CN106359475A - Fungicidal composition for preventing and treating wheat scab and application thereof - Google Patents
Fungicidal composition for preventing and treating wheat scab and application thereof Download PDFInfo
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- CN106359475A CN106359475A CN201610770825.0A CN201610770825A CN106359475A CN 106359475 A CN106359475 A CN 106359475A CN 201610770825 A CN201610770825 A CN 201610770825A CN 106359475 A CN106359475 A CN 106359475A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
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Abstract
The invention discloses a fungicidal composition for preventing and treating wheat scab and application thereof. According to different action mechanisms of various agents, in combination with a traditional Chinese medicine preparation with the fungicidal and insecticidal effects with the assistance of suitable auxiliaries and a suitable carrier, compared with a traditional agent, the fungicidal composition has the advantages that the fungicidal composition is high in efficiency, low in toxicity and residue content, good in fast-acting property, long in lasting period and environmentally friendly; the fungicidal composition does not cause cross resistance with a traditional prevailing agent for preventing and treating wheat scab; various agents have compatibility, the synergistic effect is obvious, fungicidal activity is improved, the dosage of a single fungicidal agent is reduced, and pesticide use cost is reduced; by adding the traditional Chinese medicine preparation, the risk level of resistance of pathogenic bacteria to chemical agents can be lowered, the sensitivity of pathogenic bacteria can be easily kept, and meanwhile the situation that pathogenic bacteria generate resistance to single dosages in the formula can be retarded; the fungicidal effect is significant, harm caused by diseases to crop production is reduced, and the yield and quality of agricultural products are improved.
Description
Technical field
The present invention relates to technical field of pesticide, more particularly, to a kind of bactericidal composition preventing and treating wheat scab and its should
With.
Background technology
Semen Tritici aestivi is most important frumentum raise crop in the world, is also the important cereal crops of China.Head blight, white lead
Disease, banded sclerotial blight, rust and leaf blight are to threaten the important fungal disease of Wheat Production, have a strong impact on yield and the product of Semen Tritici aestivi
Matter.Especially destructive production loss can not only be caused by the microbial wheat scab of fusarium, and the paddy in infection
The rotten Fusariumsp enol (deoxynivalenol, don) of a large amount of deoxidation snow and 6-(10-hydroxy-6-oxo-trans-1-undecenyl)-.beta.-resorcylic acid lactone also can be produced in grain
(zearalenone) toxin such as, has a strong impact on grain security, threatens the health of humans and animals.
Wheat scab be one kind can by multiple Fusarium spp. or claim Fusariumsp (fusarium spp.) cause bud-rot, Seedling
The withered and withered ascomycetess disease of fringe corruption/fringe.Its cause of disease includes Fusarium graminearum (f.graminearum), Asia Fusarium spp.
(f.asiaticum), fusarium culmorum (f.culmorum), fusarium avenaceum (f.avenaceum), fusarium moniliforme
(f.moniliforme), nearly 20 kinds such as Fusarium nivale (f.nivale).The wheat scab of China's most area be by
Fusarium graminearum (f.graminearum) and Asia Fusarium spp. (f.asiaticum) mixed population cause, the wherein southern area of wheat
Based on the Fusarium spp. of Asia, the northern area of wheat is based on Fusarium graminearum.
Because breeding for disease resistance is limited by having immunity or high anti-genetic resourceses to Fusarium spp., use antibacterial still at present
It is the important measures of effective prevention and control wheat scab.Since the sixties in last century, the benzimidazole based on carbendazim kills
Microbial inoculum is mainly used in the chemical prevention of wheat scab, but the increase of the growth with service life and using dosage, and Semen Tritici aestivi is red
Mould pathogenic bacteria develops immunity to drugs to the benzimidazole germicide based on carbendazim already, and fastness frequency is continuously increased, resistance
Scope expands year by year, often results in wheat scab and prevents and treats unsuccessfully, causes plant disease epidemic to aggravate.
CGA-173506 (fludioxonil) is that a kind of new pyrrole class non-internal-absorting wide spectrum of Syngenta Co., Ltd's development and production kills
Microbial inoculum, it derives from natural product pyrrolnitrin, and the mechanism of action is by suppressing the relevant transfer of thalline glucose phosphorylated
Enzyme, and suppress the growth of fungal mycelium, lead to pathogenic bacteria dead.To Alternaria, Ascochyta, aspergillus, Fusarium, length
The microbial disease of the cause of diseases such as Helminthosporium, Rhizoctonia and Penicillium has good protection and therapeutical effect.
Epoxiconazole iso adopted name is epoxiconazole, and fusing point is 136.2 DEG C, and stable chemical nature has preferably
Residual activity, is biological property antibacterial.Epoxiconazole is a kind of absorbability triazole bactericidal agent, by suppressing pathogenic bacteria ergosterol
Synthesis, hinder the formation of its cell wall, and epoxiconazole molecule have strength affinity to a kind of fungal enzyme, with known biocides
Compare, can more effectively suppress pathogenic fungi.
Both the above compound is all good bactericidal agent raw material sources, and there are reports at present is used for various Semen Tritici aestivis
The application of the pest and disease damage of Oryza sativa L., but there is fastness frequency and be continuously increased, prevent and treat unsuccessfully, cause asking of plant disease epidemic aggravation
Inscribe it is therefore desirable to adjust its proportioning, and introduce new effective Fungicidal substance and be combined the preventing and treating of wheat scab could be obtained
Obtain more preferable effect.
Content of the invention
Goal of the invention: there is resistance for the pesticide control preventing and treating wheat scab present in prior art to overcome
Frequency is continuously increased, and resistant range expands year by year, often results in and prevents and treats unsuccessfully, causes the problem of the popular aggravation of insect pest, and the present invention carries
Gone out a kind of there is preferable synergistic function to preventing and treating wheat scab prevention and control, applications of pesticide amount is greatly lowered, reduces
A kind of Bactericidal composite preventing and treating wheat scab of the residual of environmental pollution and agricultural product, lasting period length and raising Resistance of Wheat To Adversity
Thing and its application.
Technical scheme: in order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of bactericidal composition preventing and treating wheat scab, by weight by the helping of main component 10% of 30%-70%
The carrier composition of agent and surplus;Wherein said main component is CGA-173506, epoxiconazole, Chinese medicine sterilizing become to be grouped into, wherein Chinese medicine
Sterilization component weight accounts for the 40% of main component, and the weight of CGA-173506 and epoxiconazole is than for 1:20~20:1.
Further, in described main component the weight of CGA-173506 and epoxiconazole than for 1:10~10:1.
Further, in described main component the weight of CGA-173506 and epoxiconazole than for 1:4~4:1.
Further, in described main component the weight of CGA-173506 and epoxiconazole than for 2:1.
It is more highly preferred to, in described main component, Chinese medicine sterilizing composition is selected from Flos Caryophylli, Lignum Sappan, Semen Cassiae, Rhizoma Alpiniae Officinarum, flower
Green pepper, Radix Cirsii Japonici, the Radix Astragali, Rhizoma Curcumae, Cortex Moutan, Radix Paeoniae Rubra, Cortex Fraxini, Herba Violae, the Radix Pulsatillae, Radix Polygalae, Rhizoma Polygonati, Omphalia, Semen Arecae, Cortex Meliae, Semen Torreyae,
At least five kinds combinations in Fructus Ulmus preparatium.
It is more highly preferred to, the dosage form of bactericidal composition is aqueous emulsion, in wettable powder, suspending agent, water dispersible granules
One kind, corresponding carrier is selected from water, Kaolin, active hargil, clay, bentonite, kieselguhr, attapulgite, precipitated calcium carbonate
One or more of.
It is more highly preferred to, described auxiliary agent is sodium lignin sulfonate, polymerization alkylaryl sulfonatess, alkyl polyoxyethylene phosphoric acid
Ester, tea seed cake powder, spaonin powder, Bombyx mori L., aliphatic alcohol sulfate, alkylol polyoxyethylene Oleum Ricini, dodecylbenzene sodium sulfonate, pull open
Powder, polysorbate60, alkyl phosphate and its alkoxide, polyoxyethylene carboxylate, phosphate ester and its derivant, polyvinyl alcohol,
Sodium polyacrylate, sulfate, dimethyl sulfoxide, isopropanol, gelatinized corn starch, natural gum, Semen Glycines powder, Oleum Terebinthinae, methanol, ethanol, gelatin, Ah
Draw primary glue, lecithin, sodium lauryl sulphate, ammonium sulfate, alkylphenol polyoxyethylene, polyoxyethylene lauryl ether, phenethyl
Phenol mela mine-formaldehyde resin polyoxyethyl ether, sulfonic acid polyformaldehyde condensation substance, n- methyl pyrrolidone, alkyl benzene calcium sulfonate, butyl LOMAR PWA EINECS 246-676-2
One or more of sodium, benzoic acid, carboxymethyl cellulose, aluminium-magnesium silicate, ethyl acetate.
The invention also discloses a kind of application of above-mentioned bactericidal composition preventing and treating wheat scab, prevention and controls are to little
Wheat carries out three dispensers, for the first time for the wheat seed dressing before sowing, is for second the administration of dusting at wheat flowering initial stage, for the third time
Low-gallonage spraying for heading stage is applied, and in each bactericidal composition, the consumption of main component is 15~20g.
It is more highly preferred to, after the time of spraying administration and administration of dusting is selected from 3 points in afternoon.
Beneficial effect: a kind of bactericidal composition preventing and treating wheat scab and its application that the present invention provides, according to various
The different mechanisms of action of medicament, and combine the Chinese drugs agentia with sterilization insect-expelling function, its perfect adaptation is got up, it is suitable to be aided with
Auxiliary agent and carrier, seek the preventing and treating that most suitable proportioning carries out head blight to Semen Tritici aestivi, have following excellent compared with traditional medicament
Point: a) efficiently, low toxicity, low-residual, quick-acting is good, lasting period length, environmentally friendly;B) master of wheat scab is prevented and treated with tradition
Stream medicament no interactions Drug resistance;C) various medicaments have the compatibility, and potentiation is notable, improves bactericidal activity, decreases list
The dosage of one antibacterial, saves Pesticide use cost;D) interpolation of Chinese drugs agentia, on the one hand can reduce pathogen to change
Learn the resistance risk level of medicament, be conducive to the holding of pathogen sensitivity, can delay pathogenic bacteria that single dose in formula is gone out simultaneously
Existing Drug resistance;E) bactericidal effect is notable, and decrease that disease causes to production estimation causes harm, improve agricultural product yield and
Quality.
Specific embodiment
With reference to embodiment, the present invention is described in further detail:
Toxicity measures:
Embodiment 1:
A kind of bactericidal composition preventing and treating wheat scab, dosage form is wettable powder, and the concrete proportioning of each component is as follows: coughs up
Bacterium nitrile 12%, epoxiconazole 30%, Chinese medicine sterilizing composition 28%, alkyl polyoxyethylene phosphate 4%, spaonin powder 3%, phosphate ester and
Its derivant 3%, active hargil 10%, remaining be supplemented to 100% for precipitated calcium carbonate, wherein Chinese medicine sterilizing composition be Lignum Sappan,
Pericarpium Zanthoxyli, Cortex Moutan, the Radix Astragali, Semen Arecae, the mixture of Omphalia.
Its preparation method is: said components is fully mixed, pulverizes through sand mill and cross 300 mesh sieves, obtain Bactericidal composite
Thing wettable powder.
Embodiment 2:
A kind of bactericidal composition preventing and treating wheat scab, dosage form is suspending agent, and the concrete proportioning of each component is as follows: CGA-173506
20%th, epoxiconazole 10%, Chinese medicine sterilizing composition 20%, polymerization alkylaryl sulfonatess 2%, Bombyx mori L. 2%, isopropanol 3%, Semen Glycines powder
2%th, ethyl acetate 1%, remaining be supplemented to 100% for water, wherein Chinese medicine sterilizing composition be Rhizoma Alpiniae Officinarum, Radix Cirsii Japonici, Herba Violae, Radix Polygalae,
Omphalia, the mixture of Cortex Meliae.
Its preparation method is: said components is fully mixed, is crushed to 90% pharmacy particle diameter≤5 μ through sand mill
M, obtains bactericidal composition suspending agent.
Embodiment 3:
A kind of bactericidal composition preventing and treating wheat scab, dosage form is water dispersible granules, and the concrete proportioning of each component is as follows: coughs up
Bacterium nitrile 14%, epoxiconazole 10%, Chinese medicine sterilizing composition 16%, alkyl polyoxyethylene phosphate 2%, polysorbate60 2%, ethanol
3%th, methanol 2%, lecithin 1%, remaining be supplemented to 100% for attapulgite, wherein Chinese medicine sterilizing composition be Lignum Sappan, Cortex Fraxini,
Rhizoma Curcumae, Cortex Moutan, Radix Polygalae, Fructus Ulmus preparatium, the mixture of Cortex Meliae.
Its preparation method is: said components is fully mixed, through pulverizing preparation female powder, female powder is mixed with appropriate aqueous solution
Close uniformly, high speed shear sand mill grinds, then carry out fluidized bed prilling, be dried, sieve, you can prepared bactericidal composition water
Dispersible granule.
Embodiment 4:
A kind of bactericidal composition preventing and treating wheat scab, dosage form is aqueous emulsion, and the concrete proportioning of each component is as follows: CGA-173506
12%th, epoxiconazole 6%, Chinese medicine sterilizing composition 12%, aliphatic alcohol sulfate 2%, alkyl phosphate and its alkoxide 2%, the moon
Cinnamic alcohol polyoxyethylene ether 2%, methanol 2%, sodium butylnaphthalenesulfonate 1%, arabic gum 1%, remaining is supplemented to 100% for water, its
Middle Chinese medicine sterilizing composition is Pericarpium Zanthoxyli, Cortex Fraxini, Rhizoma Polygonati, Cortex Moutan, Radix Polygalae, Fructus Ulmus preparatium, the mixture of Semen Torreyae.
Its preparation method is: by the CGA-173506 of aforementioned proportion, epoxiconazole, Chinese medicine sterilizing composition, aliphatic alcohol sulfate, alkyl
Phosphate ester and its alkoxide and polyoxyethylene lauryl ether are added together, and are dissolved into homogeneous oil phase;By water, methanol, Arab
Glue, sodium butylnaphthalenesulfonate mix, and become homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, you can sterilization is obtained
Compositionss aqueous emulsion.
Embodiment 5:
A kind of application of the bactericidal composition preventing and treating wheat scab:
Carry out preventing and treating the field prevention and control test of pesticide effectiveness of wheat scab using the bactericidal composition of embodiment 1-4:
For examination hall ground and material: be experimental field arranged in and prevent and treat the river that wheat scab has developed immunity to drugs to traditional medicament
Soviet Union Jurong farm.It is local universal varieties of plant that Semen Tritici aestivi is subject to Varieties.
Test method: test group carries out three dispensers to Semen Tritici aestivi, for the first time for the wheat seed dressing before sowing, is for second little
The administration of dusting at wheat flowering initial stage, applies for the low-gallonage spraying at heading stage, main component in each bactericidal composition for the third time
Consumption be 18g, wherein, spraying apply and administration of dusting time be selected from 3 points in afternoon after.
The matched group of traditional medicament is set in addition, also carries out dispenser, the same test group of insecticide-applying way in three times.
Concrete field efficacy is shown in Table 1:
Table 1: bactericidal composition prevents and treats the test of pesticide effectiveness between wheat scab
Bright from the table of field test results of table 1, traditional medicament has certain prevention and control capability to preventing and treating wheat scab,
All in 70-80%, consumption increases prevention effect, and drug effect improves, and enters according to the formula of bactericidal composition of the present invention
Row preventing and treating, not only effectively reduces sickness rate, disease index, improves prevention effect, and greatly reduce dosage, section
Save substantial amounts of economic input.
It should be pointed out that above specific embodiment is only illustrative of the invention and is not intended to limit the scope of the invention,
After having read the present invention, the modification of the various equivalent form of values to the present invention for the those skilled in the art all falls within power appended by the application
Profit requires limited range.
Claims (9)
1. a kind of bactericidal composition preventing and treating wheat scab is it is characterised in that by weight by the main component of 30%-70%
The carrier composition of 10% auxiliary agent and surplus;Wherein said main component is CGA-173506, epoxiconazole, Chinese medicine sterilizing become to be grouped into,
Wherein Chinese medicine sterilizing Ingredients Weight accounts for the 40% of main component, and the weight of CGA-173506 and epoxiconazole is than for 1:20~20:1.
2. the bactericidal composition preventing and treating wheat scab according to claim 1 it is characterised in that: in described main component
The weight of CGA-173506 and epoxiconazole is than for 1:10~10:1.
3. the bactericidal composition preventing and treating wheat scab according to claim 2 it is characterised in that: in described main component
The weight of CGA-173506 and epoxiconazole is than for 1:4~4:1.
4. the bactericidal composition preventing and treating wheat scab according to claim 3 it is characterised in that: in described main component
The weight of CGA-173506 and epoxiconazole is than for 2:1.
5. the bactericidal composition preventing and treating wheat scab according to claim 1 it is characterised in that: in described main component
Chinese medicine sterilizing composition be selected from Flos Caryophylli, Lignum Sappan, Semen Cassiae, Rhizoma Alpiniae Officinarum, Pericarpium Zanthoxyli, Radix Cirsii Japonici, the Radix Astragali, Rhizoma Curcumae, Cortex Moutan, Radix Paeoniae Rubra, Cortex Fraxini,
At least five kinds combinations in fourth, the Radix Pulsatillae, Radix Polygalae, Rhizoma Polygonati, Omphalia, Semen Arecae, Cortex Meliae, Semen Torreyae, Fructus Ulmus preparatium.
6. the bactericidal composition preventing and treating wheat scab according to claim 1 it is characterised in that: the agent of bactericidal composition
Type is one of aqueous emulsion, wettable powder, suspending agent, water dispersible granules, and corresponding carrier is selected from water, Kaolin, activity
One or more of hargil, clay, bentonite, kieselguhr, attapulgite, precipitated calcium carbonate.
7. the bactericidal composition preventing and treating wheat scab according to claim 1 it is characterised in that: described auxiliary agent be wooden
Plain sodium sulfonate, polymerization alkylaryl sulfonatess, alkyl polyoxyethylene phosphate, tea seed cake powder, spaonin powder, Bombyx mori L., fatty alcohol sulphuric acid
Salt, alkylol polyoxyethylene Oleum Ricini, dodecylbenzene sodium sulfonate, pull open powder, polysorbate60, alkyl phosphate and its alkoxide
Thing, polyoxyethylene carboxylate, phosphate ester and its derivant, polyvinyl alcohol, sodium polyacrylate, sulfate, dimethyl sulfoxide, different
Propanol, gelatinized corn starch, natural gum, Semen Glycines powder, Oleum Terebinthinae, methanol, ethanol, gelatin, arabic gum, lecithin, sodium lauryl sulphate, sulfur
Sour ammonium, alkylphenol polyoxyethylene, polyoxyethylene lauryl ether, phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, sulfonic acid polyformaldehyde
Condensation substance, n- methyl pyrrolidone, alkyl benzene calcium sulfonate, sodium butylnaphthalenesulfonate, benzoic acid, carboxymethyl cellulose, aluminium-magnesium silicate,
One or more of ethyl acetate,.
8. as claimed in claim 1 a kind of application of the bactericidal composition preventing and treating wheat scab it is characterised in that preventing and treating side
Method is that Semen Tritici aestivi is carried out with three dispensers, for the first time for the wheat seed dressing before sowing, applies for dusting of wheat flowering initial stage for second
With applying for the low-gallonage spraying at heading stage for the third time, in each bactericidal composition, the consumption of main component is 15~20g.
9. the application of the bactericidal composition preventing and treating wheat scab according to claim 1 is it is characterised in that spraying is applied
After being selected from 3 points in afternoon with the time of administration of dusting.
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CN114568440A (en) * | 2022-04-07 | 2022-06-03 | 山东亿嘉农化有限公司 | Bactericidal composition containing fluopyram and fludioxonil and application thereof |
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