CN106435814A - Method for preparing graphene thermal underwear fabric - Google Patents
Method for preparing graphene thermal underwear fabric Download PDFInfo
- Publication number
- CN106435814A CN106435814A CN201610812365.3A CN201610812365A CN106435814A CN 106435814 A CN106435814 A CN 106435814A CN 201610812365 A CN201610812365 A CN 201610812365A CN 106435814 A CN106435814 A CN 106435814A
- Authority
- CN
- China
- Prior art keywords
- graphene
- thermal underwear
- preparation
- dispersion
- face fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
Abstract
The invention relates to a method for preparing underwear and provides a method for preparing a graphene thermal underwear fabric. The defects in the prior art that a thermal underwear fabric is instable in graphene bonding, non-washing-resistant and short in effective service life due to defects of a preparation method are overcome. The method comprises the following steps: (1) dispersing graphene; (2) carrying out a conjugation reaction, namely mixing a product treated in the step (1) with 3,4-ethylenedioxythiophene, uniformly stirring, and feeding into a centrifugal machine for performing centrifugal treatment, thereby obtaining a precipitate; and (3) drying the precipitate, mixing the dried precipitate, cotton fibers and soybean fibers according to a ratio of (1):(100-120):(100-110), performing melt blending and extrusion in a screw-type extruder; and spinning, winding and stretching, thereby obtaining the product.
Description
Technical field
The present invention relates to a kind of preparation method of underwear, more particularly, to a kind of preparation side of Graphene thermal underwear face fabric
Method.
Background technology
With the continuous improvement of living standard, the Functional Requirement more and more higher to clothing for the people, the especially choosing to underwear
Select not only emphasis soft comfortable, more focus on health, health care.Traditional thermal underwear face fabric mostly typically is wool, kapok fibre
Dimension etc., and generally using thickening design although warmth retention property is good, but have that clothing is excessively thick and heavy, comfortableness and poor air permeability etc.
Problem.Existing thermal underwear face fabric poor durability, after repeatedly washing, warming effect weakens significantly.Therefore, developing a kind of is no
Thermal underwear face fabric that is malicious safe and having excellent durability becomes important research topic.
Graphene is the two dimensional crystal of the only one layer of atomic thickness being stripped out from graphite, and thickness is about 0.34nm.
After the reported first of C60 (fullerene) in 1985 and CNT in 1991, the discovery of Graphene in 2004 promotes again
The research to carbon nano material for the people.Research shows, Graphene has outstanding mechanical performance, electric conductivity, calorifics
Energy and optical property.In order to these excellent properties of Graphene are carried out practical application, people have carried out entering one to Graphene
The research of step, but in prior art, with regard to Graphene, the report on cold-proof underwear is more rare.
China Patent No. 201310304643.0 discloses a kind of graphene radiation heating film and its preparation method and application：
It is the film that Graphene slurry is coated in the formation of fabric lining surface, and Graphene slurry is mixed according to weight portion by following component
After formed：3～5 parts of graphene powder, 1～3 part of far infrared transmission agent, bond 4～6 parts of diluent；In use, in fabric lining
Alternate setting graphene radiation heating film area and nano metal far infrared heating area, by nano metal far infrared heating area and inclusion
The circuit of wire, switch and power supply constitutes performance loop, graphene radiation heating film area edge and nano metal far infrared heating
Area and the gap of wire marginal existence 2-3mm；With nano metal far infrared heating area as main heating source, with graphene radiation heating
Film is auxiliary thermal source radiation heating, graphene radiation heating film area on fabric lining, nano metal far infrared heating area and lead
The positive and negative surface of line is all attached with flexible insulation protective layer.This graphene radiation heating film can conduct acquisition heat, is applied
On underwear can by high efficient radiation conduction pattern obtain heat, improve warmth retention property, but due to Graphene be by coat in the way of with
Fiber combines, not wash resistant, and after washing several times, function slowly goes down, and Acceptable life is short.
Content of the invention
Therefore, for above content, the present invention provides a kind of preparation method of Graphene thermal underwear face fabric, solves existing
Thermal underwear face fabric in technology due to the defect of preparation method lead to Graphene on underwear fabric combine built on the sand, not washable
Wash, Acceptable life is short defect.
For reaching above-mentioned purpose, the present invention is achieved by the following technical solutions：A kind of Graphene thermal underwear face fabric
Preparation method, including following process step：(1) dispersed graphite alkene：By graphene dispersion in dispersion liquid, described dispersion liquid is
Amount ratio=1 of 3- aminopropyl triethoxysilane, described Graphene and dispersion liquid：10～20, adopt mixer during dispersion, stir
Mix rotating speed controls in 2000～3000r/min；(2) conjugation reaction：Product after step (1) is processed and 3,4- ethylene dioxy thiophene
Fen mixes, and stirs, and sends into centrifuge and carries out centrifugal treating, is precipitated thing；(3) sediment is dried, by drying
Rear sediment and cotton fiber, fibre and soya are according to 1：100～120：100～110 ratio mixing, enters extruser and melts
Melt blending extrusion, granulation, be then obtained after spinning, winding, stretching.
Further：In step (3), sediment and cotton fiber, fibre and soya are according to 1：100：100 ratio mixing.
Further：Described Graphene is to be produced using mechanical stripping graphite method, by individual layer and part form the few-layer graphene alkene heap
Long-pending powder, has following technical indicator：Outward appearance, black gray expandable powder；Thickness ＜ 5nm, diameter 5～20nm, moisture content ＜
2%；Bulk density 0.02～0.04g/ml.
By adopting preceding solution, the invention has the beneficial effects as follows：The Graphene thermal underwear face fabric of the present invention
Preparation method, by carrying out to Graphene disperseing, conjugation process, locate after then carrying out with cotton fiber, fibre and soya mixed melting
Reason, the fabric obtaining has function that can be emitting far-infrared, is made into underwear, can produce during wearing 10～13 microns far red
Outer performance, has ultra-slim features but has superior thermal property simultaneously concurrently, has conditioning massage to the skin of contact simultaneously
Effect, and because Graphene and fiber are directly in conjunction with weaving, the fabric containing Graphene solving prior art is not water-fastness,
Through washing the problem with regard to loss of function several times.Furthermore, the underwear fabric of the present invention also has biocidal efficacies, more health.
Specific embodiment
To describe embodiments of the present invention in detail below with reference to specific embodiment, whereby how skill to be applied to the present invention
Art means are solving technical problem, and reach realizing process and fully understanding and implement according to this of technique effect.
If not specializing, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, the reagent being adopted and product are also available commercial.The source of agents useful for same, trade name and be necessary to list it
Constituent person, all indicates when occurring first.
Embodiments of the invention are：
A kind of preparation method of Graphene thermal underwear face fabric, including following process step：(1) dispersed graphite alkene：By stone
Black alkene is dispersed in dispersion liquid, and described dispersion liquid is 3- aminopropyl triethoxysilane, the consumption of described Graphene and dispersion liquid
Ratio=1：15, adopt mixer during dispersion, speed of agitator controls in 3000r/min；(2) conjugation reaction：After step (1) is processed
Product mix with 3,4-rthylene dioxythiophene, stir, send into centrifuge carry out centrifugal treating, be precipitated thing；(3) right
Sediment is dried, by dried sediment and cotton fiber, fibre and soya according to 1：100：100 ratio mixing, enters
Extruser melt blending extrusion, granulation, are then obtained after spinning, winding, stretching.
Described Graphene is to be produced using mechanical stripping graphite method, the powder piled up by individual layer and part form the few-layer graphene alkene
Body, has following technical indicator：Outward appearance, black gray expandable powder；Thickness is 4nm, diameter 10nm, moisture content=1%；Bulk density
0.03g/ml.
Wherein, in the present invention, amount ratio=1 of described Graphene and dispersion liquid：10～20, during dispersion, speed of agitator controls
In 2000～3000r/min；When sediment is dried, sediment and cotton fiber, fibre and soya are according to 1：100～120：100
～110 ratio mixing, carries out selecting all to can achieve the purpose of the present invention in above parameter area.
Described above, only utilize the embodiment of this origination techniques content, any those skilled in the art use this wound
Make done modification, change, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
Claims (3)
1. a kind of preparation method of Graphene thermal underwear face fabric is it is characterised in that include following process step：(1) disperse stone
Black alkene：By graphene dispersion in dispersion liquid, described dispersion liquid is 3- aminopropyl triethoxysilane, described Graphene and dispersion
Amount ratio=1 of liquid：10～20, adopt mixer during dispersion, speed of agitator controls in 2000～3000r/min；(2) it is conjugated instead
Should：Product after step (1) is processed is mixed with 3,4-rthylene dioxythiophene, stirs, and sends into centrifuge and carries out at centrifugation
Reason, is precipitated thing；(3) sediment is dried, by dried sediment and cotton fiber, fibre and soya according to 1：100
～120：100～110 ratio mixing, enters extruser melt blending extrusion, granulation, then through spinning, winding, stretching
After be obtained.
2. Graphene thermal underwear face fabric according to claim 1 preparation method it is characterised in that：In step (3), sink
Starch and cotton fiber, fibre and soya are according to 1：100：100 ratio mixing.
3. Graphene thermal underwear face fabric according to claim 1 and 2 preparation method it is characterised in that：Described graphite
Alkene is to be produced using mechanical stripping graphite method, the powder piled up by individual layer and part form the few-layer graphene alkene, has following technology
Index：Outward appearance, black gray expandable powder；Thickness ＜ 5nm, diameter 5～20nm, moisture content ＜ 2%；Bulk density 0.02～0.04g/
ml.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610812365.3A CN106435814A (en) | 2016-09-09 | 2016-09-09 | Method for preparing graphene thermal underwear fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610812365.3A CN106435814A (en) | 2016-09-09 | 2016-09-09 | Method for preparing graphene thermal underwear fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106435814A true CN106435814A (en) | 2017-02-22 |
Family
ID=58164543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610812365.3A Pending CN106435814A (en) | 2016-09-09 | 2016-09-09 | Method for preparing graphene thermal underwear fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106435814A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106880088A (en) * | 2017-04-20 | 2017-06-23 | 泉州信和石墨烯研究院有限公司 | A kind of Graphene far infrared heating socks |
| CN107142602A (en) * | 2017-04-14 | 2017-09-08 | 江南大学 | Graphene fiber multi-functional warm seamless underwear is designed and method for weaving |
| CN107215011A (en) * | 2017-05-08 | 2017-09-29 | 江苏联宏纺织有限公司 | A kind of compound fabric based on graphene composite fibre and preparation method thereof |
| CN108095207A (en) * | 2017-12-28 | 2018-06-01 | 武汉猫人制衣有限公司 | A kind of composition and its application in thermal underwear face fabric |
| CN108342785A (en) * | 2017-05-27 | 2018-07-31 | 上海三问家居服饰有限公司 | Application of the graphene in preparing soybean fiber and its fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102789842A (en) * | 2012-07-27 | 2012-11-21 | 青岛科技大学 | Preparation method of conducting polymer/grapheme composite nanometer material |
| CN105901780A (en) * | 2016-05-04 | 2016-08-31 | 曾新民 | Manufacturing method for uterus warming healthcare briefs containing graphene and used for women |
-
2016
- 2016-09-09 CN CN201610812365.3A patent/CN106435814A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102789842A (en) * | 2012-07-27 | 2012-11-21 | 青岛科技大学 | Preparation method of conducting polymer/grapheme composite nanometer material |
| CN105901780A (en) * | 2016-05-04 | 2016-08-31 | 曾新民 | Manufacturing method for uterus warming healthcare briefs containing graphene and used for women |
Non-Patent Citations (2)
| Title |
|---|
| 张宪胜等: "石墨烯粘胶复合纤维的性能研究", 《棉纺织技术》 * |
| 李昌垒等: "石墨烯与再生纤维素复合纤维制备及性能研究", 《针织工业》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142602A (en) * | 2017-04-14 | 2017-09-08 | 江南大学 | Graphene fiber multi-functional warm seamless underwear is designed and method for weaving |
| CN106880088A (en) * | 2017-04-20 | 2017-06-23 | 泉州信和石墨烯研究院有限公司 | A kind of Graphene far infrared heating socks |
| CN107215011A (en) * | 2017-05-08 | 2017-09-29 | 江苏联宏纺织有限公司 | A kind of compound fabric based on graphene composite fibre and preparation method thereof |
| CN108342785A (en) * | 2017-05-27 | 2018-07-31 | 上海三问家居服饰有限公司 | Application of the graphene in preparing soybean fiber and its fabric |
| CN108095207A (en) * | 2017-12-28 | 2018-06-01 | 武汉猫人制衣有限公司 | A kind of composition and its application in thermal underwear face fabric |
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Application publication date: 20170222 |
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