CN106348792A - Manufacturing method of antibacterial ceramic tiles - Google Patents
Manufacturing method of antibacterial ceramic tiles Download PDFInfo
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- CN106348792A CN106348792A CN201610737861.7A CN201610737861A CN106348792A CN 106348792 A CN106348792 A CN 106348792A CN 201610737861 A CN201610737861 A CN 201610737861A CN 106348792 A CN106348792 A CN 106348792A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Abstract
The invention provides a manufacturing method of antibacterial ceramic tiles, and belongs to the technical field of architectural ceramics. The manufacturing method of the antibacterial ceramic tiles is characterized by comprising the following steps: printing protective glaze after inkjet printing, wherein the protective glaze comprises the following raw materials in parts by weight: 11-13 parts of Qidao clay, 11-13 parts of calcium carbonate, 4.5-5.5 parts of barium carbonate, 4.5-5.5 parts of burnt bone stone, 28.5-32.5 parts of potassium feldspar, 14-16 parts of glaze frits, 1.7-2.3 parts of zirconium silicate, 15-18 parts of albite, 1.7-2.3 parts of zinc oxide and 7-9 parts of an antibacterial agent; and in the firing step, increasing the temperature of a kiln to 835-840 DEG C, insulating for 1.5-2.5 hours, then heating to the temperature of 1,200-1,210 DEG C, insulating for 3-4 hours, and then cooling. The protective glaze is suitable for the antibacterial agent to efficiently play effects for a long time, and by a ceramic tile firing mode for the glaze, the wear-resistant and long-acting antibacterial ceramic tile can be obtained.
Description
Technical field
A kind of manufacture method of antibiotic ceramic tile, belongs to architectural pottery technical field.
Background technology
The floor tile of architectural decoration and wall brick are widely used already, and compared to other floor decorative materials, ceramic tile is in dress
The aspects such as decorations effect, health have obvious advantage.Ceramic tile produces after being widely used in after inkjet technology, the dress of ceramic tile
Decorations pattern, texture and pattern are more life-like, lively, greatly meet the pursuit to decorative effect for the consumer.
With the raising of people's living standard, antibiotic ceramic tile is increasingly becoming a kind of emerging technology, by extensive concern: such
Function environment indoors, especially flow of the people is big, the hospital of space relatively closing, the requirement in the environment such as school and market more
Height, by adding photocatalysis catalyst in glaze, ceramic tile can have sterilization effect under ultraviolet light, and in natural light or indoor lamp
Antibacterial effect in luminous environment still can not reach ideal effect, therefore, tend to be directly added in glaze research worker more
Or to introduce metal ion in the way of carrier carries, fired after the antibiotic ceramic tile that obtains mainly use silver, copper and zinc etc.
Ion is realizing bactericidal effect, but this kind of ion is volatile when high temperature burns till, non-refractory is so that the anti-microbial property of ceramic tile is big
Amplitude reduction；Carry out the antibiotic property of activated nano complex fire resistant material using interpolation rare earth element in glaze in the technology also having
Can, specifically using lamellar clay, strontium ion and rare earth ion are adsorbed between clay crystal layer it is achieved that being swashed by rare earth ion
The antibacterial effect lived, so successfully improves the heat resistance of antibacterial granule；But this technology using clay reduces
The abrasion resistance properties of glaze layer so that ceramic tile after long-term use not only glaze layer be worn and lead to pattern imperfect, impact is attractive in appearance, with
Shi Yinwei antibacterial only can play a role in the part of glaze layer surface, and glazed thickness is big and can cause the waste of antibacterial,
So very thin not wear-resisting glaze layer, lead to ceramic tile really have antibacterial effect time very short；The antibacterial effect of ceramic tile also with
The abrasion of glaze layer and consume.And add the abrasion-resistant material of routine to be returned to the compact structure of glaze layer, lead to antibacterial granule
It is fully sealed and cannot contact with antibacterial, antibacterial effect cannot show.
Content of the invention
The technical problem to be solved in the present invention is: overcomes the deficiencies in the prior art, provides a kind of wear-resisting, long-acting antibacterial porcelain
The manufacture method of brick.
The technical solution adopted for the present invention to solve the technical problems is: the manufacture method of this antibiotic ceramic tile, and its feature exists
In: include bottom processed base, drench ground-coat enamel, drench cover-coat enamel, ink-jet printed, print protection glaze and fire step；Wherein said print protection glaze step
In the parts by weight of raw materials of protection glaze used consist of: 11 ~ 13 parts of air knife soil, 11 ~ 13 parts of Calcium Carbonate, 4.5 ~ 5.5 parts of brium carbonate,
Burn 4.5 ~ 5.5 parts of GUSHI, 28.5 ~ 32.5 parts of potassium feldspar, 14 ~ 16 parts of cullet of glaze, 1.7 ~ 2.3 parts of Zirconium orthosilicate., albite 15 ~ 18
Part, 1.7 ~ 2.3 parts of zinc oxide, 7 ~ 9 parts of antibacterial；Kiln temperature is first risen to 835 DEG C ~ 840 DEG C by described firing in step, insulation
1.5 h ~ 2.5h, then heat to 1200 DEG C ~ 1210 DEG C, are incubated 3h ~ 4h, then cool.
The primary object of the present invention is to provide the protection glaze glaze that a kind of suitable antibacterial is long-term, efficiently play a role
Material, and fire mode for the ceramic tile of this glaze.First, the present invention adds one in the major constituent of potassium feldspar and cullet of glaze
The air knife soil of quantitation, Calcium Carbonate and brium carbonate, in order to improve structural strength and micro porosity, increase the content of potassium feldspar, and cooperation is few
The burning GUSHI of amount, Zirconium orthosilicate., the crystal formation of adjustment glaze, improves the anti-wear performance of glaze.It is also added into a small amount of in protection glaze glaze
Zinc oxide, on the one hand itself there is antibacterial effect, on the other hand can strengthen the antibacterial effect of antibacterial with antibacterial cooperation.
In sintering procedure, the present invention, first when kiln temperature rises to 835 DEG C ~ 840 DEG C, is incubated 1.5 h ~ 2.5h, using Calcium Carbonate
The carbon dioxide being decomposed to form impacts gas circuit, is then further continued for heating up, gradually by the road of gas circuit in the melting process of glaze
Footpath reduces, and when temperature reaches 1200 DEG C ~ 1210 DEG C, brium carbonate can split the carbon dioxide off gas once in a while, and gas circuit is beaten again
Open, in the continuous closure of gas circuit and opening procedure, complete firing of glaze, until decrease temperature crystalline completes, protect in protection glaze layer
Stay pore micro structure, the present invention passes through the control of the amount to the carbon dioxide and burning process condition decomposed, and realizes system
The size of this pore micro structure obtaining is not enough to allow dust to enter, and gas molecule but can be allowed to pass in and out, with air (mainly moisture
Son) excite the antibacterial effect of antibacterial within glaze layer.
Preferably, it is 0.5 mm ~ 1.2mm that described print protects the thickness of the protection glaze layer applying in glaze step.The present invention
Protection glaze the antibacterial within glaze layer also can play antibacterial effect for a long time, do not result in the waste of antibacterial addition,
So the feasible region of the thickness of glaze layer is wider.
Preferably, the preparation method of described protection glaze be by air knife soil, Calcium Carbonate, brium carbonate, burning GUSHI, potassium feldspar,
Cullet of glaze, Zirconium orthosilicate., albite are broken for the granule of 200 ~ 210 mesh by weight ratio afterwards, then add zinc oxide by proportioning
Stir with antibacterial.The raw material of protection glaze layer is applied with this granularity, and when being incubated for 835 DEG C ~ 840 DEG C, glaze can be by gas
Body washes air flue open, and the viscosity after being heated by surface keeps air flue, can preferably ensure the present invention micro- pore equal
Even formation.Glaze can certainly be made printing glaze slip, by ink-jet technology, be applied in ink jet layer.
Preferably, described antibacterial is 10:3 ~ 4:8 ~ 12 configuration in mass ratio of boron oxide, rare earth ion and Pulvis Talci
Mixture.Currently preferred antibacterial more adapts to the protection glaze glaze Rotating fields of the present invention it is ensured that long-term high-efficiency antimicrobial effect.
Preferably, the parts by weight of raw materials of described protection glaze consists of: 12 parts of air knife soil, 12 parts of Calcium Carbonate, brium carbonate 5
Part, burn 5 parts of GUSHI, 29 ~ 31 parts of potassium feldspar, 15 parts of cullet of glaze, 2 parts of Zirconium orthosilicate., 16 ~ 17 parts of albite, 2 parts of zinc oxide, resist
2 parts of microbial inoculum.Currently preferred parts by weight of raw materials composition can make the anti-wear performance of protection glaze and anti-microbial property reach the present invention
Optimum state.
Preferably, kiln temperature is first appreciated 835 DEG C ~ 838 DEG C by described firing in step, is incubated 2.2 h ~ 2.5h, Ran Housheng
Temperature, to 1200 DEG C ~ 1205 DEG C, is incubated 3.5h ~ 4h, then cools.Preferably burning process condition, ensure that the micro- of formation
Pore evenly, avoids the generation of big pore completely.
Preferably, described Calcium Carbonate is 0.02 μm ~ 0.06 μm of calcium carbonate superfine powder for particle diameter.Calcium carbonate superfine powder is in this guarantor
Superpower automatic uniform dispersibility can be shown in shield glaze glaze, material will not be produced and assemble so that forming micro- pore dispersion
Evenly, aperture is less.
Preferably, described Zinc oxide particles size is the nano zine oxide of 10nm ~ 50nm.Currently preferred nano oxygen
Change zinc and can show the polymolecularity that macro object does not have, the dispersed of antibacterial can be guided simultaneously, utilize it
The antibiotic property itself possessing, improves antimicrobial efficiency.
The present invention drenched ground-coat enamel and cover-coat enamel before ink-jet printed it is ensured that ink-jet printed clear patterns, distinct.
Compared with prior art, a kind of manufacture method of antibiotic ceramic tile of the present invention is had the beneficial effect that this
Bright primary object is to provide the protection glaze glaze that a kind of suitable antibacterial is long-term, efficiently play a role, and for this
Mode fired by the ceramic tile of glaze.First, the present invention add in the major constituent of potassium feldspar and cullet of glaze a certain amount of air knife soil,
Calcium Carbonate and brium carbonate, in order to improve structural strength and micro porosity, increase the content of potassium feldspar, coordinate a small amount of burning GUSHI, silicon
Sour zirconium, the crystal formation of adjustment glaze, improves the anti-wear performance of glaze.It is also added into a small amount of zinc oxide, a side in protection glaze glaze
Face itself has antibacterial effect, on the other hand can strengthen the antibacterial effect of antibacterial with antibacterial cooperation.In sintering procedure,
The present invention, first when kiln temperature rises to 835 DEG C ~ 840 DEG C, is incubated 1.5 h ~ 2.5h, using be decomposed to form the two of Calcium Carbonate
Carbonoxide impacts gas circuit, is then further continued for heating up, gradually reduces the path of gas circuit, in temperature in the melting process of glaze
When reaching 1200 DEG C ~ 1210 DEG C, brium carbonate can split the carbon dioxide off gas once in a while, gas circuit is reopened, in gas circuit not
Complete firing of glaze in disconnected closure and opening procedure, until decrease temperature crystalline completes, in protection glaze layer, remain the micro- knot of pore
Structure, the present invention passes through the control of the amount to the carbon dioxide and burning process condition decomposed, and this pore realizing being obtained is micro-
The size of structure is not enough to allow dust to enter, and gas molecule but can be allowed to pass in and out, excite glaze layer with air (mainly hydrone)
The antibacterial effect of internal antibacterial.In a word, the preparation method of the present invention can obtain a kind of wear-resisting, long-acting antibiotic ceramic tile.
Specific embodiment
Manufacture method with reference to a kind of antibiotic ceramic tile to the present invention for the specific embodiment is described further, wherein in fact
Applying example 1 is most preferred embodiment.
Embodiment 1
Preparation process includes: blank raw material selected-ball milling slurrying-spray drying powder processed-compressing-siccative green compact-glaze becomes-drenches
Ground-coat enamel-pouring cover-coat enamel-ink-jet printed-print protection glaze-enter klining one-tenth-finished product；
By load weighted Kaolin, quartz and Anhydrite, according to mass percent, the ratio for 48:32:18 puts into ball milling after mixing
Wet ball grinding 30h in machine, obtains base substrate material grain after mist projection granulating, old 20h；Base substrate material grain is put in mould,
Green compact of ceramic tile is obtained after being pressed under 200mpa pressure；
Successively drench the glaze slip of ground-coat enamel and cover-coat enamel；
Ink-jet printer imposes on ceramic tile cover-coat enamel according to preselected pattern ink-jet；
By 12 parts of air knife soil, particle diameter is 0.02 μm ~ 0.06 μm of 12 parts of calcium carbonate superfine powder, and 5 parts of brium carbonate burns 5 parts of GUSHI, potassium is long
30.5 parts of stone, 15 parts of cullet of glaze, 2 parts of Zirconium orthosilicate., 16.5 parts of albite is broken for the granule of 200 mesh by weight ratio afterwards,
Add 2 parts of the nano zine oxide that granular size is 10nm ~ 50nm and 8 parts of antibacterial stirs, after making protection glaze glaze slip
Impose in ink jet layer, the thickness of protection glaze layer is 0.8mm；
The brick body that above-mentioned technique is made is transferred to be fired in kiln, first kiln temperature is risen to 836 DEG C, is incubated 2.3h, then heats to
1205 DEG C, it is incubated 3.5h, then cools, kiln discharge obtains final product.
Embodiment 2
Preparation process includes: blank raw material selected-ball milling slurrying-spray drying powder processed-compressing-siccative green compact-glaze becomes-drenches
Ground-coat enamel-pouring cover-coat enamel-ink-jet printed-print protection glaze-enter klining one-tenth-finished product；
By load weighted Kaolin, quartz and Anhydrite, according to mass percent, the ratio for 48:32:18 puts into ball milling after mixing
Wet ball grinding 36h in machine, obtains base substrate material grain after mist projection granulating, old 24h；Base substrate material grain is put in mould,
Green compact of ceramic tile is obtained after being pressed under 200mpa pressure；
Successively drench the glaze slip of ground-coat enamel and cover-coat enamel；
Ink-jet printer imposes on ceramic tile cover-coat enamel according to preselected pattern ink-jet；
By 11.5 parts of air knife soil, particle diameter is 0.02 μm ~ 0.06 μm of 12.5 parts of calcium carbonate superfine powder, and 4.7 parts of brium carbonate burns GUSHI
5.2 parts, 29 parts of potassium feldspar, 15.5 parts of cullet of glaze, 1.9 parts of Zirconium orthosilicate., 17 parts of albite is broken for 210 by weight ratio afterwards
Purpose granule, adds 1.9 parts of the nano zine oxide that granular size is 10nm ~ 50nm and 8.5 parts of antibacterial stirs, and makes
Impose in ink jet layer after protection glaze glaze slip, the thickness of protection glaze layer is 0.6mm；
The brick body that above-mentioned technique is made is transferred to be fired in kiln, first kiln temperature is risen to 838 DEG C, is incubated 2.2h, then heats to
1208 DEG C, it is incubated 3.2h, then cools, kiln discharge obtains final product.
Embodiment 3
Preparation process includes: blank raw material selected-ball milling slurrying-spray drying powder processed-compressing-siccative green compact-glaze becomes-drenches
Ground-coat enamel-pouring cover-coat enamel-ink-jet printed-print protection glaze-enter klining one-tenth-finished product；
By load weighted Kaolin, quartz and Anhydrite, according to mass percent, the ratio for 48:32:18 puts into ball milling after mixing
Wet ball grinding 36h in machine, obtains base substrate material grain after mist projection granulating, old 24h；Base substrate material grain is put in mould,
Green compact of ceramic tile is obtained after being pressed under 200mpa pressure；
Successively drench the glaze slip of ground-coat enamel and cover-coat enamel；
Ink-jet printer imposes on ceramic tile cover-coat enamel according to preselected pattern ink-jet；
By air knife soil 12.5 parts, 11.5 parts of Calcium Carbonate, 5.2 parts of brium carbonate, burn 4.7 parts of GUSHI, 31 parts of potassium feldspar, cullet of glaze
14.5 parts, 2.1 parts of Zirconium orthosilicate., 16 parts of albite is broken for the granule of 210 mesh by weight ratio afterwards, adds zinc oxide 2.1
Part and 7.5 parts of antibacterial stir, and impose in ink jet layer after making protection glaze glaze slip, and the thickness of protection glaze layer is 0.9mm；
The brick body that above-mentioned technique is made is transferred to be fired in kiln, first kiln temperature is risen to 837 DEG C, is incubated 2.5h, then heats to
1202 DEG C, it is incubated 3.7h, then cools, kiln discharge obtains final product.
Embodiment 4
Preparation process includes: blank raw material selected-ball milling slurrying-spray drying powder processed-compressing-siccative green compact-glaze becomes-drenches
Ground-coat enamel-pouring cover-coat enamel-ink-jet printed-print protection glaze-enter klining one-tenth-finished product；
By load weighted Kaolin, quartz and Anhydrite, according to mass percent, the ratio for 48:32:18 puts into ball milling after mixing
Wet ball grinding 36h in machine, obtains base substrate material grain after mist projection granulating, old 24h；Base substrate material grain is put in mould,
Green compact of ceramic tile is obtained after being pressed under 200mpa pressure；
Successively drench the glaze slip of ground-coat enamel and cover-coat enamel；
Ink-jet printer imposes on ceramic tile cover-coat enamel according to preselected pattern ink-jet；
By air knife soil 11 parts, 13 parts of Calcium Carbonate, 4.5 parts of brium carbonate, burn 5.5 parts of GUSHI, 28.5 parts of potassium feldspar, cullet of glaze 16
Part, 1.7 parts of Zirconium orthosilicate., 18 parts of albite is broken for the granule of 200 mesh by weight ratio afterwards, add 1.7 parts of zinc oxide and
9 parts of antibacterial stirs, and imposes in ink jet layer after making protection glaze glaze slip, and the thickness of protection glaze layer is 0.5 mm；
The brick body that above-mentioned technique is made is transferred to be fired in kiln, first kiln temperature is risen to 835 DEG C, is incubated 2.5h, then heats to
1210 DEG C, it is incubated 3h, then cools, kiln discharge obtains final product.
Embodiment 5
Preparation process includes: blank raw material selected-ball milling slurrying-spray drying powder processed-compressing-siccative green compact-glaze becomes-drenches
Ground-coat enamel-pouring cover-coat enamel-ink-jet printed-print protection glaze-enter klining one-tenth-finished product；
By load weighted Kaolin, quartz and Anhydrite, according to mass percent, the ratio for 48:32:18 puts into ball milling after mixing
Wet ball grinding 36h in machine, obtains base substrate material grain after mist projection granulating, old 24h；Base substrate material grain is put in mould,
Green compact of ceramic tile is obtained after being pressed under 200mpa pressure；
Successively drench the glaze slip of ground-coat enamel and cover-coat enamel；
Ink-jet printer imposes on ceramic tile cover-coat enamel according to preselected pattern ink-jet；
By air knife soil 13 parts, 11 parts of Calcium Carbonate, 5.5 parts of brium carbonate, burn 4.5 parts of GUSHI, 32.5 parts of potassium feldspar, cullet of glaze 14
Part, 2.3 parts of Zirconium orthosilicate., 15 parts of albite is broken for the granule of 210 mesh by weight ratio afterwards, add 2.3 parts of zinc oxide and
7 parts of antibacterial stirs, and imposes in ink jet layer after making protection glaze glaze slip, and the thickness of protection glaze layer is 1.2mm；
The brick body that above-mentioned technique is made is transferred to be fired in kiln, first kiln temperature is risen to 840 DEG C, is incubated 1.5 h, then heats to
1200 DEG C, it is incubated 4h, then cools, kiln discharge obtains final product.
Comparative example 1
Step of preparation process and process conditions are with unlike embodiment 1: the air knife soil in protection glaze glaze, Calcium Carbonate, carbonic acid
The consumption of barium is replaced with potassium feldspar.
Comparative example 2
Step of preparation process and process conditions are with unlike embodiment 1: in sintering procedure, kiln temperature directly rises to 1100 DEG C, insulation
5h.
The anti-microbial property test of each embodiment and comparative example the results are shown in Table 1:
In table 1, initial sterilizing rate is that anti-skidding antibiotic ceramic tile is after the production through the inspection of Chinese architecture material industry environmental monitoring center
24h in sterilizing rate to escherichia coli and staphylococcus aureuses；After being retained 1 year for ceramic tile using rear sterilizing rate, and pass through
The sterilizing rate to escherichia coli and staphylococcus aureuses after the tire friction of 200h.
From each embodiment and comparative example, only just can be grown under the protection glaze formula and firing condition of the present invention
The antibiotic ceramic tile of high antibacterial effect is kept after phase abrasion-resistant.In comparative example 1, antibacterial does not have due effect after being sealed, right
In ratio 2 antibacterial in use for some time, because of extraneous effect inactivation.
The above, be only presently preferred embodiments of the present invention, is not the restriction that the present invention is made with other forms, appoints
What those skilled in the art possibly also with the disclosure above technology contents changed or be modified as equivalent variations etc.
Effect embodiment.But every without departing from technical solution of the present invention content, according to the present invention technical spirit to above example institute
Any simple modification, equivalent variations and the remodeling made, still falls within the protection domain of technical solution of the present invention.
Claims (8)
1. a kind of manufacture method of antibiotic ceramic tile it is characterised in that: include bottom processed base, drench ground-coat enamel, drench cover-coat enamel, ink-jet printed, add
Print is protected glaze and is fired step；In wherein said print protection glaze step, the parts by weight of raw materials of protection glaze used consists of: air knife
11 ~ 13 parts of soil, 11 ~ 13 parts of Calcium Carbonate, 4.5 ~ 5.5 parts of brium carbonate, burns 4.5 ~ 5.5 parts of GUSHI, 28.5 ~ 32.5 parts of potassium feldspar, glaze
14 ~ 16 parts of frit of material, 1.7 ~ 2.3 parts of Zirconium orthosilicate., 15 ~ 18 parts of albite, 1.7 ~ 2.3 parts of zinc oxide, 7 ~ 9 parts of antibacterial；Described
Fire in step and first kiln temperature risen to 835 DEG C ~ 840 DEG C, be incubated 1.5 h ~ 2.5h, then heat to 1200 DEG C ~ 1210 DEG C,
Insulation 3h ~ 4h, then cool.
2. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: described print protection glaze step
The thickness of the protection glaze layer of middle applying is 0.5 mm ~ 1.2mm.
3. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: the preparation of described protection glaze
Method is by air knife soil, Calcium Carbonate, brium carbonate, burns GUSHI, potassium feldspar, cullet of glaze, Zirconium orthosilicate., albite by weight ratio
It is broken for the granule of 200 ~ 210 mesh afterwards, then add zinc oxide and antibacterial to stir by proportioning.
4. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: described antibacterial be oxidation
The mixture of boron, rare earth ion and Pulvis Talci 10:3 ~ 4:8 ~ 12 configuration in mass ratio.
5. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: the raw material of described protection glaze
Weight portion consists of: 12 parts of air knife soil, 12 parts of Calcium Carbonate, 5 parts of brium carbonate, burns 5 parts of GUSHI, 29 ~ 31 parts of potassium feldspar, cullet of glaze
15 parts, 2 parts of Zirconium orthosilicate., 16 ~ 17 parts of albite, 2 parts of zinc oxide, 2 parts of antibacterial.
6. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: described fire in step first
Kiln temperature is appreciated 835 DEG C ~ 838 DEG C, is incubated 2.2 h ~ 2.5h, then heats to 1200 DEG C ~ 1205 DEG C, be incubated 3.5h ~ 4h, then
Cool.
7. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: described Calcium Carbonate be particle diameter
For 0.02 μm ~ 0.06 μm of calcium carbonate superfine powder.
8. a kind of antibiotic ceramic tile according to claim 1 manufacture method it is characterised in that: described Zinc oxide particles are big
The little nano zine oxide for 10nm ~ 50nm.
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| CN107162423A (en) * | 2017-05-26 | 2017-09-15 | 陆洁容 | A kind of preparation method of the ceramic glaze and its Ceramic Tiles of antibacterial and antistatic |
| CN109896839A (en) * | 2019-04-24 | 2019-06-18 | 同曦集团有限公司 | A kind of antibacterial and mouldproof ceramic tile and preparation method thereof |
| CN109942277A (en) * | 2019-04-24 | 2019-06-28 | 同曦集团有限公司 | A kind of negative ion antibiotic ceramic tile and preparation method thereof |
| CN110683821A (en) * | 2019-11-27 | 2020-01-14 | 凤冈县恒兴新型建材有限责任公司 | Preparation method of aerated brick |
| CN110776257A (en) * | 2019-12-06 | 2020-02-11 | 佛山市东鹏陶瓷有限公司 | Ceramic glaze with antibacterial function and preparation method and application thereof |
| CN112094136A (en) * | 2020-09-19 | 2020-12-18 | 江苏纳鼎材料科技有限公司 | Antibacterial ceramic and manufacturing method thereof |
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| CN112830817A (en) * | 2021-01-22 | 2021-05-25 | 佛山森蒂泰珂科技有限公司 | Ceramic product with antibacterial function and preparation method thereof |
| CN113636870A (en) * | 2021-07-13 | 2021-11-12 | 广东富强陶瓷有限公司 | Production process of antibacterial wear-resistant anti-skid glazed ceramic tile |
| CN113968674A (en) * | 2021-10-14 | 2022-01-25 | 广东欧文莱陶瓷有限公司 | Antifouling digital protective glaze |
| CN115321949A (en) * | 2022-08-30 | 2022-11-11 | 山西始耳趾电子科技有限公司 | Highlight antibacterial ceramic tile and production process thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
| CN1686919A (en) * | 2004-12-29 | 2005-10-26 | 淄博博纳科技发展有限公司 | Super hydrophilic functional ceramic material easy to be cleaned and preparation technique |
| CN101654378A (en) * | 2008-08-19 | 2010-02-24 | 郑水泉 | Ceramic glaze pattern-glazed brick and production method thereof |
| CN102731169A (en) * | 2012-07-13 | 2012-10-17 | 佛山市科捷制釉有限公司 | Fully glazed ceramic chip and preparation method thereof |
| CN103602144A (en) * | 2013-12-02 | 2014-02-26 | 佛山市东鹏陶瓷有限公司 | Ceramic ink-jet printing colored glaze mixed type antibacterial ink and preparation method thereof |
| CN104774037A (en) * | 2015-04-14 | 2015-07-15 | 岑溪市新鸿基陶瓷有限公司 | Antibacterial ceramic glaze liquid and preparation method thereof |
-
2016
- 2016-08-26 CN CN201610737861.7A patent/CN106348792B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
| CN1686919A (en) * | 2004-12-29 | 2005-10-26 | 淄博博纳科技发展有限公司 | Super hydrophilic functional ceramic material easy to be cleaned and preparation technique |
| CN101654378A (en) * | 2008-08-19 | 2010-02-24 | 郑水泉 | Ceramic glaze pattern-glazed brick and production method thereof |
| CN102731169A (en) * | 2012-07-13 | 2012-10-17 | 佛山市科捷制釉有限公司 | Fully glazed ceramic chip and preparation method thereof |
| CN103602144A (en) * | 2013-12-02 | 2014-02-26 | 佛山市东鹏陶瓷有限公司 | Ceramic ink-jet printing colored glaze mixed type antibacterial ink and preparation method thereof |
| CN104774037A (en) * | 2015-04-14 | 2015-07-15 | 岑溪市新鸿基陶瓷有限公司 | Antibacterial ceramic glaze liquid and preparation method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107162423A (en) * | 2017-05-26 | 2017-09-15 | 陆洁容 | A kind of preparation method of the ceramic glaze and its Ceramic Tiles of antibacterial and antistatic |
| CN109942277B (en) * | 2019-04-24 | 2021-08-27 | 同曦集团有限公司 | Negative ion antibacterial ceramic tile and preparation method thereof |
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| CN109942277A (en) * | 2019-04-24 | 2019-06-28 | 同曦集团有限公司 | A kind of negative ion antibiotic ceramic tile and preparation method thereof |
| CN109896839B (en) * | 2019-04-24 | 2022-02-18 | 同曦集团有限公司 | Antibacterial and mildewproof ceramic tile and preparation method thereof |
| CN110683821A (en) * | 2019-11-27 | 2020-01-14 | 凤冈县恒兴新型建材有限责任公司 | Preparation method of aerated brick |
| CN110776257B (en) * | 2019-12-06 | 2021-11-02 | 佛山市东鹏陶瓷有限公司 | Ceramic glaze with antibacterial function and preparation method and application thereof |
| CN110776257A (en) * | 2019-12-06 | 2020-02-11 | 佛山市东鹏陶瓷有限公司 | Ceramic glaze with antibacterial function and preparation method and application thereof |
| CN112094136A (en) * | 2020-09-19 | 2020-12-18 | 江苏纳鼎材料科技有限公司 | Antibacterial ceramic and manufacturing method thereof |
| CN112723745A (en) * | 2020-12-24 | 2021-04-30 | 肇庆乐华陶瓷洁具有限公司 | Antibacterial purification glaze and preparation method of glazed tile using same |
| CN112830817A (en) * | 2021-01-22 | 2021-05-25 | 佛山森蒂泰珂科技有限公司 | Ceramic product with antibacterial function and preparation method thereof |
| CN113636870A (en) * | 2021-07-13 | 2021-11-12 | 广东富强陶瓷有限公司 | Production process of antibacterial wear-resistant anti-skid glazed ceramic tile |
| CN113968674A (en) * | 2021-10-14 | 2022-01-25 | 广东欧文莱陶瓷有限公司 | Antifouling digital protective glaze |
| CN115321949A (en) * | 2022-08-30 | 2022-11-11 | 山西始耳趾电子科技有限公司 | Highlight antibacterial ceramic tile and production process thereof |
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