CN106283697A - 一种室内建筑装修墙布墙纸阻燃抗菌涂层 - Google Patents

一种室内建筑装修墙布墙纸阻燃抗菌涂层 Download PDF

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CN106283697A
CN106283697A CN201610640004.5A CN201610640004A CN106283697A CN 106283697 A CN106283697 A CN 106283697A CN 201610640004 A CN201610640004 A CN 201610640004A CN 106283697 A CN106283697 A CN 106283697A
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Abstract

本发明涉及一种室内建筑装修墙布墙纸阻燃抗菌涂层，由以下组分组成：酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌、六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐、油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。

Description

一种室内建筑装修墙布墙纸阻燃抗菌涂层
技术领域
本发明涉及一种室内建筑装修墙布墙纸阻燃抗菌涂层，属于室内装饰材料技术领域。
背景技术
室内装饰是满足人们的社会活动和生活需要，合理、完美地组织和塑造具有美感而又舒适、方便的室内环境的一种综合性艺术，是环境艺术的一个门类，又称室内设计。融合了现代科学技术与文化艺术，并与建筑设计、地理，装饰艺术、人体工程学、心理学、美学，科技材料学等有着密切的联系。研究的范围和对象而言，室内装饰又可分为家庭室内装饰、宾馆室内装饰、商店室内装饰、商场购物娱乐影院等公共设施室内装饰等。室内装饰依附于建筑实体，如空间造型、绿化、装饰、壁画、灯光照明以及各种建筑设施的艺术处理等，统称为室内装修；另一类依托于建筑实体，如家具、灯具、装饰织物、家用电器、日用器皿、卫生洁具、炊具、文具和各种陈设品，统称为室内陈设，即硬装和软装。后一类具有相对独立性，可以移动或更换。室内装饰可以改善空间，即再次通过装修，对室内空间进行美化和修饰。室内装饰常用墙布墙纸，这些墙纸墙布有必要采用合适的涂层予以改进其性能。
发明内容
本发明的目的在于提供一种室内建筑装修墙布墙纸阻燃抗菌涂层，以便更好地实现室内建筑装修墙布墙纸阻燃抗菌涂层的使用功能，使产品具有阻燃、耐酸碱、防霉变抗菌性能，改善产品使用性能。
为了实现上述目的，本发明的技术方案如下。
一种室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂24～28份、聚乙烯22～26份、PVC树脂粉22～26份、环氧氯丙烷20～24份、醋酸丁酯22～26份、硬脂酸甘油酯22～26份、二乙醇胺20～24份、聚醚改性硅油22～26份、恶唑烷酮22～26份、磺胺嘧啶银20～24份、双氧水20～24份、水杨酰苯胺20～24份、海泡石粉末22～26份、红柱石粉末20～24份、磺化沥青粉18～22份、火山灰22～26份、聚甲基丙烯酸钠20～24份、磷酸钙粉末18～22份、六聚磷酸钠20～24份、铝酸锌18～22份、六溴环十二烷18～22份、三氯乙基磷酸酯20～24份、磷酸脒基脲20～24份、磷酸三辛酯20～24份、均苯四甲酸酐20～24份、油酸钾皂20～24份、双甲基丙烯酸乙二醇酯20～24份、柠檬酸三乙酯20～24份、硫酸亚铁铵20～24份、蓖麻油酸聚氧丙烯酯18～22份。
进一步地，上述室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂24份、聚乙烯22份、PVC树脂粉22份、环氧氯丙烷20份、醋酸丁酯22份、硬脂酸甘油酯22份、二乙醇胺20份、聚醚改性硅油22份、恶唑烷酮22份、磺胺嘧啶银20份、双氧水20份、水杨酰苯胺20份、海泡石粉末22份、红柱石粉末20份、磺化沥青粉18份、火山灰22份、聚甲基丙烯酸钠20份、磷酸钙粉末18份、六聚磷酸钠20份、铝酸锌18份、六溴环十二烷18份、三氯乙基磷酸酯20份、磷酸脒基脲20份、磷酸三辛酯20份、均苯四甲酸酐20份、油酸钾皂20份、双甲基丙烯酸乙二醇酯20份、柠檬酸三乙酯20份、硫酸亚铁铵20份、蓖麻油酸聚氧丙烯酯18份。
进一步地，上述室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂26份、聚乙烯24份、PVC树脂粉24份、环氧氯丙烷22份、醋酸丁酯24份、硬脂酸甘油酯24份、二乙醇胺22份、聚醚改性硅油24份、恶唑烷酮24份、磺胺嘧啶银22份、双氧水22份、水杨酰苯胺22份、海泡石粉末24份、红柱石粉末22份、磺化沥青粉20份、火山灰24份、聚甲基丙烯酸钠22份、磷酸钙粉末20份、六聚磷酸钠22份、铝酸锌20份、六溴环十二烷20份、三氯乙基磷酸酯22份、磷酸脒基脲22份、磷酸三辛酯22份、均苯四甲酸酐22份、油酸钾皂22份、双甲基丙烯酸乙二醇酯22份、柠檬酸三乙酯22份、硫酸亚铁铵22份、蓖麻油酸聚氧丙烯酯20份。
进一步地，上述室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂28份、聚乙烯26份、PVC树脂粉26份、环氧氯丙烷24份、醋酸丁酯26份、硬脂酸甘油酯26份、二乙醇胺24份、聚醚改性硅油26份、恶唑烷酮26份、磺胺嘧啶银24份、双氧水24份、水杨酰苯胺24份、海泡石粉末26份、红柱石粉末24份、磺化沥青粉22份、火山灰26份、聚甲基丙烯酸钠24份、磷酸钙粉末22份、六聚磷酸钠24份、铝酸锌22份、六溴环十二烷22份、三氯乙基磷酸酯24份、磷酸脒基脲24份、磷酸三辛酯24份、均苯四甲酸酐24份、油酸钾皂24份、双甲基丙烯酸乙二醇酯24份、柠檬酸三乙酯24份、硫酸亚铁铵24份、蓖麻油酸聚氧丙烯酯22份。
进一步地，上述室内建筑装修墙布墙纸阻燃抗菌涂层制备方法步骤如下：
(1)将所述质量份数的酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌予以混合，超声高速分散，超声波频率为20～40KHz，分散速度5000～5400r/min左右，分散时间为30～60min；
(2)加入所述质量份数的六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐，超声高速分散，超声波频率为20～35KHz，分散速度4800～5200r/min左右，分散时间为30～50min；
(3)加入所述质量份数的油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯，超声高速分散，超声波频率为20～30KHz，分散速度4600～4800r/min左右，分散时间为20～40min；混合均匀后制得本品。
该发明的有益效果在于：本发明中的室内建筑装修墙布墙纸阻燃抗菌涂层，由以下组分组成：酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌、六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐、油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能，改善了产品性能。
具体实施方式
下面结合实施例对本发明的具体实施方式进行描述，以便更好的理解本发明。
实施例1
本实施例中的室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂24份、聚乙烯22份、PVC树脂粉22份、环氧氯丙烷20份、醋酸丁酯22份、硬脂酸甘油酯22份、二乙醇胺20份、聚醚改性硅油22份、恶唑烷酮22份、磺胺嘧啶银20份、双氧水20份、水杨酰苯胺20份、海泡石粉末22份、红柱石粉末20份、磺化沥青粉18份、火山灰22份、聚甲基丙烯酸钠20份、磷酸钙粉末18份、六聚磷酸钠20份、铝酸锌18份、六溴环十二烷18份、三氯乙基磷酸酯20份、磷酸脒基脲20份、磷酸三辛酯20份、均苯四甲酸酐20份、油酸钾皂20份、双甲基丙烯酸乙二醇酯20份、柠檬酸三乙酯20份、硫酸亚铁铵20份、蓖麻油酸聚氧丙烯酯18份。
上述室内建筑装修墙布墙纸阻燃抗菌涂层制备方法步骤如下：
(1)将所述质量份数的酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌予以混合，超声高速分散，超声波频率为20kHz，分散速度5400r/min左右，分散时间为60min；
(2)加入所述质量份数的六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐，超声高速分散，超声波频率为20kHz，分散速度5200r/min左右，分散时间为50min；
(3)加入所述质量份数的油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯，超声高速分散，超声波频率为20kHz，分散速度4800r/min左右，分散时间为40min；混合均匀后制得本品。
实施例2
本实施例中的室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂26份、聚乙烯24份、PVC树脂粉24份、环氧氯丙烷22份、醋酸丁酯24份、硬脂酸甘油酯24份、二乙醇胺22份、聚醚改性硅油24份、恶唑烷酮24份、磺胺嘧啶银22份、双氧水22份、水杨酰苯胺22份、海泡石粉末24份、红柱石粉末22份、磺化沥青粉20份、火山灰24份、聚甲基丙烯酸钠22份、磷酸钙粉末20份、六聚磷酸钠22份、铝酸锌20份、六溴环十二烷20份、三氯乙基磷酸酯22份、磷酸脒基脲22份、磷酸三辛酯22份、均苯四甲酸酐22份、油酸钾皂22份、双甲基丙烯酸乙二醇酯22份、柠檬酸三乙酯22份、硫酸亚铁铵22份、蓖麻油酸聚氧丙烯酯20份。
上述室内建筑装修墙布墙纸阻燃抗菌涂层制备方法步骤如下：
(1)将所述质量份数的酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌予以混合，超声高速分散，超声波频率为30kHz，分散速度5200r/min左右，分散时间为45min；
(2)加入所述质量份数的六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐，超声高速分散，超声波频率为27kHz，分散速度5000r/min左右，分散时间为40min；
(3)加入所述质量份数的油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯，超声高速分散，超声波频率为25kHz，分散速度4700r/min左右，分散时间为30min；混合均匀后制得本品。
实施例3
本实施例中的室内建筑装修墙布墙纸阻燃抗菌涂层，由以下质量份数的组分组成：酮醛树脂28份、聚乙烯26份、PVC树脂粉26份、环氧氯丙烷24份、醋酸丁酯26份、硬脂酸甘油酯26份、二乙醇胺24份、聚醚改性硅油26份、恶唑烷酮26份、磺胺嘧啶银24份、双氧水24份、水杨酰苯胺24份、海泡石粉末26份、红柱石粉末24份、磺化沥青粉22份、火山灰26份、聚甲基丙烯酸钠24份、磷酸钙粉末22份、六聚磷酸钠24份、铝酸锌22份、六溴环十二烷22份、三氯乙基磷酸酯24份、磷酸脒基脲24份、磷酸三辛酯24份、均苯四甲酸酐24份、油酸钾皂24份、双甲基丙烯酸乙二醇酯24份、柠檬酸三乙酯24份、硫酸亚铁铵24份、蓖麻油酸聚氧丙烯酯22份。
上述室内建筑装修墙布墙纸阻燃抗菌涂层制备方法步骤如下：
(1)将所述质量份数的酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌予以混合，超声高速分散，超声波频率为40kHz，分散速度5000r/min，分散时间为30min；
(2)加入所述质量份数的六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐，超声高速分散，超声波频率为35kHz，分散速度4800r/min，分散时间为30min；
(3)加入所述质量份数的油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯，超声高速分散，超声波频率为30kHz，分散速度4600r/min左右，分散时间为20min；混合均匀后制得本品。
针对实施例1、实施例2和实施例3中的产品和某市售产品进行性能测量，所测得的数据如表1所示。防火阻燃等级测试采用UL94标准。
表1性能测试结果
可见，本发明产品具有较好的耐腐蚀、防火阻燃、防霉变、抗菌性能。
以上所述是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也视为本发明的保护范围。

Claims (5)

1.一种室内建筑装修墙布墙纸阻燃抗菌涂层，其特征在于：由以下质量份数的组分组成：酮醛树脂24～28份、聚乙烯22～26份、PVC树脂粉22～26份、环氧氯丙烷20～24份、醋酸丁酯22～26份、硬脂酸甘油酯22～26份、二乙醇胺20～24份、聚醚改性硅油22～26份、恶唑烷酮22～26份、磺胺嘧啶银20～24份、双氧水20～24份、水杨酰苯胺20～24份、海泡石粉末22～26份、红柱石粉末20～24份、磺化沥青粉18～22份、火山灰22～26份、聚甲基丙烯酸钠20～24份、磷酸钙粉末18～22份、六聚磷酸钠20～24份、铝酸锌18～22份、六溴环十二烷18～22份、三氯乙基磷酸酯20～24份、磷酸脒基脲20～24份、磷酸三辛酯20～24份、均苯四甲酸酐20～24份、油酸钾皂20～24份、双甲基丙烯酸乙二醇酯20～24份、柠檬酸三乙酯20～24份、硫酸亚铁铵20～24份、蓖麻油酸聚氧丙烯酯18～22份。
2.根据权利要求1所述的室内建筑装修墙布墙纸阻燃抗菌涂层，其特征在于：所述室内建筑装修墙布墙纸阻燃抗菌涂层由以下质量份数的组分组成：酮醛树脂24份、聚乙烯22份、PVC树脂粉22份、环氧氯丙烷20份、醋酸丁酯22份、硬脂酸甘油酯22份、二乙醇胺20份、聚醚改性硅油22份、恶唑烷酮22份、磺胺嘧啶银20份、双氧水20份、水杨酰苯胺20份、海泡石粉末22份、红柱石粉末20份、磺化沥青粉18份、火山灰22份、聚甲基丙烯酸钠20份、磷酸钙粉末18份、六聚磷酸钠20份、铝酸锌18份、六溴环十二烷18份、三氯乙基磷酸酯20份、磷酸脒基脲20份、磷酸三辛酯20份、均苯四甲酸酐20份、油酸钾皂20份、双甲基丙烯酸乙二醇酯20份、柠檬酸三乙酯20份、硫酸亚铁铵20份、蓖麻油酸聚氧丙烯酯18份。
3.根据权利要求1至2所述的室内建筑装修墙布墙纸阻燃抗菌涂层，其特征在于：所述室内建筑装修墙布墙纸阻燃抗菌涂层由以下质量份数的组分组成：酮醛树脂26份、聚乙烯24份、PVC树脂粉24份、环氧氯丙烷22份、醋酸丁酯24份、硬脂酸甘油酯24份、二乙醇胺22份、聚醚改性硅油24份、恶唑烷酮24份、磺胺嘧啶银22份、双氧水22份、水杨酰苯胺22份、海泡石粉末24份、红柱石粉末22份、磺化沥青粉20份、火山灰24份、聚甲基丙烯酸钠22份、磷酸钙粉末20份、六聚磷酸钠22份、铝酸锌20份、六溴环十二烷20份、三氯乙基磷酸酯22份、磷酸脒基脲22份、磷酸三辛酯22份、均苯四甲酸酐22份、油酸钾皂22份、双甲基丙烯酸乙二醇酯22份、柠檬酸三乙酯22份、硫酸亚铁铵22份、蓖麻油酸聚氧丙烯酯20份。
4.根据权利要求1至3所述的室内建筑装修墙布墙纸阻燃抗菌涂层，其特征在于：所述室内建筑装修墙布墙纸阻燃抗菌涂层由以下质量份数的组分组成：酮醛树脂28份、聚乙烯26份、PVC树脂粉26份、环氧氯丙烷24份、醋酸丁酯26份、硬脂酸甘油酯26份、二乙醇胺24份、聚醚改性硅油26份、恶唑烷酮26份、磺胺嘧啶银24份、双氧水24份、水杨酰苯胺24份、海泡石粉末26份、红柱石粉末24份、磺化沥青粉22份、火山灰26份、聚甲基丙烯酸钠24份、磷酸钙粉末22份、六聚磷酸钠24份、铝酸锌22份、六溴环十二烷22份、三氯乙基磷酸酯24份、磷酸脒基脲24份、磷酸三辛酯24份、均苯四甲酸酐24份、油酸钾皂24份、双甲基丙烯酸乙二醇酯24份、柠檬酸三乙酯24份、硫酸亚铁铵24份、蓖麻油酸聚氧丙烯酯22份。
5.根据权利要求1所述的室内建筑装修墙布墙纸阻燃抗菌涂层，其特征在于：所述室内建筑装修墙布墙纸阻燃抗菌涂层制备方法步骤如下：
(1)将所述质量份数的酮醛树脂、聚乙烯、PVC树脂粉、环氧氯丙烷、醋酸丁酯、硬脂酸甘油酯、二乙醇胺、聚醚改性硅油、恶唑烷酮、磺胺嘧啶银、双氧水、水杨酰苯胺、海泡石粉末、红柱石粉末、磺化沥青粉、火山灰、聚甲基丙烯酸钠、磷酸钙粉末、六聚磷酸钠、铝酸锌予以混合，超声高速分散，超声波频率为20～40KHz，分散速度约5000～5400r/min，分散时间为30～60min左右；
(2)加入所述质量份数的六溴环十二烷、三氯乙基磷酸酯、磷酸脒基脲、磷酸三辛酯、均苯四甲酸酐，超声高速分散，超声波频率为20～35KHz，分散速度为约4800～5200r/min，分散时间为30～50min左右；
(3)加入所述质量份数的油酸钾皂、双甲基丙烯酸乙二醇酯、柠檬酸三乙酯、硫酸亚铁铵、蓖麻油酸聚氧丙烯酯，超声高速分散，超声波频率为20～30KHz，分散速度为约4600～4800r/min，分散时间为20～40min左右；混合均匀后制得本品。
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