CN106396818B - A kind of cereal crops ecological mineral solution fertilizer and its preparation and application - Google Patents
A kind of cereal crops ecological mineral solution fertilizer and its preparation and application Download PDFInfo
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- CN106396818B CN106396818B CN201611187042.6A CN201611187042A CN106396818B CN 106396818 B CN106396818 B CN 106396818B CN 201611187042 A CN201611187042 A CN 201611187042A CN 106396818 B CN106396818 B CN 106396818B
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
- A01C21/005—Following a specific plan, e.g. pattern
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
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Abstract
A kind of cereal crops ecological mineral solution fertilizer and its preparation and application, formula material are natural crystal, and the natural crystal is the mixture of medical stone, smithsonite, pyrolusite, copper concentrate and paigeite.Preparation method is that natural crystal is ground into powder, by shaking-sieving, the separation that suspends, impregnates to dissolve and boil reaction, ageing extracting and filtering, polynary mineral solution is made, then the ultrasonic field cumulative shearing by alternating intense magnetic field driving, it is finally aged filtering, purification, filling again, cereal crops ecological mineral solution fertilizer is made.Cereal crops of the present invention at least contain 20 metal ion species in ecological mineral solution fertilizer, and Contents of Main Components meets 1428~2010 trace element water-soluble fertilizer standard of Ministry of Agriculture NY, have the multiple functions such as upper state, high activity, activation, catalysis crop vitality.
Description
Technical field
The present invention relates to a kind of trace element water-soluble fertilizer, especially a kind of cereal crops ecological mineral solution fertilizer and its system
Standby and application method.
Background technique
Cereal crops have upper state, high activity with ecological mineral solution fertilizer, have a variety of function such as activation, catalysis vitality
Can, it can promote crop photosynthesis, reinforce metabolism, resist disease pest and poor environment harm, increase crop yield, improve
Quality.Famous American scientist Lan Nasi ﹒ Pauling doctor claims that " all diseases cause due to a lack of trace quantity mineral substance element, not micro-
Mineral element is measured, vitamin can not be acted on enzyme, and life only vanishes into thin air ".Scientist open country island, which is set great store by military affairs or martial arts, to be thought: the micro member of life power
Element is extremely close with the life relationship of people, " it is bad to lack work, is not unlikely to survive." due to the life power element with modern
It is constantly reduced with life-related element, keeps human diseases more and more, or even cause to obtain obstinate after being ill.
It is well known that the nutrient on the person derives from food.For example iron is the necessary life power element of people, also all
Know that the comparision contents of iron in spinach are high, but the content of iron only has the spinach of the fifties in last century to contain in our spinach that eat now
The foods such as 1st/20th of iron, other vegetables and grain also have similar situation." mother that soil is food ", through chemically examining soil,
The final cause of these life power element reductions is the reduction of these life power microelements in soil in food.
The grain in China always eats yield by 32055.5 ten thousand tons of 1980, increases to 60702.6 ten thousand tons within 2014, per hectare
Per unit area yield is increased to 5892 kilograms by 2734 kilograms, increases 2 times.100 kilograms of corn kernel needs of every production are absorbed from soil
2.13 kilogram nitrogen, 1.1 kilograms of phosphorus, 1.51 kilograms of potassium.The nutrient plundered in soil is mainly supplemented by application fertilizer.
The usage amount of China's chemical fertilizer is increased to 5995.9 ten thousand tons in 2014, is increased 4.7 times by 1269.4 ten thousand tons of 1980, wherein
Nitrogenous fertilizer increases to 2392.9 ten thousand tons from 934.2 ten thousand tons, and phosphate fertilizer increases to 845.3 ten thousand tons from 273.3 ten thousand tons, and potash fertilizer is from 34.6 ten thousand tons
Increase to 641.9 ten thousand tons, compound fertilizer increases to 2115.8 ten thousand tons from 27.2 ten thousand tons.The appearance of chemical fertilizer and it is continuously increased use, promoted
It increases substantially into crop yield, has substantially met the demand of having enough to eat and wear that burgeoning population is survived substantially, meanwhile, also bring
Very important negative effect.
It is that soil nutrient is unbalance first.People when obtaining a large amount of crop products, soil not only consume a large amount of nitrogen,
Phosphorus, potassium nutrition are also consumed by a large amount of mine trace element nutrients.And the application of chemical fertilizer, only refilled merely to soil nitrogen, phosphorus,
Potassium three elements etc. fail to supplement mine trace element.Soil nutrient is unbalance to directly affect the micronutrient levels of crop products,
Leading to the quality of crop products reduces.Second is that soil physico-chemical property degenerates.The application of a large amount of chemical fertilizer, keeps soil texture hardened,
Secondary salinization aggravates, and edaphon is deficient, contaminated soil, pollutes (underground) water.Solution is to increase to soil enough
Humus, with organic agriculture fertilizer (compost) replace chemical fertilizer.
It is worth mentioning that present organic fertilizer, the organic fertilizer of the farmyard manure or plant produced either accumulated, all
It is the domestic animals and fowls excrement of the forage feed with the stalk for lacking mineral trace element or with shortage mineral trace element
It processes.Mineral trace element cannot be supplemented comprehensively with this fertilizer.
For grain with soil for this, soil is mother with rock.Therefore, it is necessary to ask for mineral trace element from natural crystal, exploitation is ground
It produces the mineral trace element new product of wide spectrum and is applied extensively, this, which has become, further increases crop yield, and
Fundamentally improve the important channel of crops quality.
Applicant once used granted patent (patent No. ZL 00121456.X, patent name: ecological mineral solution and its system
Preparation Method) production ecological mineral solution attempt be applied to agricultural aspect.But the production technology and ore raw materials system of above-mentioned patent
The standby mineral solution come out, detects through authority and finds its iron content 2.19g/l, manganese 0.15g/l, boron 0.002g/l, copper 5.1ug/ml, zinc
596.1ug/ml, molybdenum 0.02ug/ml add up to 7.96g/l, the ministry standard " NY away from Ministry of Agriculture's " trace element water-soluble fertilizer "
1428~2010 " it differs greatly.Therefore, the needs of agricultural production are unable to satisfy using prior art preparation ecological dynamic element.Mesh
Before, it needs to research and develop a kind of novel cereal crops ecological mineral solution fertilizer.
The purpose of the present invention is molten polynary mineral solution is taken out from natural crystal, in alternating intense magnetic field in original ecological mineral solution
On the Process ba- sis for shearing activation, deep research and development are carried out, significant improvement has been done to raw material and process, it is therefore intended that
The agricultural series of products of life power element, i.e. cereal crops ecological mineral solution fertilizer are developed, and provide its matched preparation to make
Use method.
To realize the above-mentioned technical purpose, the present invention adopts the following technical scheme:
A kind of cereal crops ecological mineral solution fertilizer, is liquid aqueous solution, it is characterised in that: wherein at least contain 20 kinds of gold
Belong to ion, formula material is natural crystal, and the natural crystal is medical stone, smithsonite, pyrolusite, copper concentrate and paigeite
Mixture, in the natural crystal, the weight ratio of contained component and each component are as follows: medical stone 10~20%；Smithsonite 20~
30%；Pyrolusite 20~30%；Copper concentrate 20~30%；Paigeite 5~10%, lime stone 0~10%, manufactured liquid 250
The pH of times dilution is 3.0~3.5.
Wherein, when cereal crops ecological mineral solution fertilizer is used for maize planting, medical stone, water chestnut in the natural crystal
The weight ratio of zinc ore, pyrolusite, copper concentrate and paigeite are as follows: medical stone 20%；Smithsonite 30%；Pyrolusite 20%；Copper concentrate
20%；Paigeite 10%.
Wherein, when cereal crops are used for rice cultivation with ecological mineral solution fertilizer, preferably medical stone, smithsonite, pyrolusite, copper
The weight ratio of concentrate and paigeite are as follows: medical stone 15%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Paigeite
10%；Lime stone 10%.
Further, the cereal crops with ecological mineral solution fertilizer be used for wheat planting when, preferably medical stone, smithsonite,
The weight ratio of pyrolusite, copper concentrate and paigeite are as follows: medical stone 25%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；
Paigeite 10%.
The present invention also provides the above-mentioned cereal crops preparation methods of ecological mineral solution fertilizer, it is characterised in that: will be natural
Ore is ground into powder, successively boils reaction, ageing extracting and filtering by shaking-sieving, the separation that suspends, immersion dissolution, is made
Then polynary mineral solution carries out cumulative shearing, last aged filtering, purification and filling by the ultrasonic field that alternating intense magnetic field drives
The cereal crops ecological mineral solution fertilizer of finished product is made in dress.
Preferably, the immersion dissolution is boiled in reaction, and what is used impregnates the sulfuric acid and concentration that lytic agent is concentration 98%
36% hydrochloric acid；The addition volume of the sulfuric acid of the concentration 98% is equivalent to 2 times of natural crystal volume of mixture；Concentration 36%
Hydrochloric acid addition volume it is identical as the volume of natural crystal mixture.
Preferably, the immersion dissolution is boiled in reaction, and stirring is impregnated 10~16 hours, is boiled 3~5 hours.
In addition, the production line for preparing of above-mentioned preparation method includes the pulverizer successively laid and be sequentially connected to, selection by winnowing sieve
Jarring machine boils dissolution reactor tank, filter press, ageing reactor tank, energy-gathering device, manganese sand filter, purification pot and finished pot, institute
It states to boil and is separately connected sulfuric acid storage tank and hydrochloric acid tank in dissolution reactor tank, the filter press connects Solid state fermentation system.
Finally, the present invention also provides the cereal crops prepared using the above-mentioned preparation method uses of ecological mineral solution fertilizer
Method, it is characterised in that:
(1) maize planting:
(5-7 leaf), jointing stage, trumpet period respectively spray once in seedling stage, molten with ecological mine with cereal crops per acre every time
Liquid fertilizer 100ml is spraying to water 60L；
(2) rice cultivation:
Rice seedling bed application method: respectively applying once in 1 heart stage of 1 leaf, 1 heart stage of 2 leaf, and each every square metre of seedbed is used with cereal crops
Ecological mineral solution fertilizer 1ml sprinkles 1000 times of water and pours；
Honda application method: respectively spraying once in period of seedling establishment, jointing stage, boot stage, every time per acre with cereal crops ecology
Mineral solution fertilizer 100ml is spraying to water 60L；
(3) wheat is planted:
It is respectively sprayed once in tillering stage, jointing stage, pustulation period, every time per acre with cereal crops ecological mineral solution fertilizer 100ml
It is spraying to water 60L.
Compared with prior art, the present invention has integrally made following two big improvement:
One, variety of raw material and formula design are adjusted
The present invention carries out screening study to basic material, selected medical stone rich in mineral trace element, smithsonite,
As basic formula material, preparation is plain rich in mineral trace element agricultural type ecological dynamic for pyrolusite, copper concentrate, paigeite,
Fundamentally material base is provided to solve the problems, such as that micronutrient levels is low；
Wherein, smithsonite mainly provides Zn-ef ficiency, and the zinc in smithsonite can partially be replaced by iron or manganese, or a small amount of
Magnesium, calcium, cadmium, copper, replaced cobalt or lead, it is similar with most carbonate minerals, be dissolved in hydrochloric acid and bubble can be generated.Smithsonite
Belong to that hardness is higher, the biggish one kind of specific gravity in calcite group；
Pyrolusite, main component are manganese dioxide, are a kind of common manganese minerals, contain manganese 63.19%, be important manganese ore
Stone.The general feel manganese ore of Miao Autonomous County of Songtao of Tong Ren District of Guizhou Province city verifies 1.92 hundred million tons of manganese resource amount, can be rated as Asia first；
Copper concentrate is the concentrate that low-grade cupric tcrude ore reaches certain mass index by ore-dressing technique processing, can be straight
It connects for smeltery's copper metallurgy.Copper concentrate is largely original sulfides oxygenolysis again through secondary mineral made of reduction, is contained
Copper component is high, is most important copper metallurgy ore.Yunnan Province of China Dongchuan copper etc. has a large amount of copper concentrates；
Paigeite is the raw material for refining boron, is rich in boron and iron；
Lime stone calcium constituent rich in, there are also silicon, iron, magnesium, aluminium etc.；
Medical stone is a kind of natural silicate mineral, and main chemical compositions are inorganic alumino-silicates, including
SiO2、Al2O3、Fe2O3、FeO、MgO、CaO、K2O、Na2O、TiO2、P2O5, MnO etc., also containing the member of whole constants needed for animal
Element, microelement and rare earth element, such as K, Na, Ca, Mg, Cu, Mo, as many as about 58 kinds.
Due to using copper, iron, manganese, zinc, crude boron stone on the basis of medical stone, it is ensured that the source of this 5 kinds of elements, to mention
Copper in high ore preparation ecological dynamic element, iron, manganese, zinc, boron element content and reach the Ministry of Agriculture " trace element water-soluble fertilizer "
Ministry standard " NY1428~2010 " requirement index, provide material base guarantee.
Formula design on, creatively select medical stone 10~20%, smithsonite 20~30%, pyrolusite 20~
30%, copper concentrate 20~30%, 5~10% weight ratio of paigeite ore configured, the ecological mine of the cereal crops of preparation
Solution fertilizer in copper, iron, manganese, zinc, boron, molybdenum element content be improved, reached the requirement of Ministry of Agriculture's ministry standard, i.e. copper
The sum of Cu+ iron Fe+ manganese Mn+ zinc Zn+ boron+molybdenum Mu content Da Dao≤100g/L.The highest content of microelement of the present invention reaches
144.5g/L。
Two, the improvement of production technology
(1) soak type and concentration are adjusted: cooperating 36% concentrated hydrochloric acid, that is, high concentration strong acid with 98% concentrated sulfuric acid of high concentration
Mixing is used as soaking solution, and the micronutrient levels in product can be directly adjacent to and reach the requirement of Ministry of Agriculture's ministry standard, and
If using the prior art dilute hydrochloric acid of 2~10% concentration, dilute sulfuric acid, citric acid one of which dilute concentration acid soak ore,
Water-soluble fertilizer is prepared in the ore for wherein putting into same ratio, is detected, the results showed that the concentration of soaking solution is too dilute, micro
Constituent content is seldom, and needs concentration, is unable to reach the requirement of Ministry of Agriculture's ministry standard；
(2) change and stir immersion and boiling time: stirring is impregnated 3~5 hours, it is small to be adjusted to stirring immersion 10~16
When；It by boiling time by 2~5 hours, is adjusted to boil 3~5 hours, the reaction time lengthens；It is proved through repetition test, extension is stirred
Immersion reaction and boiling time are mixed, can just miberal powder be made sufficiently to dissolve, effectively improve micronutrient levels.
Effect ingredient and the content such as table 1 of cereal crops of the present invention ecological mineral solution fertilizer:
Effect ingredient and content of 1. cereal crops of table ecological mineral solution fertilizer
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 30000~35000 | Iron | 15000~23000 |
| Manganese | 19000~23000 | Zinc | 29000~34000 |
| Calcium | 300~400 | Cobalt | 5~10 |
| Phosphorus | 1000~1450 | Nickel | 5~10 |
| Magnesium | 3200~4200 | Molybdenum | 800~1000 |
| Potassium | 1400~2000 | Lithium | 300~400 |
| Sodium | 150~200 | Vanadium | 40~60 |
| Selenium | 30~50 | Silicon | 360~480 |
| Barium | 180~230 | Titanium | 800~1400 |
| Aluminium | 11000~15000 | Boron | 3000~4000 |
It is detected through Beijing fertilizer quality supervision and inspection station and National Geology test center, this mineral solution minerals are micro
The content of element meets ministry standard " NY1428~2010 " regulation of " trace element water-soluble fertilizer " of the Ministry of Agriculture, copper Cu+ iron
The sum of Fe+ manganese Mn+ zinc Zn+ boron+molybdenum Mu content Da Dao≤100g/L.In the report of spectrum Buddhist nun's test, copper+iron+manganese+zinc+boron
+ molybdenum content adds up to 153.47g/L.Cu >=20g/L in product of the present invention, Fe >=5g/L, Mn >=30g/L, Zn >=44g/L, B >=
The highest content of 2g/L, microelement reach 144.5g/L.
Compared with prior art, the present invention has following technical advantage:
One, cereal crops in ecological mineral solution fertilizer dissolved with promote during life chemistry catalysis, activation it is dynamic
Power groups of elements, they exist all in the form of water-complex ion, e.g., Cu++,Fe++,Mn++, Zn++,Mo++,Ti++Deng contain d rail
The element ion in road, these ions can be acted on hydrone, form chelation structure, it is made to have comparatively gentle surface charge close
Degree；
Two, these elements have d orbital electron or unoccupied orbital, when above-mentioned element reaches a certain concentration, electronics are caused to turn
It moves, generates hydroxyl radical free radical, can degrade toxic organic compound, precipitation of heavy metals；
Three, under the conditions of oxygen concentration is higher, ecological oxygen is automatically generated, enhances the metabolism of crop；
Four, cereal crops ecological mineral solution fertilizer has upper state, and the cascaded structure of water clusters is cut off, and forms small point
Sub- water is easily absorbed by plant roots cauline leaf；
Five, the mineral trace element content in product, cereal crops mine contained by ecological mineral solution fertilizer can be effectively improved
Substance microelement type is more, the linear water aggressiveness of the cut formation of metal cation with the affine scale value of different charges
Length, regularity are different, serve to different cell bodies different.These elements enter in plant can accomplish it is each department its
Duty, metabolic balance, robust plant, leaf color is beautiful, and mouthfeel improves, quality improving；
Six, application method is simple, easy to promote and utilize；
Seven, obvious effect of increasing production:
By the extensive experimentation and application to cereal crops with ecological mineral solution fertilizer, can supplement crop growthing development must
The various trace elements needed, can be improved crop yield, obvious effect of increasing production, while improving crop quality.It is mentioned from various regions
The test report of confession is seen, using cereal crops ecological mineral solution fertilizer, wheat averagely increases production 7.4%, highest volume increase 20.4%；Water
Rice seedlings field energy strengthening root key seedling, prevents and treats damping-off effect up to 95%；Rice on honda, which can be improved, resists chilling injury ability, average to increase
18.6% is produced, highest volume increase 28.6%；Corn is sprayed with the jointing stage in seedling stage, averagely increases production 7.9%, highest volume increase 12.6%；
Soybean is sprayed in early flowering season and fruiting period, averagely increases production 10.8%, highest volume increase 20.9%.
1. rice test has been done in the village Xin Jia of the Lishu County township little Kuan in Jilin Province clay fertilizer station, in period of seedling establishment, jointing stage, pustulation period
A respectively cereal crops of sprinkling ecological mineral solution fertilizer, the rice performance of sprinkling is turned green, and fast, tiller is early, growth is vigorous, is supplying water
It is showed in the insufficient situation of fertilizer especially prominent.It is fast, mature early that early jointing, early booting, grouting are showed during reproductive growth
2-3 days, increase mass of 1000 kernel, volume increase 27.5%；
2. the county Sui Ling of Heilongjiang Province agricultural technology extension center carries out sprinkling cereal crops ecological mineral solution in corn field
Fertilizer test, respectively sprays once respectively in Maize at Seedling Stage, jointing stage, per acre with cereal crops ecological mineral solution fertilizer 100ml to water
500 times, foliage spray is carried out, effect of increasing production reaches 14.6-18.8%；
3. agricultural technology extension master station of autonomous prefecture of Yanbian, Jilin Province Korean nationality 2014 is in Yanji southern exposure Chuan Zhen too East Village
The cereal crops ecological mineral solution fertilizer Applied D emonstration of 75 mu of rice has been carried out, has surveyed 533 kilograms of per mu yield, has been increased production than conventional cultivation
16.5%；
4, prolong the nuisanceless Special Agriculture Product Co., Ltd in side Dongcheng will using this water-soluble fertilizer plantation organic rice respectively at
2009 and the product quality inspection of 2010 Nian Song Korean Autonomous Prefecture of Yanbian are examined, and in rice kernel detection report, apply mineral solution
The organic rice of fertilizer is more much higher than the content of mineral substances of unused organic rice, wherein manganese 9.5 > 6.3；Lithium 0.08 > 0.002；Zinc
15.2>9.1；Selenium 0.03 > 0.005；Cobalt 0.07 > 0.02；Iron 2.7 < 2.8；Calcium 95.5 > 54.2；Chromium 0.53 > 0.04.Unit: μ g/
kg。
In addition, the water-soluble fertilizer that this patent is related to is also very significant for the effect of ginseng.Ginseng is well-known " northeast
One of Triratna ", in decades, ginseng industry development are swift and violent, make can cultivated ginseng forest land resource it is almost exhausted, in old ginseng 30
It is the final conclusion for having descended how many years that ginseng cannot be planted in year again, and it is extremely urgent that renovation and utilization old ginseng plants ginseng, and ginseng connects
Work is the significant technology issues that could not be also fully solved in the world.Applicant investigated and seeked advice from the spot both at home and abroad it is famous
On the basis of experts and scholars, cereal crops are used in the village Shi Miao of Ji'an City linen thread township of Jilin Province in autumn in 2011 to autumn in 2013
Old ginseng ginseng continuous cropping test is carried out with ecological mineral solution fertilizer, ginseng survival rate reaches 70% or more after 2 years, achieves breakthrough
The achievement of property.
Detailed description of the invention
By made detailed description in conjunction with the following drawings, above-mentioned and/or other aspects of the invention and advantage will become
It becomes apparent from and is easier to understand, these attached drawings are only schematical, are not intended to limit the present invention, in which:
Fig. 1 is cereal crops ecological mineral solution fertilizer preparation process flow schematic diagram.
Appended drawing reference: 1- pulverizer, 2- selection by winnowing sieve jarring machine, 3- boil dissolution reactor tank, 4- sulfuric acid storage tank, 5- hydrochloric acid
Storage tank, 6- filter press, 7- ageing reactor tank, 8- energy-gathering device, 9- manganese sand filter, 10- purification pot, 11- finished pot, 12- are useless
Slag disposal system.
Specific embodiment
Hereinafter, cereal crops of the invention ecological mineral solution fertilizer and its preparation application method are described with reference to the accompanying drawings
Embodiment.
The embodiment recorded herein is specific specific embodiment of the invention, for illustrating design of the invention,
Be it is explanatory and illustrative, should not be construed as the limitation to embodiment of the present invention and the scope of the invention.Except what is recorded herein
Outside embodiment, those skilled in the art can also based on the claim of this application book and specification disclosure of that using aobvious and
The other technical solutions being clear to, these technical solutions include using any obvious to making for the embodiment recorded herein
The technical solution of substitutions and modifications.
The present invention relates to a kind of cereal crops ecological mineral solution fertilizer, at least contain 20 metal ion species, and formula is former
Material is natural crystal, and the natural crystal is the mixture of medical stone, smithsonite, pyrolusite, copper concentrate and paigeite.As this
The optimal technical scheme of invention, in the natural crystal, raw material components and each component weight ratio are as follows: medical stone 10~20%；Water chestnut
Zinc ore 20~30%；Pyrolusite 20~30%；Copper concentrate 20~30%；Paigeite 5~10%, lime stone 0~10%.
If Fig. 1 is cereal crops ecological mineral solution fertilizer preparation process flow schematic diagram.It is prepared according to preparation process flow
Cereal crops ecological mineral solution fertilizer, uses pulverizer 1 by days such as medical stone, smithsonite, pyrolusite, copper concentrate, paigeites first
Right ore is ground into powder, chooses 60 mesh powder through selection by winnowing sieve jarring machine 2, is respectively then medical stone 10 by weight percent
~20%, the ratio investment of smithsonite 20~30%, pyrolusite 10~20%, copper concentrate 20~30%, paigeite 5~10% is boiled
It is mixed in boil-off solution reactor tank 3, is added and to be equivalent to 2 times of ore volume of the sulfuric acid of concentration 98% and isometric with natural crystal
The hydrochloric acid of concentration 36% is added in reactor tank 3 by acid storage tank 4,5, and stirring is impregnated 10~16 hours, is boiled 3~5 hours, is carried out
Dissolution is separated by solid-liquid separation by filter press 6, and solution is packed into ageing reactor tank 7 and is aged, the high-energy ultrasonic driven by alternating intense magnetic field
Field 8, the ball of string structure for shearing, smashing cereal crops ecological mineral solution fertilizer stoste improves energy state, by 8 mistake of manganese sand filter
Filter, purification pot 9 are purified, are sent to finished product storage tank 10, line 11 to be filled is filling.Have below with reference to embodiment to the content of present invention
Body explanation:
Embodiment 1
Corn dedicated cereal crops ecological mineral solution fertilizer is prepared, with pulverizer 1 by medical stone, smithsonite, pyrolusite, copper
The natural crystals such as concentrate, paigeite are ground into powder, choose 60 mesh powder through selection by winnowing sieve jarring machine 2, then by weight % points
Not Wei medical stone 20%, smithsonite 30%, pyrolusite 20%, copper concentrate 20%, paigeite 10% ratio investment boils dissolution
Mixed in reactor tank 3, be added be equivalent to 2 times of ore volume concentration 98% sulfuric acid and the isometric concentration 36% of ore salt
Acid is added in reactor tank 3 by acid storage tank 4,5, and stirring is impregnated 10~16 hours, is boiled 3~5 hours, is dissolved, by filters pressing
Machine 6 is separated by solid-liquid separation, and solution is packed into ageing reactor tank 7 and is aged, the high-energy ultrasonic field energy-gathering device 8 driven by alternating intense magnetic field,
The ball of string structure for shearing, smashing cereal crops ecological mineral solution fertilizer stoste improves energy state, filters through manganese sand filter 9, purifies
Tank 10 purifies, and send to finished product storage tank 11, line to be filled is filling.Effect ingredient of corn dedicated cereal crops ecological mineral solution fertilizer
And content such as table 2:
Effect ingredient and content of 2. corn of table dedicated cereal crops ecological mineral solution fertilizer
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 19000~25000 | Iron | 7600~12000 |
| Manganese | 28000~36000 | Zinc | 48000~56000 |
| Calcium | 250~450 | Sodium | 260~320 |
| Phosphorus | 900~1500 | Nickel | 15~30 |
| Magnesium | 2500~4000 | Molybdenum | 800~1000 |
| Potassium | 2400~3700 | Lithium | 80~400 |
| Selenium | 30~50 | Silicon | 360~480 |
| Barium | 180~230 | Titanium | 800~1400 |
| Aluminium | 11000~15000 | Boron | 3000~4000 |
The dedicated cereal crops of corn prepared by the present invention are micro rich in copper, iron, manganese, zinc, boron, molybdenum etc. with ecological mineral solution fertilizer
Element reaches technical indicator of the Ministry of Agriculture about trace element water-soluble fertilizer, and wherein the content of Zn-ef ficiency is higher, helps to prevent and treat
The generation and sprawling of the grey seedling diseases of corn as caused by excessive application of phosphoric acid diammonium.
Embodiment 2
Rice dedicated cereal crops ecological mineral solution fertilizer is prepared, with pulverizer 1 by medical stone, smithsonite, pyrolusite, copper
The natural crystals such as concentrate, paigeite, lime stone are ground into powder, 60 mesh powder are chosen through selection by winnowing sieve jarring machine 2, then by wheat
Meal stone 15%, smithsonite 25%, pyrolusite 20%, copper concentrate 20%, paigeite 10%, the ratio (weight %) of lime stone 10%
Investment is boiled to be mixed in dissolution reactor tank 3, is added and is equivalent to 2 times of ore volume of 98% sulfuric acid of concentration and isometric dense of ore
36% hydrochloric acid to be spent to be added in reactor tank 3 by acid storage tank 4,5, stirring is impregnated 10~16 hours, and it boils 3~5 hours, is dissolved,
It is separated by solid-liquid separation by filter press 6, solution is packed into ageing reactor tank 7 and is aged, and the high-energy ultrasonic field driven by alternating intense magnetic field is poly-
Energy device 8, the ball of string structure for shearing, smashing cereal crops ecological mineral solution fertilizer stoste improves energy state, by manganese sand filter 9
Filtering, purification pot 10 are purified, are sent to finished product storage tank 11, line to be filled is filling.Rice dedicated cereal crops ecological mineral solution fertilizer
The effect of ingredient and content such as table 3:
Effect ingredient and content of 3. rice of table dedicated cereal crops ecological mineral solution fertilizer
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 18000~25000 | Iron | 8000~14000 |
| Manganese | 34000~41000 | Zinc | 48000~52000 |
| Calcium | 1200~1500 | Sodium | 260~320 |
| Phosphorus | 1000~1500 | Nickel | 15~30 |
| Magnesium | 2000~4000 | Molybdenum | 800~1000 |
| Potassium | 2000~3000 | Lithium | 180~400 |
| Selenium | 30~50 | Silicon | 1800~2800 |
| Barium | 200~230 | Titanium | 1200~1400 |
| Aluminium | 8800~12000 | Boron | 4000~6000 |
The dedicated cereal crops of rice prepared by the present invention are not only rich in copper, iron, manganese, zinc, boron, molybdenum etc. with ecological mineral solution fertilizer
Microelement reaches technical indicator of the Ministry of Agriculture about trace element water-soluble fertilizer, and wherein the content of element silicon is higher, facilitates
The growth and development and resistant to lodging, disease resistance for improving rice, to improve yield.
Embodiment 3
Wheat dedicated cereal crops ecological mineral solution fertilizer is prepared, with pulverizer 1 by medical stone, smithsonite, pyrolusite, copper
The natural crystals such as concentrate, paigeite, lime stone are ground into powder, 60 mesh powder are chosen through selection by winnowing sieve jarring machine 2, then by wheat
Meal stone 25%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Ratio (weight %) investment of paigeite 10% is boiled molten
It is mixed in solution reactor tank 3, is added and is equivalent to 2 times of ore volume of 98% sulfuric acid of concentration and isometric 36% hydrochloric acid of concentration of ore
It is added in reactor tank 3 by acid storage tank 4,5, stirring is impregnated 10~16 hours, is boiled 3~5 hours, is dissolved, by filter press 6
It is separated by solid-liquid separation, solution is packed into ageing reactor tank 7 and is aged, and the high-energy ultrasonic field energy-gathering device 8 driven by alternating intense magnetic field is cut
The ball of string structure for cutting, smashing cereal crops ecological mineral solution fertilizer stoste improves energy state, filters by manganese sand filter 9, purification
Tank 10 purifies, and send to finished product storage tank 11, line to be filled is filling.Effect ingredient and content such as table of the dedicated ecological mineral solution fertilizer of wheat
4:
Effect ingredient and content of 4. wheat of table dedicated cereal crops ecological mineral solution fertilizer
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 16000~24000 | Iron | 9000~12000 |
| Manganese | 34000~41000 | Zinc | 42000~52000 |
| Calcium | 400~500 | Sodium | 260~360 |
| Phosphorus | 1000~1500 | Nickel | 25~50 |
| Magnesium | 2600~4000 | Molybdenum | 1800~3000 |
| Potassium | 1500~3000 | Lithium | 280~400 |
| Selenium | 30~60 | Silicon | 380~580 |
| Barium | 200~280 | Titanium | 9800~1400 |
| Aluminium | 9800~15000 | Boron | 4000~6000 |
Cereal crops prepared by the present invention, rich in microelements such as copper, iron, manganese, zinc, boron, molybdenums, are reached with ecological mineral solution fertilizer
Technical indicator to the Ministry of Agriculture about trace element water-soluble fertilizer is widely used in Cereal, legume and tuber crops.
In addition, sum up during the experiment cereal crops with ecological mineral solution fertilizer it is preferable to use methods, see the table below 5:
It is preferable to use methods with ecological mineral solution fertilizer for 5. cereal crops of table
Points for attention:
(1) this product cannot replace chemical fertilizer.
(2) this product cannot with combined use of pesticides, with spray insecticide interval 5 days it is used above.
(3) this product is nontoxic to people, animal, and use is safe.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention.The present invention can also make a variety of
Content mineral solution trace element water-soluble fertilizer, is widely used in melon and fruit class, solanaceous vegetables, root vegetables and the various fruits and vegetables of leaf vegetables, can also
Foliage spray and pouring root for fruit tree etc..Any modification done within the spirit and principles of the present invention, equivalent replacement,
Improve etc., it should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of cereal crops ecological mineral solution fertilizer, is liquid aqueous solution, it is characterised in that: its formula material is natural mine
Stone, contained component and the weight ratio of each component in the natural crystal are as follows: 10~20% medical stones, 20~30% smithsonite, 20~
30% pyrolusite, 15~20% copper concentrates, 5~10% paigeites and 0~10% lime stone；250 times of dilutions of liquid, pH is made
It is 3.0~3.5.
2. cereal crops according to claim 1 ecological mineral solution fertilizer, it is characterised in that: the cereal crops ecology
Mineral solution fertilizer is used for maize planting, medical stone, smithsonite, pyrolusite in the natural crystal, the weight of copper concentrate and paigeite
Than are as follows: medical stone 20%；Smithsonite 30%；Pyrolusite 20%；Copper concentrate 20%；Paigeite 10%.
3. cereal crops according to claim 1 ecological mineral solution fertilizer, it is characterised in that: the cereal crops ecology
Mineral solution fertilizer is used for rice cultivation, the weight of medical stone, smithsonite, pyrolusite, copper concentrate and paigeite in the natural crystal
Than are as follows: medical stone 15%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Paigeite 10%；Lime stone 10%.
4. cereal crops according to claim 1 ecological mineral solution fertilizer, it is characterised in that: the cereal crops ecology
Mineral solution fertilizer is for planting wheat, the weight of medical stone, smithsonite, pyrolusite, copper concentrate and paigeite in the natural crystal
Than are as follows: medical stone 25%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Paigeite 10%.
5. the preparation method of cereal crops ecological mineral solution fertilizer, feature described in a kind of claim 1-4 any one exist
In: natural crystal is ground into powder, successively by shaking-sieving, suspend separation, impregnate dissolution boil reaction, ageing extracting and
Filtering, is made polynary mineral solution, and then the ultrasonic field by alternating intense magnetic field driving carries out cumulative shearing, last aged mistake
Filter, purification and filling, are made the cereal crops of finished product ecological mineral solution fertilizer.
6. the cereal crops according to claim 5 preparation method of ecological mineral solution fertilizer, it is characterised in that: the immersion
Dissolution is boiled in reaction, and what is used impregnates the hydrochloric acid of the sulfuric acid that lytic agent is concentration 98% and concentration 36%；The sulphur of the concentration 98%
The addition volume of acid is equivalent to 2 times of natural crystal volume of mixture；The addition volume and natural crystal of the hydrochloric acid of concentration 36% are mixed
The volume for closing object is identical.
7. the cereal crops according to claim 5 preparation method of ecological mineral solution fertilizer, it is characterised in that: the immersion
Dissolution is boiled in reaction, and stirring is impregnated 10~16 hours, is boiled 3~5 hours.
8. according to the preparation method of ecological mineral solution fertilizer of cereal crops described in claim 5~7 any one, feature exists
In: applied in preparation prepare production line include successively lay and be sequentially connected to pulverizer (1), selection by winnowing sieve jarring machine (2),
Boil dissolution reactor tank (3), filter press (6), ageing reactor tank (7), energy-gathering device (8), manganese sand filter (9), purification pot
(10) and finished pot (11), described boil is separately connected sulfuric acid storage tank (4) and hydrochloric acid tank (5) in dissolution reactor tank (3), described
Filter press (6) connects Solid state fermentation system (12).
9. a kind of user of cereal crops prepared using preparation method according to any one of claims 8 ecological mineral solution fertilizer
Method, it is characterised in that:
(1) maize planting:
5-7 leaf, jointing stage, trumpet period respectively spray once in seedling stage, every time per acre with cereal crops ecological mineral solution fertilizer
100ml is spraying to water 60L；
(2) rice cultivation:
Rice seedling bed application method: respectively applying once in 1 heart stage of 1 leaf, 1 heart stage of 2 leaf, each every square metre of seedbed cereal crops ecology
Mineral solution fertilizer 1ml sprinkles 1000 times of water and pours；
Honda application method: respectively spraying once in period of seedling establishment, jointing stage, boot stage, molten with ecological mine with cereal crops per acre every time
Liquid fertilizer 100ml is spraying to water 60L；
(3) wheat is planted:
It is respectively sprayed once in tillering stage, jointing stage, pustulation period, every time per acre with cereal crops ecological mineral solution fertilizer 100ml to water
60L is spraying.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273816A (en) * | 2000-04-28 | 2000-11-22 | 北京金山四博科技开发有限公司 | Activated and concentrated liquid containing minerals and race elements and preparing process thereof |
| CN1335272A (en) * | 2000-07-24 | 2002-02-13 | 北京金山生态动力素制造有限公司 | Ecological mineral solution and its prepn |
| CN101503321A (en) * | 2009-03-12 | 2009-08-12 | 王君信 | Method for preparing microelement in compound fertilizer |
| CN102992841A (en) * | 2012-11-13 | 2013-03-27 | 阮喜英 | Natural microelement and rare earth element-containing plant nutrient solution and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273816A (en) * | 2000-04-28 | 2000-11-22 | 北京金山四博科技开发有限公司 | Activated and concentrated liquid containing minerals and race elements and preparing process thereof |
| CN1335272A (en) * | 2000-07-24 | 2002-02-13 | 北京金山生态动力素制造有限公司 | Ecological mineral solution and its prepn |
| CN101503321A (en) * | 2009-03-12 | 2009-08-12 | 王君信 | Method for preparing microelement in compound fertilizer |
| CN102992841A (en) * | 2012-11-13 | 2013-03-27 | 阮喜英 | Natural microelement and rare earth element-containing plant nutrient solution and preparation method thereof |
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