CN106280039B - A kind of anti-tritium gloves and preparation method thereof - Google Patents

A kind of anti-tritium gloves and preparation method thereof Download PDF

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Publication number
CN106280039B
CN106280039B CN201610798593.XA CN201610798593A CN106280039B CN 106280039 B CN106280039 B CN 106280039B CN 201610798593 A CN201610798593 A CN 201610798593A CN 106280039 B CN106280039 B CN 106280039B
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gloves
dry
tritium
coagulator
time
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CN106280039A (en
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巫惠琼
陈国梁
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Two Latex Product Co Ltd In Guangzhou
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Two Latex Product Co Ltd In Guangzhou
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34—Component parts, details or accessories; Auxiliary operations
    • B29C41/52—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/48—Wearing apparel
    • B29L2031/4842—Outerwear
    • B29L2031/4864—Gloves
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Gloves (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

The present invention provides a kind of anti-tritium gloves and preparation method thereof, the latex mixing that anti-tritium gloves use is made of the raw material of following weight proportion: butyl rubber lotion 200, Emulsifier EL-60 0.10-0.25, potassium hydroxide 0-5, dispersion 20.The butyl rubber lotion is made of the raw material of following weight proportion: butyl rubber 160, oleic acid 1.0-1.5, potassium hydroxide 4.0-7.2, potassium dihydrogen phosphate 5.5-6.4, polyvinyl alcohol 35-50, Emulsifier EL-60 potash soap 0.8-1.0, soft water 94-100.The dispersion is made of the raw material of following weight proportion: sulphur 4, promotor Px 5, promotor ZDC 10, zinc oxide 8, antioxidant DBH 2, green pigment 0.4, dispersing agent NF 5, stabilizer KOH 0.8, carbon black 0.1, anti-tritium material 1.5-5.0, water 50.The beneficial effect of anti-tritium gloves of the invention compared with the prior art is that tritium-permeation rate coefficient, air-tightness, mechanical property, heat-resistant air aging property, resistance to sulfuric acid solution performance, resistance to sodium hydroxide solution performance are excellent, reaches the requirement of related military project unit.

Description

A kind of anti-tritium gloves and preparation method thereof
Technical field
The present invention relates to a kind of radiation proof materials, more particularly to a kind of anti-tritium gloves and preparation method thereof.
Background technique
As radiation proof material, anti-tritium gloves mostly use high molecular material.Due to infiltration of the tritium in high molecular material with And the decline that all can lead to material property is exposed under radiation environment for a long time, therefore, developing Tritium Protection high molecular material generally needs It solves following problems: slowing down the infiltration of tritium in the material, the radiation resistance of reinforcing material, reduces irradiation and tritium and material is made With the chemical attack of rear generation, a possibility that reducing hydrogen isotopic exchange.Anti- tritium gloves used at present are all using with good It is prepared by good butyl rubber of anti-tritium irradiation behaviour and Tritium Resistivity etc..
Currently, the producer for producing anti-tritium gloves can seldom accomplish tritium-permeation rate coefficient no more than 1.50 × 10﹣ 7cm3mm/ cm2H, while the air-tightness of gloves, mechanical property, heat-resistant air aging property, resistance to sulfuric acid solution performance, resistance to sodium hydroxide solution Performance can reach the requirement of related military project unit.
Summary of the invention
In view of the deficienciess of the prior art, the technical problem to be solved in the present invention is to provide a kind of tritium-permeation rate coefficient, Air-tightness, mechanical property, heat-resistant air aging property, resistance to sulfuric acid solution performance, resistance to sodium hydroxide solution performance are excellent to prevent Tritium gloves.The present invention makes it have the anti-tritium performance that other gloves are unable to reach by the way that anti-tritium material is added in formula.This hair It is bright particular by following technical scheme realize:
A kind of anti-tritium gloves, the latex mixing of use are made of the raw material of following weight proportion: butyl rubber lotion 200 is gathered Ethylene oxide castor oil 0.10-0.25, potassium hydroxide 0-5, dispersion 20.
Further, the butyl rubber lotion is made of the raw material of following weight proportion: butyl rubber 160, oleic acid 1.0- 1.5, potassium hydroxide 4.0-7.2, potassium dihydrogen phosphate 5.5-6.4, polyvinyl alcohol 35-50, Emulsifier EL-60 potash soap 0.8- 1.0, soft water 94-100.
Further, the dispersion is made of the raw material of following weight proportion: sulphur 4, promotor Px 5, promotor ZDC10, zinc oxide 8, antioxidant DBH 2, green pigment 0.4, dispersing agent NF 5, stabilizer KOH 0.8, carbon black 0.1, anti-tritium material 1.5-5.0, water 50.
Further, the anti-tritium material is Al2O3。
The present invention also provides three kinds of method for producing tritium-proof gloves:
1, the anti-tritium gloves are the anti-tritium gloves of long sleeves unlined, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 30 in 75 DEG C of hot water "；
(2) it soaks coagulator: lifting after production model leaching hot water and be used together clean dry cloth and dry the moisture content on model, so The clear coagulator of infusing drugs in wine afterwards, coagulator calcium content: 23-30%；
(3) dry: to be dried after model leaching coagulator at 60 DEG C, drying time 20 "；
(4) the leaching latex mixing: the residence time is 150-180 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) low temperature drying: glue film is through dry at 65-70 DEG C, drying time 70 '；
(7) crimping: the up side of roll up diameter 8-10mm from the cuff edge of gloves；
(8) demould: gloves are inverted from model and are taken off after crimping；
(9) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(10) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, repairing point want it is smooth, Securely；
(11) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(12) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 115 ± 8 DEG C after gloves are dry；
(13) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', the impurity of wash clean gloves；
(14) airtight test: all gloves carry out air-tightness inflation and check, the gloves of gas leakage are rejected；
(15) dry: will be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(16) visual examination: product 100% carries out visual examination by standard；
(17) it packs.
Preferably, the raw material weight proportioning of soup processed of the wine clear coagulator are as follows: calcium chloride 30, alcohol 70, paregal O 0-1.
2, the anti-tritium gloves are the anti-tritium gloves of cotta lining, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: infusing drugs in wine is solidifying clearly after the moisture content on compressed air drying model after production model leaching hot water Gu agent, coagulator calcium content: 27-30%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) soak a latex: the model for having soaked coagulator is immersed in residence time in the latex mixing after drying For 60-90 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue when rear process set fiber after dry through 65-70 DEG C of drying, time 15 ' Film；
(7) it covers fiber: being exactly the scaffold material fibres gloves for covering upper gloves on gloves glue film, fiber glove has to elder generation It is impregnated with pull open powder solution, is allowed to lubricate, convenient for covering in gloves film surface；
(8) it arranges: first drenching the pull open powder solution on fiber glove surface hot water completely, then by fiber glove and glue film Docile is arranged, and the moisture content of fiber surface is dried with dry cloth；
(9) secondary glue is soaked: i.e. second of leaching latex mixing, it is therefore an objective to be fully bonded to fiber glove and glue film Together；
(10) dry: after having soaked secondary glue, dry 20 ' at a temperature of 90 DEG C；
(11) cutting edge: in order to facilitate the operation and guarantee product quality, it is exactly by fiber glove that fiber glove is longer when weaving The part that edge has more is cut, and rear process crimping is conducive to；
(12) crimping: wearing and security consideration for convenience, the up roll up diameter 5mm- from the cuff edge of gloves The side of 8mm；
(13) demould: gloves are inverted from model and are taken off after crimping；
(14) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(15) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, repairing point want it is smooth, Securely；
(16) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(17) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 115 ± 8 DEG C after gloves are dry；
(18) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(19) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, will leak The gloves of gas are rejected；
(20) dry: will be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(21) visual examination: product carries out 100% and carries out visual examination by standard；
(22) it packs.
Preferably, the raw material weight proportioning of soup processed of the wine clear coagulator are as follows: calcium chloride 30, alcohol 70, paregal O 0-1.
3, the anti-tritium gloves are the anti-tritium gloves of cotta unlined, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: infusing drugs in wine is solidifying clearly after the moisture content on compressed air drying model after production model leaching hot water Gu agent, coagulator calcium content: 27-30%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) impregnation cream: the model for having soaked coagulator is immersed in stop in latex mixing described in claim 1 after drying Time is 120-160 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 70 DEG C of dryings, time 20 '；
(7) crimping: wearing and security consideration for convenience, the up roll up diameter 4mm- from the cuff edge of gloves The side of 8mm；
(8) entrucking: gang mould plate is attached on vulcanized vehicle together after product crimping；
(9) temperature cabinet in bottom is dry: product loading pusher into the temperature cabinet of bottom dry 120 ' at a temperature of 70 DEG C；
(10) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 115 ± 8 DEG C after gloves are dry；
(11) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(12) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, will leak The gloves of gas are rejected；
(13) dry: will be dried in drying drum at 75 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(14) visual examination: product carries out 100% and carries out visual examination by standard；
(15) it packs.
Preferably, the raw material weight proportioning of soup processed of the wine clear coagulator are as follows: calcium chloride 30, alcohol 70, paregal O 0-1.
Anti- tritium gloves of the invention have the advantages that compared with the prior art
1, anti-tritium performance: tritium-permeation rate coefficient is not more than 1.50 × 10﹣ 7cm3mm/cm2h。
2, air-tightness: cotta insert gloves continue under 12kPa ± 1kPa pressure 10~15 seconds it is air tight；Long sleeves unlined Gloves continue under 4.0kPa ± 1kPa pressure 10~15 seconds it is air tight；Cotta unlined gloves are under 4.0kPa ± 1kPa pressure Continue 10~15 seconds it is air tight.(adding one later)
3, mechanical property: tensile strength >=12Mpa of long sleeves unlined gloves, elongation at break >=750%, cotta lining Breaking tenacity >=100N/mm of gloves.
4, heat-resistant air aging property: under the conditions of temperature 70 C, ageing time 72h, gloves glue surface is tacky, delamination and It cracks, and the anti-tritium gloves breaking tenacity of cotta lining is not less than 90N/mm, the anti-tritium gloves tensile strength of long sleeves unlined is not small In 11.0MPa.Note: it will pull apart and change stretching
5, resistance to sulfuric acid solution performance: temperature 70 C, 68% sulfuric acid solution in impregnate 10h after, gloves glue surface is tacky, It delamination and cracks, and the anti-tritium gloves breaking tenacity of cotta lining is not less than 90N/25mm, the anti-tritium gloves of long sleeves unlined stretch Intensity is not less than 11.0MPa.Note: it will pull apart and change stretching
6, resistance to sodium hydroxide solution performance: after impregnating 10h in the sodium hydroxide solution in temperature 70 C, 40%, gloves Glue surface is tacky, delamination and cracks, and the anti-tritium gloves breaking tenacity of cotta lining is not less than 90N/mm, the anti-tritium of long sleeves unlined Gloves tensile strength is not less than 11.0MPa.Note: it will pull apart and change stretching
The anti-tritium gloves of long sleeves unlined of the invention have tightened up requirement to the parameter of production technology.It only soaks primary Glue, low temperature drying, leaching hot water and dry temperature require stringent control, if hot water temperature is improper to be easy in glue film table The defects of face causes hot water to steep, and drying temperature can leave high warm bathing that is obvious, can not repairing in glove surface if overtemperature.
Specific embodiment
The present invention will be further explained by examples below, but described specific embodiment is not constituted to this The limitation of invention.
Embodiment 1
A kind of anti-tritium gloves, the latex mixing of use are made of the raw material of following weight proportion: butyl rubber lotion 200 is gathered Ethylene oxide castor oil 0.10, potassium hydroxide 5, dispersion 20.The butyl rubber lotion is made of the raw material of following weight proportion: fourth It is base rubber 160, oleic acid 1.0, potassium hydroxide 7.2, potassium dihydrogen phosphate 5.5, polyvinyl alcohol 50, Emulsifier EL-60 potash soap 0.8, soft Water 100.The dispersion is made of the raw material of following weight proportion: sulphur 4, promotor Px 5, promotor ZDC 10, zinc oxide 8, antioxidant DBH 2, green pigment 0.4, dispersing agent NF 5, stabilizer KOH 0.8, carbon black 0.1, anti-tritium material 1.5, water 50.Institute Stating anti-tritium material is Al2O3。
1, the anti-tritium gloves are the anti-tritium gloves of long sleeves unlined, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 30 in 75 DEG C of hot water "；
(2) it soaks coagulator: lifting after production model leaching hot water and be used together clean dry cloth and dry the moisture content on model, so The clear coagulator of infusing drugs in wine afterwards, coagulator calcium content: 23%；
(3) dry: to be dried after model leaching coagulator at 60 DEG C, drying time 20 "；
(4) the leaching latex mixing: the residence time is 180 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) low temperature drying: glue film is through dry at 65 DEG C, drying time 70 '；
(7) crimping: the up side of roll up diameter 10mm from the cuff edge of gloves；
(8) demould: gloves are inverted from model and are taken off after crimping；
(9) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(10) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, repairing point want it is smooth, Securely；
(11) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(12) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 107 DEG C after gloves are dry；
(13) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', the impurity of wash clean gloves；
(14) airtight test: all gloves carry out air-tightness inflation and check, the gloves of gas leakage are rejected；
(15) dry: will be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(16) visual examination: product 100% carries out visual examination by standard；
(17) it packs.
2, the anti-tritium gloves are the anti-tritium gloves of cotta lining, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: infusing drugs in wine is solidifying clearly after the moisture content on compressed air drying model after production model leaching hot water Gu agent, coagulator calcium content: 27%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) soak a latex: the model for having soaked coagulator is immersed in residence time in the latex mixing after drying It is 90 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 65 DEG C of dryings, time 15 '；
(7) it covers fiber: being exactly the scaffold material fibres gloves for covering upper gloves on gloves glue film, fiber glove has to elder generation It is impregnated with pull open powder solution, is allowed to lubricate, convenient for covering in gloves film surface；
(8) it arranges: first drenching the pull open powder solution on fiber glove surface hot water completely, then by fiber glove and glue film Docile is arranged, and the moisture content of fiber surface is dried with dry cloth；
(9) secondary glue is soaked: i.e. second of leaching latex mixing, it is therefore an objective to be fully bonded to fiber glove and glue film Together；
(10) dry: after having soaked secondary glue, dry 20 ' at a temperature of 90 DEG C；
(11) cutting edge: in order to facilitate the operation and guarantee product quality, it is exactly by fiber glove that fiber glove is longer when weaving The part that edge has more is cut, and rear process crimping is conducive to；
(12) crimping: wearing and security consideration for convenience, the up roll up diameter 8mm from the cuff edge of gloves Side；
(13) demould: gloves are inverted from model and are taken off after crimping；
(14) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(15) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, repairing point want it is smooth, Securely；
(16) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(17) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 107 DEG C after gloves are dry；
(18) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(19) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, will leak The gloves of gas are rejected；
(20) dry: will be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(21) visual examination: product carries out 100% and carries out visual examination by standard；
(22) it packs.
3, the anti-tritium gloves are the anti-tritium gloves of cotta unlined, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: infusing drugs in wine is solidifying clearly after the moisture content on compressed air drying model after production model leaching hot water Gu agent, coagulator calcium content: 27%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) impregnation cream: the model for having soaked coagulator is immersed in stop in latex mixing described in claim 1 after drying Time is 120 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 70 DEG C of dryings, time 20 '；
(7) crimping: wearing and security consideration for convenience, the up roll up diameter 4mm from the cuff edge of gloves Side；
(8) entrucking: gang mould plate is attached on vulcanized vehicle together after product crimping；
(9) temperature cabinet in bottom is dry: product loading pusher into the temperature cabinet of bottom dry 120 ' at a temperature of 70 DEG C；
(10) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 107 DEG C after gloves are dry；
(11) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(12) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, will leak The gloves of gas are rejected；
(13) dry: will be dried in drying drum at 75 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(14) visual examination: product carries out 100% and carries out visual examination by standard；
(15) it packs.
Embodiment 2
A kind of anti-tritium gloves, the latex mixing of use are made of the raw material of following weight proportion: butyl rubber lotion 200 is gathered Ethylene oxide castor oil 0.25, dispersion 20.The butyl rubber lotion is made of the raw material of following weight proportion: butyl rubber 160, oil Sour 1.5, potassium hydroxide 4.0, potassium dihydrogen phosphate 6.4, polyvinyl alcohol 35, Emulsifier EL-60 potash soap 1.0, soft water 94.It is described Dispersion is made of the raw material of following weight proportion: sulphur 4, promotor Px 5, promotor ZDC 10, zinc oxide 8, anti-aging agent DBH 2, green pigment 0.4, dispersing agent NF 5, stabilizer KOH 0.8, carbon black 0.1, anti-tritium material 5, water 50.The anti-tritium material For Al2O3。
1, the anti-tritium gloves are the anti-tritium gloves of long sleeves unlined, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 30 in 75 DEG C of hot water "；
(2) it soaks coagulator: lifting after production model leaching hot water and be used together clean dry cloth and dry the moisture content on model, so The clear coagulator of infusing drugs in wine afterwards, coagulator calcium content: 30%；
(3) dry: to be dried after model leaching coagulator at 60 DEG C, drying time 20 "；
(4) the leaching latex mixing: the residence time is 150 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) low temperature drying: glue film is through dry at 70 DEG C, drying time 70 '；
(7) crimping: the up side of roll up diameter 8mm from the cuff edge of gloves；
(8) demould: gloves are inverted from model and are taken off after crimping；
(9) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(10) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, repairing point want it is smooth, Securely；
(11) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(12) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 123 DEG C after gloves are dry；
(13) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', the impurity of wash clean gloves；
(14) airtight test: all gloves carry out air-tightness inflation and check, the gloves of gas leakage are rejected；
(15) dry: will be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(16) visual examination: product 100% carries out visual examination by standard；
(17) it packs.
2, the anti-tritium gloves are the anti-tritium gloves of cotta lining, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: infusing drugs in wine is solidifying clearly after the moisture content on compressed air drying model after production model leaching hot water Gu agent, coagulator calcium content: 30%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) soak a latex: the model for having soaked coagulator is immersed in residence time in the latex mixing after drying It is 60 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 70 DEG C of dryings, time 15 '；
(7) it covers fiber: being exactly the scaffold material fibres gloves for covering upper gloves on gloves glue film, fiber glove has to elder generation It is impregnated with pull open powder solution, is allowed to lubricate, convenient for covering in gloves film surface；
(8) it arranges: first drenching the pull open powder solution on fiber glove surface hot water completely, then by fiber glove and glue film Docile is arranged, and the moisture content of fiber surface is dried with dry cloth；
(9) secondary glue is soaked: i.e. second of leaching latex mixing, it is therefore an objective to be fully bonded to fiber glove and glue film Together；
(10) dry: after having soaked secondary glue, dry 20 ' at a temperature of 90 DEG C；
(11) cutting edge: in order to facilitate the operation and guarantee product quality, it is exactly by fiber glove that fiber glove is longer when weaving The part that edge has more is cut, and rear process crimping is conducive to；
(12) crimping: wearing and security consideration for convenience, the up roll up diameter 5mm from the cuff edge of gloves Side；
(13) demould: gloves are inverted from model and are taken off after crimping；
(14) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(15) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, repairing point want it is smooth, Securely；
(16) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(17) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 123 DEG C after gloves are dry；
(18) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(19) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, will leak The gloves of gas are rejected；
(20) dry: will be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(21) visual examination: product carries out 100% and carries out visual examination by standard；
(22) it packs.
3, the anti-tritium gloves are the anti-tritium gloves of cotta unlined, and preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: infusing drugs in wine is solidifying clearly after the moisture content on compressed air drying model after production model leaching hot water Gu agent, coagulator calcium content: 30%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) impregnation cream: the model for having soaked coagulator is immersed in stop in latex mixing described in claim 1 after drying Time is 160 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 70 DEG C of dryings, time 20 '；
(7) crimping: wearing and security consideration for convenience, the up roll up diameter 8mm from the cuff edge of gloves Side；
(8) entrucking: gang mould plate is attached on vulcanized vehicle together after product crimping；
(9) temperature cabinet in bottom is dry: product loading pusher into the temperature cabinet of bottom dry 120 ' at a temperature of 70 DEG C；
(10) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 123 DEG C after gloves are dry；
(11) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(12) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, will leak The gloves of gas are rejected；
(13) dry: will be dried in drying drum at 75 DEG C through the gastight gloves of airtight test, product with Subject to parching；
(14) visual examination: product carries out 100% and carries out visual examination by standard；
(15) it packs.

Claims (7)

1. a kind of anti-tritium gloves, which is characterized in that the latex mixing of use is made of the raw material of following weight proportion: butyl latex Liquid 200, Emulsifier EL-60 0.10-0.25, potassium hydroxide 0-5, dispersion 20；The butyl rubber lotion is matched by following weight The raw material of ratio is made: butyl rubber 160, oleic acid 1.0-1.5, potassium hydroxide 4.0-7.2, potassium dihydrogen phosphate 5.5-6.4, polyvinyl alcohol 35-50, Emulsifier EL-60 potash soap 0.8-1.0, soft water 94-100；The dispersion by following weight proportion raw material system At: sulphur 4, promotor Px 5, promotor ZDC 10, zinc oxide 8, antioxidant DBH 2, green pigment 0.4, dispersing agent NF 5, steady Determine agent KOH 0.8, carbon black 0.1, anti-tritium material 1.5-5.0, water 50；The anti-tritium material is Al2O3。
2. a kind of anti-tritium gloves according to claim 1, which is characterized in that the anti-tritium gloves are the anti-tritium of long sleeves unlined Gloves, preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 30 in 75 DEG C of hot water "；
(2) it soaks coagulator: lifting after production model leaching hot water and be used together clean dry cloth and dry the moisture content on model, then soak Wine clear coagulator, coagulator calcium content: 23-30%；
(3) dry: to be dried after model leaching coagulator at 60 DEG C, drying time 20 "；
(4) soak latex mixing described in claim 1: the residence time is 150-180 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) low temperature drying: glue film is through dry at 65-70 DEG C, drying time 70 '；
(7) crimping: the up side of roll up diameter 8-10mm from the cuff edge of gloves；
(8) demould: gloves are inverted from model and are taken off after crimping；
(9) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(10) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, and repairing point wants smooth, secured； (11) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(12) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 115 ± 8 DEG C after gloves are dry；
(13) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', the impurity of wash clean gloves；
(14) airtight test: all gloves carry out air-tightness inflation and check, the gloves of gas leakage are rejected；
(15) dry: will to be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product is to parch Subject to；
(16) visual examination: product 100% carries out visual examination by standard；
(17) it packs.
3. a kind of anti-tritium gloves according to claim 2, which is characterized in that the raw material weight proportioning of soup processed of the wine clear coagulator Are as follows: calcium chloride 30, alcohol 70, paregal O 0-1.
4. a kind of anti-tritium gloves according to claim 1, which is characterized in that the anti-tritium gloves are the anti-tritium hand of cotta lining Set, preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: the clear coagulator of infusing drugs in wine after the moisture content dried up on model after production model leaching hot water through compressed air, Coagulator calcium content: 27-30%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) soak a latex: the model for having soaked coagulator is immersed in stop in latex mixing described in claim 1 after drying Time is 60-90 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 65-70 DEG C of drying, time 15 '；
(7) it covers fiber: being exactly the scaffold material fibres gloves for covering upper gloves on gloves glue film, fiber glove has to first with drawing The immersion of powder solution is opened, is allowed to lubricate, convenient for covering in gloves film surface；
(8) it arranges: first the pull open powder solution on fiber glove surface hot water being drenched completely, then arranges fiber glove and glue film Docile, and the moisture content of fiber surface is dried with dry cloth；
(9) it soaks secondary glue: soaking latex mixing described in claim 1 for the second time, it is therefore an objective to which fiber glove is complete with glue film It is bonded together；
(10) dry: after having soaked secondary glue, dry 20 ' at a temperature of 90 DEG C；
(11) cutting edge: in order to facilitate the operation and guarantee product quality, it is exactly by fiber glove edge that fiber glove is longer when weaving The part having more is cut, and rear process crimping is conducive to；
(12) crimping: wearing and security consideration for convenience, the up roll up diameter 5mm-8mm from the cuff edge of gloves Side；
(13) demould: gloves are inverted from model and are taken off after crimping；
(14) cover die: by the product taken off cover again same specification sulfide model up, for carrying out gloves repairing；
(15) mend bubble: latex examination gloves appearance is repaired at defective position with latex mixing, and repairing point wants smooth, secured； (16) dry: to be dried at 70 DEG C after gloves repairing, the time 80 '；
(17) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 115 ± 8 DEG C after gloves are dry；
(18) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(19) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, by gas leakage Gloves are rejected；
(20) dry: will to be dried in drying drum at 80 DEG C through the gastight gloves of airtight test, product is to parch Subject to；
(21) visual examination: product carries out 100% and carries out visual examination by standard；
(22) it packs.
5. a kind of anti-tritium gloves according to claim 4, which is characterized in that the raw material weight proportioning of soup processed of the wine clear coagulator Are as follows: calcium chloride 30, alcohol 70, paregal O 0-1.
6. a kind of anti-tritium gloves according to claim 1, which is characterized in that the anti-tritium gloves are the anti-tritium of cotta unlined Gloves, preparation method includes the following steps:
(1) soak hot water: the production model of gloves soaks 50 in 75 DEG C of hot water "；
(2) infusing drugs in wine essence coagulator: the clear coagulator of infusing drugs in wine after the moisture content dried up on model after production model leaching hot water through compressed air, Coagulator calcium content: 27-30%；
(3) dry: to be dried at 60 DEG C after model leaching coagulator, the time 20 "；
(4) impregnation cream: the model for having soaked coagulator is immersed in residence time in latex mixing described in claim 1 after drying For 120-160 "；
(5) leaching: 3 ' are impregnated after impregnation in 70 DEG C of hot water, the impurity that water is dissolved in glue film is cleaned up；
(6) dry: glue film is conducive to be not easy to injure glue film when rear process set fiber after dry through 70 DEG C of dryings, time 20 '；
(7) crimping: wearing and security consideration for convenience, the up roll up diameter 4mm-8mm from the cuff edge of gloves Side；
(8) entrucking: gang mould plate is attached on vulcanized vehicle together after product crimping；
(9) temperature cabinet in bottom is dry: product loading pusher into the temperature cabinet of bottom dry 120 ' at a temperature of 70 DEG C；
(10) vulcanize: carrying out direct vapour vulcanization, time 60 ' in vulcanizing tank at 115 ± 8 DEG C after gloves are dry；
(11) it water process: is washed at 60 DEG C after gloves vulcanization, the time 30 ', it is therefore an objective to the impurity of wash clean gloves；
(12) airtight test: all gloves carry out air-tightness inflation and check, understanding gloves whether there is gas leakage, by gas leakage Gloves are rejected；
(13) dry: will to be dried in drying drum at 75 DEG C through the gastight gloves of airtight test, product is to parch Subject to；
(14) visual examination: product carries out 100% and carries out visual examination by standard；
(15) it packs.
7. a kind of anti-tritium gloves according to claim 6, which is characterized in that the raw material weight proportioning of soup processed of the wine clear coagulator Are as follows: calcium chloride 30, alcohol 70, paregal O 0-1.
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CN107263900A (en) * 2017-06-30 2017-10-20 广州咖登橡胶科技有限公司 A kind of preparation method of the butyl nylon insert gloves of acid and alkali-resistance
CN108215031A (en) * 2017-12-23 2018-06-29 广州双乳胶制品有限公司 A kind of preparation process of butyronitrile nylon insert gloves
CN108690229B (en) * 2018-06-12 2020-05-29 中国热带农业科学院农产品加工研究所 Tritium shielding modified natural latex and preparation method thereof, and radiation shielding tool prepared from latex
CN109503963A (en) * 2018-11-02 2019-03-22 广州双乳胶制品有限公司 A kind of preparation method of butyl latex and preparation method thereof and the gloves with its preparation
CN110801065B (en) * 2019-10-18 2021-08-31 广州双一乳胶制品有限公司 Composite chemical corrosion resistant airtight protective gloves and preparation process thereof
CN112140431A (en) * 2020-09-19 2020-12-29 孙福亮 Glove demoulding device
CN112315074B (en) * 2020-09-28 2024-01-23 中国辐射防护研究院 Multi-layer tritium-proof glove and manufacturing method thereof
CN112706336A (en) * 2020-12-24 2021-04-27 安徽攀望科技有限公司 Production process of anti-slip heat-resistant rubber gloves

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