CN106350941B - A kind of reverse osmosis multifunctional non-woven fabric of antibacterial and its production technology - Google Patents
A kind of reverse osmosis multifunctional non-woven fabric of antibacterial and its production technology Download PDFInfo
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- CN106350941B CN106350941B CN201610839882.XA CN201610839882A CN106350941B CN 106350941 B CN106350941 B CN 106350941B CN 201610839882 A CN201610839882 A CN 201610839882A CN 106350941 B CN106350941 B CN 106350941B
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- miberal powder
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- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
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- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
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Abstract
The invention belongs to the technical fields of non-woven fabrics, and in particular to a kind of reverse osmosis multifunctional non-woven fabric of antibacterial and its production technology.The reverse osmosis multifunctional non-woven fabric area load of the antibacterial has nano anti-biotic material, is made and in the slurry for being impregnated in nano anti-biotic material by non-woven fabrics, according to the mass fraction, 1.5~3 parts of the nano anti-biotic material, 97~98.5 parts of non-woven fabrics;The nano anti-biotic material is magnetic miberal powder.Multifunctional non-woven fabric obtained by the present invention, with good moisture absorbing, antibacterial functions, reverse osmosis function, anti-ultraviolet function, far infrared emission function, it can be widely applied for health fields or other related fieldss such as the high-grade skin-material of disposable adsorption object.The present invention uses magnetic miberal powder as nano anti-biotic material for the first time, avoids using chemical agent as anti-biotic material.The present invention is also modified by carrying out surface to magnetic miberal powder, its dispersion performance in the slurry is improved, to further improve its antibacterial effect.
Description
Technical field
The invention belongs to the technical fields of non-woven fabrics, and in particular to a kind of reverse osmosis multifunctional non-woven fabric of antibacterial and its production
Technique.
Background technique
Non-woven fabrics is also known as nonwoven fabric, is to be made of fiber orient or random, is environment-friendly materials of new generation, has anti-
Damp, ventilative, light, not combustion-supporting, easy the features such as decomposing, is nontoxic nonirritant, rich in color, cheap, recyclable,
Cloth is called because of the appearance and certain performances with cloth.
Non-woven fabrics is widely used in the health fields such as the high-grade skin-material of disposable adsorption object or other are related
Field.But the embodiment of its function mainly uses chemical agent, such as to be sterilized, the functions such as antibacterial, or addition correlative
Material is managed, certain simple function is obtained;In addition existing non-woven fabrics has good moisture absorbing, but after it is under pressure,
Its moisture etc. absorbed can also be infiltrated from a side of absorption.
It is characteristic of the invention that not using chemical agent or additive, mixed with different physical materials, to obtain one
The multi-functional non-woven fabrics of kind.Non-woven fabrics of the present invention has good moisture absorbing, antibacterial functions, reverse osmosis function, uvioresistant function
Energy, far infrared emission function, the irritation of no chemical agent can be applied to high-grade health field.
Summary of the invention
The present invention for had a single function existing for non-woven fabrics in background technique, using the technical issues of chemical agent antibacterial and
A kind of reverse osmosis multifunctional non-woven fabric of antibacterial is provided.
Another object of the present invention is to provide a kind of production technology of reverse osmosis multifunctional non-woven fabric of antibacterial.
The technical solution realizing the object of the invention and using are as follows: a kind of reverse osmosis multifunctional non-woven fabric of antibacterial, the antibacterial are anti-
Infiltration multifunctional non-woven fabric area load has nano anti-biotic material, is by non-woven fabrics by being impregnated in the slurry of nano anti-biotic material
In and be made, according to the mass fraction, 1.5~3 parts of the nano anti-biotic material, 97~98.5 parts of non-woven fabrics;The nanometer is anti-
Bacterium material is magnetic miberal powder.
Preferably, the magnetic miberal powder is surface-modified, specific modification procedure are as follows:
1) magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether are added in grinder, grinding 1~3 is small
When, vinyl magnetic miberal powder is made after drying;
2) it disperses vinyl magnetic miberal powder made from step 1) in butanone solvent, amido silicon oil is added, carries out at dispersion
The modified magnetic miberal powder in surface is made in reason 1~3 hour.
Wherein, the magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether mass ratio be 100:(5~
10): the mass volume ratio of (1~5), the vinyl magnetic miberal powder and butanone is 1g:10mL, the vinyl magnetic miberal powder and amino
The mass ratio of silicone oil is 1:1.
Preferably, the non-woven fabrics is made by two-layer nonwoven web through spun lacing, the dry technique of bundle, wherein described
Two-layer nonwoven web is combined by first layer web and second layer web, according to the mass fraction, the first layer
40~60 parts of web, 40~60 parts of second layer web.
The first layer web and second layer web are by the combing networking of multifunctional non-woven fabric fiber, wherein first layer
Web selects one or more of viscose rayon, cotton fiber or acid fiber by polylactic, and the second layer web is selected double
One or both of component ES fiber or PP fiber.Wherein, the multifunctional non-woven fabric fibre diameter is 26.2~30 μm,
Fiber number is 311~331dtex.
A kind of technical solution realizing another object of the present invention and using are as follows: production of the reverse osmosis multifunctional non-woven fabric of antibacterial
Technique, the specific process steps are as follows:
1) preparation of magnetic miberal powder slurry
Magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether are added in grinder, ground 1~3 hour,
Vinyl magnetic miberal powder is made after drying;It disperses vinyl magnetic miberal powder obtained in butanone solvent, amido silicon oil is added, carry out
Decentralized processing 1~3 hour, the modified magnetic miberal powder in surface is made;
2) preparation of non-woven fabrics
Viscose rayon or cotton fiber or acid fiber by polylactic are combed into networking, as first layer web;Again by two-component
ES fiber or PP fiber comb networking, as second layer web;Second layer web is combined on first layer web, it is multiple
Web after conjunction passes through spun-laced machine spun lacing, dries technique, is made into non-woven fabrics;
3) preparation of the reverse osmosis multifunctional non-woven fabric of antibacterial
By non-woven fabrics made from step 2 as starching machine be impregnated in step 1) made from the modified magnetic miberal powder slurry in surface
In, the obtained non-woven fabrics for being impregnated with nano anti-biotic material magnetic miberal powder is made using drying with the reverse osmosis multi-functional nothing of antibacterial
Woven fabric.
Wherein, first layer web described in step 2 and second layer web, according to the mass fraction, first layer fiber
40~60 parts of net, 40~60 parts of second layer web.
Nano anti-biotic material described in step 3) and non-woven fabrics, according to the mass fraction, 1.5~3 parts of nano anti-biotic material, nothing
98.5~97 parts of woven fabric.
Preferably, the magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether mass ratio are 100:(5
~10): the mass volume ratio of (1~5), the vinyl magnetic miberal powder and butanone is 1g:10mL, the vinyl magnetic miberal powder and ammonia
The mass ratio of base silicone oil is 1:1.
Compared with prior art, technological merit of the invention is: 1) multifunctional non-woven fabric obtained by the present invention has
Good moisture absorbing, antibacterial functions, reverse osmosis function, anti-ultraviolet function, far infrared emission function, can be widely applied for
Health fields or other related fieldss such as the high-grade skin-material of disposable adsorption object.2) present invention uses magnetic miberal powder for the first time
As nano anti-biotic material, avoid using chemical agent as anti-biotic material.3) present invention is also by carrying out surface to magnetic miberal powder
It is modified, its dispersion performance in the slurry is improved, to further improve its antibacterial effect.4) present invention is by passing through first
Layer web and the compound structure design of second layer web and the preferred content of first layer web and second layer web,
By being mixed with different physical materials, not only makes non-woven fabrics that there is good moisture absorbing, also there is reverse osmosis function.5)
Magnetic miberal powder of the present invention also has far infrared emission function and certain ultraviolet absorption ability.
Specific embodiment
Below with reference to embodiment, the present invention will be further described, but unlimited and following several embodiments of the invention.
A kind of production technology of the reverse osmosis multifunctional non-woven fabric of antibacterial of the present invention, comprises the following steps that
1) preparation of magnetic miberal powder slurry;
Magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether are added in grinder, made after grinding, drying
Obtain vinyl magnetic miberal powder;It disperses vinyl magnetic miberal powder obtained in butanone solvent, amido silicon oil is added, carries out at dispersion
The modified magnetic miberal powder slurry in surface is made in reason;
2) preparation of non-woven fabrics;
Viscose rayon or cotton fiber or acid fiber by polylactic are combed into networking, as first layer web;Again by two-component
ES fiber or PP fiber comb networking, as second layer web;Second layer web is combined on first layer web, it is multiple
Web after conjunction passes through spun-laced machine spun lacing, dries technique, is made into non-woven fabrics;
3) preparation of the reverse osmosis multifunctional non-woven fabric of antibacterial;
By non-woven fabrics made from step 2 as starching machine be impregnated in step 1) made from the modified magnetic miberal powder slurry in surface
In, the obtained non-woven fabrics for being impregnated with nano anti-biotic material magnetic miberal powder is made using drying with the reverse osmosis multi-functional nothing of antibacterial
Woven fabric.
Embodiment 1
Magnetic miberal powder 100g, vinyltriethoxysilane 5g and hydroxymethyl cellulose ether 1g are added in grinder, grinding 1
Hour, vinyl magnetic miberal powder is made after drying;It takes vinyl magnetic miberal powder 100g obtained to be scattered in 1L butanone solvent, is added
100g amido silicon oil carries out decentralized processing, and the modified magnetic miberal powder slurry in surface is made.
Selecting diameter is 28 μm, and fiber number is the non-woven fibrous materials of 320dtex.It selects viscose rayon to comb networking, makees
For first layer web;Two-component ES fiber is combed into networking again, as second layer web.Second layer web is combined to
On first layer web, the quality proportioning of first layer web and second layer web are as follows: 45 parts of first layer web, the second layer
55 parts of web.Web after compound passes through spun-laced machine spun lacing, dries technique, is made into non-woven fabrics.
Then pass through starching machine, dipping nano anti-biotic material (the magnetic miberal powder for originating in Brazil), nano anti-biotic material and nonwoven
The quality proportioning of cloth are as follows: 2 parts of nano anti-biotic material, 98 parts of non-woven fabrics;Using stoving process, it is made reverse osmosis more with antibacterial
Functional non-woven fabric.
Embodiment 2
Magnetic miberal powder 100g, vinyltriethoxysilane 10g and hydroxymethyl cellulose ether 5g are added in grinder, grinding
3 hours, vinyl magnetic miberal powder is made after drying;It takes vinyl magnetic miberal powder 100g obtained to be scattered in 1L butanone solvent, is added
100g amido silicon oil carries out decentralized processing, and the modified magnetic miberal powder slurry in surface is made.
Selecting diameter is 28 μm, and fiber number is the non-woven fabrics fiber of 320 dtex.Acid fiber by polylactic is combed into networking, as
One layer of web.Two-component ES fiber is combed into networking again, as second layer web.Second layer web is combined to first
On layer web, the quality proportioning of first layer web and second layer web are as follows: 40 parts of first layer web, second layer fiber
60 parts of net.Web after compound passes through spun-laced machine spun lacing, dries technique, is made into non-woven fabrics.
Then pass through starching machine, dipping nano anti-biotic material (the magnetic miberal powder for originating in Brazil), nano anti-biotic material and nonwoven
The quality proportioning of cloth are as follows: 3 parts of nano anti-biotic material, 97 parts of non-woven fabrics;Using stoving process, it is made reverse osmosis more with antibacterial
Functional non-woven fabric.
Embodiment 3
Magnetic miberal powder 100g, vinyltriethoxysilane 8g and hydroxymethyl cellulose ether 3g are added in grinder, grinding 2
Hour, vinyl magnetic miberal powder is made after drying;It takes vinyl magnetic miberal powder 100g obtained to be scattered in 1L butanone solvent, is added
100g amido silicon oil carries out decentralized processing, and the modified magnetic miberal powder slurry in surface is made.
Selecting diameter is 26.2 μm, and fiber number is the non-woven fabrics fiber of 311 dtex.Cotton fiber is combed into networking, as
One layer of web.Two-component ES fiber is combed into networking again, as second layer web.Second layer web is combined to first
On layer web, the quality proportioning of first layer web and second layer web are as follows: 60 parts of first layer web, second layer fiber
40 parts of net.Web after compound passes through spun-laced machine spun lacing, dries technique, is made into non-woven fabrics.
Then pass through starching machine, dipping nano anti-biotic material (the magnetic miberal powder for originating in Brazil), nano anti-biotic material and nonwoven
The quality proportioning of cloth are as follows: 2.5 parts of nano anti-biotic material, 97.5 parts of non-woven fabrics;Using stoving process, it is made with antibacterial reverse osmosis
Saturating multifunctional non-woven fabric.
Embodiment 4
Magnetic miberal powder 100g, vinyltriethoxysilane 6g and hydroxymethyl cellulose ether 2g are added in grinder, grinding 1
Hour, vinyl magnetic miberal powder is made after drying;It takes vinyl magnetic miberal powder 100g obtained to be scattered in 1L butanone solvent, is added
100g amido silicon oil carries out decentralized processing, and the modified magnetic miberal powder slurry in surface is made.
Selecting diameter is 30 μm, and fiber number is the non-woven fabrics fiber of 331 dtex.Acid fiber by polylactic is combed into networking, as
One layer of web.PP fiber is combed into networking again, as second layer web.Second layer web is combined to first layer fiber
On the net, the quality proportioning of first layer web and second layer web are as follows: 45 parts of first layer web, second layer web 55
Part.Web after compound passes through spun-laced machine spun lacing, dries technique, is made into non-woven fabrics.
Then pass through starching machine, dipping nano anti-biotic material (the magnetic miberal powder for originating in Brazil), nano anti-biotic material and nonwoven
The quality proportioning of cloth are as follows: 1.5 parts of nano anti-biotic material, 98.5 parts of non-woven fabrics;Using stoving process, it is made with antibacterial reverse osmosis
Saturating multifunctional non-woven fabric.
Claims (8)
1. a kind of reverse osmosis multifunctional non-woven fabric of antibacterial, it is characterised in that: the reverse osmosis multifunctional non-woven fabric area load of the antibacterial
It has nano anti-biotic material, is made and in the slurry for being impregnated in nano anti-biotic material by non-woven fabrics, according to the mass fraction, institute
1.5~3 parts of the nano anti-biotic material stated, 97~98.5 parts of non-woven fabrics;The nano anti-biotic material is magnetic miberal powder;
The magnetic miberal powder is surface-modified, specific modification procedure are as follows:
Magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether are added in grinder, ground 1~3 hour, drying
Vinyl magnetic miberal powder is made afterwards;
It disperses vinyl magnetic miberal powder made from step 1) in butanone solvent, amido silicon oil is added, carry out decentralized processing 1~3
Hour, the modified magnetic miberal powder in surface is made;
Magnetic miberal powder, vinyltriethoxysilane and the hydroxymethyl cellulose ether mass ratio is 100:(5~10): (1~
5), the mass volume ratio of the vinyl magnetic miberal powder and butanone is 1g:10mL, the matter of the vinyl magnetic miberal powder and amido silicon oil
Amount is than being 1:1.
2. the reverse osmosis multifunctional non-woven fabric of antibacterial according to claim 1, it is characterised in that: the non-woven fabrics is by two layers
Non-woven fabrics fiber net through spun lacing, prick dry technique and be made, wherein the two-layer nonwoven web is by first layer web and the
Bilaminar fiber net is combined, according to the mass fraction, 40~60 parts of the first layer web, second layer web 60~40
Part.
3. the reverse osmosis multifunctional non-woven fabric of antibacterial according to claim 2, it is characterised in that: the first layer web and
Second layer web combs networking by multifunctional non-woven fabric fiber, wherein first layer web selects viscose rayon, cotton fiber
Or one or more of acid fiber by polylactic, the second layer web select one of two-component ES fiber or PP fiber or
Two kinds.
4. the reverse osmosis multifunctional non-woven fabric of antibacterial according to claim 3, it is characterised in that: the multifunctional non-woven fabric
Fibre diameter is 26.2~30 μm, and fiber number is 311~331dtex.
5. a kind of technique for producing the reverse osmosis multifunctional non-woven fabric of antibacterial as described in claim 1, it is characterised in that: concrete technology
Steps are as follows:
The preparation of magnetic miberal powder slurry
Magnetic miberal powder, vinyltriethoxysilane and hydroxymethyl cellulose ether are added in grinder, ground 1~3 hour, drying
Vinyl magnetic miberal powder is made afterwards;It disperses vinyl magnetic miberal powder obtained in butanone solvent, amido silicon oil is added, is dispersed
The modified magnetic miberal powder slurry in surface is made in processing 1~3 hour;
The preparation of non-woven fabrics
Viscose rayon or cotton fiber or acid fiber by polylactic are combed into networking, as first layer web;It is again that two-component ES is fine
Dimension or PP fiber comb networking, as second layer web;Second layer web is combined on first layer web, after compound
Web by spun-laced machine spun lacing, dry technique, be made into non-woven fabrics;
The preparation of the reverse osmosis multifunctional non-woven fabric of antibacterial
By non-woven fabrics made from step 2) as starching machine be impregnated in step 1) made from the modified magnetic miberal powder slurry in surface, system
It must be impregnated with the non-woven fabrics of nano anti-biotic material magnetic miberal powder, using drying, be made with the reverse osmosis multifunctional non-woven fabric of antibacterial.
6. the technique of the reverse osmosis multifunctional non-woven fabric of antibacterial according to claim 5, it is characterised in that: described in step 2)
First layer web and second layer web, according to the mass fraction, 40~60 parts of first layer web, second layer web 40~
60 parts.
7. the technique of the reverse osmosis multifunctional non-woven fabric of antibacterial according to claim 6, it is characterised in that: received described in step 3)
Nano antibacterial material and non-woven fabrics, according to the mass fraction, 1.5~3 parts of nano anti-biotic material, 97~98.5 parts of non-woven fabrics.
8. the technique of the reverse osmosis multifunctional non-woven fabric of antibacterial according to claim 7, it is characterised in that: the magnetic miberal powder,
Vinyltriethoxysilane and hydroxymethyl cellulose ether mass ratio are 100:(5~10): (1~5), the vinyl magnetic miberal powder
It is 1g:10mL with the mass volume ratio of butanone, the mass ratio of the vinyl magnetic miberal powder and amido silicon oil is 1:1.
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CN1251399A (en) * | 1998-10-21 | 2000-04-26 | 海南欣龙无纺股份有限公司 | Hydro-entangled compound non-woven cloth and its production method |
CN1624234A (en) * | 2004-10-22 | 2005-06-08 | 上海工程技术大学 | Modified nanometer dxide multifunction finishing agent, preparation method and its use |
CN101307563A (en) * | 2008-06-17 | 2008-11-19 | 苏州大学 | Nanometer silver antibiotic textile finishing method |
CN103882704A (en) * | 2012-12-22 | 2014-06-25 | 青岛同冠王实业有限公司 | Preparation method for anti-microbial non-woven fabric |
CN106618870A (en) * | 2017-01-25 | 2017-05-10 | 深圳市前海州福科技有限公司 | Method for manufacturing physiotherapeutic sanitary towel |
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CN1251399A (en) * | 1998-10-21 | 2000-04-26 | 海南欣龙无纺股份有限公司 | Hydro-entangled compound non-woven cloth and its production method |
CN1624234A (en) * | 2004-10-22 | 2005-06-08 | 上海工程技术大学 | Modified nanometer dxide multifunction finishing agent, preparation method and its use |
CN101307563A (en) * | 2008-06-17 | 2008-11-19 | 苏州大学 | Nanometer silver antibiotic textile finishing method |
CN103882704A (en) * | 2012-12-22 | 2014-06-25 | 青岛同冠王实业有限公司 | Preparation method for anti-microbial non-woven fabric |
CN106618870A (en) * | 2017-01-25 | 2017-05-10 | 深圳市前海州福科技有限公司 | Method for manufacturing physiotherapeutic sanitary towel |
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