CN106349762A - 一种耐油性复合碳酸钙及其制备方法 - Google Patents
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Abstract
本发明公开了一种耐油性复合碳酸钙及其制备方法,包括以下原料:碳酸钙、有机硅树脂、纤维素树脂、磷铁粉、环氧树脂、乙烯树脂、甲苯、丙二醇甲醚、丙二醇、改性剂、水适量;其制备方法包括以下步骤:(1)制得预混料待用;(2)制得混合液;(3)制得改性剂;(4)将预混料、混合液和改性剂混合,搅拌均匀,研磨、烘干、粉碎成超细粉末即得。本发明通过将碳酸钙与环氧树脂、有机硅树脂、纤维素树脂、乙烯树脂等综合性能较佳的材料进行组合,改进生产工艺,采用改性剂等有效地增加了组合物的耐油性能;其生产工艺简单,生产周期短,质量稳定,生产成本低,应用价值较高。
Description
技术领域
本发明涉及工业填料领域,尤其涉及一种耐油性复合碳酸钙及其制备方法。
背景技术
碳酸钙是一种无机化合物,CaCO3俗称:灰石、石灰石、石粉、大理石等,是由钙离子和碳酸根离子结合生成的,是一类重要的功能性无机填料,工业上用途甚广,具有价格低廉、储量丰富、性能稳定、易加工、无毒等优点,能够显著的改善材料的加工性能、物理性能以及降低生产成本等等,广泛应用于塑料、橡胶、涂料、造纸等领域。
在碳酸钙的应用领域中,大多产品属于聚合物的范畴,然而,碳酸钙粒子表面分布有强亲水性的羟基,表现为碱性,和有机高聚物基质材料的界面性质不同,相容性差,难以在基质材料中分散均匀以及和基质材料形成强的结合力,造成两材料之间的界面缺陷,使复合材料某些力学性能下降。因此需要改变传统碳酸钙产品的性能,改善其应用性能以满足新材料、新技术发展的需要,是碳酸钙工业急需解决的问题。
发明内容
本发明的目的在于,提供一种耐油性复合碳酸钙及其制备方法,通过将综合性能较佳的材料进行组合,改进生产工艺,采用改性剂等有效地增加了组合物的耐油性能。
为了实现上述目的,本发明采用的技术方案如下:
一种耐油性复合碳酸钙及其制备方法,包括以下重量份的原料:碳酸钙50~80份、有机硅树脂2~4份、纤维素树脂1~3份、磷铁粉1~3份、环氧树脂3~5份、乙烯树脂4~6份、甲苯2~3份、丙二醇甲醚1~1.5份、丙二醇1~2份、改性剂5~8份、水适量;其中所述改性剂由以下重量份的原料制成:纳米二氧化钛30~50份、锌粉2~4份、丁基三苯基氟化膦3~5份、醋丙乳液2~5份、季戊四醇1~3份、磷酸二氢铵3~5份、异佛尔酮2~4份;
其制备方法包括以下步骤:
(1)将碳酸钙、有机硅树脂、纤维素树脂、磷铁粉混合均匀加入砂磨机内,研磨至300~400目,得预混料待用;
(2)将环氧树脂、乙烯树脂、甲苯放入混料机中,升温至75~85℃,混合搅拌半小时,然后加入丙二醇甲醚、丙二醇,继续升温至120~140℃,搅拌均匀,得混合液;
(3)将纳米二氧化钛、锌粉、丁基三苯基氟化膦、醋丙乳液加适量水搅拌,并升温至75~85℃,搅拌均匀后加入季戊四醇、磷酸二氢铵、异佛尔酮,继续加热至120~140℃,混合搅拌均匀,得改性剂;
(4)将步骤(1)得到的预混料、步骤(2)得到的混合液和步骤(3)得到的改性剂混合,搅拌均匀,研磨、烘干、粉碎成超细粉末即得。
本发明的有益效果为:
本发明通过将碳酸钙与环氧树脂、有机硅树脂、纤维素树脂、乙烯树脂等综合性能较佳的材料进行组合,改进生产工艺,采用改性剂等有效地增加了组合物的耐油性能;本发明生产工艺简单,生产过程环保无污染,实现了资源和能源的充分利用,生产周期短,质量稳定,生产成本低,应用价值较高。
具体实施方式:
以下以具体实施例来说明本发明的技术方案,但本发明的保护范围不限于此:
实施例1:
一种耐油性复合碳酸钙及其制备方法,包括以下重量份的原料:碳酸钙50份、有机硅树脂2份、纤维素树脂1份、磷铁粉1份、环氧树脂3份、乙烯树脂4份、甲苯2份、丙二醇甲醚1份、丙二醇1份、改性剂5份、水适量;其中所述改性剂由以下重量份的原料制成:纳米二氧化钛30份、锌粉2份、丁基三苯基氟化膦3份、醋丙乳液2份、季戊四醇1份、磷酸二氢铵3份、异佛尔酮2份;
其制备方法包括以下步骤:
(1)将碳酸钙、有机硅树脂、纤维素树脂、磷铁粉混合均匀加入砂磨机内,研磨至300~400目,得预混料待用;
(2)将环氧树脂、乙烯树脂、甲苯放入混料机中,升温至75℃,混合搅拌半小时,然后加入丙二醇甲醚、丙二醇,继续升温至140℃,搅拌均匀,得混合液;
(3)将纳米二氧化钛、锌粉、丁基三苯基氟化膦、醋丙乳液加适量水搅拌,并升温至85℃,搅拌均匀后加入季戊四醇、磷酸二氢铵、异佛尔酮,继续加热至120℃,混合搅拌均匀,得改性剂;
(4)将步骤(1)得到的预混料、步骤(2)得到的混合液和步骤(3)得到的改性剂混合,搅拌均匀,研磨、烘干、粉碎成超细粉末即得。
实施例2:
一种耐油性复合碳酸钙及其制备方法,包括以下重量份的原料:碳酸钙80份、有机硅树脂4份、纤维素树脂3份、磷铁粉3份、环氧树脂5份、乙烯树脂6份、甲苯3份、丙二醇甲醚1.5份、丙二醇2份、改性剂8份、水适量;其中所述改性剂由以下重量份的原料制成:纳米二氧化钛50份、锌粉4份、丁基三苯基氟化膦5份、醋丙乳液5份、季戊四醇3份、磷酸二氢铵5份、异佛尔酮4份;
其制备方法包括以下步骤:
(1)将碳酸钙、有机硅树脂、纤维素树脂、磷铁粉混合均匀加入砂磨机内,研磨至300~400目,得预混料待用;
(2)将环氧树脂、乙烯树脂、甲苯放入混料机中,升温至85℃,混合搅拌半小时,然后加入丙二醇甲醚、丙二醇,继续升温至120℃,搅拌均匀,得混合液;
(3)将纳米二氧化钛、锌粉、丁基三苯基氟化膦、醋丙乳液加适量水搅拌,并升温至75℃,搅拌均匀后加入季戊四醇、磷酸二氢铵、异佛尔酮,继续加热至140℃,混合搅拌均匀,得改性剂;
(4)将步骤(1)得到的预混料、步骤(2)得到的混合液和步骤(3)得到的改性剂混合,搅拌均匀,研磨、烘干、粉碎成超细粉末即得。
以上实施例仅用以说明本发明的技术方案,而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细地说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。
Claims (1)
1.一种耐油性复合碳酸钙及其制备方法,其特征在于,包括以下重量份的原料:碳酸钙50~80份、有机硅树脂2~4份、纤维素树脂1~3份、磷铁粉1~3份、环氧树脂3~5份、乙烯树脂4~6份、甲苯2~3份、丙二醇甲醚1~1.5份、丙二醇1~2份、改性剂5~8份、水适量;其中所述改性剂由以下重量份的原料制成:纳米二氧化钛30~50份、锌粉2~4份、丁基三苯基氟化膦3~5份、醋丙乳液2~5份、季戊四醇1~3份、磷酸二氢铵3~5份、异佛尔酮2~4份;
其制备方法包括以下步骤:
(1)将碳酸钙、有机硅树脂、纤维素树脂、磷铁粉混合均匀加入砂磨机内,研磨至300~400目,得预混料待用;
(2)将环氧树脂、乙烯树脂、甲苯放入混料机中,升温至75~85℃,混合搅拌半小时,然后加入丙二醇甲醚、丙二醇,继续升温至120~140℃,搅拌均匀,得混合液;
(3)将纳米二氧化钛、锌粉、丁基三苯基氟化膦、醋丙乳液加适量水搅拌,并升温至75~85℃,搅拌均匀后加入季戊四醇、磷酸二氢铵、异佛尔酮,继续加热至120~140℃,混合搅拌均匀,得改性剂;
(4)将步骤(1)得到的预混料、步骤(2)得到的混合液和步骤(3)得到的改性剂混合,搅拌均匀,研磨、烘干、粉碎成超细粉末即得。
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