CN105394056A - Pesticide composition containing benziothiazolinone and tetramycin - Google Patents
Pesticide composition containing benziothiazolinone and tetramycin Download PDFInfo
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- CN105394056A CN105394056A CN201510899541.7A CN201510899541A CN105394056A CN 105394056 A CN105394056 A CN 105394056A CN 201510899541 A CN201510899541 A CN 201510899541A CN 105394056 A CN105394056 A CN 105394056A
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Abstract
The invention discloses a pesticide composition containing benziothiazolinone and tetramycin. The pesticide composition contains active components benziothiazolinone and tetramycin in a weight ratio of 300:1-1:12. The benziothiazolinone and tetramycin used in the invention can achieve a significant synergistic effect after compounding, the control effect is improved, and the dosage is reduced, thereby reducing the cost and alleviating pollution to the environment.
Description
Technical field
The present invention relates to technical field of pesticide combination, be specifically related to a kind of composition pesticide containing benziothiazolinone and tetramycin.
Background technology
Kiwi fruit contains the nutritive elements such as a large amount of vitamin groups, several amino acids and natural inositol, have the good reputation of " king of fruit ", has huge economic worth.In recent years, the area under cultivation of kiwi fruit constantly increases, and at the low end in 2012, China's kiwi fruit cultivated area was more than 1,500,000 mu, and gross yield breaks through 1,100,000 tons, and area and output all rank first in the world.Kiwi fruit industry has become Chaoyang rich people's pillar industry with competitive advantage.But Prospect on Kiwifruit Bacterial Canker large area outburst in recent years, it is reported, 2009-2011 Kiwi canker reaches more than 80% (its tinkling of pieces of jade 2013 yellow) in part orchard diseased plant rate.Prospect on Kiwifruit Bacterial Canker has become our province and most important disease planted by China's kiwi fruit, has a strong impact on the development constraining kiwi fruit industry.
Prospect on Kiwifruit Bacterial Canker is that one has destructive bacteriosis, at present, both at home and abroad to the Prevention Technique of Prospect on Kiwifruit Bacterial Canker mainly: (1) controls orchard assanation, protection wound site; (2) disease-resistant variety is cultivated; (3) chemical bactericide is sprayed.Streptomycin and copper agent are this sick topmost bactericide of control.Research shows, excessive use copper agent and streptomycin can develop immunity to drugs; Also find, copper agent and streptomycin have poisoning, can make leaf chlorosis simultaneously, and stem stalk ftractures.At present, market there is no the product of effective preventive effect Prospect on Kiwifruit Bacterial Canker.Therefore, the product of efficient, the safety of exploitation control Prospect on Kiwifruit Bacterial Canker, environmental protection is extremely urgent.
Summary of the invention
In view of this, in order to overcome the deficiencies in the prior art, the invention provides a kind of composition pesticide containing benziothiazolinone and tetramycin newly, said composition and be conducive to germ resistance management.
The invention provides a kind of composition pesticide containing benziothiazolinone and tetramycin, described composition pesticide comprises active component benziothiazolinone and tetramycin, and in described composition pesticide, the percentage by weight of active component benziothiazolinone and tetramycin is 300:1 ~ 1:12.
Further, described active component benziothiazolinone and tetramycin percentage by weight are 120:1 ~ 1:5.
Further, in described composition pesticide, the weight sum of active component benziothiazolinone and tetramycin accounts for the percentage of composition pesticide gross weight is 2% one 50%, and all the other components are acceptable auxiliary element in agricultural chemicals.
Further, in described composition pesticide, the weight sum of active component benziothiazolinone and tetramycin accounts for the percentage of composition pesticide gross weight is 5% one 25%, and all the other components are acceptable auxiliary element in agricultural chemicals.
According to the above-mentioned wetting powder composition containing benziothiazolinone and tetramycin agricultural chemicals, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, dispersant 3 ~ 10%, wetting agent 2 ~ 10%, filler supplies 100%.Its compound method: former for active component benziothiazolinone medicine, the former medicine of active component tetramycin, dispersant, wetting agent, filler are knocked down in blender and mixed, then mix after airslide disintegrating mill is pulverized, i.e. the wetting powder product of the obtained present composition.
According to the above-mentioned water dispersible granules composition containing benziothiazolinone and tetramycin agricultural chemicals, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, dispersant 2 ~ 12%, wetting agent 1 ~ 8%, disintegrant 1 ~ 10%, binding agent 1 ~ 8%, filler supplies 100%.Its compound method: the ratio in formula such as former for active component benziothiazolinone medicine, the former medicine of active component tetramycin, dispersant, wetting agent, disintegrant, binding agent, filler is mixed, wetting powder is become through air-flow crushing, add other auxiliary agents such as binding agent again and material is made in a certain amount of water mixing extruding, then carry out drying, the screening i.e. water dispersible granules product of the obtained present composition.
According to the above-mentioned suspension agent composition containing benziothiazolinone and tetramycin agricultural chemicals, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, wetting agent 2 ~ 10%, dispersant 2 ~ 10%, defoamer 0.1 ~ 2%, thickener 0.1 ~ 2%, antifreezing agent 0.1 ~ 10%, adds water to 100%.Its compound method: the former medicine of active component benziothiazolinone in formula above, the former medicine of active component tetramycin, wetting agent, dispersant are dropped in mixing kettle and mix through high speed shear, then defoamer, thickener, antifreezing agent is added, ball milling 2 ~ 3 hours in ball milling kettle, make diameter of particle at below 5mm, the suspending agent product of the obtained present composition.
According to the above-mentioned water emulsion composition containing benziothiazolinone and tetramycin agricultural chemicals, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, solvent 5 ~ 30%, emulsifier 3 ~ 15%, adds water to 100%.Its compound method: active component benziothiazolinone, solvent, emulsifier are added together, makes to be dissolved into homogeneous oil phase; By active component tetramycin and the obtained aqueous phase of water mixing; Under high velocity agitation, oil phase is mixed with water, the aqueous emulsion product of the obtained present composition.
According to the above-mentioned micro-emulsion composition containing benziothiazolinone and tetramycin agricultural chemicals, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, solvent 5 ~ 30%, emulsifier 3 ~ 25%, adds water to 100%.Its compound method: active component benziothiazolinone, solvent, emulsifier are added together, makes to be dissolved into homogeneous oil phase; By active component tetramycin and the obtained aqueous phase of water mixing; Under agitation, oil phase is mixed with water, the microemulsion product of the obtained present composition.
Surfactant (emulsifier), dispersant, wetting agent all belong to auxiliary agent, and the auxiliary agent in composition pesticide of the present invention, solvent and filler (carrier) are known in those skilled in the art.According to different dosage form, in composition, also thickener conventionally known to one of skill in the art, defoamer, disintegrant, binding agent or antifreeze etc. can be contained.
Described auxiliary agent is selected from: 600# phosphate, sodium lignin sulfonate, alkyl benzene sulfonate calcium salt, fatty alcohol-polyoxyethylene ether, dispersing agent MF, alkylphenol polyoxyethylene phosphate, alkyl phenol formaldehyde resin polyoxyethylene ether, phosphate naphthalene sulfonic acid-formaldehyde condensation product, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, spaonin powder, sodium metnylene bis-naphthalene sulfonate, sodium lignin sulfonate, sldium lauryl sulfate, polyoxyethylene sorbitan fatty acid ester, Nekal BX, sodium methylene bis-naphthalene sulfonate, sodium butylnaphthalenesulfonate, macromolecule modified lignin, agriculture breast 600#, agriculture breast 1601#, dispersant NNO, lauryl sodium sulfate, polycarboxylate, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylphenol polyoxyethylene, triphen ethyl phenol APEO, dinaphthylmethanedisulfonic acid sodium, urea resin prepolymer, sodium alginate etc.
Described solvent is polyvinylpyrrolidone, cyclohexanone, ethanol, N-methyl adjoin in pyrrolidone, methyl naphthalene, isopropyl alcohol, methyl alcohol, dimethylbenzene etc. one or more.
Described filler (carrier) is selected from: one or more in white carbon, kaolin, precipitated calcium carbonate, talcum powder, potter's clay, diatomite, bentonite, attapulgite, pyrophyllite, montmorillonite, clay, illite, mica powder, perlite, calcite, deionized water, water or castor-oil plant wet goods.
Described thickener is selected from: gum Arabic, xanthans, white carbon etc.
Described defoamer is selected from: organosilicon etc.
Described disintegrant is selected from: sodium bicarbonate, urea, ammonium sulfate etc.
Described binding agent is selected from: starch, gelatin, corn flour, polyvinyl alcohol, carboxymethyl cellulose etc.
Described antifreezing agent is selected from: polyvinyl alcohol, ethylene glycol, propane diols, glycerine etc.
Benziothiazolinone is a kind of novel, wide-spectrum bactericide, is mainly used in various bacteria, the fungal disease of preventing and treating and treating cucumber downy mildew, pear scab, apple scab, citrus bacterial canker disease, anthracnose of grape etc.
Tetramycin is the fermentating metabolism product of S. ahygroscopicus Wuzhou subspecies, fungicidal spectrum is wide, all there is stronger killing action to three main kind of 26 kinds of known disease funguses such as mastigomycetes, sac fungi and Deuteromycotina fungies, be suitable for the multiple fungi of various crop, the control of bacteriosis.
Bactericidal composition of the present invention can be applied in control plant disease agriculturally, especially prevents and treats Prospect on Kiwifruit Bacterial Canker.
The method use that composition of the present invention usually adopts spraying or smears, also can take other operation techniques according to agriculture needs of production.
Compared with prior art, beneficial effect of the present invention is:
1. the benziothiazolinone that the present invention is used and tetramycin composite after there is obvious synergistic function, improve control efficiency;
2. the benziothiazolinone that the present invention is used and tetramycin composite after decrease dosage, thus reduce cost.
Embodiment
Further illustrate the present invention in the following embodiments, this does not limit the scope of the invention.
toxicity measures embodiment
Benziothiazolinone and the composite Toxicity Determination to Prospect on Kiwifruit Bacterial Canker of tetramycin
Subjects: Prospect on Kiwifruit Bacterial Canker pathogen pseudomonas syringae kiwi fruit pvs oryzae and oryzicola, from the sampling of Zhouzhi County Chinese gooseberry garden morbidity branch, adopts the separation and purification of dilution method of scoring, the separator of purifying is carried out Molecular Identification gained.
Test method: with sterile water preparation containing pathogen cell 10
6-10
7the bacteria suspension of individual/mL, adds bacteria suspension 1.5mL in every ware, pour the NA medium of about 12mL into, make flat board after shaking up.Each medicament arranges 5 concentration gradients, is that the sterilized filter paper sheet of 6mm put into liquid immersion after 1 hour, takes out diameter and put into plate, soak filter paper for contrast, be placed in 28 DEG C of cultivations, often process three repetitions with sterile water.Observe after 48 hours, measure antibacterial circle diameter, calculate bacteriostasis rate.Bacteriostasis rate is converted into antibacterial probability, to set the mass concentration of medicament as abscissa, with antibacterial probability for ordinate makes regression line, obtains each medicament to the virulence regression equation of Prospect on Kiwifruit Bacterial Canker and in suppressing dense (EC50).
Toxicity index and the co-toxicity coefficient (CTC) of medicament is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent EC
50/ reagent agent EC
50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index x mixture in the percentage composition of B
Co-toxicity coefficient (CTC)=[theoretical toxicity index (TTI) × 100 of mixture actual measurement toxicity index (ATI)/mixture
When CTC≤80, then composition shows as Hangzhoupro short of money effect, and work as 80<CTC<120, then composition shows as summation action, and when CTC >=120, then composition shows as synergistic effect.
Toxicity Determination the results are shown in following table 1:
Table 1 benziothiazolinone and the composite Toxicity Determination result to Prospect on Kiwifruit Bacterial Canker of tetramycin
Toxicity Determination result shows, and benziothiazolinone and tetramycin proportioning, between 300:1 ~ 1:12, have synergistic effect to Prospect on Kiwifruit Bacterial Canker, and especially between 120:1 ~ 1:5, co-toxicity coefficient is more than 150, and synergy is more obvious.
Composition pesticide of the present invention can be prepared into any one formulation of applicable agricultural use by known method, reasonable formulation is wetting powder, suspending agent, water dispersible granules, aqua.
In order to make object of the present invention, technical scheme and advantage clearly understand, the following specific embodiment of the present invention is described, but the present invention is limited to absolutely not these examples.
embodiment 1:45.15% benziothiazolinone tetramycin water dispersible granules
Ingredient names percentage by weight
Benziothiazolinone 45.0%
Tetramycin 0.15%
Lauryl sodium sulfate (wetting agent) 4.0%
Sodium lignin sulfonate (dispersant) 6.0%
Ammonium sulfate (disintegrant) 5.0%
Starch (binding agent) 2.0%
Precipitated calcium carbonate (filler) complements to 100.0%
Active component, dispersant, wetting agent, disintegrant and the filler ratio in formula is mixed, wetting powder is become through air-flow crushing, add a certain amount of water mixing extruding again and make material, after drying screening, obtain 45.15% benziothiazolinone tetramycin water dispersible granules.
embodiment 2:24.2% benziothiazolinone tetramycin suspending agent
Ingredient names percentage by weight
Benziothiazolinone 24.0%
Tetramycin 0.2%
Dispersant NNO(dispersant) 3.0%
Alkyl phenol formaldehyde resin polyoxyethylene ether (wetting agent) 2.0%
Polyoxyethylene sorbitan fatty acid ester (wetting agent) 1.0%
Xanthans (thickener) 0.2%
White carbon (thickener) 0.5%
Organosilicon (defoamer) 0.2%
Ethylene glycol (antifreezing agent) 4.0%
Water complements to 100.0%
The ratio of each components such as active component, dispersant, thickener, wetting agent and water in formula is mixed, after grinding and/or high speed shear, obtains 24.2 benziothiazolinone tetramycin suspending agents.
embodiment 3:13% benziothiazolinone tetramycin wetting powder
Ingredient names percentage by weight
Benziothiazolinone 1.0%
Tetramycin 12.0%
Lauryl sodium sulfate (wetting agent) 3.0%
Sodium lignin sulfonate (dispersant) 4.0%
White Carbon black (filler) 7.0%
Kaolin (filler) complements to 100.0%
The ratio in formula such as active component, various auxiliary agent and filler is fully mixed, after ultra-fine pulverizer disintegrating, obtains 13% benziothiazolinone tetramycin wetting powder.
embodiment 4:2% benziothiazolinone tetramycin aqueous emulsion
Ingredient names percentage by weight
Benziothiazolinone 1.4%
Tetramycin 0.6%
N monomethyl adjoins pyrrolidone (solvent) 10.0%
Calcium dodecyl benzene sulfonate (emulsifier) 5.0%
Agriculture breast 600# (emulsifier) 5.0%
Water complements to 100.0%
Former for benziothiazolinone medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; By tetramycin and the obtained aqueous phase of water mixing; Under high velocity agitation, oil phase is mixed with water, obtained 2% benziothiazolinone tetramycin aqueous emulsion.
embodiment 5: 50% benziothiazolinone tetramycin water dispersible granules
Ingredient names percentage by weight
Benziothiazolinone 48.0%
Tetramycin 2.0%
Lauryl sodium sulfate (wetting agent) 5.0%
Sodium lignin sulfonate (dispersant) 6.0%
Ammonium sulfate (disintegrant) 5.0%
Starch (binding agent) 2.0%
Precipitated calcium carbonate (filler) complements to 100.0%
Active component, dispersant, wetting agent, disintegrant and the filler ratio in formula mixed, become wetting powder, then add a certain amount of water mixing extruding and make material through air-flow crushing, drying obtains 50% benziothiazolinone tetramycin water dispersible granules after sieving.
embodiment 625% benziothiazolinone tetramycin wetting powder
Ingredient names percentage by weight
Benziothiazolinone 23.0%
Tetramycin 2.0%
Lauryl sodium sulfate (wetting agent) 2.0%
Sodium lignin sulfonate (dispersant) 5.0%
White Carbon black (filler) 10.0%
Kaolin (filler) complements to 100.0%
The ratio in formula such as active component, various auxiliary agent and filler is fully mixed, after ultra-fine pulverizer disintegrating, obtains 25% benziothiazolinone tetramycin wetting powder.
embodiment 7: 6% benziothiazolinone tetramycin microemulsion
Ingredient names percentage by weight
Benziothiazolinone 1.0%
Tetramycin 5.0%
Isopropyl alcohol (solvent) 15.0%
N monomethyl adjoins pyrrolidone (solvent) 10.0%
Agriculture breast 600# (emulsifier) 8.0%
Agriculture breast 1601# (emulsifier) 8.0%
Water complements to 100.0%
Former for benziothiazolinone medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase; By tetramycin and the obtained aqueous phase of water mixing; Under agitation, oil phase is evenly mixed with water, obtained 6% benziothiazolinone tetramycin microemulsion.
embodiment 8:5% benziothiazolinone tetramycin suspending agent
Ingredient names percentage by weight
Benziothiazolinone 4.5%
Tetramycin 0.5%
Dispersant NNO(dispersant) 2.0%
Alkyl phenol formaldehyde resin polyoxyethylene ether (wetting agent) 2.0%
Polyoxyethylene sorbitan fatty acid ester (wetting agent) 1.0%
Xanthans (thickener) 0.2%
White carbon (thickener) 0.5%
Organosilicon (defoamer) 0.2%
Ethylene glycol (antifreezing agent) 5.0%
Water complements to 100.0%
The ratio of each components such as active component, dispersant, thickener, wetting agent and water in formula is mixed, after grinding and/or high speed shear, obtains 5% benziothiazolinone tetramycin suspending agent.
Above-described embodiment is applied to control Prospect on Kiwifruit Bacterial Canker, adopt spraying add strike off scab after smear the method dispenser combined, different preparation compositions to the control efficiency of Prospect on Kiwifruit Bacterial Canker in table 2.
The different preparation compositions of table 2 is to the control efficiency of Prospect on Kiwifruit Bacterial Canker
As can be seen from table 2 result of the test, benziothiazolinone and tetramycin complex composition all more than 85%, are significantly higher than single dose contrast medicament and Routine control medicament to the preventive effect of Prospect on Kiwifruit Bacterial Canker.Test each process and all do not occur the bad reaction problems such as poisoning.Illustrate that benziothiazolinone and tetramycin compounded combination use actual control efficiency to be significantly better than single dose thus, this result conforms to indoor biometrics embodiment experimental result, and both explanations are composite to have significant synergies.
Benziothiazolinone and the composite use of tetramycin can reduce dosage, decrease use cost, can delay the generation of drug resistance problem simultaneously, to agricultural synthesis administer have important meaningful.
Although by referring to some preferred embodiment of the present invention, invention has been described, but those of ordinary skill in the art is to be understood that, various change can be made to it in the form and details, and not depart from the spirit and scope of the present invention that appended claims limits.
Claims (10)
1. contain a composition pesticide for benziothiazolinone and tetramycin, described composition pesticide comprises active component benziothiazolinone and tetramycin, and in described composition pesticide, the weight ratio of active component benziothiazolinone and tetramycin is 300:1 ~ 1:12; Described composition pesticide comprises or does not comprise other activity; Described active component benziothiazolinone and tetramycin weight ratio are preferably 120:1 ~ 1:5; Preferred further, described weight ratio is 60:1 ~ 1:2.5.
2. composition pesticide according to claim 1, in described composition pesticide, the weight sum of active component benziothiazolinone and tetramycin accounts for the percentage of composition pesticide gross weight is 2%-50%, and all the other components are acceptable auxiliary element in agricultural chemicals.
3. composition pesticide according to claim 2, in described composition pesticide, the weight sum of active component benziothiazolinone and tetramycin accounts for the percentage of composition pesticide gross weight is 5%-25%.
4. the composition pesticide according to claim 1-3 any one, described composition pesticide is wetting powder composition, water dispersible granules composition, suspension agent composition, water emulsion composition or micro-emulsion composition.
5. composition pesticide according to claim 4, described composition pesticide is wetting powder composition, comprises by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, dispersant 3 ~ 10%, wetting agent 2 ~ 10%, filler supplies 100%; Its compound method: former for active component benziothiazolinone medicine, the former medicine of active component tetramycin, dispersant, wetting agent, filler are knocked down in blender and mixed, then mix after airslide disintegrating mill is pulverized, i.e. obtained wetting powder product.
6. composition pesticide according to claim 4, described composition pesticide is water dispersible granules composition, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, dispersant 2 ~ 12%, wetting agent 1 ~ 8%, disintegrant 1 ~ 10%, binding agent 1 ~ 8%, filler supplies 100%; Its compound method: the ratio in formula such as former for active component benziothiazolinone medicine, the former medicine of active component tetramycin, dispersant, wetting agent, disintegrant, binding agent, filler is mixed, wetting powder is become through air-flow crushing, add other auxiliary agents such as binding agent again and material is made in a certain amount of water mixing extruding, then carry out drying, screening i.e. obtained water dispersible granules product.
7. composition pesticide according to claim 4, described composition pesticide is suspension agent composition, comprise by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, wetting agent 2 ~ 10%, dispersant 2 ~ 10%, defoamer 0.1 ~ 2%, thickener 0.1 ~ 2%, antifreezing agent 0.1 ~ 10%, adds water to 100%; Its compound method: the former medicine of active component benziothiazolinone in formula above, the former medicine of active component tetramycin, wetting agent, dispersant are dropped in mixing kettle and mix through high speed shear, then defoamer, thickener, antifreezing agent is added, ball milling 2 ~ 3 hours in ball milling kettle, make diameter of particle at below 5mm, obtained suspending agent product.
8. composition pesticide according to claim 4, described composition pesticide is water emulsion composition, comprises by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, solvent 5 ~ 30%, emulsifier 3 ~ 15%, adds water to 100%; Its compound method: active component benziothiazolinone, solvent, emulsifier are added together, makes to be dissolved into homogeneous oil phase; By active component tetramycin and the obtained aqueous phase of water mixing; Under high velocity agitation, oil phase is mixed with water, obtained aqua product.
9. composition pesticide according to claim 4, described composition pesticide is micro-emulsion composition, comprises by weight percentage: active component benziothiazolinone 1 ~ 50%, active component tetramycin 0.1 ~ 12%, solvent 5 ~ 30%, emulsifier 3 ~ 25%, adds water to 100%; Its compound method: active component benziothiazolinone, solvent, emulsifier are added together, makes to be dissolved into homogeneous oil phase; By active component tetramycin and the obtained aqueous phase of water mixing; Under agitation, oil phase is mixed with water, obtained microemulsion product.
10. the composition pesticide described in claim 1-9 any one, in controlling plant diseases, especially prevents and treats the application in Prospect on Kiwifruit Bacterial Canker.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106852334A (en) * | 2016-12-30 | 2017-06-16 | 四川农业大学 | A kind of method for integrated control of Prospect on Kiwifruit Bacterial Canker |
| CN109463390A (en) * | 2018-11-14 | 2019-03-15 | 张永 | A kind of formula about prevention and treatment trees rot disease |
| CN112075438A (en) * | 2020-09-01 | 2020-12-15 | 陕西西大华特科技实业有限公司 | Bactericidal composition containing benziothiazolinone and shenqinmycin and application thereof |
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| CN105230640A (en) * | 2015-10-31 | 2016-01-13 | 青岛奥迪斯生物科技有限公司 | Bactericidal composition containing tetramycin and benziothiazolinone |
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| CN105230640A (en) * | 2015-10-31 | 2016-01-13 | 青岛奥迪斯生物科技有限公司 | Bactericidal composition containing tetramycin and benziothiazolinone |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106852334A (en) * | 2016-12-30 | 2017-06-16 | 四川农业大学 | A kind of method for integrated control of Prospect on Kiwifruit Bacterial Canker |
| CN106852334B (en) * | 2016-12-30 | 2019-04-19 | 四川农业大学 | A kind of method for integrated control of Prospect on Kiwifruit Bacterial Canker |
| CN109463390A (en) * | 2018-11-14 | 2019-03-15 | 张永 | A kind of formula about prevention and treatment trees rot disease |
| CN112075438A (en) * | 2020-09-01 | 2020-12-15 | 陕西西大华特科技实业有限公司 | Bactericidal composition containing benziothiazolinone and shenqinmycin and application thereof |
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Application publication date: 20160316 |