CN106349801A - Compound active mineral environment-friendly ink - Google Patents

Compound active mineral environment-friendly ink Download PDF

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CN106349801A
CN106349801A CN201610735633.6A CN201610735633A CN106349801A CN 106349801 A CN106349801 A CN 106349801A CN 201610735633 A CN201610735633 A CN 201610735633A CN 106349801 A CN106349801 A CN 106349801A
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oil
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herba
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史玉桂
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/16—Writing inks
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/06—Printing inks based on fatty oils
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The environment-friendly composite active mineral ink comprises the following components in parts by weight: 23 parts of pigment color paste, 19 parts of bisphenol A, 4.5 parts of glycerol, 2.3 parts of anhydrous sodium sulfate, 2.7 parts of triethanolamine, 3.3 parts of triethylamine, 3.6 parts of acetone, 0.25 part of dithiocarbamic acid ester and 1.7 parts of active mineral powder.

Description

A kind of built reactive mineral environment-friendly ink
The application is the Application No. 2016107230304 that 2016 applyings date August is submitted on the 25th, invention entitled " one The divisional application of the Chinese invention patent application of kind built reactive mineral environment-friendly ink ".
Technical field
The present invention relates to a kind of built reactive mineral environment-friendly ink.
Background technology
Ink can be used for routine office work or textile printing field, but traditional general ink do not have refresh oneself and generation bear from The health-care effects such as son, user using with producing taediumvitae, due to the single function of traditional ink, can not meet people when long Multi-demandses.
Content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of abnormal smells from the patient pure and fresh for the user of ink, has and refreshes oneself Effect and the ink of negative ion health effect, it not only can discharge negative aeroion, purify air for a long time, is good for beneficial to human body Health；Also to staphylococcuses, escherichia coli, gram-positive bacteria etc., multiple pathogenic bacterias and funguses have certain suppression, killing action；With When fragrant odour, pure and fresh soothe the spirit, pressure of releiving, also can expelling mosquito, will not to human body produce harmful effect, have widely Application prospect.
The purpose of the present invention is achieved by the following technical solution:
A kind of built reactive mineral environment-friendly ink it is characterised in that: by following component by weight: dispersible pigment color paste 23 weight portions, bis-phenol a19 weight portion, glycerol 4.5 weight portion, anhydrous sodium sulfate 2.3 weight portion, triethanolamine 2.7 weight portion, three Ethamine 3.3 weight portion, acetone 3.6 weight portion, double thiocarbamate 0.25 weight portions, active mineral matter powder 1.7 weight portion, Surfactant blend 1.2 weight portion, slow releasing agent 0.55 weight portion, essential oil of traditional Chinese medicine 3.85 weight portion, deionized water 62 weight Part, the pigment of described mill base is high-carbon black pigment, and the mean diameter of described dispersible pigment color paste is 75nm, described active mineral matter powder For germanite, fluorite, tourmaline, gahnite by weight 2.5:3:3.7:2 mixture, wherein tourmaline be dravite and By weight the mixture of 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine leads to elbaite Cross following steps to be prepared from,
S1, take Herba Desmodii Triquetri (Herba Tadehagi Triquetri) 35 weight portion clean, naturally dry, be subsequently placed in 90 DEG C of frying pans and fry to savory effusion, then spray Drench deionized water 17 weight portion, be placed in constant temperature oven less than 60 DEG C and dry, water content≤6.5%；
S2, Folium Bambusae 14.5 weight portion is cleaned, puts in saline and soak 3.5 hours, the salt water yield by immersion spice quality 3.7 Times, put into and steam in pot thoroughly, take out, dry, the concentration of saline is 27%；
S3, by Semen Pharbitidiss 15.5 weight portion, lavandula angustifolia 12 weight portion, Herba Anemones Hupehensiss 4.5 weight portion, Stigma Croci 1 weight portion, gold Flos Lonicerae 1 weight portion, Origanum majorana 0.75 weight portion decontamination, put into super micron mill together with step s1 and the made crude drug of s2 In be crushed to 60 mesh, prepared crude drug powder, standby；
S4, by step s3 be obtained crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, adjust extraction Pressure power 27.65mpa, 45.10 DEG C of extraction temperature, carbon dioxide flow is 0.6m3/ h, dynamic extraction 2.5h, are directly separating Kettle outlet triangular flask collects volatile oil a, standby；
S5, by Cortex ulmi pumilae 8.5 weight portion, Lignum Aquilariae Resinatum 2.5 weight portion, Lignum cinnamomi camphorae 15.5 weight portion, Rhizoma Acori Graminei 4.5 weight portion, Herba Menthae 1 weight Amount part, Radix Scutellariae 1 weight portion is cleaned and is dried, and puts in super micron mill together and is crushed to 70 mesh, then plus deionized water soak 6 little When, amount of water by 6.5 times of immersion crude drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby；
S6, the Traditional Chinese drug mixture that step s5 is obtained decoct 2 hours in 80 DEG C, collect distillate, and add ether to extract, distillation Then plus anhydrous sodium sulfate drying the volume ratio of liquid and ether is 2:1, takes upper oil phase, that is, volatile oil b is obtained, standby；
S7, step s4 and s6 made volatile oil a and volatile oil b mixing are mixed well prepared miscella, then sequentially add while stirring Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress quintessence oil, are sufficiently stirred for 35 minutes, stand 30 minutes, fill Stirring is divided to mix well, filtering and impurity removing, obtain final product essential oil of traditional Chinese medicine, wherein, described miscella is smart with Flos Rosae Rugosae quintessence oil, P-Cymene, Flos Pelargonii The mass ratio of oil, tea tree ethereal oil and cypress quintessence oil is 1.3:0.4:0.75:0.6:0.5:0.3.
In a preferred embodiment, also include Herba Origani oil 1.3 weight portion in the crude drug powder of step s3 and spend in vain Pyrethrum 1.5 weight portion.
In a preferred embodiment, the Traditional Chinese drug mixture of step s5 also includes Borneolum Syntheticum 0.6 weight portion and Folium Nelumbinis 0.4 Weight portion.
In a preferred embodiment, the essential oil of traditional Chinese medicine of step s7 also includes Eucalyptus oil 0.3 weight portion.
Equipment involved in the present invention, raw material and method, are the usual equipment using of the industry, raw material and method, This repeats no more.
Wherein each essential oil component must be sufficiently mixed with surfactant, slow releasing agent, to reach slow release effect, each quintessence oil and The addition of anion natural mineral powder must be appropriate, and not only antibiotic and sterilizing is moreover it is possible to stable emotion, so to the not normal heart Reason state has the effect in front, can purify, pacify soul, can mitigate angry and beaten sensation, and making one can be with the flat gas of the heart With ground to life, because its energy centre of equilibrium nerve, helpful to alarmed and dejected state, also have significantly flat Quiet with releive function, insomniac is had goodish relax to put console with spirit, for pacify hot-tempered enter or moody temper have Goodish effect, can improve work efficiency.
The present invention with reference to modern Chinese medicine pharmacological research, verifies from the drug screening of existing Chinese medicine and repeatedly, gives full play to respectively Group weight portion synergism, wherein each Chinese medicinal components are described as follows.
Herba Desmodii Triquetri (Herba Tadehagi Triquetri), is pulse family beggar-ticks plant.Possess heat-clearing and toxic substances removing, removing food stagnancy dampness removing, parasite killing anti-corrosion the effects such as, can be used for Prevention heatstroke, treatment cold, fever, laryngopharynx swelling and pain, nephritis etc..
Folium Bambusae: there is excellent free radical resisting, antioxidation, resisting fatigue, expansion blood capillary, dredging microcirculation, activation greatly Brain, promote remember, improve the health care of sleep, anticancer, beautify skin the effects such as.According to research reports, its natural biological flavone antagonism Bone marrow toxicity and the impact of immunological function repression that cancer guiding drug rises, to patients with coronary heart disease microcirculation, the impact of platelet function and The improvement of myocardium bleeding.
Semen Pharbitidiss: cold in nature, bitter in the mouth；Poisonous, removing water retention by purgation relieving constipation, drink is washed in expectorant, and parasite killing is attacked long-pending.For oedema turgor, two are not just Logical, phlegm retention is gathered, and QI rising in reverse order is breathed with cough, abdominal pain due to worm stagnation
Lavandula angustifolia not only can replace camphor ball moreover it is possible to leave one except ant, except roach, acaricide when being placed under wardrobe, medicated pillow Stock oozes the fragrance of people, and research finds, lavandula angustifolia has obvious antibacterial action, and the linalool containing in lavandula angustifolia is lavandula angustifolia antibacterial Main component, it can suppress 17 kinds of antibacterials (include gram-negative bacteria and gram-positive bacteria), the growth of 10 kinds of funguses.
Herba Anemones Hupehensiss: 1. " Shaanxi Chinese herbal medicine ": " bitter, cool, slightly poisonous." 2. " Chinese herbal medicine is commonly used in Sichuan ": " and toil, temperature, Slightly poisonous." removing toxic substances, evacuation of pus granulation promoting, scattered stasis detumescence, have and kill maggot, wriggler, change long-pending, detumescence, dissipating blood stasis, control stubborn dermatitis, tinea alba, malaria Disease, infantile malnutrition, dysentery, carbuncle furuncle swells, scrofula, traumatic injury.
Stigma Croci: there is powerful physiologically active, its stigma has calmness, eliminating the phlegm, spasmolytic in Asia and Europe as medicinal Effect, is abroad used as calm, carminative, blood circulation promoting and blood stasis dispelling, removing pathogenic heat from blood and toxic substance from the body, resolving stagnation for tranquilization.Maculae caused by violent heat pathogen, melancholy painful abdominal mass are vexed, palpitation with fear is sent out Mad.
Flos Lonicerae: its effect is mainly heat-clearing and toxic substances removing, to pharmacological components such as chlorogenic acid, cyanidenon glycosides, to golden yellow Color staphylococcuses, Hemolytic streptococcuss, escherichia coli, dysentery bacterium, vibrio cholera, Bacillus typhi, Salmonella paratyphi etc. all have Certain inhibitory action, also effective to streptococcus pneumoniae, meningococcus, bacillus pyocyaneus, tubercule bacillus, also can enhancing immunity.
Origanum majorana: can improve that mood is depressed and addictive disease, especially to liberal-mindedness and vigorous endurance stress symptom effectively, can expansion of blood vessels, Blood pressure lowering, mitigation and burden, help eliminate cardiopalmus, have excellent nerve to pacify and calm function.
Cortex ulmi pumilae: the dry bark for Ulmaceae or root bark, sweet, flat, nontoxic；Diuretic, treating stranguria, detumescence, for urine Obstructed, stranguria with turbid discharge, edema, carbuncle carbuncle on the back, erysipelas, scabies.
Lignum Aquilariae Resinatum: " Compendium of Materia Medica " record wood has strong antibacterial efficacy, fragrance enters spleen, god's qi-regulating, tonifying five ZANG-organses, cough-relieving clearly Resolving sputum, warming the stomach warming the spleen, ventilation analgesic therapy, can be used as medicine, be first-class medical material superfine product.
Lignum cinnamomi camphorae: aiphyllium, bark yellowish-brown, there is irregular longitudinal crack, on the south main product the Changjiang river and southwestern various places.Winter Cut down trees and split broken or be sawn into bulk, dry or air-dry.Timber bulk is not of uniform size, surface rufous to burgundy, and transverse section is visible Annual ring.Matter is again hard.There is strong Camphora fragrance, taste is refrigerant, have pungent sense, warm in nature, acrid in the mouth；Sensible can ward off dirty, warming middle-JIAO to stop Bitterly, dampness removing parasite killing.
Rhizoma Acori Graminei: its flower, stem aromatic flavor, have functions that to have one's ideas straightened out, eliminating the phlegm, dissipate wind, epidemic disease of can dispelling Fructus Alpiniae Oxyphyllae, building body, can Make spice or mosquito dispersing.
Herba Menthae: for the dry aerial parts of labiate Herba Menthae, dispelling wind and heat pathogens, the sharp clearly head, sore-throat relieving rash, soothing the liver row Gas.
Radix Scutellariae: antibacterial, antiviral, there is suppression to make multiple gram positive bacterias, gram-negative bacteria, pathogenic dermatophytess With suppression influenza virus, hepatitis B viruss.
Flos Rosae Rugosae quintessence oil: have antibacterial, sterilize, promote the sexual maturity, calm, the effects such as mend body, have and smooth emotion, improve mood, relax Delay nervous and pressure, woman can be made to produce impression actively and positively to self, its natural fragrance enters people through olfactory nervess After body, spiritual happiness, satisfied can be made one, alleviate anxiety, depression, pressure, help for sleep, enhance metabolism, sanguimotor Effect.
P-Cymene: to anthrax bacillus, Alpha-hemolytic streptococcus, b- Streptococcus hemolyticuss, diphtheria corynebacterium, bacillus pseudodiphthericus, lung 10 kinds of Gram-positives such as diplococcoid, staphylococcus aureuses, Staphylococcus citreus, white Portugal Portugal coccus, bacillus subtilis Aerophil all has antibacterial action, also has bacteriostasis for multiple pathomycetes.
Geranium Essential: there is hemostasis, vasoconstrictive, asthma, liver and expelling toxin, cholelithiasis, kidney toxin expelling, renal calculuss, diuresis, flesh Carnic acid pain, oily skin, aging skin activates, herpess, palor, fat-reducing, promotes to scab, eczema, sunburn of burning, tinea, the moon Through having some setbacks, engorgement of breasts inflammation, mitigate melancholy uneasy, there is deodorization, antibacterial, the effect of sterilization.
Tea tree ethereal oil: for air cleaning, elimination of off flavor, deodorization, insect protected is dust-proof to be hidden from, to Candida albicans, staphylococcuses Contour disease carrying germ has the effect of killing, and is effective against 26 kinds of dermatophytes, 32 kinds of Candida albicans and 22 kinds of little sporeformer, It is potent antibiotic essential oil.
Cypress quintessence oil: have a charming succinum taste as wooden and face cream, rheumatism, antibacterial, spasmolytic, suppression diaphoresis, convergence, Promote to scab, except bromhidrosis, diuresis, bring down a fever, stop blooding, sharp liver, parasite killing, rehabilitation, calmness, astringing to arrest bleeding, benefit body, vasoconstrictive.Disappear Except fatigue, angry emotion of releiving, alleviate heart anxiety and pressure, purification of the mind.
Herba Origani oil: the herb of Labiatae origanum Adeps Bovis seu Bubali origznum vul-garel., also known as careless, the wild chaste tree of dysentery relieving The ground such as mustard accord with name, have heat clearing away, removing dampness, driving away summer heat, induce sweat, sterilization that qi-regulating is extremely strong, bacteriostasis, the volatilization extracted from Adeps Bovis seu Bubali Oil, cause enteritis antibacterial common to 31 kinds and shigella flexneri, are the pure Chinese medicine additives of most broad-spectrum antiseptic.
Herba et Flos Pyrethri Cinerariifolii: Tanacetum vulgare L belongs to the general designation of (tanacetum) several plants, removing dampness and killing parasites, kills pubic louse, head louse, body Louse, flea, the effect except mosquito parasite killing.
Borneolum Syntheticum: pungent, bitter, cool.There is inducing resuscitation of having one's ideas straightened out, heat-clearing dissipates poison, improving acuity of vision and removing nebula.Cure mainly high fever apoplexy coma due to blocking of the respiratory system shies epilepsy, middle wind-phlegm Faint infantile convulsion, summer-heat and damp blinds clear key, larynx numbness is deaf, aphtha tooth swells, sore carbuncle infantile malnutrition due to digestive disturbances or intestinalparasites hemorrhoid, conjunctival congestion and swelling pain, pterygium.
Folium Nelumbinis: for the leaf of nymphaeaceae plant lotus, play the role of heat-clearing and toxic substances removing, removing heat from blood, hemostasis.There is clearing away summer-heat and eliminating dampness, rise and send out clearly The effects such as sun, cooling blood for hemostasis.
Eucalyptus oil: one of most common and widest quintessence oil of purposes, there is good health-care effect, help focused attention Power.Sinus infection, influenza, bronchitis, cold nasal obstruction and other respiratory system diseases can effectively be alleviated.There is good resisting Bacterium and sterilization idiocratic, in some certain food, Eucalyptus oil is also as fragrance component.Carry this quintessence oil in travelling, permissible Effectively resist mosquito bite and insect bite, treat skin measles.It is good anophelifuge.Mixing with water can become a kind of and simple and effective disappear Toxic agent.
Beneficial effects of the present invention:
The present invention provides a kind of abnormal smells from the patient pure and fresh for user, has stimulating effect and the ink of negative ion health effect, it is not only Negative aeroion can be discharged for a long time, purify air, beneficial to health；Also thin to staphylococcuses, escherichia coli, Grain-positive Multiple pathogenic bacteria such as bacterium and funguses have certain suppression, killing action；Fragrant odour simultaneously, pure and fresh soothe the spirit, pressure of releiving, also can drive Catch up with mosquito, harmful effect will not be produced it is adaptable to each age groups to human body, its appropriate add other function ingredients after still Original effect and quality can be kept.
1st, tourmaline is a kind of silicate mineral, and its chemical formula is na (mg, fe, mn, li, al) 3al6 (si6o18) (bo3) 3 (oh, f) 4, it contacts under electrostatic field with hydrone, just hydrone can be ionized into hydrion (h+) and hydrogen-oxygen Radical ion (oh-), hydroxide ion and water molecules form basic hydroxide group anion (h2o oh-), as " air bear from Son ", current scientific research proves: anion can not only facilitate human body synthesis and vitamin storage, the life of strengthening and human activin Reason activity, has highly important impact to the vital movement of human body and other biological, is referred to as " air vitamin ".Anion Active adsorption interior harmful substance, the such as construction and decoration harmful substance such as formaldehyde, toluene, not only itself do not increase pollution, Er Qieqing Purifying room air, is inherently eliminated construction and decoration syndrome, ensures that health is unaffected.
2nd, the Chinese medicine ingredients containing in the present invention, not only thin to staphylococcuses, tubercule bacillus, bacillus pyocyaneus, Grain-negative Multiple pathogenic bacteria such as bacterium and gram-positive bacteria and funguses have certain suppression, killing action；Fragrant odour simultaneously, property is gentle, Pure and fresh soothe the spirit, help hormone secretion, the effect of anxiety of releiving, also there is certain mosquito-repelling effect simultaneously, more it is essential that The life-time service present invention will not produce harmful effect it is adaptable to each age groups to human body, before having application widely Scape.
Specific embodiment
Embodiment.
A kind of built reactive mineral environment-friendly ink it is characterised in that: by following component by weight: pigment Mill base 23 weight portion, bis-phenol a19 weight portion, glycerol 4.5 weight portion, anhydrous sodium sulfate 2.3 weight portion, triethanolamine 2.7 weight Part, triethylamine 3.3 weight portion, acetone 3.6 weight portion, double thiocarbamate 0.25 weight portions, active mineral matter powder 1.7 weight Amount part, surfactant blend 1.2 weight portion, slow releasing agent 0.55 weight portion, essential oil of traditional Chinese medicine 3.85 weight portion, deionized water 62 Weight portion, the pigment of described mill base is high-carbon black pigment, and the mean diameter of described dispersible pigment color paste is 75nm, described active mineral Matter powder is germanite, fluorite, tourmaline, the gahnite mixture of 2.5:3:3.7:2 by weight, and wherein tourmaline is that magnesium is electric Stone and elbaite by weight the mixture of 5:3, particle diameter≤13 μm of described active mineral matter powder, wherein said middle YAOJING Oil is made by the steps and forms,
S1, take Herba Desmodii Triquetri (Herba Tadehagi Triquetri) 35 weight portion clean, naturally dry, be subsequently placed in 90 DEG C of frying pans and fry to savory effusion, then spray Drench deionized water 17 weight portion, be placed in constant temperature oven less than 60 DEG C and dry, water content≤6.5%；
S2, Folium Bambusae 14.5 weight portion is cleaned, puts in saline and soak 3.5 hours, the salt water yield by immersion spice quality 3.7 Times, put into and steam in pot thoroughly, take out, dry, the concentration of saline is 27%；
S3, by Semen Pharbitidiss 15.5 weight portion, lavandula angustifolia 12 weight portion, Herba Anemones Hupehensiss 4.5 weight portion, Stigma Croci 1 weight portion, gold Flos Lonicerae 1 weight portion, Origanum majorana 0.75 weight portion decontamination, put into super micron mill together with step s1 and the made crude drug of s2 In be crushed to 60 mesh, prepared crude drug powder, standby；
S4, by step s3 be obtained crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, adjust extraction Pressure power 27.65mpa, 45.10 DEG C of extraction temperature, carbon dioxide flow is 0.6m3/ h, dynamic extraction 2.5h, are directly separating Kettle outlet triangular flask collects volatile oil a, standby；
S5, by Cortex ulmi pumilae 8.5 weight portion, Lignum Aquilariae Resinatum 2.5 weight portion, Lignum cinnamomi camphorae 15.5 weight portion, Rhizoma Acori Graminei 4.5 weight portion, Herba Menthae 1 weight Amount part, Radix Scutellariae 1 weight portion is cleaned and is dried, and puts in super micron mill together and is crushed to 70 mesh, then plus deionized water soak 6 little When, amount of water by 6.5 times of immersion crude drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby；
S6, the Traditional Chinese drug mixture that step s5 is obtained decoct 2 hours in 80 DEG C, collect distillate, and add ether to extract, distillation Then plus anhydrous sodium sulfate drying the volume ratio of liquid and ether is 2:1, takes upper oil phase, that is, volatile oil b is obtained, standby；
S7, step s4 and s6 made volatile oil a and volatile oil b mixing are mixed well prepared miscella, then sequentially add while stirring Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress quintessence oil, are sufficiently stirred for 35 minutes, stand 30 minutes, fill Stirring is divided to mix well, filtering and impurity removing, obtain final product essential oil of traditional Chinese medicine, wherein, described miscella is smart with Flos Rosae Rugosae quintessence oil, P-Cymene, Flos Pelargonii The mass ratio of oil, tea tree ethereal oil and cypress quintessence oil is 1.3:0.4:0.75:0.6:0.5:0.3.
In a preferred embodiment, also include Herba Origani oil 1.3 weight portion in the crude drug powder of step s3 and spend in vain Pyrethrum 1.5 weight portion.
In a preferred embodiment, the Traditional Chinese drug mixture of step s5 also includes Borneolum Syntheticum 0.6 weight portion and Folium Nelumbinis 0.4 Weight portion.
In a preferred embodiment, the essential oil of traditional Chinese medicine of step s7 also includes Eucalyptus oil 0.3 weight portion.
Test the ink in this above-described embodiment using air ion static method of testing, anion burst size is in 430-650 Individual/m3, and sustained release negative aeroion, it is more beneficial for long-term purify air, reach the basic demand of health of people.
Reference examples.
Colour carbon black 20g, phenol 11g, glycerol 4g, BTA 3g, triethanolamine 1g, triethylamine 3g, sodium bicarbonate 5g, polyoxyethylene groups ethers nonionic fluorocarbon surfactant 1.5g, slow releasing agent 0.4g, Origanum majorana quintessence oil 0.6g, Semen Tritici aestivi Bud quintessence oil 0.5g, Herba Lysimachiae foenum-graeci quintessence oil 0.5g, Radix Paeoniae Alba quintessence oil 0.4g, cypress quintessence oil 0. 4g, eucalyptus quintessence oil 0.4g, Folium Artemisiae Argyi essence Oily 0. 4g, Peppermint essential oil 0.4g, deionized water 75g.
Test the ink in this above-mentioned reference examples using air ion static method of testing, anion burst size is in 0/m3, There is no the function of release negative aeroion.
(1) acute toxicity test is carried out to obtained essential oil of traditional Chinese medicine, result is as follows:
1. Mouse oral acute toxicity test: the ld50 of Mouse oral essential oil of traditional Chinese medicine is 383.55g/kg, 95% credible is limited to 294.68g/kg～499.31g/kg.And the toxicity criterion of air freshener is: Mouse oral anxious poison ld50 >=5g/ Kg, is judged to nontoxic.The ld50 of this essential oil of traditional Chinese medicine is higher than 76 times of nontoxic standard, therefore, it is determined that being nontoxic.
2. chmice acute toxicity on inhalation test: the lc50 that chmice acute sucks essential oil of traditional Chinese medicine is 24863.99g/m3,95% Credible be limited to 16837.34g/m3～33387.46g/m3.And the toxicity criterion of air freshener is: chmice acute Suck (2h) lc50 ＞ 10000mg/m3, the nontoxic level in true border.The lc50 of this essential oil of traditional Chinese medicine is higher than the 2486 of nontoxic standard Times, therefore, it is determined that being nontoxic.
Through inspection, its fragrance, color and luster, refraction index, relative density, arsenic content, heavy metal contain obtained essential oil of traditional Chinese medicine Amount, ph value all meet the requirement of national standard.
(2) check above-mentioned ink anion burst size result such as table 1:
(3) repelling effect test.
Repelling effect according to common ink of the prior art and ink in above-described embodiment carries out contrast test, test Data is shown in Table 2.
Conclusion: the ink in the embodiment of the present invention has preferable repelling effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, common for art For technical staff, can also make other changes in different forms on the basis of the above description, here need not All of embodiment cannot be exhaustive, all any modifications within the spirit and principles in the present invention, made, equivalent replace Change, improve, be still included within protection scope of the present invention.

Claims (1)

1. a kind of built reactive mineral environment-friendly ink it is characterised in that: by following component by weight: pigment colour Starch 23 weight portions, bis-phenol a19 weight portion, glycerol 4.5 weight portion, anhydrous sodium sulfate 2.3 weight portion, triethanolamine 2.7 weight portion, Triethylamine 3.3 weight portion, acetone 3.6 weight portion, double thiocarbamate 0.25 weight portions, active mineral matter powder 1.7 weight Part, surfactant blend 1.2 weight portion, slow releasing agent 0.55 weight portion, essential oil of traditional Chinese medicine 3.85 weight portion, deionized water 62 weight Amount part, the pigment of described mill base is high-carbon black pigment, and the mean diameter of described dispersible pigment color paste is 75nm, described active mineral matter Powder is germanite, fluorite, tourmaline, the gahnite mixture of 2.5:3:3.7:2 by weight, and wherein tourmaline is dravite With elbaite by weight 5:3 mixture, particle diameter≤13 μm of described active mineral matter powder, wherein said essential oil of traditional Chinese medicine It is made by the steps and form,
S1, take Herba Desmodii Triquetri (Herba Tadehagi Triquetri) 35 weight portion clean, naturally dry, be subsequently placed in 90 DEG C of frying pans and fry to savory effusion, then spray Drench deionized water 17 weight portion, be placed in constant temperature oven less than 60 DEG C and dry, water content≤6.5%；
S2, Folium Bambusae 14.5 weight portion is cleaned, puts in saline and soak 3.5 hours, the salt water yield by immersion spice quality 3.7 Times, put into and steam in pot thoroughly, take out, dry, the concentration of saline is 27%；
S3, by Semen Pharbitidiss 15.5 weight portion, lavandula angustifolia 12 weight portion, Herba Anemones Hupehensiss 4.5 weight portion, Stigma Croci 1 weight portion, gold Flos Lonicerae 1 weight portion, Origanum majorana 0.75 weight portion, Herba Origani oil 1.3 weight portion and Herba et Flos Pyrethri Cinerariifolii 1.5 weight portion decontamination, with Put into together with step s1 crude drug made with s2 and in super micron mill, be crushed to 60 mesh, prepared crude drug powder, standby；
S4, by step s3 be obtained crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, adjust extraction Pressure power 27.65mpa, 45.10 DEG C of extraction temperature, carbon dioxide flow is 0.6m3/ h, dynamic extraction 2.5h, are directly separating Kettle outlet triangular flask collects volatile oil a, standby；
S5, by Cortex ulmi pumilae 8.5 weight portion, Lignum Aquilariae Resinatum 2.5 weight portion, Lignum cinnamomi camphorae 15.5 weight portion, Rhizoma Acori Graminei 4.5 weight portion, Herba Menthae 1 weight Amount part, Radix Scutellariae 1 weight portion, Borneolum Syntheticum 0.6 weight portion and Folium Nelumbinis 0.4 weight portion are cleaned and are dried, and put into powder in super micron mill together Be broken to 70 mesh, then plus deionized water soaks 6 hours, amount of water by 6.5 times of immersions crude drug quality, dispersed with stirring tune Even, prepared Traditional Chinese drug mixture, standby；
S6, the Traditional Chinese drug mixture that step s5 is obtained decoct 2 hours in 80 DEG C, collect distillate, and add ether to extract, distillation Then plus anhydrous sodium sulfate drying the volume ratio of liquid and ether is 2:1, takes upper oil phase, that is, volatile oil b is obtained, standby；
S7, step s4 and s6 made volatile oil a and volatile oil b mixing are mixed well prepared miscella, then sequentially add while stirring Flos Rosae Rugosae quintessence oil, P-Cymene, Geranium Essential, tea tree ethereal oil and cypress quintessence oil, are sufficiently stirred for 35 minutes, stand 30 minutes, fill Stirring is divided to mix well, filtering and impurity removing, obtain final product essential oil of traditional Chinese medicine, wherein, described miscella is smart with Flos Rosae Rugosae quintessence oil, P-Cymene, Flos Pelargonii The mass ratio of oil, tea tree ethereal oil and cypress quintessence oil is 1.3:0.4:0.75:0.6:0.5:0.3, also comprises in described essential oil of traditional Chinese medicine There is Eucalyptus oil 0.3 weight portion.
CN201610735633.6A 2016-02-19 2016-08-25 Compound active mineral environment-friendly ink Pending CN106349801A (en)

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CN107828277A (en) * 2017-11-09 2018-03-23 江苏淮阴华新纸品有限公司 A kind of environment-friendly type aqueous ink and preparation method thereof

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CN106009534A (en) * 2016-05-23 2016-10-12 魏国营 Multifunctional environment-friendly lampshade structure
CN106084988B (en) * 2016-06-17 2019-03-19 苍南县宝丰印业有限公司 A kind of multifunctional water-based ink

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CN107828277A (en) * 2017-11-09 2018-03-23 江苏淮阴华新纸品有限公司 A kind of environment-friendly type aqueous ink and preparation method thereof

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Application publication date: 20170125