CN106342830A - Bactericidal composition containing benziothiazolinone and Saisen Tong - Google Patents
Bactericidal composition containing benziothiazolinone and Saisen Tong Download PDFInfo
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- CN106342830A CN106342830A CN201610751571.8A CN201610751571A CN106342830A CN 106342830 A CN106342830 A CN 106342830A CN 201610751571 A CN201610751571 A CN 201610751571A CN 106342830 A CN106342830 A CN 106342830A
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- benziothiazolinone
- thiophene
- bactericidal composition
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- rice
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention relates to a bactericidal composition containing benziothiazolinone and Saisen Tong. The bactericidal composition contains effective ingredients such as benziothiazolinone and Saisen Tong. The mass ratio of benziothiazolinone to Saisen Tong is 1:80-80:1. The bactericidal composition can be prepared into microemulsion, water emulsion, a suspension concentrate, suspoemulsion, water dispersible granules and wettable powder. The bactericidal composition mainly prevents from bacterial and fungi diseases including rice blast, rice stripe virus, rice sheath blight and bacterial leaf streak.
Description
Technical field
The present invention relates to agricultural disease prevention and control field, specifically a kind of bactericidal composition containing benziothiazolinone and thiophene gloomy copper sodium.
Background technology
Benziothiazolinone (benziothiazolinone) is the heterocyclic of Shaanxi Xida Huate Science ＆ Technology Industrial Co., Ltd.'s exploitation
Antibacterial.Molecular formula: c7h5nos, chemical name: 1,2 benzisothiazole-3-ketone.
Benziothiazolinone is a kind of efficient, low toxicity, broad-spectrum germicide, can destroy pathogen cell membrane protein and synthesis system
System, thus suppressing pathogen to breed, interference pathogen cell metabolism, so as to physiologic derangement, leads to pathogen dead.This change
To antibacterial, fungus-caused multiple kinds of crops disease has good prevention effect to compound, and fool proof to crops and environment.
The gloomy copper of thiophene is the organic copper fungicide of thiazoless, and main registration prevents and treats bacterial blight of rice, bacterial stripe, Chinese cabbage
Soft rot and bacterial wilt of tomato.High-efficiency broad spectrum, toxicity is low, safety and environmental protection, nuisanceless, to bacterial disease specially good effect, to fungoids
Disease is efficient.
Rice blast also known as rice blast, burn pestilence, pestilence of kowtowing, be worldwide fungal disease, be China's north and south rice workspace
One of rice disease of harm most serious, with banded sclerotial blight, bacterial leaf-blight and claim Oryza sativa L. three big disease.The each rice region of China all has to be sent out
Raw, especially few with sunshine, mist reveals the mountain area of persistent period length and knob occurs weight.The popular time, the general underproduction 10%～
20%, weight reach 40%～50%, or even total crop failure.
Stripe disease, belongs to Disease.Many can not the heading of plant morbidity morning, slow fringe of falling ill is little, lopsided.
General diseased plant 5% about, the underproduction 3%～5%；Severe disease field diseased plant up to more than 30%, the underproduction more than 20%.In recent years, exist
Band round-grained rice (glutinous) rice is aggrieved heavier for Jiangsu and Zhejiang Provinces one, and in continuing the situation that runs rampant, has a strong impact on Rice Production.
Rice sheath blight disease, another name moire disease, flower foot lever, it is commonly called as rotten foot pestilence, belong to fungal disease.The each rice region in the whole nation all has to be sent out
Raw, it is one of Major Diseases of China's rice region, its occurring area, occurrence frequency, production loss of causing etc. at present all occupies each disease
First of evil.This sick main harm rice leaf sheath and blade, also endanger cane and fringe portion, the typically aggrieved light underproduction 5% when serious
～10%, severe one is up to 50%～70%.Paddy growth early stage is seriously aggrieved, causes " the pool " or " string top ", possible granule is no
Receive.Increase with planting density in Rice Production and the raising of Fertilization Level, be especially a lack of antigen, has and increases year by year
Trend.Moreover it is possible to encroach on Fructus Hordei Vulgaris, Semen Maydiss, chestnut, Caulis Sacchari sinensis, Semen sojae atricolor, peanut and other crops in addition to hazard rice.
Bacterial leaf streak of rice, also known as slice disease, cecospora spot, belongs to bacterial disease, is China's domestic plant disease inspection
One of epidemic disease object.In addition to hazard rice, also endanger multiple wild rices, Leersia Sw.The general underproduction 10%～20%, serious reaches
40%～60%.
Content of the invention
It is an object of the invention to proposing a kind of Bactericidal composite that can prevent and treat rice disease and have synergistic function concurrently
Thing, the effective ingredient of this bactericidal composition is benziothiazolinone and the gloomy copper of thiophene, can be used for preventing and treating rice blast, stripe virus disease, stricture of vagina
Rot, bacterial stripe etc. be bacillary and fungal disease.
For achieving the above object, the present invention also can employ the following technical solutions:
A kind of bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene it is characterised in that bactericidal composition effective ingredient benziothiazolinone and
The gloomy copper of thiophene, the wherein mass ratio of benziothiazolinone and the gloomy copper of thiophene are 1-80:1-80, preferably 20:1-1:40.
The described bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene, the weight percent of effective ingredient benziothiazolinone and the gloomy copper of thiophene contains
Amount sum is 1-90%；
The described bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene adds corresponding adjuvant, can be made into microemulsion, water
The upper acceptable dosage form of the agricultural application such as Emulsion, suspending agent, suspension emulsion, water dispersible granules, wettable powder.
Described adjuvant includes solvent, cosolvent, emulsifying agent, wetting agent, dispersant, disintegrating agent, stabilizer, ph value tune
Various composition, concrete composition and consumption root conventional or that allow use in the pesticidal preparations such as section agent, defoamer, thickening agent, filler
Determined by simple experiment according to recipe requirements.
Described solvent and cosolvent are selected from ethanol, isopropanol, n-butyl alcohol, n-amyl alcohol, acetone, Ketohexamethylene, dimethyl methyl
Amide, hexamethylene benzene, toluene and, dimethylbenzene, diesel oil, methanol, petroleum ether s-200, one or more of.
Described emulsifying agent be nonionic with the complex of anion surfactant, be selected from agriculture breast 500, agriculture breast 600
Number series, Nongru-700 series, np-10, No. 1600 series of agriculture breast, agriculture breast 2000, agriculture breast 11, agriculture breast 12, by system
Row, the combination of one or more of op series, TWEEN Series, sorpol series.
Described wetting agent is sodium lauryl sulphate, calcium dodecyl benzene sulfonate, pull open powder, pungent (nonyl) base phenol polyethenoxy
One of base ether, sodium laurylsulfate, octylphenol polyethylene oxyethylene group ether sulfate, Bombyx mori L., tea saponin, Negel or
Multiple.
Described dispersant is naphthalene sulfonate, lignosulfonates, polycarboxylate, Ketohexamethylene formaldehyde condensation products, benzene sulfonamide
Hydrochlorate, alkylphenol polyoxyethylene, aliphatic alcohol polyoxyethylene sulfonate, carboxymethyl cellulose, alkylphenol-polyethenoxy base phosphorus
Acid esters, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy base ether, castor oil polyoxyethylene ether,
One or more of fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate.
Described disintegrating agent is one or more of calcium nitrate, magnesium nitrate, sodium sulfate, aluminum chloride, ammonium sulfate, carbamide.
Described stabilizer is one or more of bht, ra-w3, epoxychloropropane, epoxy soybean oil.
Described ph regulator is citric acid, benzoic acid, glacial acetic acid, one or more in tartaric acid.
Described defoamer be one of organic silicone oil defoamer, c8-10 aliphatic alcohols compound, silicone defoamer or
Multiple.
The above thickening agent is xanthan gum, arabic gum, aluminium-magnesium silicate, polyvinyl alcohol, carboxymethyl cellulose, Guar
One or more of glue, sodium alginate.
Described filler is white carbon, sodium sulfate, ammonium sulfate, attapulgite, starch, Kaolin, precipitated calcium carbonate, swelling
One or more of soil, kieselguhr.
When the dosage form of described bactericidal composition is microemulsion, its component includes: benziothiazolinone 0.1-30%, thiophene gloomy copper 0.1-
30%, solvent, cosolvent 0.1%-40%, emulsifying agent 0.1%-20%, other auxiliary agents 0.1%-5%, filler supplies 100%.
When the dosage form of described bactericidal composition is aqueous emulsion, its component includes: benziothiazolinone 0.1-30%, thiophene gloomy copper 0.1-
30%, solvent, cosolvent 0.1%-40%, emulsifying agent 0.1%-20%, other auxiliary agents 0.1%-5%, filler supplies 100%.
When the dosage form of described bactericidal composition is suspending agent, its component includes: benziothiazolinone 0.1-30%, thiophene gloomy copper 0.1-
30%, dispersant 0.1%-10%, antifreezing agent 0.1%-5%, thickening agent 0.1%-3%, defoamer 0.01%-0.5%, water is mended
Foot 100%.
When the dosage form of described bactericidal composition is suspension emulsion, its component includes: benziothiazolinone 0.1-30%, thiophene gloomy copper 0.1-
30%, solvent, cosolvent 0.1%-40%, emulsifying agent 0.1%-20%, dispersant 0.1%-10%, antifreezing agent 0.1%-5%,
Thickening agent 0.1%-3%, defoamer 0.01%-0.5%, water supplies 100%.
When the dosage form of described bactericidal composition is water dispersible granules, its component includes: benziothiazolinone 0.1-30%, the gloomy copper of thiophene
0.1-30%, dispersant 0.1%-10%, wetting agent 0.1%-5%, disintegrating agent 0.1%-10%, filler supplies 100%.
When the dosage form of described bactericidal composition is wettable powder, its component includes: benziothiazolinone 0.1-30%, the gloomy copper of thiophene
0.1-30%, dispersant 0.1%-10%, wetting agent 0.1%-5%, filler supplies 100%.
The present invention has advantages below and significant technique effect, and benziothiazolinone and mixture both the gloomy copper of thiophene all have obvious association
Same synergy, can be greatly improved drug effect, reduce usage amount and the negative effect to environment.Can be used for preventing and treating Oryza sativa L. rice blast
The paddy bacterials such as disease, stripe virus disease, banded sclerotial blight, bacterial stripe and fungal disease.
Specific embodiment
With reference to specific embodiment, technical scheme and technique effect are described further, institute of the present invention
The percentage ratio stated all is weight percentage, but embodiments of the present invention are not limited to the scope of embodiment statement.
First, prepare embodiment
Embodiment 1, the microemulsion containing benziothiazolinone and the gloomy copper of thiophene
Component includes: benziothiazolinone 5%, the gloomy copper of thiophene 15%, Ketohexamethylene 5%, ethanol 20%, agriculture breast 500#4%, Nongru-700 #
1%, agriculture breast 602#5%, carbamide 5%, water supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by benziothiazolinone, thiophene gloomy copper Ketohexamethylene, ethanol are thorough
Dissolving, is sufficiently mixed with agriculture breast 500#, Nongru-700 #, agriculture breast 602# and uniformly makes oil phase, and carbamide is put into mix homogeneously in water
For aqueous phase, then aqueous phase is added in oil phase, be stirred well to bright shape, that is, obtain the gloomy copper microemulsion of 20% benziothiazolinone thiophene.
Embodiment 2, the aqueous emulsion containing benziothiazolinone and the gloomy copper of thiophene
Component includes: benziothiazolinone 10%, the gloomy copper of thiophene 10%, methanol 10%, s-200 solvent naphtha 25%, agriculture breast 500#
4.5%, Nongru-700 #2%, agriculture breast 601#3%, ethylene glycol 5%, water supplies 100%.
Preparation technology is: weigh material by above-mentioned mass percent, by benziothiazolinone, and thiophene gloomy copper methanol and s-200 solvent
Oil thoroughly dissolves, and is sufficiently mixed with agriculture breast 500#, Nongru-700 #, agriculture breast 601# and uniformly makes oil phase, and ethylene glycol is put in water
Mix homogeneously is aqueous phase, under 3000 revs/min of high shear agitation, oil phase is added in aqueous phase, and shearing dispersion 1 hour obtains final product
To the gloomy aqueous emulsion of copper of 20% benziothiazolinone thiophene.
Embodiment 3, the suspending agent containing benziothiazolinone and the gloomy copper of thiophene
Component includes: benziothiazolinone 5%, the gloomy copper of thiophene 25%, alkylbenzenesulfonate 2%, fatty alcohol-polyoxyethylene ether 2%, urine
Element 4%, aluminium-magnesium silicate 0.4%, xanthan gum 0.15%, organic silicon defoamer 0.4%, water supplies 100%.
Preparation technology is: weighs material, by water, alkylbenzenesulfonate, fatty alcohol polyoxy second by above-mentioned mass percent
Alkene ether, carbamide, aluminium-magnesium silicate, xanthan gum, defoamer mix homogeneously, then add benziothiazolinone and the gloomy copper of thiophene while stirring.Will be upper
State material mixing shearing 30 minutes, make material mix homogeneously.It is ground to particle diameter d90 and is less than 5 microns in sand mill, obtain final product 30%
Benziothiazolinone thiophene gloomy copper suspending agent.
Embodiment 4, the suspension emulsion containing benziothiazolinone and the gloomy copper of thiophene
Component includes: benziothiazolinone 15%, the gloomy copper of thiophene 25%, s-200 solvent naphtha 10%, ethanol 15%, agriculture breast 500#5%,
Lignosulfonates 2%, fatty alcohol-polyoxyethylene ether 2%, ethylene glycol 5%, aluminium-magnesium silicate 0.5%, xanthan gum 0.12%, organic
Silicon defoaming agent 0.5%, water supplies 100%.
Preparation technology is: by the material that weighs of above-mentioned mass percent, first will be thorough with s-200 solvent naphtha and ethanol for gloomy for thiophene copper
Bottom is dissolved, and is sufficiently mixed with agriculture breast 500# and uniformly makes oil phase a, then by water, lignosulfonates, fatty alcohol-polyoxyethylene ether,
Ethylene glycol, aluminium-magnesium silicate, xanthan gum, defoamer mix homogeneously, then add benziothiazolinone while stirring, make b mixture, a and b
Mixing.By above-mentioned material mixing shearing 30 minutes, make material mix homogeneously.It is ground to particle diameter d90 micro- less than 5 in sand mill
Rice, obtains final product the gloomy copper suspension emulsion of 40% benziothiazolinone thiophene.
Embodiment 5, the water dispersible granules containing benziothiazolinone and the gloomy copper of thiophene
Component includes: benziothiazolinone 10%, the gloomy copper of thiophene 20%, lignosulfonates 3%, alkyl polyoxyethylene sulfate salt 3%,
White carbon 3%, ammonium sulfate 10%, polyvinyl alcohol 0.1%, Kaolin supplies 100%.
Preparation technology is: weigh material by above-mentioned mass percent, by benziothiazolinone, and the gloomy copper of thiophene, lignosulfonates, alkyl
Polyoxyethylene sulfonic acid salt, white carbon, ammonium sulfate, Kaolin puts into mix homogeneously in mixer, then carries out comminution by gas stream.Mixed
The good material of comminution by gas stream is added, the aqueous solution that spray people contains polyvinyl alcohol carries out fluidized bed prilling, in 50-80 degree condition in conjunction machine
Under dry qualified to moisture, obtain final product the gloomy copper water dispersion granula of 30% benziothiazolinone thiophene.
Embodiment 6, the wettable powder containing benziothiazolinone and the gloomy copper of thiophene
Component includes: benziothiazolinone 10%, the gloomy copper of thiophene 60%, phenethyl phenol polyoxyethylene poly-oxygen propylene aether 4%, dodecyl
Sodium sulfate 3%, white carbon 4%, Kaolin supplies 100%.
Preparation technology is: weigh material by above-mentioned mass percent, by benziothiazolinone, and the gloomy copper of thiophene, phenethyl phenol polyoxyethylene
Polyethenoxy ether, sodium lauryl sulphate, white carbon, Kaolin put into mixing and blending machine stir, stream be crushed to 800 mesh with
Under obtain final product the gloomy copper wettable powder of 70% benziothiazolinone thiophene.
2nd, preventive effect embodiment
Application Example 1, benziothiazolinone compounds the Toxicity Determination to bacterial leaf streak of rice with the gloomy copper of thiophene.
Experimental subject: bacterial leaf streak of rice
Test method:
Investigate the incidence of whole rice blade according to test grade scale, calculate disease index and prevention effect.Will
Prevention effect is converted into niqueMin (y), and amount of liquid medicine height (ug/ml) is converted into logarithm value (x), calculates virulence with method of least square
Konzentration c50 in equation and suppression, calculates toxicity index level co-toxicity coefficient (ctc) of medicament according to the abundant method of Sun Yun.
Actual measurement toxicity index (ati)=(standard agent ec50/ supplies reagent to imitate ec50) * 100
Toxicity index * of the percentage composition+b medicament of a in the toxicity index * mixture of theoretical virulence coefficient (tti)=a medicament
The percentage composition of b in mixture.
Co-toxicity coefficient (ctc)=[mixture actual measurement toxicity index (ati)/mixture theoretical toxicity index (tti)] * 100
As ctc, < when 80, compositionss show as antagonism；When 80 < ctc, < when 120, compositionss show as summation action；
As ctc > 120 when, compositionss show as potentiation.
Benziothiazolinone and thiophene gloomy copper different proportion compound and bacterial leaf streak of rice Toxicity Determination be the results are shown in Table with 1:
| Reagent agent | Proportioning | Ec50 value (mg/l) | ctc |
| Benziothiazolinone (a) | 0.325 | ||
| The gloomy copper (b) of thiophene | 8.953 | ||
| a:b | 80:1 | 4.93 | 123.9 |
| a:b | 60:1 | 4.28 | 125.6 |
| a:b | 40:1 | 3.54 | 137.5 |
| a:b | 20:1 | 2.69 | 149.8 |
| a:b | 5:1 | 1.78 | 152.4 |
| a:b | 1:1 | 1.25 | 189.5 |
| a:b | 1:5 | 2.47 | 224.5 |
| a:b | 1:20 | 3.65 | 179.9 |
| a:b | 1:40 | 4.24 | 152.1 |
| a:b | 1:60 | 5.38 | 143.7 |
| a:b | 1:80 | 6.96 | 135.4 |
As shown in Table 1, in 80:1-1:80, co-toxicity coefficient (ctc) is all higher than 120 for benziothiazolinone and thiophene gloomy copper mixed ratio,
Show good potentiation, the potentiation to bacterial leaf streak of rice wherein after both are compounded in 20:1-1:40 ratio
Effect is especially pronounced.
Application Example 2, benziothiazolinone thiophene gloomy copper complex preparation preventing and treating rice blast, stripe virus disease, banded sclerotial blight, antibacterial
Property cecospora spot field control effectiveness test
This experimental establishment is carried by Shaanxi Xida Huate Science ＆ Technology Industrial Co., Ltd.'s research and development in Anhui Province Fengyang County, test medicine
For comparison medicament 20% benziothiazolinone suspending agent, 20% thiophene gloomy copper suspending agent (commercial).
Rice blast, stripe virus disease, banded sclerotial blight, the bacterial stripe state of an illness is investigated respectively, in the state of an illness initial stage before medicine
First time medication, dispenser in every seven days once, is total to dispenser three times.7 days after third time dispenser, 14 days respectively investigation rice blast,
Stripe virus disease, banded sclerotial blight, the bacterial stripe state of an illness simultaneously calculate preventive effect.Experimental result is as follows:
The gloomy copper complex preparation of table 2 benziothiazolinone thiophene prevents and treats the rice blast test of pesticide effectiveness
Benziothiazolinone thiophene gloomy copper complex preparation can effectively prevent and treat Oryza sativa L. anthrax as can be seen from Table 2, compares two kinds of single doses multiple
Preparaton prevention effect is notable, illustrates that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
The gloomy copper complex preparation of table 3 benziothiazolinone thiophene prevents and treats the stripe disease test of pesticide effectiveness
Benziothiazolinone thiophene gloomy copper complex preparation effectively can prevent and treat stripe disease as can be seen from Table 3, compares two kinds of lists
Agent complex preparation prevention effect is notable, illustrates that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
The gloomy copper complex preparation of table 4 benziothiazolinone thiophene prevents and treats the rice sheath blight disease test of pesticide effectiveness:
Benziothiazolinone thiophene gloomy copper complex preparation effectively can prevent and treat rice sheath blight disease as can be seen from Table 4, compares two kinds of single doses multiple
Preparaton prevention effect is notable, illustrates that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
The table 5 benziothiazolinone thiophene gloomy copper complex preparation preventing and treating bacterial leaf streak of rice test of pesticide effectiveness:
Benziothiazolinone thiophene gloomy copper complex preparation effectively can prevent and treat bacterial leaf streak of rice as can be seen from Table 5, compares two kinds
Single dose complex preparation prevention effect is notable, illustrates that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
Claims (4)
1. a kind of bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene it is characterised in that: the matter of effective ingredient benziothiazolinone and the gloomy copper of thiophene
Amount ratio is 1-80:1-80.
2. a kind of bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene according to claim 1 it is characterised in that: effective ingredient
The mass ratio of benziothiazolinone and the gloomy copper of thiophene is 20:1-1:40.
3. a kind of bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene according to claim 1 is it is characterised in that effective ingredient
The weight percentage sum of benziothiazolinone and the gloomy copper of thiophene is 1-90%.
4. according to a kind of arbitrary described bactericidal composition containing benziothiazolinone and the gloomy copper of thiophene of claim 1,2 or 3 it is characterised in that
Described compositionss can be configured to microemulsion, aqueous emulsion, suspending agent, suspension emulsion, water dispersible granules, wettable powder by prior art
Agent.
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Cited By (3)
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| CN107136099A (en) * | 2017-05-26 | 2017-09-08 | 河北威远生化农药有限公司 | A kind of bactericidal composition containing Thiodiazole-copper and benziothiazolinone |
| CN108669082A (en) * | 2018-08-01 | 2018-10-19 | 浙江东风化工有限公司 | A kind of bactericidal composition containing probenazole Yu the gloomy copper of thiophene |
| CN110881476A (en) * | 2018-09-07 | 2020-03-17 | 刘力 | High-efficiency broad-spectrum low-toxicity environment-friendly agricultural new compound and composition thereof |
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| CN103416411A (en) * | 2013-07-08 | 2013-12-04 | 中国中化股份有限公司 | Agricultural sterilization composition adopting flumorph and organic copper |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107136099A (en) * | 2017-05-26 | 2017-09-08 | 河北威远生化农药有限公司 | A kind of bactericidal composition containing Thiodiazole-copper and benziothiazolinone |
| CN108669082A (en) * | 2018-08-01 | 2018-10-19 | 浙江东风化工有限公司 | A kind of bactericidal composition containing probenazole Yu the gloomy copper of thiophene |
| CN110881476A (en) * | 2018-09-07 | 2020-03-17 | 刘力 | High-efficiency broad-spectrum low-toxicity environment-friendly agricultural new compound and composition thereof |
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Application publication date: 20170125 |