en) * 2018-08-22 2021-08-10 新乡市新星特种织物有限公司 Knitting threne dyeing process
CN109355834A (en) * 2018-10-11 2019-02-19 江苏康尼纺织品有限公司 A kind of environment-friendly type lint cloth colouring method and its residual mill base treatment process

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