CN106380988A - Anti-corrosion paint for aging-resistant environment-friendly solar water storage box - Google Patents
Anti-corrosion paint for aging-resistant environment-friendly solar water storage box Download PDFInfo
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- CN106380988A CN106380988A CN201610906371.5A CN201610906371A CN106380988A CN 106380988 A CN106380988 A CN 106380988A CN 201610906371 A CN201610906371 A CN 201610906371A CN 106380988 A CN106380988 A CN 106380988A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses anti-corrosion paint for an aging-resistant environment-friendly solar water storage box. The anti-corrosion paint is prepared from the following raw materials including poly(2-(Dimethylamino)ethyl methacrylate), high-chlorinated polyethylene resin, polyurethane, zinc acrylate resin, water-based acrylic emulsion, polypropylene acrylamide solution, chloroparaffin, aluminum oxide, bentonite, putty powder, polyvinyl alcohol fiber, boron nitride, hydroxypropyl methylcellulose, polyester fiber, a surfactant, a coupling agent, a degasifying agent, a flatting agent, a dispersing agent, a wetting agent, a diluting agent, an adhesion force promoter, a catalyst, an initiator, a pattern making agent, a toughening agent, a gloss enhancer, an antifoaming agent, a tackifier, a curing agent, an anti-corrosion agent, an antioxidant, a light stabilizer, a heat stabilizer, an ultraviolet light absorber, a thickening agent, a coalescing agent and a fire retardant. The paint provided by the invention has the advantages of excellent adhesion force, excellent physical performance, good water-resistant performance, aging-resistant performance, toughness, impact resistance, non-toxicity and environment-friendly effect, and can effectively prolong the service life of a carbon steel water box.
Description
Technical field
The invention belongs to coating preparation technology neck is and in particular to a kind of aging-resisting type environmental protection anti-corrosion painting of solar energy water storage tank
Material.
Background technology
The utilization technical field of solar energy, is broadly divided into Photo-thermal technology application and photovoltaic application.Photo-thermal technology application technology mainly has too
Sun can hot-water heating system, heating refrigeration system, heat generating system etc.；Photovoltaic application technology includes solar power system.China has
Abundant solar energy resources, therefore Solar use association area obtain the support energetically of country, and solar water heater is as too
A kind of industry that sun can utilize, becomes most widely used in solar energy heat utilization, the most rapid field of industrialized development.China
70% that total amount promoted by Liang Zhan world solar water heater promoted by solar water heater, exceedes the summation that American-European countries promotes for 10 years,
It is " world's solar energy production and application total amount first big country ".
Thermal storage water tank is main devices using solar energy, and the development that its development represents whole water heater is gone through
Journey, but its using process in the middle of exposed day by day go out its drawback；Lead to the generation of electrochemical corrosion.Ordinary carbon steel storage heat
Water tank can form flakey oxide skin in the operations such as high temperature hot rolling, but the coefficient of expansion of this oxide skin is less than steel；In addition water
Case is chronically in the hot water environment that 30-80 DEG C of temperature becomes, and is vulnerable to the corrosive environment such as water and oxygen in water, chlorine molecule or ion
The erosion of medium and produce micro-crack, the consequence such as lead to steel plate local perforations leak, water tank to be scrapped, the immediate cause of its problem is just
It is the corrosive environment directly contact such as steel plate and hot water.
Method using anticorrosive coating can not only be separated above-mentioned corrosive medium and plain steel effectively, and coating
Can act on stoping or to delay the corrosion of water tank by shielding, inhibition and passivation, electrochemical protection etc..This method economically than
Adopt merely stainless steel water tank economy, the weld defect of stainless steel water tank stack shell longitudinal seam presence, magnesium rod can be overcome simultaneously again to disappear
The shortcomings of consumption is too fast, replacing is frequent.Facts have proved：In numerous anticorrosion techniques, high using external coating corrosion-resistant ratio
Reach 65%, be to be acknowledged as most economical, effective, universal anti-corrosion method at present.If but imperfection, painting design are processed to matrix
It is improper to select, coating meeting premature failure, does not reach preferable protection effect and causes certain economic loss and cannot make up.Mesh
Before, existing document report adopts organic titanium, polyurethane rock crystal paint, LKF-1 glass-flake coating, laccol aluminium powder Berlin black, rubber and plastic
The anti-corrosive organic coatings such as composite coating, but underfilm corrosion can be caused after water tank comes into operation earlier (bubbling, stripping, wet
Adhesive force is lost) and make water tank retired in advance, its protection effect is not good.For this reason, research is applied to carbon steel in hot water environment
The anticorrosive paint of water tank is particularly important, and has realistic meaning.
Content of the invention
The present invention provides a kind of aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, to solve traditional coating for carbon
Reinforced plastic water container is anti-corrosion, easily causes bubbling, and the problems such as resistance to water, resistance to ag(e)ing, pliability, poor impact resistance.The present invention's
Coating had both had excellent adhesive force and mechanical property, had excellent resistance to water, resistance to ag(e)ing, pliability and impact resistance again
Property, and asepsis environment-protecting, can effectively delay the service life of carbon steel water tank, be more beneficial for the popularization of solar water heater.
For solving above technical problem, the present invention employs the following technical solutions：
A kind of aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, in units of weight, including following raw material：Poly- methyl-prop
Olefin(e) acid dimethylaminoethyl 160-205 part, HCPE 46-62 part, polyurethane 32-44 part, zinc acrylate resin
22-30 part, aqueous acrylic emulsion 40-49 part, polyacrylic acid/acrylamide solution 32-38 part, chlorinated paraffin 25-42 part, three oxygen
Change two aluminium 5-9 parts, bentonite 4-7 part, powder of lacquer putty for use on 6-10 part, vinal 5-9 part, boron nitride 4-6 part, hydroxypropyl methyl
Cellulose 5-9 part, polyester fiber 3-6 part, surfactant 0.4-0.8 part, coupling agent 0.3-0.5 part, degasser 0.3-0.5
Part, levelling agent 0.3-0.5 part, dispersant 0.4-0.7 part, wetting agent 0.2-0.3 part, diluent 0.2-0.4 part, adhesive force promote
Agent 0.4-0.6 part, catalyst 0.2-0.3 part, initiator 0.2-0.4 part, hang down line agent 0.4-0.7 part, toughener 0.3-0.6 part,
Optical brightener 0.4-0.8 part, defoamer 0.5-0.7 part, tackifier 0.3-0.4 part, curing agent 0.9-1.6 part, preservative 0.4-0.6
Part, antioxidant 0.3-0.5 part, light stabilizer 0.2-0.3 part, heat stabilizer 0.1-0.2 part, ultra-violet absorber 0.3-0.4 part,
Thickener 0.4-0.7 part, coalescents 0.4-0.6 part, fire retardant 1.4-1.6 part；
Described surfactant is surfactant TRITONCF-10；
Described coupling agent is silane coupler；
Described degasser is stearic acid；
Described levelling agent is polyether polyester azo polyether polyeste；
Described dispersant is dispersant NC；
Described wetting agent is wetting agent CF-10；
Described diluent is 515- diluent；
Described preservative is preservative KY；
Described antioxidant is antioxidant 2246；
Described light stabilizer is light stabilizer 3853；
Described heat stabilizer is Dythal；
Described ultra-violet absorber is septichen phenyl ester；
Described thickener is xanthans；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：2,4- mesitylenic acid ethyl ester 32-56 parts, polyurethane
15-28 part, APP 13-18 part, pentaerythrite 9-16 part, urea 8-14 part, aluminium hydroxide 5-9 part, antimony oxide 9-
15 parts, manganese oxide 4-8 part, atlapulgite 7-13 part, bleeding agent 0.9-1.4 part, synergist 0.5-0.8 part；
Described bleeding agent is AEO
Described synergist is ammonium sulfate；
The preparation method of described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, comprises the following steps：
S1：By polymethylacrylic acid dimethylaminoethyl, HCPE, polyurethane, zinc acrylate resin, chlorination stone
Wax, alundum (Al2O3), bentonite, powder of lacquer putty for use on, vinal, boron nitride, hydroxypropyl methyl cellulose, polyester fiber, table
Face activating agent, coupling agent, degasser, levelling agent, dispersant, wetting agent, diluent, adhesion promoter, catalyst, initiator
Mixing, is 148-180W in microwave power, and temperature is 90-96 DEG C, and rotating speed is to stir 2-2.8h under 2300-3600r/min, is obtained
Mixture a；
S2：Aqueous acrylic emulsion, polyacrylic acid/acrylamide solution, hang down line agent, increasing is added in the mixture a being obtained to step S1
Tough dose, optical brightener, defoamer, tackifier, be 162-196W in microwave power, temperature be 112-128 DEG C, rotating speed be 400-
2.3-4.7h, prepared mixture b is stirred under 600r/min；
S3：Curing agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, thickener, coalescents, fire retardant, are 130-226W in microwave power, and temperature is 115-118 DEG C, and rotating speed is
1.8-3.2h, prepared mixture c is stirred under 200-400r/min；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, water 180-250 part are added in microwave reactor, stirs under speed of agitator is for 300-500r/min
6-10min, prepared mixture A；
S32：2,4- mesitylenic acid ethyl ester, polyurethane, pentaerythrite, urine is added in the mixture A being obtained to step S31
Element, aluminium hydroxide, antimony oxide, manganese oxide, atlapulgite, bleeding agent, synergist, are 400-600r/ in speed of agitator
Min, microwave power is 150-220W, and temperature stirs 1.6-2.4h, prepared mixture B at being 86-90 DEG C；
S33：The mixture B that step S32 is obtained is cooled to after room temperature, sediment is filtered, is 3000-5000r/ in rotating speed
Under min, centrifugal drying is to water content≤3%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112-118 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：140-200 mesh sieve is crossed in the pelletizing that step S5 is obtained after pulverizing, prepared aging-resisting type environmental protection solar energy water storage tank is used
Anticorrosive paint.
Further, described adhesion promoter is colourless cobalt.
Further, described catalyst is platinum catalyst.
Further, described initiator is azo two isobutyric acid（Acrylic acid ethylene glycol）Ester.
Further, described vertical line agent is the line agent ART-300 that hangs down.
Further, described toughener is MBS terpolymer.
Further, described optical brightener is optical brightener gz-56.
Further, described defoamer is defoamer NXZ.
Further, described tackifier are propyl trimethoxy silicane.
Further, described curing agent is epoxylite curing agent.
The invention has the advantages that：
The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent resistance to water, resistance to ag(e)ing, pliable and tough again
Property and resistance to impact, and asepsis environment-protecting, can effectively delay the service life of carbon steel water tank, be more beneficial for solar water heater
Promote.
Specific embodiment
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the present invention's
Protection domain, but do not limit the scope of the invention.
In an embodiment, described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, in units of weight, including with
Lower raw material：Polymethylacrylic acid dimethylaminoethyl 160-205 part, HCPE 46-62 part, polyurethane 32-44
Part, zinc acrylate resin 22-30 part, aqueous acrylic emulsion 40-49 part, polyacrylic acid/acrylamide solution 32-38 part, chlorination stone
Wax 25-42 part, alundum (Al2O3) 5-9 part, bentonite 4-7 part, powder of lacquer putty for use on 6-10 part, vinal 5-9 part, boron nitride 4-
6 parts, hydroxypropyl methyl cellulose 5-9 part, polyester fiber 3-6 part, surfactant 0.4-0.8 part, coupling agent 0.3-0.5 part,
Degasser 0.3-0.5 part, levelling agent 0.3-0.5 part, dispersant 0.4-0.7 part, wetting agent 0.2-0.3 part, diluent 0.2-0.4
Part, adhesion promoter 0.4-0.6 part, catalyst 0.2-0.3 part, initiator 0.2-0.4 part, the line agent 0.4-0.7 part, toughness reinforcing hung down
Agent 0.3-0.6 part, optical brightener 0.4-0.8 part, defoamer 0.5-0.7 part, tackifier 0.3-0.4 part, curing agent 0.9-1.6 part,
Preservative 0.4-0.6 part, antioxidant 0.3-0.5 part, light stabilizer 0.2-0.3 part, heat stabilizer 0.1-0.2 part, ultraviolet are inhaled
Receive agent 0.3-0.4 part, thickener 0.4-0.7 part, coalescents 0.4-0.6 part, fire retardant 1.4-1.6 part；
Described surfactant is surfactant TRITONCF-10；
Described coupling agent is silane coupler；
Described degasser is stearic acid；
Described levelling agent is polyether polyester azo polyether polyeste；
Described dispersant is dispersant NC；
Described wetting agent is wetting agent CF-10；
Described diluent is 515- diluent；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isobutyric acid（Acrylic acid ethylene glycol）Ester；
Described vertical line agent is the line agent ART-300 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener gz-56；
Described defoamer is defoamer NXZ；
Described tackifier are propyl trimethoxy silicane；
Described curing agent is epoxylite curing agent；
Described preservative is preservative KY；
Described antioxidant is antioxidant 2246；
Described light stabilizer is light stabilizer 3853；
Described heat stabilizer is Dythal；
Described ultra-violet absorber is septichen phenyl ester；
Described thickener is xanthans；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：2,4- mesitylenic acid ethyl ester 32-56 parts, polyurethane
15-28 part, APP 13-18 part, pentaerythrite 9-16 part, urea 8-14 part, aluminium hydroxide 5-9 part, antimony oxide 9-
15 parts, manganese oxide 4-8 part, atlapulgite 7-13 part, bleeding agent 0.9-1.4 part, synergist 0.5-0.8 part；
Described bleeding agent is AEO
Described synergist is ammonium sulfate；
The preparation method of described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, comprises the following steps：
S1：By polymethylacrylic acid dimethylaminoethyl, HCPE, polyurethane, zinc acrylate resin, chlorination stone
Wax, alundum (Al2O3), bentonite, powder of lacquer putty for use on, vinal, boron nitride, hydroxypropyl methyl cellulose, polyester fiber, table
Face activating agent, coupling agent, degasser, levelling agent, dispersant, wetting agent, diluent, adhesion promoter, catalyst, initiator
Mixing, is 148-180W in microwave power, and temperature is 90-96 DEG C, and rotating speed is to stir 2-2.8h under 2300-3600r/min, is obtained
Mixture a；
S2：Aqueous acrylic emulsion, polyacrylic acid/acrylamide solution, hang down line agent, increasing is added in the mixture a being obtained to step S1
Tough dose, optical brightener, defoamer, tackifier, be 162-196W in microwave power, temperature be 112-128 DEG C, rotating speed be 400-
2.3-4.7h, prepared mixture b is stirred under 600r/min；
S3：Curing agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, thickener, coalescents, fire retardant, are 130-226W in microwave power, and temperature is 115-118 DEG C, and rotating speed is
1.8-3.2h, prepared mixture c is stirred under 200-400r/min；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, water 180-250 part are added in microwave reactor, stirs under speed of agitator is for 300-500r/min
6-10min, prepared mixture A；
S32：2,4- mesitylenic acid ethyl ester, polyurethane, pentaerythrite, urine is added in the mixture A being obtained to step S31
Element, aluminium hydroxide, antimony oxide, manganese oxide, atlapulgite, bleeding agent, synergist, are 400-600r/ in speed of agitator
Min, microwave power is 150-220W, and temperature stirs 1.6-2.4h, prepared mixture B at being 86-90 DEG C；
S33：The mixture B that step S32 is obtained is cooled to after room temperature, sediment is filtered, is 3000-5000r/ in rotating speed
Under min, centrifugal drying is to water content≤3%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112-118 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：140-200 mesh sieve is crossed in the pelletizing that step S5 is obtained after pulverizing, prepared aging-resisting type environmental protection solar energy water storage tank is used
Anticorrosive paint.
Embodiment 1
A kind of aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, in units of weight, including following raw material：Poly- methyl-prop
180 parts of olefin(e) acid dimethylaminoethyl, 53 parts of HCPE, 38 parts of polyurethane, 26 parts of zinc acrylate resin, aqueous third
45 parts of olefin(e) acid emulsion, 35 parts of polyacrylic acid/acrylamide solution, 34 parts of chlorinated paraffin, 8 parts of alundum (Al2O3), 6 parts of bentonite, putty
8 parts of powder, 8 parts of vinal, 5 parts of boron nitride, 7 parts of hydroxypropyl methyl cellulose, 5 parts of polyester fiber, surfactant 0.6
Part, 0.4 part of coupling agent, 0.4 part of degasser, 0.4 part of levelling agent, 0.6 part of dispersant, 0.2 part of wetting agent, 0.3 part of diluent, attached
0.5 part of adhesion promoter, 0.2 part of catalyst, 0.3 part of initiator, hang down 0.6 part of line agent, 0.5 part of toughener, 0.6 part of optical brightener,
0.6 part of defoamer, 0.3 part of tackifier, 1.4 parts of curing agent, 0.5 part of preservative, 0.4 part of antioxidant, 0.2 part of light stabilizer, heat
0.1 part of stabilizer, 0.3 part of ultra-violet absorber, 0.6 part of thickener, 0.5 part of coalescents, 1.5 parts of fire retardant；
Described surfactant is surfactant TRITONCF-10；
Described coupling agent is silane coupler；
Described degasser is stearic acid；
Described levelling agent is polyether polyester azo polyether polyeste；
Described dispersant is dispersant NC；
Described wetting agent is wetting agent CF-10；
Described diluent is 515- diluent；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isobutyric acid（Acrylic acid ethylene glycol）Ester；
Described vertical line agent is the line agent ART-300 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener gz-56；
Described defoamer is defoamer NXZ；
Described tackifier are propyl trimethoxy silicane；
Described curing agent is epoxylite curing agent；
Described preservative is preservative KY；
Described antioxidant is antioxidant 2246；
Described light stabilizer is light stabilizer 3853；
Described heat stabilizer is Dythal；
Described ultra-violet absorber is septichen phenyl ester；
Described thickener is xanthans；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：2,4- 45 parts of mesitylenic acid ethyl esters, polyurethane 22
Part, 15 parts of APP, 12 parts of pentaerythrite, 12 parts of urea, 7 parts of aluminium hydroxide, 12 parts of antimony oxide, 6 parts of manganese oxide, work
10 parts of carclazyte of property, 1.2 parts of bleeding agent, 0.7 part of synergist；
Described bleeding agent is AEO
Described synergist is ammonium sulfate；
The preparation method of described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, comprises the following steps：
S1：By polymethylacrylic acid dimethylaminoethyl, HCPE, polyurethane, zinc acrylate resin, chlorination stone
Wax, alundum (Al2O3), bentonite, powder of lacquer putty for use on, vinal, boron nitride, hydroxypropyl methyl cellulose, polyester fiber, table
Face activating agent, coupling agent, degasser, levelling agent, dispersant, wetting agent, diluent, adhesion promoter, catalyst, initiator
Mixing, is 164W in microwave power, and temperature is 94 DEG C, and rotating speed is to stir 2.6h, prepared mixture a under 3000r/min；
S2：Aqueous acrylic emulsion, polyacrylic acid/acrylamide solution, hang down line agent, increasing is added in the mixture a being obtained to step S1
Tough dose, optical brightener, defoamer, tackifier, be 186W in microwave power, temperature be 122 DEG C, rotating speed be 500r/min under stir
3.5h, prepared mixture b；
S3：Curing agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, thickener, coalescents, fire retardant, are 210W in microwave power, and temperature is 115 DEG C, and rotating speed is under 300r/min
Stirring 2.9h, prepared mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, 220 parts of water are added in microwave reactor, stirs 8min, system under speed of agitator is for 400r/min
Obtain mixture A；
S32：2,4- mesitylenic acid ethyl ester, polyurethane, pentaerythrite, urine is added in the mixture A being obtained to step S31
Element, aluminium hydroxide, antimony oxide, manganese oxide, atlapulgite, bleeding agent, synergist, are 500r/min in speed of agitator, micro-
Wave power is 180W, and temperature stirs 2h, prepared mixture B at being 88 DEG C；
S33：By step S32 be obtained mixture B be cooled to after room temperature, sediment is filtered, under rotating speed is for 4000r/min from
Heart drying to water content is 3%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 116 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 180 mesh sieve after pulverizing, and prepared aging-resisting type environmental protection solar energy water storage tank is with anti-corrosion
Coating.
Embodiment 2
A kind of aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, in units of weight, including following raw material：Poly- methyl-prop
160 parts of olefin(e) acid dimethylaminoethyl, 46 parts of HCPE, 32 parts of polyurethane, 22 parts of zinc acrylate resin, aqueous third
40 parts of olefin(e) acid emulsion, 32 parts of polyacrylic acid/acrylamide solution, 25 parts of chlorinated paraffin, 5 parts of alundum (Al2O3), 4 parts of bentonite, putty
6 parts of powder, 5 parts of vinal, 4 parts of boron nitride, 5 parts of hydroxypropyl methyl cellulose, 3 parts of polyester fiber, surfactant 0.4
Part, 0.3 part of coupling agent, 0.3 part of degasser, 0.3 part of levelling agent, 0.4 part of dispersant, 0.2 part of wetting agent, 0.2 part of diluent, attached
0.4 part of adhesion promoter, 0.2 part of catalyst, 0.2 part of initiator, hang down 0.4 part of line agent, 0.3 part of toughener, 0.4 part of optical brightener,
0.5 part of defoamer, 0.3 part of tackifier, 0.9 part of curing agent, 0.4 part of preservative, 0.3 part of antioxidant, 0.2 part of light stabilizer, heat
0.1 part of stabilizer, 0.3 part of ultra-violet absorber, 0.4 part of thickener, 0.4 part of coalescents, 1.4 parts of fire retardant；
Described surfactant is surfactant TRITONCF-10；
Described coupling agent is silane coupler；
Described degasser is stearic acid；
Described levelling agent is polyether polyester azo polyether polyeste；
Described dispersant is dispersant NC；
Described wetting agent is wetting agent CF-10；
Described diluent is 515- diluent；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isobutyric acid（Acrylic acid ethylene glycol）Ester；
Described vertical line agent is the line agent ART-300 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener gz-56；
Described defoamer is defoamer NXZ；
Described tackifier are propyl trimethoxy silicane；
Described curing agent is epoxylite curing agent；
Described preservative is preservative KY；
Described antioxidant is antioxidant 2246；
Described light stabilizer is light stabilizer 3853；
Described heat stabilizer is Dythal；
Described ultra-violet absorber is septichen phenyl ester；
Described thickener is xanthans；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：2,4- 32 parts of mesitylenic acid ethyl esters, polyurethane 15
Part, 13 parts of APP, 9 parts of pentaerythrite, 8 parts of urea, 5 parts of aluminium hydroxide, 9 parts of antimony oxide, 4 parts of manganese oxide, activity
7 parts of carclazyte, 0.9 part of bleeding agent, 0.5 part of synergist；
Described bleeding agent is AEO
Described synergist is ammonium sulfate；
The preparation method of described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, comprises the following steps：
S1：By polymethylacrylic acid dimethylaminoethyl, HCPE, polyurethane, zinc acrylate resin, chlorination stone
Wax, alundum (Al2O3), bentonite, powder of lacquer putty for use on, vinal, boron nitride, hydroxypropyl methyl cellulose, polyester fiber, table
Face activating agent, coupling agent, degasser, levelling agent, dispersant, wetting agent, diluent, adhesion promoter, catalyst, initiator
Mixing, is 148W in microwave power, and temperature is 90 DEG C, and rotating speed is to stir 2.8h, prepared mixture a under 2300r/min；
S2：Aqueous acrylic emulsion, polyacrylic acid/acrylamide solution, hang down line agent, increasing is added in the mixture a being obtained to step S1
Tough dose, optical brightener, defoamer, tackifier, be 162W in microwave power, temperature be 112 DEG C, rotating speed be 400r/min under stir
4.7h, prepared mixture b；
S3：Curing agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, thickener, coalescents, fire retardant, are 130W in microwave power, and temperature is 115 DEG C, and rotating speed is under 200r/min
Stirring 3.2h, prepared mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, 180 parts of water are added in microwave reactor, stirs 10min, system under speed of agitator is for 300r/min
Obtain mixture A；
S32：2,4- mesitylenic acid ethyl ester, polyurethane, pentaerythrite, urine is added in the mixture A being obtained to step S31
Element, aluminium hydroxide, antimony oxide, manganese oxide, atlapulgite, bleeding agent, synergist, are 400r/min in speed of agitator, micro-
Wave power is 150W, and temperature stirs 2.4h, prepared mixture B at being 86 DEG C；
S33：By step S32 be obtained mixture B be cooled to after room temperature, sediment is filtered, under rotating speed is for 3000r/min from
Heart drying to water content is 2.6%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 140 mesh sieve after pulverizing, and prepared aging-resisting type environmental protection solar energy water storage tank is with anti-corrosion
Coating.
Embodiment 3
A kind of aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, in units of weight, including following raw material：Poly- methyl-prop
205 parts of olefin(e) acid dimethylaminoethyl, 62 parts of HCPE, 44 parts of polyurethane, 30 parts of zinc acrylate resin, aqueous third
49 parts of olefin(e) acid emulsion, 38 parts of polyacrylic acid/acrylamide solution, 42 parts of chlorinated paraffin, 9 parts of alundum (Al2O3), 7 parts of bentonite, putty
10 parts of powder, 9 parts of vinal, 6 parts of boron nitride, 9 parts of hydroxypropyl methyl cellulose, 6 parts of polyester fiber, surfactant
0.8 part, 0.5 part of coupling agent, 0.5 part of degasser, 0.5 part of levelling agent, 0.7 part of dispersant, 0.3 part of wetting agent, diluent 0.4
Part, 0.6 part of adhesion promoter, 0.3 part of catalyst, 0.4 part of initiator, vertical 0.7 part of line agent, 0.6 part of toughener, optical brightener
0.8 part, 0.7 part of defoamer, 0.4 part of tackifier, 1.6 parts of curing agent, 0.6 part of preservative, 0.5 part of antioxidant, light stabilizer 0.3
Part, 0.2 part of heat stabilizer, 0.4 part of ultra-violet absorber, 0.7 part of thickener, 0.6 part of coalescents, 1.6 parts of fire retardant；
Described surfactant is surfactant TRITONCF-10；
Described coupling agent is silane coupler；
Described degasser is stearic acid；
Described levelling agent is polyether polyester azo polyether polyeste；
Described dispersant is dispersant NC；
Described wetting agent is wetting agent CF-10；
Described diluent is 515- diluent；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isobutyric acid（Acrylic acid ethylene glycol）Ester；
Described vertical line agent is the line agent ART-300 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener gz-56；
Described defoamer is defoamer NXZ；
Described tackifier are propyl trimethoxy silicane；
Described curing agent is epoxylite curing agent；
Described preservative is preservative KY；
Described antioxidant is antioxidant 2246；
Described light stabilizer is light stabilizer 3853；
Described heat stabilizer is Dythal；
Described ultra-violet absorber is septichen phenyl ester；
Described thickener is xanthans；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：2,4- 56 parts of mesitylenic acid ethyl esters, polyurethane 28
Part, 18 parts of APP, 16 parts of pentaerythrite, 14 parts of urea, 9 parts of aluminium hydroxide, 15 parts of antimony oxide, 8 parts of manganese oxide, work
13 parts of carclazyte of property, 1.4 parts of bleeding agent, 0.8 part of synergist；
Described bleeding agent is AEO
Described synergist is ammonium sulfate；
The preparation method of described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, comprises the following steps：
S1：By polymethylacrylic acid dimethylaminoethyl, HCPE, polyurethane, zinc acrylate resin, chlorination stone
Wax, alundum (Al2O3), bentonite, powder of lacquer putty for use on, vinal, boron nitride, hydroxypropyl methyl cellulose, polyester fiber, table
Face activating agent, coupling agent, degasser, levelling agent, dispersant, wetting agent, diluent, adhesion promoter, catalyst, initiator
Mixing, is 180W in microwave power, and temperature is 96 DEG C, and rotating speed is to stir 2h, prepared mixture a under 3600r/min；
S2：Aqueous acrylic emulsion, polyacrylic acid/acrylamide solution, hang down line agent, increasing is added in the mixture a being obtained to step S1
Tough dose, optical brightener, defoamer, tackifier, be 196W in microwave power, temperature be 128 DEG C, rotating speed be 600r/min under stir
2.3h, prepared mixture b；
S3：Curing agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, thickener, coalescents, fire retardant, are 226W in microwave power, and temperature is 118 DEG C, and rotating speed is under 400r/min
Stirring 1.8h, prepared mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, 250 parts of water are added in microwave reactor, stirs 6min, system under speed of agitator is for 500r/min
Obtain mixture A；
S32：2,4- mesitylenic acid ethyl ester, polyurethane, pentaerythrite, urine is added in the mixture A being obtained to step S31
Element, aluminium hydroxide, antimony oxide, manganese oxide, atlapulgite, bleeding agent, synergist, are 600r/min in speed of agitator, micro-
Wave power is 220W, and temperature stirs 1.6h, prepared mixture B at being 90 DEG C；
S33：By step S32 be obtained mixture B be cooled to after room temperature, sediment is filtered, under rotating speed is for 5000r/min from
Heart drying to water content is 2.2%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 118 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 200 mesh sieve after pulverizing, and prepared aging-resisting type environmental protection solar energy water storage tank is with anti-corrosion
Coating.
Embodiment 1-3 gained coating is carried out performance test.
1st, the preparation of substrate to be coated sample
A3Steel curved beam, for soak test in 80 DEG C of hot tap-water environment of constant temperature for the simulation.Specification：75mm×150mm×
2mm, through coarse sand cloth, 0#-5#Abrasive paper for metallograph is thoroughly polishing to non-scale, iron rust, with absolute ethyl alcohol eliminating water, acetone oil removing, is dried
After put in drier in case coating.
Tinplate sample, for laboratory Accelerating immersion and mechanical property test.Specification 50mm × 120mm × 0.2-
0.3mm, through 200#It is in metallic luster (rustless, no zinc coat) that sand paper is fully polishing to matrix, with acetone washed samples surface,
Put into after drying in drier in case coating.
2nd, resistance to water（80℃）, heat resistance, temp. variation resistant test
Using spread coating in A3Steel curved beam surface is coated；After solidification, coating dry film gross thickness is 180-200 μm.
（1）Water Resistance Test
Sample is respectively put in the glass container filling running water, airtight, 80 DEG C of constant temperature, after observation paint film after 30d
Situation of change.
（2）Heat-resistance test
After sample is boiled 6h in 100 DEG C of boiling water, take out and observe the situation of change of paint film.
（3）Temp. variation resistant is tested
By sample after 100 DEG C of boiling water boiling 1min, rapid taking-up is put in 20 DEG C of cold water, and so on circulates, through 60
After the people circulate 60 times, take out and observe the situation of change of sample.
3rd, Accelerating immersion test and coating mechanical property test
With film applicator, each sample is respectively coated with tinplate test plate (panel), build is 60 μm about, each after being fully cured
Sample carries out paint film bubbling, the evaluation of rusting grade and wet adhesion after accelerated immersion 7d in 80 DEG C, 5%Na Cl solution
Test, surveys dry state adhesive force to contrast simultaneously.
The dry wet adhesion of paint film, pliability, resistance to impact measure and respectively refer to GB/T9286-1998, GB/T1731-
93、GB/T1732-93；Coating surface bubbling grade, rusting grade respectively refer to ASTMD714-87, ASTMD610-85.
Result is as follows：
Corrosion resisting property result of the test
Note：Bubbling grade represents by good to bad from 0-5；Rusting grade represents by good to bad from 0-9.
The adhesive force test result of coating after coating mechanical property and laboratory Accelerating immersion
Note：Bubbling grade represents by good to bad from 0-5；Rusting grade represents by good to bad from 0-9.
The coating of the present invention had both had excellent adhesive force and mechanical property, have again excellent resistance to water, resistance to ag(e)ing,
Pliability and resistance to impact, and product nonhazardous itself, are a kind of aging-resisting type environmental protection sun of excellent combination property
Can water storage tank anticorrosive paint.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, the affiliated technology neck for the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined all should be considered as belonging to by the claims submitted to.
Claims (10)
1. a kind of aging-resisting type environmental protection solar energy water storage tank anticorrosive paint is it is characterised in that in units of weight, including following
Raw material：Polymethylacrylic acid dimethylaminoethyl 160-205 part, HCPE 46-62 part, polyurethane 32-44 part,
Zinc acrylate resin 22-30 part, aqueous acrylic emulsion 40-49 part, polyacrylic acid/acrylamide solution 32-38 part, chlorinated paraffin
25-42 part, alundum (Al2O3) 5-9 part, bentonite 4-7 part, powder of lacquer putty for use on 6-10 part, vinal 5-9 part, boron nitride 4-6
Part, hydroxypropyl methyl cellulose 5-9 part, polyester fiber 3-6 part, surfactant 0.4-0.8 part, coupling agent 0.3-0.5 part, de-
Gas agent 0.3-0.5 part, levelling agent 0.3-0.5 part, dispersant 0.4-0.7 part, wetting agent 0.2-0.3 part, diluent 0.2-0.4
Part, adhesion promoter 0.4-0.6 part, catalyst 0.2-0.3 part, initiator 0.2-0.4 part, the line agent 0.4-0.7 part, toughness reinforcing hung down
Agent 0.3-0.6 part, optical brightener 0.4-0.8 part, defoamer 0.5-0.7 part, tackifier 0.3-0.4 part, curing agent 0.9-1.6 part,
Preservative 0.4-0.6 part, antioxidant 0.3-0.5 part, light stabilizer 0.2-0.3 part, heat stabilizer 0.1-0.2 part, ultraviolet are inhaled
Receive agent 0.3-0.4 part, thickener 0.4-0.7 part, coalescents 0.4-0.6 part, fire retardant 1.4-1.6 part；
Described surfactant is surfactant TRITONCF-10；
Described coupling agent is silane coupler；
Described degasser is stearic acid；
Described levelling agent is polyether polyester azo polyether polyeste；
Described dispersant is dispersant NC；
Described wetting agent is wetting agent CF-10；
Described diluent is 515- diluent；
Described preservative is preservative KY；
Described antioxidant is antioxidant 2246；
Described light stabilizer is light stabilizer 3853；
Described heat stabilizer is Dythal；
Described ultra-violet absorber is septichen phenyl ester；
Described thickener is xanthans；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：2,4- mesitylenic acid ethyl ester 32-56 parts, polyurethane
15-28 part, APP 13-18 part, pentaerythrite 9-16 part, urea 8-14 part, aluminium hydroxide 5-9 part, antimony oxide 9-
15 parts, manganese oxide 4-8 part, atlapulgite 7-13 part, bleeding agent 0.9-1.4 part, synergist 0.5-0.8 part；
Described bleeding agent is AEO
Described synergist is ammonium sulfate；
The preparation method of described aging-resisting type environmental protection solar energy water storage tank anticorrosive paint, comprises the following steps：
S1：By polymethylacrylic acid dimethylaminoethyl, HCPE, polyurethane, zinc acrylate resin, chlorination stone
Wax, alundum (Al2O3), bentonite, powder of lacquer putty for use on, vinal, boron nitride, hydroxypropyl methyl cellulose, polyester fiber, table
Face activating agent, coupling agent, degasser, levelling agent, dispersant, wetting agent, diluent, adhesion promoter, catalyst, initiator
Mixing, is 148-180W in microwave power, and temperature is 90-96 DEG C, and rotating speed is to stir 2-2.8h under 2300-3600r/min, is obtained
Mixture a；
S2：Aqueous acrylic emulsion, polyacrylic acid/acrylamide solution, hang down line agent, increasing is added in the mixture a being obtained to step S1
Tough dose, optical brightener, defoamer, tackifier, be 162-196W in microwave power, temperature be 112-128 DEG C, rotating speed be 400-
2.3-4.7h, prepared mixture b is stirred under 600r/min；
S3：Curing agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, thickener, coalescents, fire retardant, are 130-226W in microwave power, and temperature is 115-118 DEG C, and rotating speed is
1.8-3.2h, prepared mixture c is stirred under 200-400r/min；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, water 180-250 part are added in microwave reactor, stirs under speed of agitator is for 300-500r/min
6-10min, prepared mixture A；
S32：2,4- mesitylenic acid ethyl ester, polyurethane, pentaerythrite, urine is added in the mixture A being obtained to step S31
Element, aluminium hydroxide, antimony oxide, manganese oxide, atlapulgite, bleeding agent, synergist, are 400-600r/ in speed of agitator
Min, microwave power is 150-220W, and temperature stirs 1.6-2.4h, prepared mixture B at being 86-90 DEG C；
S33：The mixture B that step S32 is obtained is cooled to after room temperature, sediment is filtered, is 3000-5000r/ in rotating speed
Under min, centrifugal drying is to water content≤3%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112-118 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：140-200 mesh sieve is crossed in the pelletizing that step S5 is obtained after pulverizing, prepared aging-resisting type environmental protection solar energy water storage tank is used
Anticorrosive paint.
2. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described institute
Stating adhesion promoter is colourless cobalt.
3. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described urge
Agent is platinum catalyst.
4. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described draw
Sending out agent is azo two isobutyric acid（Acrylic acid ethylene glycol）Ester.
5. according to claim 1 aging-resisting type environmental protection solar energy water storage tank anticorrosive paint it is characterised in that described vertical line
Agent is the line agent ART-300 that hangs down.
6. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described increasing
Tough dose is MBS terpolymer.
7. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described increasing
Photo etching is optical brightener gz-56.
8. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described disappear
Infusion is defoamer NXZ.
9. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described increasing
Stick is propyl trimethoxy silicane.
10. aging-resisting type environmental protection solar energy water storage tank anticorrosive paint according to claim 1 is it is characterised in that described
Curing agent is epoxylite curing agent.
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| CN201610906371.5A CN106380988A (en) | 2016-10-17 | 2016-10-17 | Anti-corrosion paint for aging-resistant environment-friendly solar water storage box |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286761A (en) * | 2017-08-01 | 2017-10-24 | 合肥康之恒机械科技有限公司 | It is a kind of for anticorrosive paint of engineering machinery and preparation method thereof |
| CN107573734A (en) * | 2017-08-22 | 2018-01-12 | 安徽杰特电气有限公司 | Corrosion-resistant brushless direct current motor |
| CN107652798A (en) * | 2017-09-22 | 2018-02-02 | 国网吉林省电力有限公司松原供电公司 | Corrosion-resistant electric force pole tower outer layer coating |
| CN108373638A (en) * | 2018-03-01 | 2018-08-07 | 温州环诺新材料科技有限公司 | A kind of universal aqueous mallear stria self-drying paint |
| CN109181517A (en) * | 2018-08-03 | 2019-01-11 | 苏州东沧涂料科技有限公司 | A kind of microwave absorption rapid draing water-borne wood coating and preparation method thereof, coating process |
| CN114634737A (en) * | 2022-05-23 | 2022-06-17 | 潍坊工程职业学院 | High chlorinated polyethylene coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875851A (en) * | 2012-09-12 | 2013-01-16 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN105949969A (en) * | 2016-06-27 | 2016-09-21 | 广西平果宝信涂料有限公司 | Sand-textured weather-resistant powder coating and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875851A (en) * | 2012-09-12 | 2013-01-16 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN105949969A (en) * | 2016-06-27 | 2016-09-21 | 广西平果宝信涂料有限公司 | Sand-textured weather-resistant powder coating and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286761A (en) * | 2017-08-01 | 2017-10-24 | 合肥康之恒机械科技有限公司 | It is a kind of for anticorrosive paint of engineering machinery and preparation method thereof |
| CN107573734A (en) * | 2017-08-22 | 2018-01-12 | 安徽杰特电气有限公司 | Corrosion-resistant brushless direct current motor |
| CN107652798A (en) * | 2017-09-22 | 2018-02-02 | 国网吉林省电力有限公司松原供电公司 | Corrosion-resistant electric force pole tower outer layer coating |
| CN108373638A (en) * | 2018-03-01 | 2018-08-07 | 温州环诺新材料科技有限公司 | A kind of universal aqueous mallear stria self-drying paint |
| CN109181517A (en) * | 2018-08-03 | 2019-01-11 | 苏州东沧涂料科技有限公司 | A kind of microwave absorption rapid draing water-borne wood coating and preparation method thereof, coating process |
| CN114634737A (en) * | 2022-05-23 | 2022-06-17 | 潍坊工程职业学院 | High chlorinated polyethylene coating and preparation method thereof |
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Application publication date: 20170208 |