CN106380959B - A kind of plated film button and preparation method thereof - Google Patents
A kind of plated film button and preparation method thereof Download PDFInfo
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- CN106380959B CN106380959B CN201510455293.7A CN201510455293A CN106380959B CN 106380959 B CN106380959 B CN 106380959B CN 201510455293 A CN201510455293 A CN 201510455293A CN 106380959 B CN106380959 B CN 106380959B
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Abstract
The present invention provides a kind of paint vehicles for plated film button, diluent, the defoaming agent of 0.05~0.25 parts by weight and the levelling agent of 0.35~0.65 parts by weight of the cross-linking monomer of photosensitive resin, 15~24 parts by weight, the photosensitizer of 3.3~4.5 parts by weight, 19~38 parts by weight including 65~75 parts by weight.The paint vehicle of preparation process provided by the invention and specific composition can add other colorants in paint vehicle, realize product colour diversity, provide more color selections, improve added value of product, meet the diversified demand of market Fashion trend collocation.
Description
Technical field
The invention belongs to garment production technical fields more particularly to a kind of plated film button and preparation method thereof.
Background technique
Button is exactly the fastener being connected on clothes for the both sides hem, and initial effect is for connection to the door of clothes
The flap, gradually development for had more in addition to keeping its original function artistry and dicoration and dress ornament personalization with
The representative of multifunction.
Button presses the classification of its material, can be divided into natural class, chemical and other materials, in chemical knob among these
Button again be divided into organic button, resin button, combination button, urea is buckled, spray painting is buckled, plating is buckled, by the emperor himself buckle.With the quick hair of button industry
Exhibition, requires also increasingly to improve that it is necessary to have wearabilities is good, heat-resisting quantity is good, good corrosion resistance and miscellaneous to button
Kind, and the features such as color of light is vivid beautiful, and also need to cope with clothes sometimes and produce many different styles, thousand surprise hundred of shape
Strange button.Thus, it is also put on sale one after another with the various button that various materials make, bucket victory strives surprise, such as gold-plated button, silver-plated button, spiral shell
Line button, engraving button, enameling button, material button etc., there are also valuable, there are also white jade fingered citron buttons, pearl button covered with gold leaf, three inlaid with jade buttons, embedding gold
Even there are also diamond buttons for agate button and coral button, beeswax button, amber button etc..The decorative pattern of button is also rich and varied, such as rolls over
Branch flowers, happiness,position and longevity is auspiciousness etc., it may be said that has everything, meets the different of various fashion dress ornaments and require.
Among these, surface coating button is a kind of emerging button pattern, and surface coating button refers to the table in button
After face carries out effect process and modification, then coating film treatment is carried out, is also possible to carry out other effects again after first carrying out coating film treatment
Processing or modification, to form diversified pattern or font effects on button surface.Currently, with increasingly fierce market
Competition and the development in pluralism of dress ornament color, surface coating button have become one of the element of many trend dress ornament indispensabilities,
Surface effect is easier to collocation clothes fashion, and pattern is many kinds of, novel brilliant.
However, the production technology of existing plated film button, still limits the development of plated film button, conventional production at present
Mode is that button surface primer spray → plated film → effect process → topcoating, the plated film button produced in batches in this way, is in product
Effect process sprays colored varnish protection again after surface coating, so that button surface effect is single, it is basic after can only realizing out plated film
Color (silver lustre, bright rifle or mute silver-colored, mute rifle etc.), button surface is a kind of color of direct plated film, and the color of plated film is also opposite
Single, the market demand is not high, additionally due to producing by the way of being painted after direct consumptive material color plated film again effect process
Product surface film plating layer is easy to scratch in journey, and process influences product total quality and the problems such as customer demand are not achieved.
Thus, a kind of preparation method of better plated film button how is found, so that plated film button is with richer
Rich colorful color, appearance and pattern, are always one of manufacturer's urgent problem to be solved in field.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is that providing a kind of plated film button and preparation method thereof, this hair
Plated film button of bright offer and preparation method thereof can enrich the type of plated film color, provide more colors for plated film button
Selection, to further be suitable for the collocation of all kinds of pattern clothes.
The invention discloses a kind of paint vehicles for plated film button, which is characterized in that including
Preferably, the cross-linking monomer includes trimethylolpropane trimethacrylate and tripropylene glycol two
Preferably, the photosensitizer is 1- hydroxy-cyclohexyl phenyl ketone；
The defoaming agent is Defom 5700；
The levelling agent is Levelol 835.
It preferably, further include colorant in the paint vehicle.
The present invention provides a kind of preparation methods of plated film button, which comprises the following steps:
A) after button blank surface spray-applied primer, then coating process is carried out, the button blank after obtaining plated film；
B) after the button blank surface emanation spraying paint after the plated film that above-mentioned steps obtain, button semi-finished product are obtained；It is described
Paint vehicle is paint vehicle described in above-mentioned any one technical solution；
C after) the button semi-finished product for obtaining above-mentioned steps B) carry out process of surface treatment, then spray paint, obtain plated film
Button.
Preferably, the process of surface treatment is laser engraving.
Preferably, 1~2H of hardness of paint film of the button semi-finished product.
Preferably, after the button blank surface spray-applied primer, hardness of paint film is 6~9H.
Preferably, the button is resin button, urea button, ox horn button, injection molding button, shell button and metal electricity
Plate one of class button or a variety of.
The invention discloses a kind of paint vehicles for plated film button, photosensitive resin including 65~75 parts by weight, 15~24
The cross-linking monomer of parts by weight, the photosensitizer of 3.3~4.5 parts by weight, the diluent of 19~38 parts by weight, 0.05~0.25 parts by weight
Defoaming agent and 0.35~0.65 parts by weight levelling agent.The invention also discloses a kind of preparation method of plated film button, packets
Following steps are included, first after button blank surface spray-applied primer, then carry out coating process, the button blank after obtaining plated film；
Then after the button blank surface emanation spraying paint after the plated film that above-mentioned steps obtain, button semi-finished product are obtained；The paint vehicle is
Any one paint vehicle in above-mentioned technical proposal；After the button semi-finished product that finally above-mentioned steps are obtained carry out process of surface treatment,
Spray paint again obtains plated film button.Compared with prior art, the present invention is after button blank surface spray-applied primer plated film, then
Secondary spraying paint vehicle disclosed by the invention, by adjusting hardness of paint film and varnish composition, so that two kinds of paint vehicles can be realized preferably
Attachment, after laser engraving, finally obtains plated film button.The paint vehicle of preparation process provided by the invention and specific composition,
Other colorants can be added in paint vehicle, realize product colour diversity, and more color selections are provided, it is additional to improve product
Value meets the diversified demand of market Fashion trend collocation；Enrich plated film class button color prolongs liter, gives lower tourist
Family is more selective；Meanwhile product quality is also improved, effectively control phenomena such as product surface film layer scratches.In addition, this hair
Button material needed for the preparation method of bright offer can be adapted for resin, urea, ox horn, injection molding, true shellfish, metal plating class
Button.The experimental results showed that plated film button prepared by the present invention, realize the diversity of product colour, but also have 4 grades with
On color fastness, can satisfy the application requirement of conventional dress material.
Detailed description of the invention
Fig. 1 is the appearance photo of resin plated film button prepared by the embodiment of the present invention 1；
Fig. 2 is the appearance photo of the resin plated film button of traditional technology preparation；
Fig. 3 is the appearance photo of natural seashell plated film button prepared by the embodiment of the present invention 2；
Fig. 4 is the appearance photo of natural ox horn plated film button prepared by the embodiment of the present invention 3.
Specific embodiment
In order to further appreciate that the present invention, the preferred embodiments of the invention are described below with reference to embodiment, but
It is it should be appreciated that these descriptions only require the invention patent to further illustrate the features and advantages of the present invention
Limitation.
All raw materials of the present invention, are not particularly limited its source, buying on the market or according to those skilled in the art
The preparation of conventional method known to member.
All raw materials of the present invention, are not particularly limited its purity, pure present invention preferably employs analyzing.
Laser engraving of the present invention carves space pattern or font by Radium art on button surface.
The invention discloses a kind of paint vehicles for plated film button, which is characterized in that including
In paint vehicle of the present invention for plated film button, the additional amount of the photosensitive resin is preferably 65~75 weight
Part, more preferably 67~73 parts by weight, most preferably 69~71 parts by weight；The present invention is to the concrete composition of photosensitive resin without spy
It does not limit, with the photosensitive resin well known to those skilled in the art for this field, the present invention is to improve the attachment of paint vehicle
Effect and appearance characteristic, preferably acrylate copolymer and/or urethane acrylate, more preferably acrylate copolymer and poly-
Urethane acrylate, most preferably Hypomer UV-M6 and Hypomer UR-61；The acrylate copolymer accounts for the paint vehicle
The percentage of gross mass is preferably 44.5%~46.2%, more preferably 44.8%~46.0%, most preferably 45%~
45.8%；The percentage that the urethane acrylate accounts for the paint vehicle gross mass is preferably 24.5%~25.5%, more preferably
It is 24.7%~25.3%, most preferably 24.9%~25.1%.
The additional amount of cross-linking monomer of the present invention is preferably 15~24 parts by weight, more preferably 17~22 parts by weight, most
Preferably 19~20 parts by weight；The concrete composition of cross-linking monomer is not particularly limited in the present invention, ripe with those skilled in the art
The cross-linking monomer for this field known, the present invention are to improve the adhesion effect and appearance characteristic of paint vehicle, preferably three hydroxyls
Propane tri and/or tri (propylene glycol) diacrylate, more preferably trimethylolpropane trimethacrylate
And tri (propylene glycol) diacrylate；The percentage that the trimethylolpropane trimethacrylate accounts for the paint vehicle gross mass is excellent
It is selected as 11.5%~12.3%, more preferably 11.7%~12.1%, most preferably 11.8%~12.0%；Two contracting 3 third
The percentage that omega-diol diacrylate accounts for the paint vehicle gross mass is preferably 7.2%-8.0%, and more preferably 7.4%~7.8%,
Most preferably 7.5%~7.7%.
The additional amount of photosensitizer of the present invention is preferably 3.5~4.5 parts by weight, more preferably 3.7~4.2 parts by weight,
Most preferably 3.8~4.1 parts by weight；Photosensitizer is not particularly limited in the present invention, is used for well known to those skilled in the art
The photosensitizer of this field, the present invention are to improve the adhesion effect and appearance characteristic of paint vehicle, preferably 1- hydroxy-cyclohexyl benzene
Base ketone (photoinitiator 184).The additional amount of the photosensitizer is preferably 3.5~4.5 parts by weight, more preferably 3.7~4.2 weights
Measure part, most preferably 3.8~4.1 parts by weight；The concrete composition of photosensitizer is not particularly limited in the present invention, with art technology
The photosensitizer of this field is used for known to personnel, the present invention to be to improve the adhesion effect and appearance characteristic of paint vehicle, preferably
1- hydroxy-cyclohexyl phenyl ketone (photoinitiator 184).
The additional amount of defoaming agent of the present invention is preferably 0.05~0.25 parts by weight, more preferably 0.1~0.2 weight
Part, most preferably 0.13~0.17 parts by weight；Defoaming agent is not particularly limited in the present invention, with well known to those skilled in the art
For the defoaming agent of this field, the present invention is to improve the adhesion effect and appearance characteristic of paint vehicle, preferably Defom 5700
Defoaming agent.
The additional amount of levelling agent of the present invention is preferably 0.35~0.65 parts by weight, more preferably 0.4~0.6 weight
Part, most preferably 0.45~0.55 parts by weight；Levelling agent is not particularly limited in the present invention, with well known to those skilled in the art
For the levelling agent of this field, the present invention is to improve the adhesion effect and appearance characteristic of paint vehicle, preferably Levelol 835
Levelling agent.
The additional amount of solvent of the present invention is preferably 19~38 parts by weight, more preferably 22~35 parts by weight, most preferably
For 26~31 parts by weight；The additional amount of solvent of the present invention be also preferably according to main body photosensitive resin parts by weight 30%~
50%, more preferably 35%~45%, more preferably 40%~45%, most preferably 45%.Specific group to solvent of the present invention
At being not particularly limited, with the solvent well known to those skilled in the art for this field, the present invention is to improve paint vehicle
One of adhesion effect and appearance characteristic, preferably ethyl acetate, isopropanol and isobutanol are a variety of, more preferably acetic acid second
Ester, isopropanol and isobutanol；The solvent is preferably according to mass ratio m (ethyl acetate): m (isopropanol): m (isobutanol)=2:1:
1 prepares；The viscosity of the solvent is preferably 10s~14s (apply -4 glasss, 25 degree), and more preferably 11s~13s (- 4 glasss of painting, 25
Degree), most preferably 12s (applies -4 glasss, 25 degree).
The model of above-mentioned concrete model raw material is not particularly limited in the present invention, with industry well known to those skilled in the art
Interior universal models raw material；The source of above-mentioned concrete model raw material is not particularly limited in the present invention, with those skilled in the art
Member known to method preparation or commercially.
The present invention is to improve the diversity of button product colour, more color selections is provided, preferably in above-mentioned paint vehicle
It further include colorant；The mass fraction of the colorant is not particularly limited in the present invention, and those skilled in the art can be according to reality
The condition of production, button appearance requirement and quality control are selected and are arranged in pairs or groups, and the present invention is preferably 5~15 parts by weight, more excellent
It is selected as 7~13 parts by weight, most preferably 9~11 parts by weight；The present invention especially limits the colorant without other, with this field
For producing the colorant of button known to technical staff, those skilled in the art can be according to practical condition, button
Appearance requirement and quality control are selected and are arranged in pairs or groups.
The present invention also provides a kind of preparation methods of plated film button, which comprises the following steps:
A) after button blank surface spray-applied primer, then coating process is carried out, the button blank after obtaining plated film；
B) after the button blank surface emanation spraying paint after the plated film that above-mentioned steps obtain, button semi-finished product are obtained；It is described
Paint vehicle is any one paint vehicle in above-mentioned technical proposal；
C after) the button semi-finished product for obtaining above-mentioned steps B) carry out process of surface treatment, then spray paint, obtain plated film
Button.
The material of button of the present invention is preferably in resin, urea, ox horn, injection molding, Zhen Bei and metal plating class button
One or more, more preferably resin, urea, ox horn, injection molding, Zhen Bei or metal plating class button, most preferably resin, ox
Angle, Zhen Bei or metal plating class button.
The present invention is first after button blank surface spray-applied primer, then carries out coating process, the button base after obtaining plated film
Material；After the button blank surface spray-applied primer, hardness of paint film is preferably 6~9H, more preferably 7~9H, most preferably 7~
8H；The process of the spraying is not particularly limited in the present invention, with spraying process well known to those skilled in the art；
The condition of the spraying is not particularly limited in the present invention, with spraying conditions well known to those skilled in the art；The present invention
The equipment of the spraying is not particularly limited, with the equipment well known to those skilled in the art for button spraying.This
The process of the plated film is not particularly limited in invention, with coating process well known to those skilled in the art；This hair
The bright condition to the plated film is not particularly limited, with plating conditions well known to those skilled in the art；The present invention is to institute
The equipment for stating plated film is not particularly limited, with the equipment well known to those skilled in the art for button plated film.The present invention
The priming paint is not particularly limited, with well known to those skilled in the art for spraying the priming paint of button.
The surface of the present invention then button blank after the plated film that above-mentioned steps obtain obtains button half after emanation spraying paint
Finished product；The paint vehicle is paint vehicle described in above-mentioned any one technical solution.It is used in paint vehicle in the above-mentioned preparation method of the present invention
The optimum principle of raw material and additional amount in aforementioned paint vehicle optimum principle and additional amount it is consistent, this is no longer going to repeat them.
The hardness of the button semi-finished product is not particularly limited in the present invention, those skilled in the art can according to practical condition and
The conditions such as appearance characteristic have carried out optimum choice, and the present invention is to improve the adhesion effect and appearance characteristic of paint vehicle, the button half
The hardness of paint film of finished product is preferably 1~2H.The process of the spraying is not particularly limited in the present invention, with art technology
Spraying process known to personnel；The condition of the spraying is not particularly limited in the present invention, ripe with those skilled in the art
The spraying conditions known；The equipment of the spraying is not particularly limited in the present invention, with use well known to those skilled in the art
In the equipment of button spraying.
After the button semi-finished product that the present invention finally obtains above-mentioned steps carry out process of surface treatment, then spray paint, it obtains
To plated film button；The process of surface treatment is not particularly limited in the present invention, with button table well known to those skilled in the art
Surface treatment technique, the present invention is preferably that the process of surface treatment is preferably laser engraving, more preferably radium-shine to carve characters；This
The process of the spraying is not particularly limited in invention, with spraying process well known to those skilled in the art；This hair
The bright condition to the spraying is not particularly limited, with spraying conditions well known to those skilled in the art；The present invention is to institute
The equipment for stating spraying is not particularly limited, with the equipment well known to those skilled in the art for button spraying.The present invention
The finishing coat is not particularly limited, with well known to those skilled in the art for spraying the finishing coat of button, the present invention is excellent
It is selected as bright finishing coat and/or dull finishing coat.
It further include system button moulding, polishing, blank oil removing according to different button materials in the above-mentioned preparation process of the present invention
Pre-treating technologies, the present invention such as cleaning, drying, upper button are not particularly limited it, with well known to those skilled in the art common
The corresponding pre-treating technology of button.
The plated film button that the present invention is prepared by the above method, after spraying special edematus paint vehicle due to use after plated film
Laser engraving can reach the color of abundant plated film by adding various edematus in paint vehicle, can also utilize engraving
Method after coloring paint vehicle and coating get rid of together, background color needed for exposing product itself forms a kind of film coating color and produces
The contrast effect of product background color, while on button surface, there are two kinds of luminosity, and by spraying the clear finish enhancing such as bright, mute again
It surface effect and plays a protective role.Plated film button prepared by the present invention can add other colorants in paint vehicle, realize production
Product color diversity provides more color selections, meets the diversified demand of market Fashion trend collocation, effectively more
Existing plated film button is mended, Essential colour (silver lustre, bright rifle or mute silver-colored, mute rifle etc.) surface color effect after can only realizing out plated film
Single problem, enrich plated film class button color prolongs liter, gives downstream client more selectivity.
Meanwhile product quality is also improved, phenomena such as product surface film layer scratches effectively is controlled, is solved using directly consumption
The mode that wood color plated film paints after carving again, product surface film plating layer are easy to scratch, the problem of plated film color richness deficiency.This
Outside, button material needed for preparation method provided by the invention can be adapted for resin, urea, ox horn, injection molding, true shellfish, metal
Class button is electroplated.The experimental results showed that plated film button prepared by the present invention, realizes the diversity of product colour, but also have
There is 4 grades or more of color fastness, can satisfy the application requirement of conventional dress material.
For a further understanding of the present invention, below with reference to embodiment to the preparation method of plated film button provided by the invention into
Row explanation, protection scope of the present invention are not limited by the following examples.
Embodiment 1
Resin plated film button
Polishing (polishing): pouring into water roll cast ray machine for the resin button blank after moulding, further polished, with
Reach required luminosity, then by ultrasonic cleaning, the dust and extra burnishing oil on button surface is removed, to increase paint
Fastness, the clean button blank after finally obtaining polishing.
Spraying filming process: the rear button blank of above-mentioned polishing and cleaning is placed on special fixture, rail is passed through
Road formula UV assembly line is 1000 in ultraviolet energy using 3 automatic spray guns continuously to above-mentioned button blank surface spray-applied primer
Solidify and form a film under the ultraviolet light of release value.
Filming process: it by the button blank after above-mentioned adhesion primer film forming, is placed into evaporation coating machine, vacuumizes 15 points
Clock, then the dedicated aluminium wire consumptive material of plated film is flashed into ionic condition mirror surface film forming and forms mirror surface film layer, time in button blank surface
It is 3 minutes, is released into atmosphere 5 minutes, the button blank after finally obtaining the plated film that plated film color is mirror surface silver color.
Paint vehicle spray treatment: first weighing the photosensitive resin of 70 parts by weight, and wherein Hypomer UV-M6 accounts for paint vehicle gross mass
45%, Hypomer UR-61 account for paint vehicle gross mass 25%；The cross-linking monomer of 20 parts by weight, wherein trimethylolpropane tris propylene
Acid esters accounts for paint vehicle gross mass 11.5%, and tri (propylene glycol) diacrylate accounts for paint vehicle gross mass 7.5%；The light of 4 parts by weight draws
Send out agent 184；The levelling agent of the diluent of 25 parts by weight, the defoaming agent Defom 5700 of 0.1 parts by weight and 0.45 parts by weight
Levelol 835。
After stating red, yellow, blue and the black UV colorant for being added in paint vehicle and adding up to 10 parts by weight then up, mixing
The paint vehicle containing colorant is obtained afterwards, and paint vehicle is sprayed on the button blank surface after plated film, obtains knob by second hand rail road formula UV assembly line
Detain semi-finished product.
Surface treatment procedure: by above-mentioned button semi-finished product according to pre-set figure, according to button moulding, by laser
The metal laser machine that energy is 50 carries out laser engraving, finally spray paint again.
Baking processing: the button after above-mentioned carry out process of surface treatment is toasted, 60 degrees Celsius of temperature, the time 60 divides
Clock obtains the sold resin plated film button that surface is claret after lower button.
Moreover, passing through above-mentioned local laser, moreover it is possible to realize two-color effect of the button with edge itself.
The sold resin plated film button that embodiment 1 is prepared carries out appearance detection, the experimental results showed that, referring to Fig. 1,
Fig. 1 is the appearance photo of resin plated film button prepared by the embodiment of the present invention 1；Referring to fig. 2, Fig. 2 is the tree of traditional technology preparation
The appearance photo of rouge plated film button.It is existing by Fig. 1 and Fig. 2 comparison it is found that the present invention can be realized a variety of variations of plated film color
Plated film button technique most basic mirror surface silver color and rifle color can only be realized out by consumptive material itself；And use the present invention and mirror
The combination of face silver can realize out claret made of various colorants reconciliations in plated film mirror surface silver color, while can carry out part
Laser engraving realizes that button background color itself and the collocation of edge film coating color generate metallochrome and background color two-color effect.
The sold resin plated film button that embodiment 1 is prepared carries out physicochemical property detection, experimental result referring to table 1,
Table 1 is the physicochemical property testing result of sold resin plated film button,
1 sold resin plated film button physicochemical property testing result of table
As shown in Table 1, the sold resin plated film button that embodiment 1 is prepared has 4 grades or more of color fastness, Neng Gouman
The application requirement of foot routine dress material, and product surface film layer damage resistant.
Embodiment 2
Natural seashell plated film button
Polishing (polishing): pouring into water roll cast ray machine for the shell button blank after moulding, further polished, with
Reach required luminosity, then by ultrasonic cleaning, the dust and extra burnishing oil on button surface is removed, to increase paint
Fastness, the clean button blank after finally obtaining polishing.
Spraying filming process: the rear button blank of above-mentioned polishing and cleaning is placed on special fixture, rail is passed through
Road formula UV assembly line is 800 in ultraviolet energy using 4 automatic spray guns continuously to above-mentioned button blank surface spray-applied primer
Solidify and form a film under the ultraviolet light of release value.
Filming process: it by the button blank after above-mentioned adhesion primer film forming, is placed into evaporation coating machine, vacuumizes 20 points
Clock, then the dedicated aluminium wire consumptive material of plated film is flashed into ionic condition mirror surface film forming and forms mirror surface film layer, time in button blank surface
It is 5 minutes, is released into atmosphere 3 minutes, the button blank after finally obtaining the plated film that plated film color is mirror surface rifle color.
Paint vehicle spray treatment: first weighing the photosensitive resin of 75 parts by weight, and wherein Hypomer UV-M6 accounts for paint vehicle gross mass
46%, Hypomer UR-61 account for paint vehicle gross mass 24.5%；The cross-linking monomer of 15 parts by weight, wherein trimethylolpropane tris third
Olefin(e) acid ester accounts for paint vehicle gross mass 12%, and tri (propylene glycol) diacrylate accounts for paint vehicle gross mass 7.2%；The light of 4.5 parts by weight
Initiator 184；The levelling of the diluent of 20 parts by weight, the defoaming agent Defom 5700 of 0.2 parts by weight and 0.55 parts by weight
Agent Levelol 835.
It states after the blue for amounting to 15 parts by weight and black UV colorant are added in paint vehicle, obtains after mixing containing colorant then up
Paint vehicle, paint vehicle is sprayed on the button blank surface after plated film, obtains button semi-finished product by second hand rail road formula UV assembly line.
Surface treatment procedure: by above-mentioned button semi-finished product according to pre-set figure, according to button moulding, by laser
The metal laser machine that energy is 50 carries out laser engraving, finally spray paint again.
Baking processing: the button after above-mentioned carry out process of surface treatment is toasted, 60 degrees Celsius of temperature, the time 60 divides
Clock obtains the finished product natural seashell plated film button that surface is black after lower button.
Moreover, passing through above-mentioned local laser, moreover it is possible to realize the shell background color of button itself and the two-color effect at edge.
Appearance detection is carried out to the finished product natural seashell plated film button that embodiment 2 is prepared, the experimental results showed that, referring to
Fig. 3, Fig. 3 are the appearance photo of natural seashell plated film button prepared by the embodiment of the present invention 2.From the figure 3, it may be seen that the present invention can be real
A variety of variations of existing plated film color can be realized out on plated film mirror surface rifle color and be adjusted using the combination of the present invention and mirror surface rifle color
The black with made of, while local laser engraving can be carried out, realize the shell background color of button itself and the two-color effect at edge.
The finished product natural seashell plated film button that embodiment 2 is prepared carries out physicochemical property detection, experimental result referring to
Table 2, table 2 are the physicochemical property testing result of finished product natural seashell plated film button,
2 finished product natural seashell plated film button physicochemical property testing result of table
As shown in Table 2, the finished product natural seashell plated film button that embodiment 2 is prepared has 4 grades or more of color fastness, energy
Enough application requirements for meeting conventional dress material, and product surface film layer damage resistant.
Embodiment 3
Natural ox horn plated film button
Polishing (polishing): pouring into water roll cast ray machine for the ox horn button blank after moulding, further polished, with
Reach required luminosity, then by ultrasonic cleaning, the dust and extra burnishing oil on button surface is removed, to increase paint
Fastness, the clean button blank after finally obtaining polishing.
Spraying filming process: the rear button blank of above-mentioned polishing and cleaning is placed on special fixture, rail is passed through
Road formula UV assembly line is 900 in ultraviolet energy using 4 automatic spray guns continuously to above-mentioned button blank surface spray-applied primer
Solidify and form a film under the ultraviolet light of release value.
Filming process: it by the button blank after above-mentioned adhesion primer film forming, is placed into evaporation coating machine, vacuumizes 20 points
Clock, then the dedicated nickel wire consumptive material of plated film is flashed into ionic condition mirror surface film forming and forms mirror surface film layer, time in button blank surface
It is 4 minutes, is released into atmosphere 4 minutes, the button blank after finally obtaining the plated film that plated film color is mirror surface silver color.
Paint vehicle spray treatment: first weighing the photosensitive resin of 65 parts by weight, and wherein Hypomer UV-M6 accounts for paint vehicle gross mass
44.5%, Hypomer UR-61 account for paint vehicle gross mass 25.5%；The cross-linking monomer of 22 parts by weight, wherein trimethylolpropane tris
Acrylate accounts for paint vehicle gross mass 12.3%, and tri (propylene glycol) diacrylate accounts for paint vehicle gross mass 8.0%；3.5 parts by weight
Photoinitiator 184；The diluent of 15 parts by weight, the defoaming agent Defom 5700 of 0.05 parts by weight and 0.35 parts by weight
Levelling agent Levelol835.
After stating the red, yellow and black UV colorant for being added in paint vehicle and amounting to 13 parts by weight then up, obtained after mixing
Paint vehicle is sprayed on the button blank surface after plated film by the paint vehicle containing colorant, second hand rail road formula UV assembly line, obtain button half at
Product.
Surface treatment procedure: by above-mentioned button semi-finished product according to pre-set figure, according to button moulding, by laser
The metal laser machine that energy is 80 carries out laser engraving, finally spray paint again.
Baking processing: the button after above-mentioned carry out process of surface treatment is toasted, 50 degrees Celsius of temperature, the time 50 divides
Clock obtains the natural ox horn plated film button of finished product that surface is coffee gold after lower button.
Moreover, passing through above-mentioned local laser, moreover it is possible to realize the ox horn background color of button itself and the two-color effect at edge.
Appearance detection is carried out to the natural ox horn plated film button of finished product that embodiment 3 is prepared, the experimental results showed that, referring to
Fig. 4, Fig. 4 are the appearance photo of natural ox horn plated film button prepared by the embodiment of the present invention 3.As shown in Figure 4, the present invention can be real
A variety of variations of existing plated film color can be realized out in plated film mirror surface silver color and be adjusted using the combination of the present invention and mirror surface silver color
The coffee with made of is golden, while can carry out local laser engraving, realizes the ox horn background color of button itself and the double-colored effect at edge
Fruit.
The natural ox horn plated film button of the finished product that embodiment 3 is prepared carries out physicochemical property detection, experimental result referring to
Table 3, table 3 are the physicochemical property testing result of the natural ox horn plated film button of finished product,
The natural ox horn plated film button physicochemical property testing result of 3 finished product of table
As shown in Table 3, the natural ox horn plated film button of the finished product that embodiment 3 is prepared has 4 grades or more of color fastness, energy
Enough application requirements for meeting conventional dress material, and product surface film layer damage resistant.
A kind of plated film button provided by the present invention and preparation method thereof is described in detail above.It is used herein
Principle and implementation of the present invention are described for a specific example, and the explanation of above example is only intended to help to manage
Solve method and its core concept of the invention.It should be pointed out that for those skilled in the art, not departing from
, can be with several improvements and modifications are made to the present invention under the premise of the principle of the invention, these improvement and modification also fall into this hair
In bright scope of protection of the claims.
Claims (9)
1. a kind of preparation method of plated film button, which comprises the following steps:
A) after button blank surface spray-applied primer, then coating process is carried out, the button blank after obtaining plated film；
B) after the button blank surface emanation spraying paint after the plated film that above-mentioned steps obtain, button semi-finished product are obtained；
C after) the button semi-finished product for obtaining above-mentioned steps B) carry out process of surface treatment, then spray paint, obtain plated film button；
The paint vehicle, consists of the following compositions:
2. preparation method according to claim 1, which is characterized in that the photosensitive resin includes acrylate copolymer and gathers
Urethane acrylate.
3. preparation method according to claim 1, which is characterized in that the cross-linking monomer includes trimethylolpropane tris third
Olefin(e) acid ester and tri (propylene glycol) diacrylate.
4. preparation method according to claim 1, which is characterized in that the photosensitizer is 1- hydroxy-cyclohexyl phenyl first
Ketone；
The defoaming agent is Defom 5700；
The levelling agent is Levelol 835.
5. preparation method according to claim 1, which is characterized in that further include colorant in the paint vehicle.
6. preparation method according to claim 1, which is characterized in that the process of surface treatment is laser engraving.
7. preparation method according to claim 1, which is characterized in that 1~2H of hardness of paint film of the button semi-finished product.
8. preparation method according to claim 1, which is characterized in that after the button blank surface spray-applied primer, paint film
Hardness is 6~9H.
9. preparation method according to claim 1, which is characterized in that the button is resin button, urea button, ox horn
One of button, injection molding button, shell button and metal plating class button are a variety of.
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| CN107398822A (en) * | 2017-07-27 | 2017-11-28 | 合肥远科服装设计有限公司 | A kind of surface processing technique of plastic button |
| CN108244770A (en) * | 2017-12-07 | 2018-07-06 | 岳西县海创饰品有限公司 | A kind of Environment-friendlywear-resistant wear-resistant resin button and preparation method thereof |
| CN109967328A (en) * | 2019-03-18 | 2019-07-05 | 浙江伟星实业发展股份有限公司 | A kind of processing method and button on button surface |
| CN110776766A (en) * | 2019-09-18 | 2020-02-11 | 浙江伟星实业发展股份有限公司 | Ice texture UV primer for button with ice texture effect, button with ice texture effect and manufacturing process |
| CN115505303A (en) * | 2021-06-07 | 2022-12-23 | 浙江伟星实业发展股份有限公司 | Dream color-plating effect paint, preparation method thereof and button surface treatment process |
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| CN103767248A (en) * | 2012-10-23 | 2014-05-07 | 浙江伟星实业发展股份有限公司 | Plastic button and method for treating surface of button |
| CN103920632A (en) * | 2014-04-09 | 2014-07-16 | 浙江伟星实业发展股份有限公司 | Coated resin product and production method thereof |
| CN104530924A (en) * | 2014-12-22 | 2015-04-22 | 湖州南浔双林振森实木加工厂 | Ultraviolet curing coating and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103767248A (en) * | 2012-10-23 | 2014-05-07 | 浙江伟星实业发展股份有限公司 | Plastic button and method for treating surface of button |
| CN103920632A (en) * | 2014-04-09 | 2014-07-16 | 浙江伟星实业发展股份有限公司 | Coated resin product and production method thereof |
| CN104530924A (en) * | 2014-12-22 | 2015-04-22 | 湖州南浔双林振森实木加工厂 | Ultraviolet curing coating and preparation method thereof |
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