CN106366865B - A kind of antibacterial water resistance ultraviolet-cured paint - Google Patents
A kind of antibacterial water resistance ultraviolet-cured paint Download PDFInfo
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- CN106366865B CN106366865B CN201610737120.9A CN201610737120A CN106366865B CN 106366865 B CN106366865 B CN 106366865B CN 201610737120 A CN201610737120 A CN 201610737120A CN 106366865 B CN106366865 B CN 106366865B
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- water resistance
- fluorine
- antibacterial water
- nano
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- 239000003973 paint Substances 0.000 title claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 22
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 37
- 239000011737 fluorine Substances 0.000 claims abstract description 37
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 31
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 30
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 claims abstract description 28
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 claims abstract description 28
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 27
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 15
- -1 1, 6- hexanediyl ester Chemical class 0.000 claims abstract description 13
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000728 polyester Polymers 0.000 claims abstract description 13
- 235000013312 flour Nutrition 0.000 claims abstract description 12
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 claims abstract description 12
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims abstract description 11
- NIWFIJFHALTBRN-UHFFFAOYSA-N 2-methyl-5-propan-2-ylidenecyclopentan-1-one Chemical compound CC1CCC(=C(C)C)C1=O NIWFIJFHALTBRN-UHFFFAOYSA-N 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 10
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 9
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- TXNXVKSSXJDGIR-UHFFFAOYSA-N OC(C)N1CN(CN(C1)O)O Chemical compound OC(C)N1CN(CN(C1)O)O TXNXVKSSXJDGIR-UHFFFAOYSA-N 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000013339 cereals Nutrition 0.000 claims description 24
- 150000002148 esters Chemical class 0.000 claims description 17
- 229940106691 bisphenol a Drugs 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 9
- 150000001336 alkenes Chemical class 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical class CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical class CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 3
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 230000000845 anti-microbial effect Effects 0.000 abstract description 3
- 238000001723 curing Methods 0.000 description 12
- 239000000126 substance Substances 0.000 description 4
- GBDLBTQHXOOMAV-UHFFFAOYSA-N (2-hexylphenyl)-phenylmethanone Chemical compound C(CCCCC)C1=C(C(=O)C2=CC=CC=C2)C=CC=C1 GBDLBTQHXOOMAV-UHFFFAOYSA-N 0.000 description 3
- 108050008598 Phosphoesterases Proteins 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- OHYINUJIHLYARE-UHFFFAOYSA-N 2-(2H-1,3,5-triazin-1-yl)ethane-1,1,1-triol Chemical compound OC(CN1CN=CN=C1)(O)O OHYINUJIHLYARE-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- PCIRJWTVSRUWCU-UHFFFAOYSA-N (3,3,5-trimethylcyclohexyl)methyl prop-2-enoate Chemical compound CC1CC(COC(=O)C=C)CC(C)(C)C1 PCIRJWTVSRUWCU-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- YVKJGLZZMYZTNO-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)ethane-1,1,1-triol Chemical compound OC(O)(O)CC1=NC=NC=N1 YVKJGLZZMYZTNO-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of antibacterial water resistance ultraviolet-cured paints, its raw material includes: bisphenol A epoxy acrylate resin, polyester acrylate, tri (propylene glycol) diacrylate, 1, 6- hexanediyl ester, 3, 3, 5- 3-methyl cyclohexanol methyl acrylate, propoxylated glycerol triacrylate, Alpha-hydroxy phenylcyclohexyl ketone, camphorone, talcum powder, silica flour, carclazyte, carbon nanotube, nano vanadium dioxide, nano zirconium dioxide, n-octyl trimethoxy silane, fluorine-containing quaternary ammonium salt, hexahydro -1, 3, 5- trihydroxyethyl s-triazine, polydimethyl diallyl ammonium chloride, defoaming agent, levelling agent, wetting agent, butyl acetate.Antibacterial water resistance ultraviolet-cured paint proposed by the present invention, water resistance, wearability and anti-pollution are good, and anti-microbial property is excellent.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of antibacterial water resistance ultraviolet-cured paints.
Background technique
UV-curing technology has that curing rate fast (0.1~10s), low in the pollution of the environment, energy consumption is low, can automate
The advantages that producing, being suitable for use on heat-sensitive substrate material.Divide according to its purposes, mainly there is ultraviolet-curing paint, adhesive, oil
Ink etc..Wherein most wide with ultraviolet-curing paint use scope, production kind is most.Ultraviolet-curing paint is led according to its application
The different of domain can be divided into again: woodenware ultraviolet-curing paint, plastics ultraviolet-curing paint, the solidification of metal ultraviolet light apply
Material, paper ultraviolet-curing paint, optical fiber ultraviolet-curing paint etc..
But as the development of society and the requirement of consumer are higher and higher, the performance and appearance requirement of coating are also mentioning therewith
Height, for a long time, that there are hardness is low for ultraviolet-curing paint, chemical resistance is poor, water resistance and antibiotic property is less desirable lacks
It falls into.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of antibacterial water resistance ultraviolet-cured paint,
Water resistance, wearability and anti-pollution are good, and anti-microbial property is excellent.
A kind of antibacterial water resistance ultraviolet-cured paint proposed by the present invention, raw material include: bisphenol-A epoxy third by weight
20-40 parts of alkene acid ester resin, 3-15 parts of polyester acrylate, 5-15 parts of tri (propylene glycol) diacrylate, 1,6-HD
5-15 parts of diacrylate, 6-15 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylated glycerol triacrylate
3-15 parts, 1-5 parts of Alpha-hydroxy phenylcyclohexyl ketone, 0.2-1 parts of camphorone, 2-10 parts of talcum powder, 1-5 parts of silica flour, carclazyte 1-5
Part, 1-3.5 parts of carbon nanotube, 0.5-2 parts of nano vanadium dioxide, 1-3 parts of nano zirconium dioxide, n-octyl trimethoxy silane 1-
4 parts, quaternary ammonium salt 3-8 parts fluorine-containing, 0.2-1 parts of hexahydro -1,3,5- trihydroxyethyl s-triazine, polydimethyl diallyl ammonium chloride 2-
5 parts, 0.1-0.5 parts of defoaming agent, 0.1-1 parts of levelling agent, 0.2-1 parts of wetting agent, 3-10 parts of butyl acetate.
Preferably, in raw material, bisphenol A epoxy acrylate resin, polyester acrylate weight ratio be 25-35:6-
13。
Preferably, in raw material, tri (propylene glycol) diacrylate, 1,6- hexanediyl ester, 3,3,5- tri-
Methylcyclohexylmethyl acrylate, propoxylated glycerol triacrylate weight ratio be 8-13:6-12:8-13:5-13.
Preferably, raw material include: by weight 30 parts of bisphenol A epoxy acrylate resin, 12 parts of polyester acrylate,
11 parts of tri (propylene glycol) diacrylate, 10 parts of 1,6 hexanediol diacrylate, 3,3,5- trimethylcyclohexyl methyl-prop
12 parts of olefin(e) acid ester, 3.8 parts of Alpha-hydroxy phenylcyclohexyl ketone, 0.7 part of camphorone, is slided 10 parts of propoxylated glycerol triacrylate
5 parts of mountain flour, 3.2 parts of silica flour, 4 parts of carclazyte, 2 parts of carbon nanotube, 1.6 parts of nano vanadium dioxide, 2.1 parts of nano zirconium dioxide,
3.1 parts of n-octyl trimethoxy silane, 5 parts of fluorine-containing quaternary ammonium salt, 0.6 part of hexahydro -1,3,5- trihydroxyethyl s-triazine, poly dimethyl
3 parts of diallyl ammonium chloride, 0.4 part of defoaming agent, 0.6 part of levelling agent, 0.7 part of wetting agent, 8 parts of butyl acetate.
Preferably, the nano vanadium dioxide be average grain diameter be 30-80nm nano vanadium dioxide, average grain diameter be
The nano vanadium dioxide of 250-400nm is the mixture of 3-12:2-40 by weight.
Preferably, the nano zirconium dioxide be average grain diameter be 300-500nm nano zirconium dioxide, average grain diameter be
2-5 μm of nano zirconium dioxide is the mixture of 5-15:5-30 by weight.
In the present invention, the nano vanadium dioxide be average grain diameter be 30-80nm nano vanadium dioxide, average grain diameter be
The nano vanadium dioxide of 250-400nm is the mixture of 3-12:2-40 by weight；The nano zirconium dioxide is average grain diameter
The nano zirconium dioxide for being 2-5 μm for the nano zirconium dioxide of 300-500nm, average grain diameter is 5-15:5-30's by weight
Mixture；By the content and its particle size of control nano vanadium dioxide and nano zirconium dioxide in system, to make
Nano vanadium dioxide and nano zirconium dioxide are closely spaced in system, improve its bulk density in system,
Its pining force in the base is improved while obtaining better mechanical property, to improve the wear-resisting property of paint film, hardness and resistance to
It is hot.
Preferably, the fluorine-containing quaternary ammonium salt is prepared according to following technique: by weight in 50-80 parts of dimethyl formyls
8-15 parts of dimethylaminoethyl methacrylates are added in amine, 2,3,4,5,6- five fluorine bromobenzyl of 30-45 part and 0.05- is then added
0.5 part of hydroquinone, 3.5-5h is stirred to react at 50-65 DEG C, is cooled to room temperature after reaction, then heavy through anhydrous ether
It forms sediment, wash, being dried to obtain the fluorine-containing quaternary ammonium salt.
Preferably, the fluorine-containing quaternary ammonium salt is prepared according to following technique: by weight in 65 parts of dimethylformamides
12 parts of dimethylaminoethyl methacrylates of middle addition, are then added 40 part 2, and 3,4,5,6- five fluorine bromobenzyls and 0.3 part are to benzene two
Phenol is stirred to react 4.2h at 60 DEG C, is cooled to room temperature after reaction, then precipitates, washs, is dried to obtain through anhydrous ether
The fluorine-containing quaternary ammonium salt.
Preferably, the defoaming agent is dimethicone.
Preferably, the levelling agent is epoxidized soybean oil fatty acid；The wetting agent is alkyl phenol polyoxyethylene ether phosphoric acid
One of ester, phenethyl phenol polyoxyethylene groups ether phosphate or two kinds of mixture.
Antibacterial water resistance ultraviolet-cured paint of the present invention can be according to conventional ultraviolet-curing paint preparation process
It is prepared.
Bisphenol A epoxy acrylate resin has the hardness that laser curing velocity is fast, solidifies caudacoria and glossiness high, heat resistance
It is good, the advantages that resistance to chemical corrosion is excellent, in the present invention, with bisphenol A epoxy acrylate resin for main performed polymer, and
Cooperation joined suitable polyester acrylate, make the performance collaboration of the two, and cooperate specific photoinitiator Alpha-hydroxy hexamethylene
Base Benzophenone and camphorone are keeping the hardness and gloss that bisphenol A epoxy acrylate resin laser curing velocity is fast, solidifies caudacoria
Degree is high, and heat resistance and good resistance to chemical corrosion while improves the toughness and weatherability of system；With tripropylene glycol two
Acrylate, 1,6 hexanediol diacrylate, 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylated glycerol 3 third
Olefin(e) acid ester cooperates the reactive diluent as system, improves the viscosity of system, simultaneously participates in the solidification of system, further increase
It prevents paint film to wrinkle while the toughness of paint film, while improving the hardness and adhesive force of system；Talcum powder, silica flour,
Carclazyte, carbon nanotube, nano vanadium dioxide, in nano zirconium dioxide addition system, in n-octyl trimethoxy silane, fluorine-containing season
It is uniformly dispersed in system under the action of ammonium salt, polydimethyl diallyl ammonium chloride, significantly improves hardness, the toughness of paint film
And wearability；System is added in fluorine-containing quaternary ammonium salt, hexahydro -1,3,5- trihydroxyethyl s-triazine, polydimethyl diallyl ammonium chloride
In there is Synergistic antimicrobial, while improving the hygroscopicity of paint film, assign paint film excellent water resistance；In preferred embodiment, institute
Fluorine-containing quaternary ammonium salt is stated with dimethylaminoethyl methacrylate, 2,3,4,5,6- five fluorine bromobenzyls are raw material, thus by metering system
Sour dimethylaminoethyl and 2,3,4,5,6- five fluorine bromobenzyls are combined as a whole, obtain have high surface, high heat resistance stability,
The fluorine-containing quaternary ammonium salt of the properties such as high chemical stability and water and oil repellence, in addition system, on the one hand, with hexahydro -1,3,5-
Trihydroxyethyl s-triazine and polydimethyl diallyl ammonium chloride cooperation assign paint film excellent antibiotic property, on the other hand, and just
The cooperation of octyl trimethoxy silane, improves the compatibility of system, improves the water resistance of paint film.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of antibacterial water resistance ultraviolet-cured paint proposed by the present invention, raw material include: bisphenol-A epoxy third by weight
40 parts of alkene acid ester resin, 3 parts of polyester acrylate, 15 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
5 parts of ester, 15 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 3 parts of propoxylated glycerol triacrylate, Alpha-hydroxy hexamethylene
5 parts of base Benzophenone, 0.2 part of camphorone, 10 parts of talcum powder, 1 part of silica flour, 5 parts of carclazyte, 1 part of carbon nanotube, nano vanadium dioxide
2 parts, 1 part of nano zirconium dioxide, 4 parts of n-octyl trimethoxy silane, 3 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,5- trihydroxyethyl it is equal
1 part of triazine, 2 parts of polydimethyl diallyl ammonium chloride, 0.5 part of defoaming agent, 0.1 part of levelling agent, 1 part of wetting agent, butyl acetate 3
Part.
Embodiment 2
A kind of antibacterial water resistance ultraviolet-cured paint proposed by the present invention, raw material include: bisphenol-A epoxy third by weight
20 parts of alkene acid ester resin, 15 parts of polyester acrylate, 5 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
15 parts of ester, 6 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 15 parts of propoxylated glycerol triacrylate, Alpha-hydroxy ring
1 part of hexyl Benzophenone, 1 part of camphorone, 2 parts of talcum powder, 5 parts of silica flour, 1 part of carclazyte, 3.5 parts of carbon nanotube, nanometer titanium dioxide
0.5 part of vanadium, 3 parts of nano zirconium dioxide, 1 part of n-octyl trimethoxy silane, 8 parts of fluorine-containing quaternary ammonium salt, three hydroxyl second of hexahydro -1,3,5-
0.2 part of base s-triazine, 5 parts of polydimethyl diallyl ammonium chloride, 0.1 part of defoaming agent, 1 part of levelling agent, 0.2 part of wetting agent, vinegar
10 parts of acid butyl ester.
Embodiment 3
A kind of antibacterial water resistance ultraviolet-cured paint proposed by the present invention, raw material include: bisphenol-A epoxy third by weight
35 parts of alkene acid ester resin, 6 parts of polyester acrylate, 13 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
6 parts of ester, 13 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 5 parts of propoxylated glycerol triacrylate, Alpha-hydroxy hexamethylene
3.8 parts of base Benzophenone, 0.5 part of camphorone, 8 parts of talcum powder, 3.1 parts of silica flour, 3.6 parts of carclazyte, carbon nanotube 2.7 part, nanometer
1.7 parts of vanadium dioxide, 2 parts of nano zirconium dioxide, 3 parts of n-octyl trimethoxy silane, 4.8 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,
0.8 part of 5- trihydroxyethyl s-triazine, 3.8 parts of polydimethyl diallyl ammonium chloride, 0.4 part of defoaming agent, 0.5 part of levelling agent, profit
0.75 part of humectant, 5.8 parts of butyl acetate；
Wherein, the nano vanadium dioxide be average grain diameter be 30nm nano vanadium dioxide, average grain diameter be 400nm's
Nano vanadium dioxide is the mixture of 3:40 by weight；
The nano zirconium dioxide be average grain diameter be 300nm nano zirconium dioxide, the nanometer two that average grain diameter is 5 μm
Zirconium oxide is the mixture of 5:30 by weight；
The fluorine-containing quaternary ammonium salt is prepared according to following technique: being added 15 in 50 parts of dimethylformamides by weight
Part dimethylaminoethyl methacrylate, then 30 part 2 of addition, 3,4,5,6- five fluorine bromobenzyls and 0.5 part of hydroquinone, at 50 DEG C
Under be stirred to react 5h, be cooled to room temperature after reaction, then precipitate, wash through anhydrous ether, being dried to obtain the fluorine-containing season
Ammonium salt.
Embodiment 4
A kind of antibacterial water resistance ultraviolet-cured paint proposed by the present invention, raw material include: bisphenol-A epoxy third by weight
25 parts of alkene acid ester resin, 13 parts of polyester acrylate, 8 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
12 parts of ester, 8 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 13 parts of propoxylated glycerol triacrylate, Alpha-hydroxy ring
2 parts of hexyl Benzophenone, 0.8 part of camphorone, 5.8 parts of talcum powder, 4 parts of silica flour, 3 parts of carclazyte, 3.2 part, nanometer two of carbon nanotube
1 part of vanadium oxide, 2.5 parts of nano zirconium dioxide, 2.3 parts of n-octyl trimethoxy silane, 6 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,5-
0.55 part of trihydroxyethyl s-triazine, 4.3 parts of polydimethyl diallyl ammonium chloride, 0.28 part of defoaming agent, 0.8 part of levelling agent, alkane
.2 parts of base phenol polyethenoxy ether phosphoesterase 30 .3 parts of phenethyl phenol polyoxyethylene ether phosphoesterase 30,8 parts of butyl acetate；
Wherein, the nano vanadium dioxide be average grain diameter be 80nm nano vanadium dioxide, average grain diameter be 250nm's
Nano vanadium dioxide is the mixture of 12:2 by weight；
The nano zirconium dioxide be average grain diameter be 500nm nano zirconium dioxide, the nanometer two that average grain diameter is 2 μm
Zirconium oxide is the mixture of 15:5 by weight；
The fluorine-containing quaternary ammonium salt is prepared according to following technique: being added 8 in 80 parts of dimethylformamides by weight
Part dimethylaminoethyl methacrylate, then 45 part 2 of addition, 3,4,5,6- five fluorine bromobenzyls and 0.05 part of hydroquinone, 65
It is stirred to react 3.5h at DEG C, is cooled to room temperature after reaction, then precipitates, wash through anhydrous ether, being dried to obtain described contain
Fluorine quaternary ammonium salt.
Embodiment 5
A kind of antibacterial water resistance ultraviolet-cured paint proposed by the present invention, raw material include: bisphenol-A epoxy third by weight
30 parts of alkene acid ester resin, 12 parts of polyester acrylate, 11 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
10 parts of ester, 12 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 10 parts of propoxylated glycerol triacrylate, Alpha-hydroxy ring
3.8 parts of hexyl Benzophenone, 0.7 part of camphorone, 5 parts of talcum powder, 3.2 parts of silica flour, 4 parts of carclazyte, 2 part, nanometer two of carbon nanotube
1.6 parts of vanadium oxide, 2.1 parts of nano zirconium dioxide, 3.1 parts of n-octyl trimethoxy silane, 5 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,
0.6 part of 5- trihydroxyethyl s-triazine, 3 parts of polydimethyl diallyl ammonium chloride, 0.4 part of dimethicone, epoxidized soybean oil rouge
Fat acid 0.6 part .7 parts of alkyl phenol polyoxyethylene ether phosphoesterase 30,8 parts of butyl acetate；
Wherein, the nano vanadium dioxide be average grain diameter be 60nm nano vanadium dioxide, average grain diameter be 300nm's
Nano vanadium dioxide is the mixture of 6:21 by weight；
The nano zirconium dioxide be average grain diameter be 400nm nano zirconium dioxide, the nanometer that average grain diameter is 3.8 μm
Zirconium dioxide is the mixture of 12:17 by weight；
The fluorine-containing quaternary ammonium salt is prepared according to following technique: being added 12 in 65 parts of dimethylformamides by weight
Part dimethylaminoethyl methacrylate, then 40 part 2 of addition, 3,4,5,6- five fluorine bromobenzyls and 0.3 part of hydroquinone, at 60 DEG C
Under be stirred to react 4.2h, be cooled to room temperature after reaction, then precipitate, wash through anhydrous ether, be dried to obtain it is described fluorine-containing
Quaternary ammonium salt.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of antibacterial water resistance ultraviolet-cured paint, which is characterized in that its raw material includes: bisphenol-A epoxy propylene by weight
20-40 parts of acid ester resin, 3-15 parts of polyester acrylate, 5-15 parts of tri (propylene glycol) diacrylate, 1,6-HD two
5-15 parts of acrylate, 6-15 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylated glycerol triacrylate 3-
15 parts, 1-5 parts of Alpha-hydroxy phenylcyclohexyl ketone, 0.2-1 parts of camphorone, 2-10 parts of talcum powder, 1-5 parts of silica flour, carclazyte 1-5
Part, 1-3.5 parts of carbon nanotube, 0.5-2 parts of nano vanadium dioxide, 1-3 parts of nano zirconium dioxide, n-octyl trimethoxy silane 1-
4 parts, quaternary ammonium salt 3-8 parts fluorine-containing, 0.2-1 parts of hexahydro -1,3,5- trihydroxyethyl s-triazine, polydimethyl diallyl ammonium chloride 2-
5 parts, 0.1-0.5 parts of defoaming agent, 0.1-1 parts of levelling agent, 0.2-1 parts of wetting agent, 3-10 parts of butyl acetate；
The fluorine-containing quaternary ammonium salt is prepared according to following technique: 8- is added in 50-80 parts of dimethylformamides by weight
Then 2,3,4,5,6- five fluorine bromobenzyl of 30-45 part and 0.05-0.5 parts are added to benzene in 15 parts of dimethylaminoethyl methacrylates
Diphenol is stirred to react 3.5-5h at 50-65 DEG C, is cooled to room temperature after reaction, then precipitate, wash through anhydrous ether,
It is dried to obtain the fluorine-containing quaternary ammonium salt.
2. antibacterial water resistance ultraviolet-cured paint according to claim 1, which is characterized in that in its raw material, bisphenol-A epoxy third
Alkene acid ester resin, polyester acrylate weight ratio be 25-35:6-13.
3. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that in its raw material, two contractings 3 third
Omega-diol diacrylate, 1,6 hexanediol diacrylate, 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylation are sweet
The weight ratio of oily triacrylate is 8-13:6-12:8-13:5-13.
4. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that its raw material wraps by weight
It includes: 30 parts of bisphenol A epoxy acrylate resin, 12 parts of polyester acrylate, 11 parts of tri (propylene glycol) diacrylate, 1,6-
10 parts of hexanediyl ester, 12 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, three acrylic acid of propoxylated glycerol
10 parts of ester, 3.8 parts of Alpha-hydroxy phenylcyclohexyl ketone, 0.7 part of camphorone, 5 parts of talcum powder, 3.2 parts of silica flour, 4 parts of carclazyte, carbon are received
2 parts of mitron, 1.6 parts of nano vanadium dioxide, 2.1 parts of nano zirconium dioxide, 3.1 parts of n-octyl trimethoxy silane, fluorine-containing quaternary ammonium
5 parts of salt, 0.6 part of hexahydro -1,3,5- trihydroxyethyl s-triazine, 3 parts of polydimethyl diallyl ammonium chloride, 0.4 part of defoaming agent, stream
0.6 part of flat agent, 0.7 part of wetting agent, 8 parts of butyl acetate.
5. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that the nano vanadium dioxide
For average grain diameter be 30-80nm nano vanadium dioxide, average grain diameter be 250-400nm nano vanadium dioxide be by weight
The mixture of 3-12:2-40.
6. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that the nano zirconium dioxide
For average grain diameter be 300-500nm nano zirconium dioxide, average grain diameter be 2-5 μm nano zirconium dioxide be by weight 5-
The mixture of 15:5-30.
7. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that the fluorine-containing quaternary ammonium salt is pressed
It is prepared according to following technique: 12 parts of dimethylaminoethyl second being added by weight in 65 parts of dimethylformamides
Ester, then 40 part 2 of addition, 3,4,5,6- five fluorine bromobenzyls and 0.3 part of hydroquinone are stirred to react 4.2h, reaction knot at 60 DEG C
It is cooled to room temperature after beam, then precipitates, washs through anhydrous ether, being dried to obtain the fluorine-containing quaternary ammonium salt.
8. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that the defoaming agent is diformazan
Base silicone oil.
9. antibacterial water resistance ultraviolet-cured paint according to claim 1 or claim 2, which is characterized in that the levelling agent is epoxy
Change soy(a)-bean oil fatty acid；The wetting agent is alkyl phenol polyoxyethylene ether phosphate, in phenethyl phenol polyoxyethylene groups ether phosphate
One or two kinds of mixture.
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| CN101372562A (en) * | 2008-10-09 | 2009-02-25 | 浙江工业大学 | UV photo-curing hydrophobic antifouling paint and preparation thereof |
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