CN106397812A - Bacteriostatic filter plate of automobile air conditioner and preparation method of bacteriostatic filter plate - Google Patents

Bacteriostatic filter plate of automobile air conditioner and preparation method of bacteriostatic filter plate Download PDF

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Publication number
CN106397812A
CN106397812A CN201610805866.9A CN201610805866A CN106397812A CN 106397812 A CN106397812 A CN 106397812A CN 201610805866 A CN201610805866 A CN 201610805866A CN 106397812 A CN106397812 A CN 106397812A
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CN
China
Prior art keywords
consumption
weight portion
preparation
screen plate
filter plate
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Pending
Application number
CN201610805866.9A
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Chinese (zh)
Inventor
杜红华
王仁俊
汪玲玲
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Wuhu Dexin Automotive Parts Co Ltd
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Wuhu Dexin Automotive Parts Co Ltd
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Priority to CN201610805866.9A priority Critical patent/CN106397812A/en
Publication of CN106397812A publication Critical patent/CN106397812A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02Homopolymers or copolymers of hydrocarbons
    • C08J2425/04Homopolymers or copolymers of styrene
    • C08J2425/14Homopolymers or copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a bacteriostatic filter plate of an automobile air conditioner and a preparation method of the bacteriostatic filter plate. The preparation method comprises the following steps: blending polyethylene, carbon fibers, silicon dioxide, epoxy resin and a plasticizer to form a mixture M, and curing for molding the mixture M to obtain a filter plate blank N; mixing styrene-acrylic emulsion, titanium dioxide, calcium carbonate, zinc oxide, water, ethylene resin and a thickener, and performing ultrasonic dispersion to obtain bacteriostatic emulsion paint; coating the surface of the filter plate blank N with the bacteriostatic emulsion paint, and drying to obtain the bacteriostatic filter plate of the automobile air conditioner. The problem that the existing filter plate can effectively filter out dust but the bacteriostatic property is low, and the problem that the filter plate can be embrittled and softened and even broken when working under an alternately cold and hot environment for a long time are solved.

Description

Antibacterial screen plate of air conditioning for automobiles and preparation method thereof
Technical field
The present invention relates to automobile air conditioner accessories, in particular it relates to antibacterial screen plate of air conditioning for automobiles and preparation method thereof.
Background technology
Air conditioning for automobiles does not use for a long time, and its internal pipeline or air outlet can gather a large amount of dusts, so in air outlet Screen plate can be set and carry out blocks dust.Wet environment within air-conditioning can grow substantial amounts of antibacterial, although existing screen plate energy Effectively filter dirt, but it is antibacterial limited in one's ability, and screen plate works for a long time in the environment of colding and heat succeed each other simultaneously, can become embrittlement Soft, or even rupture, existing screen plate is difficult to meet simultaneously and is provided simultaneously with higher mechanical strength and stronger bacteriostasis.
Therefore it provides a kind of possess excellent bacteriostasis, the air conditioning for automobiles also possessing higher mechanical strength is antibacterial Screen plate and preparation method thereof is the problem of urgent need to resolve of the present invention.
Content of the invention
It is an object of the invention to provide antibacterial screen plate of a kind of air conditioning for automobiles and preparation method thereof, solve existing filtration Although dirt can effectively be filtered by plate, it is antibacterial limited in one's ability, and screen plate works for a long time in the environment of colding and heat succeed each other simultaneously, Can be become fragile deliquescing, or even the problem of fracture.
To achieve these goals, the invention provides a kind of preparation method of the antibacterial screen plate of air conditioning for automobiles, wherein, institute State preparation method to include:
(1) polyethylene, carbon fiber, silicon dioxide, epoxy resin and plasticizer are kneaded and form mixture M, and will mix Thing M curing molding, obtains screen plate base substrate N;
(2) styrene-acrylic emulsion, titanium dioxide, Calcium Carbonate, zinc oxide, water, vinyl and thickening agent are mixed and carry out ultrasonic Dispersion, obtains antibacterial breast paint;
(3) described antibacterial breast paint is coated in screen plate base substrate N surface, after drying, obtains the antibacterial screen plate of air conditioning for automobiles.
Present invention also offers a kind of antibacterial screen plate of air conditioning for automobiles, wherein, the antibacterial screen plate of described air conditioning for automobiles is by upper The preparation method stated is obtained.
By technique scheme, the invention provides antibacterial screen plate of a kind of air conditioning for automobiles and preparation method thereof, wherein, Described preparation method includes:Polyethylene, carbon fiber, silicon dioxide, epoxy resin and plasticizer are kneaded and forms mixture M, and By mixture M curing molding, obtain screen plate base substrate N;By styrene-acrylic emulsion, titanium dioxide, Calcium Carbonate, zinc oxide, water, vinyl Mix with thickening agent and carry out ultrasonic disperse, obtain antibacterial breast paint;Described antibacterial breast paint is coated in screen plate base substrate N surface, The antibacterial screen plate of air conditioning for automobiles is obtained after drying;By the synergism between each raw material so that prepared screen plate possess excellent Good mechanical strength, work long hours in the environment of colding and heat succeed each other the deliquescing that will not become fragile, and filter surface is coated with suppression simultaneously Bacterium breast paint is so that it possesses excellent bacteriostasis.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that it is described herein concrete Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of preparation method of the antibacterial screen plate of air conditioning for automobiles, wherein, described preparation method includes:
(1) polyethylene, carbon fiber, silicon dioxide, epoxy resin and plasticizer are kneaded and form mixture M, and will mix Thing M curing molding, obtains screen plate base substrate N;
(2) styrene-acrylic emulsion, titanium dioxide, Calcium Carbonate, zinc oxide, water, vinyl and thickening agent are mixed and carry out ultrasonic Dispersion, obtains antibacterial breast paint;
(3) described antibacterial breast paint is coated in screen plate base substrate N surface, after drying, obtains the antibacterial screen plate of air conditioning for automobiles.
So that the screen plate being obtained possesses more excellent mechanical strength, it is coated in the antibacterial breast on its surface meanwhile Paint can play good fungistatic effect, the present invention one kind preferred embodiment in, with respect to the poly- second of 100 weight portions Alkene, the consumption of described carbon fiber is 5-15 weight portion, and the consumption of described silicon dioxide is 2-10 weight portion, described epoxy resin Consumption is 20-40 weight portion, and the consumption of described plasticizer is 2-7 weight portion;With respect to the styrene-acrylic emulsion of 100 weight portions, described The consumption of titanium dioxide is 3-10 weight portion, and the consumption of described Calcium Carbonate is 3-9 weight portion, and the consumption of described zinc oxide is 2-8 weight Amount part, the consumption of described water is 20-40 weight portion, and the consumption of described vinyl is 10-20 weight portion, the use of described thickening agent Measure as 2-5 weight portion.
Preferably, with respect to the polyethylene of 100 weight portions, the consumption of described carbon fiber is 7-12 weight portion, described dioxy The consumption of SiClx is 4-6 weight portion, and the consumption of described epoxy resin is 25-35 weight portion, and the consumption of described plasticizer is 4-6 weight Amount part;With respect to the styrene-acrylic emulsion of 100 weight portions, the consumption of described titanium dioxide is 5-7 weight portion, and the consumption of described Calcium Carbonate is 5-7 weight portion, the consumption of described zinc oxide is 4-6 weight portion, and the consumption of described water is 25-35 weight portion, described vinyl Consumption be 14-17 weight portion, the consumption of described thickening agent is 3-4 weight portion.
So that raw material is easily worked, increase the toughness of the finished product being obtained, in a kind of preferred embodiment party of the present invention In formula, described plasticizer is in BBP(Butyl Benzyl Phthalate, di-sec-octyl phthalate and dibutyl phthalate Plant or multiple.
In order to increase the viscosity of antibacterial breast paint, prevent that sagging phenomenon occurs in coating procedure, excellent in one kind of the present invention In the embodiment of choosing, described thickening agent is in methylcellulose, hydroxypropyl methyl cellulose and sodium carboxymethyl cellulose Plant or multiple.
The present invention one kind preferred embodiment in, in order to improve the mechanical performance of prepared screen plate, step (1) In the temperature of mixing be 140-160 DEG C, time of mixing is 1-2h.
Described polyethylene can be the conventional use of type of those skilled in the art, for example, preferably real in one kind of the present invention Apply in mode, in order to improve the mechanical performance of prepared screen plate, the weight average molecular weight of described polyethylene is 8000-12000.
So that the raw material in antibacterial breast paint can be sufficiently mixed each other, a kind of in the present invention preferably implements In mode, in step (2), the frequency of ultrasonic disperse is 20-25KHz.
Present invention also offers a kind of antibacterial screen plate of air conditioning for automobiles, wherein, the antibacterial screen plate of described air conditioning for automobiles is by upper The preparation method stated is obtained.
Hereinafter will be described the present invention by embodiment.In following examples, polyethylene and carbon fiber are mountain The commercially available product that Dong Huaao Su Ye company limited provides, and the weight average molecular weight of polyethylene is 8000-12000;Plasticizer and thickening The commercially available product that agent provides for Puyang sincerity plasticizer company limited;Styrene-acrylic emulsion, vinyl and titanium dioxide are that Dongguan City is flourish The commercially available product your Import and Export Co., Ltd. provides.
Embodiment 1
100g polyethylene, 7g carbon fiber, 4g silicon dioxide, 25g epoxy resin and 4g BBP(Butyl Benzyl Phthalate are kneaded Form mixture M (wherein, the temperature of mixing is 140 DEG C, and the time of mixing is 1h), and by mixture M curing molding, obtained Filter plate base substrate N;By 100g styrene-acrylic emulsion, 5g titanium dioxide, 5g Calcium Carbonate, 4g zinc oxide, 25g water, 14g vinyl and 3g methyl Cellulose mixes and carries out ultrasonic disperse (frequency of ultrasonic disperse is 20KHz), obtains antibacterial breast paint;Described antibacterial breast paint is applied Overlay on screen plate base substrate N surface, after drying, obtain air conditioning for automobiles antibacterial screen plate A1.
Embodiment 2
100g polyethylene, 12g carbon fiber, 6g silicon dioxide, 35g epoxy resin and 6g di-sec-octyl phthalate are mixed Refining forms mixture M (wherein, the temperature of mixing is 160 DEG C, and the time of mixing is 2h), and by mixture M curing molding, obtains Screen plate base substrate N;By 100g styrene-acrylic emulsion, 7g titanium dioxide, 7g Calcium Carbonate, 6g zinc oxide, 35g water, 17g vinyl and 4g hydroxyl Propyl methocel mixes and carries out ultrasonic disperse (frequency of ultrasonic disperse is 25KHz), obtains antibacterial breast paint;By described suppression Bacterium breast paint is coated in screen plate base substrate N surface, obtains air conditioning for automobiles antibacterial screen plate A2 after drying.
Embodiment 3
100g polyethylene, 10g carbon fiber, 5g silicon dioxide, 30g epoxy resin and 5g dibutyl phthalate are kneaded Form mixture M (wherein, the temperature of mixing is 150 DEG C, and the time of mixing is 1.5h), and by mixture M curing molding, obtain Screen plate base substrate N;By 100g styrene-acrylic emulsion, 6g titanium dioxide, 6g Calcium Carbonate, 5g zinc oxide, 30g water, 15g vinyl and 3.5g Sodium carboxymethyl cellulose mixes and carries out ultrasonic disperse (frequency of ultrasonic disperse is 22KHz), obtains antibacterial breast paint;By described suppression Bacterium breast paint is coated in screen plate base substrate N surface, obtains air conditioning for automobiles antibacterial screen plate A3 after drying.
Embodiment 4
Method according to embodiment 1 is prepared, except for the difference that, with respect to the polyethylene of 100g, the use of described carbon fiber Measure as 5g, the consumption of described silicon dioxide is 2g, the consumption of described epoxy resin is 20g, described BBP(Butyl Benzyl Phthalate Consumption is 2g;With respect to the styrene-acrylic emulsion of 100g, the consumption of described titanium dioxide is 3g, and the consumption of described Calcium Carbonate is 3g, described The consumption of zinc oxide is 2g, and the consumption of described water is 20g, and the consumption of described vinyl is 10g, the use of described methylcellulose Measure as 2g, obtain air conditioning for automobiles antibacterial screen plate A4.
Embodiment 5
Method according to embodiment 1 is prepared, except for the difference that, with respect to the polyethylene of 100g, the use of described carbon fiber Measure as 15g, the consumption of described silicon dioxide is 10g, the consumption of described epoxy resin is 40g, described BBP(Butyl Benzyl Phthalate Consumption be 7g;With respect to the styrene-acrylic emulsion of 100g, the consumption of described titanium dioxide is 10g, and the consumption of described Calcium Carbonate is 9g, institute The consumption stating zinc oxide is 8g, and the consumption of described water is 40g, and the consumption of described vinyl is 20g, described methylcellulose Consumption is 5g, obtains air conditioning for automobiles antibacterial screen plate A5.
Comparative example 1
Method according to embodiment 1 is prepared, and except for the difference that, the method according to embodiment 1 is prepared, different It is that with respect to the polyethylene of 100g, the consumption of described carbon fiber is 3g, and the consumption of described silicon dioxide is 1g, described asphalt mixtures modified by epoxy resin The consumption of fat is 15g, and the consumption of described BBP(Butyl Benzyl Phthalate is 1g;With respect to the styrene-acrylic emulsion of 100g, described titanium dioxide Consumption be 2g, the consumption of described Calcium Carbonate is 2g, and the consumption of described zinc oxide is 1g, and the consumption of described water is 15g, described second The consumption of olefine resin is 8g, and the consumption of described methylcellulose is 1g, obtains air conditioning for automobiles antibacterial screen plate D1.
Comparative example 2
Method according to embodiment 1 is prepared, except for the difference that, with respect to the polyethylene of 100g, the use of described carbon fiber Measure as 20g, the consumption of described silicon dioxide is 12g, the consumption of described epoxy resin is 45g, described BBP(Butyl Benzyl Phthalate Consumption be 10g;With respect to the styrene-acrylic emulsion of 100g, the consumption of described titanium dioxide is 12g, and the consumption of described Calcium Carbonate is 12g, The consumption of described zinc oxide is 10g, and the consumption of described water is 45g, and the consumption of described vinyl is 25g, described Methyl cellulose The consumption of element is 7g, obtains air conditioning for automobiles antibacterial screen plate D2.
Test case 1
The air conditioning for automobiles antibacterial screen plate A1-A5 that will be obtained, D1 and D2 are placed on temperature and are 25 DEG C, and relative humidity is 60% Environment in, observe its surface mould speckle situation after 7 days.
Table 1
Can be seen that, by upper table data, the screen plate A1-A5 being obtained within the scope of the present invention, to possess higher stretching strong Degree, and visible mould bacterial plaque in rear surface after tested, and the screen plate D1 and D2 stretching being obtained outside the scope of the invention Intensity is relatively low, and more visible mold speckle in surface, illustrates that A1-A5 possesses excellent mechanical strength and antibacterial energy Power, meanwhile, the screen plate A1-A3 performance being obtained in currently preferred scope is more excellent.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the range of the technology design of the present invention, multiple simple variant can be carried out to technical scheme, this A little simple variant belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The compound mode of energy no longer separately illustrates.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, it equally should be considered as content disclosed in this invention.

Claims (9)

1. a kind of preparation method of the antibacterial screen plate of air conditioning for automobiles is it is characterised in that described preparation method includes:
(1) polyethylene, carbon fiber, silicon dioxide, epoxy resin and plasticizer are kneaded and form mixture M, and mixture M is solid Chemical conversion type, obtains screen plate base substrate N;
(2) styrene-acrylic emulsion, titanium dioxide, Calcium Carbonate, zinc oxide, water, vinyl and thickening agent are mixed and carry out ultrasonic disperse, Obtain antibacterial breast paint;
(3) described antibacterial breast paint is coated in screen plate base substrate N surface, after drying, obtains the antibacterial screen plate of air conditioning for automobiles.
2. preparation method according to claim 1 it is characterised in that with respect to 100 weight portions polyethylene, described carbon is fine The consumption of dimension is 5-15 weight portion, and the consumption of described silicon dioxide is 2-10 weight portion, and the consumption of described epoxy resin is 20-40 Weight portion, the consumption of described plasticizer is 2-7 weight portion;
With respect to the styrene-acrylic emulsion of 100 weight portions, the consumption of described titanium dioxide is 3-10 weight portion, and the consumption of described Calcium Carbonate is 3-9 weight portion, the consumption of described zinc oxide is 2-8 weight portion, and the consumption of described water is 20-40 weight portion, described vinyl Consumption be 10-20 weight portion, the consumption of described thickening agent is 2-5 weight portion.
3. preparation method according to claim 1 it is characterised in that with respect to 100 weight portions polyethylene, described carbon is fine The consumption of dimension is 7-12 weight portion, and the consumption of described silicon dioxide is 4-6 weight portion, and the consumption of described epoxy resin is 25-35 Weight portion, the consumption of described plasticizer is 4-6 weight portion;
With respect to the styrene-acrylic emulsion of 100 weight portions, the consumption of described titanium dioxide is 5-7 weight portion, and the consumption of described Calcium Carbonate is 5-7 weight portion, the consumption of described zinc oxide is 4-6 weight portion, and the consumption of described water is 25-35 weight portion, described vinyl Consumption be 14-17 weight portion, the consumption of described thickening agent is 3-4 weight portion.
4. preparation method according to claim 1 is it is characterised in that described plasticizer is BBP(Butyl Benzyl Phthalate, neighbour One or more of phthalic acid di-sec-octyl and dibutyl phthalate.
5. preparation method according to claim 1 is it is characterised in that described thickening agent is methylcellulose, hydroxypropyl first One or more of base cellulose and sodium carboxymethyl cellulose.
6. preparation method according to claim 1 is it is characterised in that the temperature of mixing in step (1) is 140-160 DEG C, the time of mixing is 1-2h.
7. preparation method according to claim 1 is it is characterised in that the weight average molecular weight of described polyethylene is 8000- 12000.
8. preparation method according to claim 1 it is characterised in that in step (2) ultrasonic disperse frequency be 20- 25KHz.
9. a kind of antibacterial screen plate of air conditioning for automobiles is it is characterised in that the antibacterial screen plate of described air conditioning for automobiles is by claim 1-8 Preparation method described in any one is obtained.
CN201610805866.9A 2016-09-07 2016-09-07 Bacteriostatic filter plate of automobile air conditioner and preparation method of bacteriostatic filter plate Pending CN106397812A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652846A (en) * 2017-10-24 2018-02-02 安徽艾米伦特建材科技有限公司 Rock wool plate surface composite and preparation method thereof
CN111114071A (en) * 2019-12-31 2020-05-08 东莞市尼的科技股份有限公司 Electrostatic protection film and preparation method thereof

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CN205037542U (en) * 2015-10-17 2016-02-17 安徽工程大学机电学院 Air conditioner filter screen device

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CN102241849A (en) * 2011-06-16 2011-11-16 上海邦中新材料有限公司 Carbon-fiber-reinforced polyethylene composite material
CN102391731A (en) * 2011-10-24 2012-03-28 沈阳建筑大学 Preparation method of rare earth anti-bacteria tilelike coating
CN205037542U (en) * 2015-10-17 2016-02-17 安徽工程大学机电学院 Air conditioner filter screen device

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652846A (en) * 2017-10-24 2018-02-02 安徽艾米伦特建材科技有限公司 Rock wool plate surface composite and preparation method thereof
CN111114071A (en) * 2019-12-31 2020-05-08 东莞市尼的科技股份有限公司 Electrostatic protection film and preparation method thereof

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Application publication date: 20170215