CN106009535A - Decomposition type environment-friendly lighting lampshade - Google Patents

Decomposition type environment-friendly lighting lampshade Download PDF

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CN106009535A
CN106009535A CN201610574249.2A CN201610574249A CN106009535A CN 106009535 A CN106009535 A CN 106009535A CN 201610574249 A CN201610574249 A CN 201610574249A CN 106009535 A CN106009535 A CN 106009535A
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魏国营
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10Epoxy resins modified by unsaturated compounds
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V3/00Globes; Bowls; Cover glasses
    • F21V3/04Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
    • F21V3/06Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material
    • F21V3/062Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material the material being plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/54Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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Abstract

The invention discloses a disassembled environment-friendly illuminating lamp shade, which comprises at least two lamp shade sheets and a fixing part, wherein the fixing part is used for assembling the lamp shade sheets into a complete lamp shade and comprises an installation convex part, an installation concave part and a fixing frame, the installation convex part is used for fixing the joint of the two adjacent lamp shade sheets, and the fixing frame is provided with a radial supporting rod.

Description

A kind of disassembled type environmental-protection illuminating lamp shade
Technical field
The present invention relates to electron-optical field, particularly relate to a kind of disassembled type environmental-protection illuminating lamp shade.
Background technology
Along with the continuous change of human being's production technology, as the light fixture of people's daily necessities, its function is also a day crescent Different;Simultaneously as the environmental protection idea of current people is increasingly stronger, thus the illuminator of environmental protection can be more by people Favor, therefore, in addition to possessing traditional lighting function, the pursuit of hommization functions more to light fixture, it has also become illuminate now One development trend in field.
On the one hand, by negative aeroion Technology application in light fixture product, make light fixture discharge for a long time in indoor air bear from Son, especially negative oxygen ion.Owing to it is structurally similar to ultra-oxygen anion free radical, therefore there is similar biology and live Property, it is possible to make the biological cell lived electronegative, so that virus loses the attacking ability to cell;Meanwhile, negative oxygen ion energy The finishing pollution things such as enough and formaldehyde, toluene, TVOC react, and product is nonpoisonous and tasteless carbon dioxide and water, without secondary dirt The generation of dye, has certain effect purified the air of a room, such as, in artificial air's anion environment, and air after measured Middle mycete, bacterial population can reduce by more than 90%.After negative oxygen ion is inhaled into human body, neural excitatory state can be regulated, change The ventilatory of kind lung, improves blood circulation, enhances metabolism, strengthens immune system ability, makes that people is in high spirits, improve work Making efficiency etc., it also has certain therapeutical effect to numerous diseases such as hypertension, asthma, influenza, insomnia, arthritis, so people Anion is called " vitamin in air " " long-lived element ";On the other hand, light fixture is made to have the function of certain expelling mosquito, no Only promote the comfort level of user, also greatly enrich the use function of light fixture.
So far, the Technology design making conventional lamp product simultaneously have expelling mosquito and negative ion-releasing function does not also have See.
Summary of the invention
The deficiency existed for prior art, the technical problem to be solved is to provide a kind of disassembled type environmental-protection and shines Bright lamp cover, not only long-term negative ion release, also have certain expelling mosquito effect, also has certain antibacterial action simultaneously, There is certain effect removing the finishing pollution things such as formaldehyde, toluene, TVOC simultaneously, there is the effect achieved many things at one stroke, enrich The use function of conventional lamp.
It is an object of the invention to be achieved through the following technical solutions:
A kind of disassembled type environmental-protection illuminating lamp shade, including at least two lampshade sheet, for lampshade sheet is assembled into consolidating of complete lampshade Determining portion, described fixed part includes the mounting boss for fixing adjacent two lampshade sheet junctions, installs recess and be provided with The fixed mount of radial strut, certainly, belongs to prior art by the method that adjacent two lampshade sheets couple together, includes but not limited to Buckle, the mode such as bonding, described lampshade sheet is prepared from according to parts by weight by following component:
Resin 50-65 weight portion;Glass fibre 10-20 weight portion;Fire retardant 5-8 weight portion;Graphene 3-4.5 weight portion;Change Property aromatic amine curing agent 3-4 weight portion;Fluorescent material 0.1-0.3 weight portion;The good solid 754 light trigger 2-4 weight portions of vapour Ba Yan;Poly- Ether amines catalyst 0.5-0.7 weight portion;Ceria 0.1-0.15 weight portion;Active mineral matter powder 0.7-1 weight portion;Middle YAOJING Oil 1-1.2 weight portion;Wherein, described resin is epoxy soybean oil acrylate and the mixture of bisphenol A-type E51 epoxy resin, The mass ratio of described epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin is 2:1-3:2, and described fire retardant is poly-phosphorus Acid ammonium, tripolycyanamide and the mixture of expanded graphites, the quality of described APP, tripolycyanamide and expanded graphites Ratio 2:1.5:1.3, described fluorescent material is Ce and YAG fluorescent powder mixture, particle diameter≤13 μm of described fluorescent material, described work Property mineral powder be germanite, fluorite, tourmaline, hexacyclic ring stone by weight the mixture of 2.5:3:3.7:2, wherein tourmaline is magnesium The mixture of tourmaline and elbaite 5:3 by weight, particle diameter≤13 μm of described active mineral matter powder, described lampshade sheet leads to Cross following steps to be prepared from:
S1, the resin by required parts by weight, fire retardant, Graphene, fluorescent material, vapour Ba Yan are good to be consolidated 754 light triggers and gathers Ether amines catalyst is placed in blender, mixes well 70-80 DEG C of next part high speed stirring, and mixing time is 15-30 minute, to be mixed Take out from blender after Jun Yun, i.e. prepare mixture A, standby;
S2, by material Cortex Meliae 50-60 weight portion, Radix Clematidis 1.5-2 weight portion, lavandula angustifolia 15-20 weight portion, Radix Pulsatillae 3-5 Weight portion, Rhizoma Coptidis 1-3 weight portion, Semen Torreyae 20-25 weight portion, Herba Anemones Hupehensis 3-5 weight portion, Caulis Polygoni Multiflori 3-5 weight portion, Lignum cinnamomi camphorae Leaf 6-8 weight portion, Cortex Albiziae 3-5 weight portion decontamination, it is placed in vacuum still 2-3 hour of-20 DEG C together, is placed in microwave the most again Drying machine carries out pretreatment, and wherein drying time is 30-40 minute, and microwave power is 17kw;
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With;
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 27.65MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, and dynamic extraction 2 hours, directly at separating still Outlet triangular flask collects crude oil, standby;
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby;
S6, by Fructus Chebulae's 1-3 weight portion, Cortex Phellodendri 1-3 weight portion, Origanum majorana 1.5-2.5 weight portion, vanilla 1.5-2 weight portion, Herba Portulacae 3-4 weight portion, Radix Salviae Miltiorrhizae 4-4.5 weight portion, Herba polygoni hydropiperis 2-3 weight portion, Herba Pogostemonis 3-4 weight portion, Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3-4 weight portion, Radix Stemonae 6-7.5 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 3-4 weight portion is cleaned and is dried, and puts in super micron mill together and is crushed to 30 mesh, then adds Ionized water soaks 5 hours, amount of water by 7 times of immersions crude drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby With;
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13-0.2 weight portion and be dried, the most prepared Volatile oil C, standby;
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, eucalyptus quintessence oil and blue Flos Chrysanthemi quintessence oil, be sufficiently stirred for 45 minutes, stand 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, You Jia The mass ratio of profit quintessence oil and blue Flos Chrysanthemi quintessence oil is 2:0.6:0.5:0.65:0.5:0.45;
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared and step S1 prepare, at 70-80 DEG C, concentrates in blender Stirring mixing 30 minutes, obtains mixture D;
S10, mixture D step S9 prepared put into ball mill, then add active mineral matter powder, ceria, modification Aromatic amine curing agent and glass fibre, carry out concentrating at 70-80 DEG C and grind 4.5 hours, filters decontamination, i.e. prepares premix Material;
S11, the premix material of step S10 being put into twin-screw extrusion equipment, wherein, the rotating speed of twin-screw extrusion equipment is 150- 250 revs/min, extrusion temperature is 260-280 ° of C, extrusion, cooling, and pelletizing i.e. obtains needed for manufacturing described lampshade shell Composite;
S12, the composite that step S11 is prepared through injection machine heating, extruding, molding, cool down, repair, obtain lampshade sheet.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surface activity Agent 3 parts, diethyltoluamide 0.2 part, butyl butyrate 1 part, Eucalyptus oil 1.5 parts, chlorhexidine acetate 0.5 part, fatty alcohol-polyoxyethylene ether sulfur 1 part of sodium of acid and sodium benzoate 0.2 part.
It should be noted that the experiment proved that, active mineral matter powder adds appropriate ceria (CeO2), utilize The emittance of this rare earth element is high, the feature of half degradation period limit for length, and the anion that active mineral matter powder can be significantly increased produces Rate, its principle is as follows: the Ce in ceria4+Ce is changed under photoenvironment3+, in conversion process, electron-hole Recombination probability reduces, then in active mineral matter powder under the effect of the material electric field such as tourmaline, part electronics is passively with electric field side To displacement, electron-hole recombination probability reduces, thus at tourmaline/CeO2Substantial amounts of electricity has been gathered on composite powder surface The energy of solution air molecule, and then create the negative aeroion of high concentration, Ce simultaneously3+It is oxidized into again Ce4+, then repeat Aforesaid conversion process;Meanwhile, through practice detection, interpolation titanium dioxide it is being combined in the active mineral matter powder of proportioning through the present invention Cerium component, higher more than 10 times than the concentration without the active mineral matter powder anion adding ceria, r ray and natural environment Identical.
The present invention is based on motherland's traditional medicine, with reference to modern Chinese medicine pharmacological research, from the drug screening of existing Chinese medicine with anti- Reviewing card, give full play to each component synergism, wherein the effect brief introduction of primary raw material is as follows.
Cortex Meliae: can ascarifuge and ancylostome, but poisonous, the used time sternly to follow the doctor's advice, and root bark powder adjusts vinegar can control scabies, uses Melia azedarach L. Son makes ointment can control tinea capitis.In addition, really nucleolus oil is available for lubricating oil processed and soap etc..
Radix Clematidis: root is used as medicine, can wind-damp dispelling, diuresis, stimulate the menstrual flow, ease pain, fresh strain energy treating acute tonsillitis, pharyngolaryngitis;Root Controlling filaricide, toothache (Chinese herbology) is controlled in external.Herb can used as pesticides, prevent and treat bridging worm, Pieris rapae, cutworm, wriggler etc. of going out (Henan economic plants will).
Lavandula angustifolia can remove ant, except roach, acaricide, the when of being placed under wardrobe, medicated pillow, not only can replace camphor ball, moreover it is possible to stay The fragrance of one people that oozes lower, research finds, lavandula angustifolia has obvious antibacterial action, and the linalool contained in lavandula angustifolia is lavandula angustifolia Antibacterial main component, it can suppress 17 kinds of antibacterials (including gram-negative bacteria and gram-positive bacteria), the life of 10 kinds of funguses Long.
The Radix Pulsatillae: cohosh, perennial herb, another name has how grass, powder silkweed, Bai Toucao, Lao Gucao, chrysanthemum chrysanthemum Seedling, Lao Wenghua, being always preced with flower, ram's horn flower etc., have heat-clearing and toxic substances removing, eliminating pathogenic heat from blood to cure dysentery, effect of removing dampness and killing parasites, to golden yellow Fructus Vitis viniferae Coccus bacillus pyocyaneus has inhibitory action, and its ethanol extraction has calmness, analgesia and spasmolytic effect.
Rhizoma Coptidis: belong to herbaceos perennial, antibacterial action 2, antifungic action 3, antivirus action 4, anti-ameba are made With 5, antiinflammatory, anti-CaM antibody 6., to Cardiovascular 7, refrigeration function 8, hypoglycemic activity 9, effect for reducing blood fat 10, Antioxidation 11, on blood system affect 12, antiulcer action.
Semen Torreyae " herbal classic ": pathogen in main abdomen, goes three worms, and Serpentis stings.
Herba Anemones Hupehensis: 1. " Shaanxi Chinese herbal medicine ": " bitter, cool, slightly poisonous." 2. " Chinese herbal medicine is commonly used in Sichuan ": " and toil, temperature, Slightly poisonous." removing toxic substances, evacuation of pus granulation promoting, dissipating blood stasis of subsiding a swelling, have and kill maggot, wriggler, change long-pending, detumescence, dissipating blood stasis, control stubborn dermatitis, tinea alba, malaria Disease, infantile malnutrition, dysentery, carbuncle furuncle swells, scrofula, traumatic injury.
Caulis Polygoni Multiflori: Caulis Polygoni Multiflori is put down nontoxic, sweet and slightly bitter taste, enter the heart, Liver Channel, have effect of tranquilizing and blood nourishing, dispelling wind and removing obstruction in the collateral, Cure mainly the diseases such as deficiency of YIN insufficiency of blood, restlessness of asrhenia type and insomnia, rheumatic arthralgia, itchy skin eruption.
Cortex Albiziae: for the dry bark of leguminous plant Herba Albiziae, Cortex Albiziae sweet-bitter flavor, property are flat, GUIXIN, Liver Channel;Herba Albiziae leatherware There is resolving stagnation for tranquilization, effect of promoting blood circulation and detumescence;Cortex Albiziae cures mainly melancholy insomnia, irritability, inside and outside carbuncle and ulcer, injury from falling down.
Cortex Phellodendri: to staphylococcus aureus, streptococcus pneumoniae, diphtheria corynebacterium, Streptococcus viridans, dysentery bacterium (Song Nei Shi Except), Hemolytic streptococcus, meningococcus, vibrio cholera, anthrax bacillus all effectively or have stronger inhibitory action;To withered Grass bacillus, bordetella pertussis, clostridium tetani also have inhibitory action.
Origanum majorana: can improve that mood is depressed and addictive disease, especially effective to liberal-mindedness and vigorous endurance stress symptom, can expand blood vessel, Blood pressure lowering, alleviate and burden, help to eliminate cardiopalmus, have the nerve of excellence to pacify and calm function.
Vanilla: have special fragrance, has resisting fatigue and mood is gloomy, help hormone secretion, anxiety of releiving and improvement The effects such as insomnia.There is heart tonifying, supplementing the brain, stomach invigorating, removing toxic substances, wind dispelling, effect of enhancing muscle strength, make aroma type nervous system emerging Put forth energy agent and kidney-reinforcing drug, be used for treating hysteria, melancholia, sexual impotence, deficiency-heat and rheumatism.
Herba Portulacae: Portulacaceae annual herb plant.Plump succulence, without hair, high 10-30cm, be born in roadside, field and The area without shade such as ruins, flower garden.All there is distribution domestic various places.This kind is medicine food dual purpose plant.Herb hyoscine, has clearing away heat-damp and promoting diuresis, solution Poison detumescence, antiinflammatory, quench the thirst, diuresis.
Radix Salviae Miltiorrhizae: nature and flavor are bitter, are slightly cold.GUIXIN, Liver Channel." the southern regions of the Yunnan Province book on Chinese herbal medicine " is recorded: reinforcing the heart sedate, calming heart and tranquilizing mind.Control forgetful seized with terror Punching, palpitation with fear is insomnia, and has stasis-dispelling and pain-killing, promoting blood circulation to restore menstrual flow, the effect of the relieving restlessness that clears away heart-fire, and for menoxenia, amenorrhea dysmenorrhea, lump in the abdomen amasss Poly-, chest and abdomen twinge, pyretic arthralgia pain, skin infection.
Herba polygoni hydropiperis: all have inhibitory action, current clinical medicine research to show in test tube to various dysentery bacteriums, Herba polygoni hydropiperis has There are the effects such as antibacterial, antiviral, antiinflammatory, antioxidation.
Herba Pogostemonis: acrid in the mouth, slightly warm in nature.Effect: removing dampness for regulating stomach, the effect of administration of inducing sweat, solve, cure mainly dampness taste, breast gastral cavity is vexed swollen, Appetite is the most fragrant, Nausea and vomiting;Summer, heat-damp in summer was sleepy, uncomfortable in chest did not relaxed, and affection of exogenous wind-cold. the diseases such as aversion to cold is uncomfortable in chest, and have and have relatively Strong Fungistasis and antibacterial action.
The Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae): the another name river Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae), continuous poison, Radix Stellerae, chervil, vexed fresh idea, Re Jiaba, Herba Senecionis Dianthui, Radix scopoliae sinensis, perfume, Medicine sieve foretells, raw pull, flourishing bavin headdress flower, monkey root, Gelsemium elegans Benth., in Chinese medicine with its root eliminate the phlegm, pain relieving, removing food stagnancy, parasite killing.
The Radix Stemonae: can driving away mosquito, resisting pathogenic microbes effect, to beta hemolytic streptococcus, meningococcus, golden yellow The multiple pathomycetes such as staphylococcus, Staphylococcus albus, Bacillus typhi, pneumobacillus, bacillus pestis, anthrax bacillus have necessarily Inhibitory action, its infusion all has killing action to mosquitos and flies larva, head louse, clothing louse and Cimex bedbug etc..
Artemisia argyi Levl. et Van. var. argyi cv. Qiai: have another name called: containing 17 kinds of known compounds, has and relievings asthma, antitussive, eliminates the phlegm and clear scorching effect, reasonable QI and blood, by cold The effects such as wet, regulating menstruation is antiabortive, warming the meridian for stopping bleeding, clearing and antitussive expectorant.Cure mainly cold type of pain in menoxenia, abdomen, vaginal bleeding during pregnancy hematochezia, fetal movement not The diseases such as peace, infertility.
It should be noted that be proven, after carrying out the Radix Salviae Miltiorrhizae of certain part by weight, Herba polygoni hydropiperis and the Radix Stemonae compounding, no Only it is remarkably improved degerming antibacterial ability, also can produce a kind of delicate fragrance taste having no side effect, refreshing, have certain Effect of refreshing oneself;, it is proven, by the Cortex Meliae of certain part by weight, Radix Clematidis, Folium cinnamomi camphorae, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae), Semen Torreyae with break meanwhile After bowl flower carries out compounding, the mosquito dispersing ability of said composition is made to be significantly improved;It addition, Rhizoma Coptidis, Cortex Phellodendri, the Radix Pulsatillae, horse After the components such as bitterroot, Artemisia argyi Levl. et Van. var. argyi cv. Qiai and Fructus Chebulae carry out compatibility, substantially increase the antibacterial degerming ability of compositions, through practice detection, multiple Compositions after joining is to staphylococcus aureus, anthrax bacillus, hemophilus influenza, micrococcus catarrhalis, streptococcus pneumoniae, escherichia coli, second Type streptococcus, diphtheria corynebacterium, Bacillus typhi, green pus liver bacterium, dysentery bacteriums etc. more than 40 are planted pathogenic bacteria and have certain suppression and kill Effect.
The effect of the present invention:
The present invention uses Chinese medicinal ingredients to compound with active mineral matter, makes the present invention be possible not only to expelling mosquito, it is also possible to release is negative Ion, fresh air, simultaneously fragrant odour, there is effect of body-building, anophelifuge, sterilization, in actual applications, also have certain Remove effect of the finishing pollution things such as formaldehyde, toluene, TVOC, there is the effect achieved many things at one stroke, enrich the use of conventional lamp Function.
Accompanying drawing explanation
Fig. 1 is overall schematic of the present invention.
Fig. 2 is decomposing schematic representation of the present invention.
Detailed description of the invention
Embodiment 1:
Referring to shown in Fig. 1 to Fig. 2, a kind of disassembled type environmental-protection illuminating lamp shade, including at least two lampshade sheet 1, for by lampshade Sheet 1 is assembled into the fixed part of complete lampshade, and described fixed part includes that the installation for fixing adjacent two lampshade sheet 1 junctions is protruding Portion 2, recess 20 is installed and is provided with the fixed mount 3 of radial strut 30, described lampshade sheet 1 by following component according to weight portion Number is prepared from:
Resin 50 weight portion;Glass fibre 20 weight portion;Fire retardant 5 weight portion;Graphene 4.5 weight portion;Modified aromatic amine is solid Agent 3 weight portion;Fluorescent material 0.3 weight portion;Good solid 754 light trigger 2 weight portions of vapour Ba Yan;Polyetheramine catalyst 0.7 weight Part;Ceria 0.1 weight portion;Active mineral matter powder 1 weight portion;Essential oil of traditional Chinese medicine 1 weight portion;Wherein, described resin is epoxy Soybean oil acrylate and the mixture of bisphenol A-type E51 epoxy resin, described epoxy soybean oil acrylate and bisphenol A-type E51 The mass ratio of epoxy resin is 3:2, and described fire retardant is the mixture of APP, tripolycyanamide and expanded graphites, institute Stating the mass ratio 2:1.5:1.3 of APP, tripolycyanamide and expanded graphites, described fluorescent material is Ce and YAG fluorescence Powder mixture, particle diameter≤13 μm of described fluorescent material, described active mineral matter powder be germanite, fluorite, tourmaline, hexacyclic ring stone by The mixture of weight ratio 2.5:3:3.7:2, wherein tourmaline is dravite and the mixture of elbaite 5:3 by weight, Particle diameter≤13 μm of described active mineral matter powder, described lampshade sheet is made by the steps and forms:
S1, the resin by required parts by weight, fire retardant, Graphene, fluorescent material, vapour Ba Yan are good to be consolidated 754 light triggers and gathers Ether amines catalyst is placed in blender, mixes well in the stirring of 70 DEG C of next part high speeds, and mixing time is 30 minutes, to be mixed uniformly after Take out from blender, i.e. prepare mixture A, standby;
S2, by material Cortex Meliae 60 weight portion, Radix Clematidis 1.5 weight portion, lavandula angustifolia 20 weight portion, the Radix Pulsatillae 3 weight portion, Rhizoma Coptidis 3 weight portions, Semen Torreyae 20 weight portion, Herba Anemones Hupehensis 5 weight portion, Caulis Polygoni Multiflori 3 weight portion, Folium cinnamomi camphorae 8 weight portion, Cortex Albiziae 3 weight Amount part decontamination, is placed in the vacuum still 2 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, be wherein dried Time is 40 minutes, and microwave power is 17kw;
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With;
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 27.65MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, and dynamic extraction 2 hours, directly at separating still Outlet triangular flask collects crude oil, standby;
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby;
S6, by Fructus Chebulae 3 weight portion, Cortex Phellodendri 1 weight portion, Origanum majorana 2.5 weight portion, vanilla 1.5 weight portion, Herba Portulacae 4 weight Amount part, Radix Salviae Miltiorrhizae 4 weight portion, Herba polygoni hydropiperis 3 weight portion, Herba Pogostemonis 3 weight portion, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 4 weight portion, the Radix Stemonae 6 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 4 weight Part is cleaned and is dried, and puts in super micron mill together and is crushed to 30 mesh, then adds deionized water and soaks 5 hours, and amount of water is institute Soak crude drug quality 7 times, dispersed with stirring is mixed well, and prepares Traditional Chinese drug mixture, standby;
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13 weight portion and be dried, and i.e. prepares volatilization Oil C, standby;
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, eucalyptus quintessence oil and blue Flos Chrysanthemi quintessence oil, be sufficiently stirred for 45 minutes, stand 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, You Jia The mass ratio of profit quintessence oil and blue Flos Chrysanthemi quintessence oil is 2:0.6:0.5:0.65:0.5:0.45;
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared and step S1 prepare, at 80 DEG C, concentrates in blender and stirs Mix mixing 30 minutes, obtain mixture D;
S10, mixture D step S9 prepared put into ball mill, then add active mineral matter powder, ceria, modification Aromatic amine curing agent and glass fibre, carry out concentrating at 70 DEG C and grind 4.5 hours, filter decontamination, i.e. prepare premix material;
S11, the premix material of step S10 being put into twin-screw extrusion equipment, wherein, the rotating speed of twin-screw extrusion equipment is 250 Rev/min, extrusion temperature is 260 ° of C, extrusion, cooling, and pelletizing i.e. obtains for manufacturing the composite wood needed for described lampshade shell Material;
S12, the composite that step S11 is prepared through injection machine heating, extruding, molding, cool down, repair, obtain lampshade sheet.
It should be noted that the experiment proved that, active mineral matter powder adds appropriate ceria (CeO2), utilize The emittance of this rare earth element is high, the feature of half degradation period limit for length, and the anion that active mineral matter powder can be significantly increased produces Rate, its principle is as follows: the Ce in ceria4+Ce is changed under photoenvironment3+, in conversion process, electron-hole is multiple Conjunction probability reduces, then under tourmaline electric field action, part electronics is passively with direction of an electric field displacement, and electron-hole is combined Probability reduces, thus at tourmaline/CeO2The energy of substantial amounts of electrolysis air molecule has been gathered on composite powder surface, thus produces The negative aeroion of high concentration, simultaneously Ce are given birth to3+It is oxidized into again Ce4+, then repeat aforesaid conversion process;Meanwhile, through reality Trampling detection, the active mineral matter powder being combined proportioning through the present invention is higher 10 times than the tourmaline powder negative ion concentration without proportioning Above, r ray is identical with natural environment.
As preferably, described bisphenol A-type E51 epoxy resin uses the standard bisphenol A-type E51 ring of Yueyang Ba Ling petrochemical iy produced Epoxy resins;Described epoxy soybean oil acrylate uses the epoxy soybean oil acrylic acid that Zhong Shan Yongfeng Chemical Co., Ltd. produces Ester;Described APP uses the APP that Yunnan Tian Yao Chemical Co., Ltd. produces;Described expanded graphites uses Qingdao The expanded graphites that Chen Yang graphite company limited produces.
In a preferred embodiment, essential oil of traditional Chinese medicine in step s 8 also includes the component of following weight portion: surface activity Agent 3 parts, diethyltoluamide 0.2 part, butyl butyrate 1 part, Eucalyptus oil 1.5 parts, chlorhexidine acetate 0.5 part, fatty alcohol-polyoxyethylene ether sulfur 1 part of sodium of acid and sodium benzoate 0.2 part.
Embodiment 2:
A kind of disassembled type environmental-protection illuminating lamp shade, including at least two lampshade sheet 1, for lampshade sheet 1 is assembled into complete lampshade Fixed part, described fixed part include the mounting boss 2 for fixing adjacent two lampshade sheet 1 junctions, install recess 20 with And it is provided with the fixed mount 3 of radial strut 30, described lampshade sheet 1 is prepared from according to parts by weight by following component:
Resin 65 weight portion;Glass fibre 15 weight portion;Fire retardant 6 weight portion;Graphene 4 weight portion;Modified aromatic amine solidifies Agent 3.5 weight portion;Fluorescent material 0.2 weight portion;Good solid 754 light trigger 3 weight portions of vapour Ba Yan;Polyetheramine catalyst 0.6 weight Part;Ceria 0.15 weight portion;Active mineral matter powder 0.8 weight portion;Essential oil of traditional Chinese medicine 1.2 weight portion;Wherein, described resin is Epoxy soybean oil acrylate and the mixture of bisphenol A-type E51 epoxy resin, described epoxy soybean oil acrylate and bisphenol-A The mass ratio of type E51 epoxy resin is 2:1, and described fire retardant is the mixing of APP, tripolycyanamide and expanded graphites Thing, the mass ratio 2:1.5:1.3 of described APP, tripolycyanamide and expanded graphites, described fluorescent material is Ce and YAG Phosphor mixture, particle diameter≤13 μm of described fluorescent material, described active mineral matter powder is germanite, fluorite, tourmaline, six rings Stone is by weight the mixture of 2.5:3:3.7:2, and wherein tourmaline is dravite and the mixing of elbaite 5:3 by weight Thing, particle diameter≤13 μm of described active mineral matter powder, described lampshade sheet is made by the steps and forms:
S1, the resin by required parts by weight, fire retardant, Graphene, fluorescent material, vapour Ba Yan are good to be consolidated 754 light triggers and gathers Ether amines catalyst is placed in blender, mixes well in the stirring of 75 DEG C of next part high speeds, and mixing time is 20 minutes, to be mixed uniformly after Take out from blender, i.e. prepare mixture A, standby;
S2, by material Cortex Meliae 50 weight portion, Radix Clematidis 2 weight portion, lavandula angustifolia 15 weight portion, the Radix Pulsatillae 5 weight portion, Rhizoma Coptidis 1 Weight portion, Semen Torreyae 25 weight portion, Herba Anemones Hupehensis 3 weight portion, Caulis Polygoni Multiflori 5 weight portion, Folium cinnamomi camphorae 6 weight portion, Cortex Albiziae 5 weight Part decontamination, is placed in the vacuum still 2.5 hours of-20 DEG C together, is placed in microwave dryer the most again and carries out pretreatment, be wherein dried Time is 35 minutes, and microwave power is 17kw;
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With;
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 27.65MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, and dynamic extraction 2 hours, directly at separating still Outlet triangular flask collects crude oil, standby;
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby;
S6, by Fructus Chebulae 1 weight portion, Cortex Phellodendri 3 weight portion, Origanum majorana 1.5 weight portion, vanilla 2 weight portion, Herba Portulacae 3 weight Part, Radix Salviae Miltiorrhizae 4.5 weight portion, Herba polygoni hydropiperis 2 weight portion, Herba Pogostemonis 4 weight portion, the Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3 weight portion, the Radix Stemonae 7.5 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 3 weight Amount part is cleaned and is dried, and puts in super micron mill together and is crushed to 30 mesh, then adds deionized water and soaks 5 hours, and amount of water is 7 times of soaked crude drug quality, dispersed with stirring is mixed well, and prepares Traditional Chinese drug mixture, standby;
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.15 weight portion and be dried, and i.e. prepares volatilization Oil C, standby;
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, eucalyptus quintessence oil and blue Flos Chrysanthemi quintessence oil, be sufficiently stirred for 45 minutes, stand 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, You Jia The mass ratio of profit quintessence oil and blue Flos Chrysanthemi quintessence oil is 2:0.6:0.5:0.65:0.5:0.45;
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared and step S1 prepare, at 75 DEG C, concentrates in blender and stirs Mix mixing 30 minutes, obtain mixture D;
S10, mixture D step S9 prepared put into ball mill, then add active mineral matter powder, ceria, modification Aromatic amine curing agent and glass fibre, carry out concentrating at 75 DEG C and grind 4.5 hours, filter decontamination, i.e. prepare premix material;
S11, the premix material of step S10 being put into twin-screw extrusion equipment, wherein, the rotating speed of twin-screw extrusion equipment is 200 Rev/min, extrusion temperature is 270 ° of C, extrusion, cooling, and pelletizing i.e. obtains for manufacturing the composite wood needed for described lampshade shell Material;
S12, the composite that step S11 is prepared through injection machine heating, extruding, molding, cool down, repair, obtain lampshade sheet.
Remaining is with embodiment 1.
The test index of Example 1 and Example 2 of the present invention is as follows:
(1) abnormal smells from the patient inspection: sense organ, nonirritant abnormal flavour.
(2) light transmittance test.
The light fixture of preparation Example 1 and Example 2 of the present invention, with the light transmittance of spectrophotometric determination 600nm wavelength, warp Test, light transmittance is all higher than 80%.
(3) weatherability test.
Light fixture in inventive embodiments 1 and embodiment 2 is placed in 500W ultra violet lamp, and light fixture with uviol lamp distance is 20cm, Continuous irradiation is without obvious xanthochromia after 40 hours, and the light fixture that the display present invention prepares has the weatherability of excellence.
(4) repelling effect test.
Contrast test is carried out according to the repelling effect of ordinary lamp and lantern of the prior art with above-described embodiment 1 and embodiment 2, Test data ask for an interview table 1.
Conclusion: Example 1 and Example 2 of the present invention, compared with ordinary lamp and lantern on market, is respectively provided with certain anophelifuge and makees With.
(5) anionic textiles.
Use anion test instrument, be primarily directed to timber, Ore, ceramic material, negative ion powder are made to relevant The anion quantity that commodity (such as anion medicated clothing, necklace, woollen blanket) etc. are discharged makes measurement.
Test result is shown in Table 2.
Conclusion: the embodiment of the present invention 1, embodiment 2 can be with sustained release negative aeroions, with ordinary lamps of the prior art Tool compares, and the present invention has obviously advantage.

Claims (2)

1. a disassembled type environmental-protection illuminating lamp shade, it is characterised in that: include at least two lampshade sheet (1), for by lampshade sheet (1) Being assembled into the fixed part of complete lampshade, described fixed part includes that the installation for fixing adjacent two lampshade sheet (1) junctions is protruding Portion (2), installing recess (20) and be provided with the fixed mount (3) of radial strut (30), described lampshade sheet (1) is by following component It is prepared from according to parts by weight:
Resin 50-65 weight portion;Glass fibre 10-20 weight portion;Fire retardant 5-8 weight portion;Graphene 3-4.5 weight portion;Change Property aromatic amine curing agent 3-4 weight portion;Fluorescent material 0.1-0.3 weight portion;The good solid 754 light trigger 2-4 weight portions of vapour Ba Yan;Poly- Ether amines catalyst 0.5-0.7 weight portion;Ceria 0.1-0.15 weight portion;Active mineral matter powder 0.7-1 weight portion;Middle YAOJING Oil 1-1.2 weight portion;Wherein, described resin is epoxy soybean oil acrylate and the mixture of bisphenol A-type E51 epoxy resin, The mass ratio of described epoxy soybean oil acrylate and bisphenol A-type E51 epoxy resin is 2:1-3:2, and described fire retardant is poly-phosphorus Acid ammonium, tripolycyanamide and the mixture of expanded graphites, the quality of described APP, tripolycyanamide and expanded graphites Ratio 2:1.5:1.3, described fluorescent material is Ce and YAG fluorescent powder mixture, particle diameter≤13 μm of described fluorescent material, described work Property mineral powder be germanite, fluorite, tourmaline, hexacyclic ring stone by weight the mixture of 2.5:3:3.7:2, wherein tourmaline is magnesium The mixture of tourmaline and elbaite 5:3 by weight, particle diameter≤13 μm of described active mineral matter powder, described lampshade sheet leads to Cross following steps to be prepared from:
S1, the resin by required parts by weight, fire retardant, Graphene, fluorescent material, vapour Ba Yan are good to be consolidated 754 light triggers and gathers Ether amines catalyst is placed in blender, mixes well 70-80 DEG C of next part high speed stirring, and mixing time is 15-30 minute, to be mixed Take out from blender after Jun Yun, i.e. prepare mixture A, standby;
S2, by material Cortex Meliae 50-60 weight portion, Radix Clematidis 1.5-2 weight portion, lavandula angustifolia 15-20 weight portion, Radix Pulsatillae 3-5 Weight portion, Rhizoma Coptidis 1-3 weight portion, Semen Torreyae 20-25 weight portion, Herba Anemones Hupehensis 3-5 weight portion, Caulis Polygoni Multiflori 3-5 weight portion, Lignum cinnamomi camphorae Leaf 6-8 weight portion, Cortex Albiziae 3-5 weight portion decontamination, it is placed in vacuum still 2-3 hour of-20 DEG C together, is placed in microwave the most again Drying machine carries out pretreatment, and wherein drying time is 30-40 minute, and microwave power is 17kw;
S3, step S2 is processed after material put into together in super micron mill and be crushed to 60 mesh, prepare crude drug powder, standby With;
S4, by step S3 prepare crude drug powder put into supercritical carbon dioxide extraction apparatus extraction kettle in, regulation extraction Pressure power 27.65MPa, extraction temperature 45 DEG C, carbon dioxide flow is 1100L/h, and dynamic extraction 2 hours, directly at separating still Outlet triangular flask collects crude oil, standby;
S5, the crude oil prepared in step S4 is placed in 5 DEG C of environment freezing 70 minutes, then the crude oil after freezing is placed in rotating speed is The High speed refrigerated centrifuge of 17000r/min is centrifuged 25 minutes, goes the removal of impurity to be placed on 85 DEG C of vacuum tank evacuation 3 hours, i.e. Prepare volatile oil B, standby;
S6, by Fructus Chebulae's 1-3 weight portion, Cortex Phellodendri 1-3 weight portion, Origanum majorana 1.5-2.5 weight portion, vanilla 1.5-2 weight portion, Herba Portulacae 3-4 weight portion, Radix Salviae Miltiorrhizae 4-4.5 weight portion, Herba polygoni hydropiperis 2-3 weight portion, Herba Pogostemonis 3-4 weight portion, Radix Euphorbiae Fischerianae (Radix Euphorbiae Ebracteolatae) 3-4 weight portion, Radix Stemonae 6-7.5 weight portion, Artemisia argyi Levl. et Van. var. argyi cv. Qiai 3-4 weight portion is cleaned and is dried, and puts in super micron mill together and is crushed to 30 mesh, then adds Ionized water soaks 5 hours, amount of water by 7 times of immersions crude drug quality, dispersed with stirring is mixed well, prepared Traditional Chinese drug mixture, standby With;
S7, Traditional Chinese drug mixture step S6 prepared decoct 2 hours in 80 DEG C, collect distillate, and add ether extraction, distillation Liquid is 2.5:1 with the volume ratio of ether, takes upper oil phase, then adds anhydrous sodium sulfate 0.13-0.3 weight portion and be dried, the most prepared Volatile oil C, standby;
S8, made to step S5 and S7 volatile oil B and volatile oil C are mixed and mixes well prepared miscella, then be sequentially added into while stirring Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, eucalyptus quintessence oil and blue Flos Chrysanthemi quintessence oil, be sufficiently stirred for 45 minutes, stand 30 points Clock, filtering and impurity removing, obtain essential oil of traditional Chinese medicine, wherein, described miscella and Radix Paeoniae Alba quintessence oil, cypress quintessence oil, Herba Saussureae Involueratae quintessence oil, You Jia The mass ratio of profit quintessence oil and blue Flos Chrysanthemi quintessence oil is 2:0.6:0.5:0.65:0.5:0.45;
The mixture A that S9, essential oil of traditional Chinese medicine step S8 prepared and step S1 prepare, at 70-80 DEG C, concentrates in blender Stirring mixing 30 minutes, obtains mixture D;
S10, mixture D step S9 prepared put into ball mill, then add active mineral matter powder, ceria, modification Aromatic amine curing agent and glass fibre, carry out concentrating at 70-80 DEG C and grind 4.5 hours, filters decontamination, i.e. prepares premix Material;
S11, the premix material of step S10 being put into twin-screw extrusion equipment, wherein, the rotating speed of twin-screw extrusion equipment is 150- 250 revs/min, extrusion temperature is 260-280 ° of C, extrusion, cooling, and pelletizing obtains composite;
S12, the composite that step S11 is prepared through injection machine heating, extruding, molding, cool down, repair, obtain lampshade sheet.
A kind of disassembled type environmental-protection illuminating lamp shade the most according to claim 1, it is characterised in that: middle YAOJING in step s 8 The oily component also including following weight portion: 3 parts of surfactant, diethyltoluamide 0.2 part, butyl butyrate 1 part, Eucalyptus oil 1.5 parts, vinegar Acid hibitane 0.5 part, polyoxyethylenated alcohol sodium sulfate 1 part and sodium benzoate 0.2 part.
CN201610574249.2A 2016-05-23 2016-07-20 Decomposition type environment-friendly lighting lampshade Pending CN106009535A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2702171Y (en) * 2004-05-12 2005-05-25 陈登丰 Demountable lampshade
CN102911490A (en) * 2012-09-20 2013-02-06 建湖坤杰照明科技有限公司 Polycarbonate resin fluorescent composite material and fluorescent LED lampshade production method
CN105504987A (en) * 2016-02-19 2016-04-20 史玉桂 Compound activated mineral environment-friendly ink
CN105542557A (en) * 2016-02-19 2016-05-04 史玉桂 Waterborne UV ink for ink jet printing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2702171Y (en) * 2004-05-12 2005-05-25 陈登丰 Demountable lampshade
CN102911490A (en) * 2012-09-20 2013-02-06 建湖坤杰照明科技有限公司 Polycarbonate resin fluorescent composite material and fluorescent LED lampshade production method
CN105504987A (en) * 2016-02-19 2016-04-20 史玉桂 Compound activated mineral environment-friendly ink
CN105542557A (en) * 2016-02-19 2016-05-04 史玉桂 Waterborne UV ink for ink jet printing

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Application publication date: 20161012