CN106277781A - Utilize the method that high-temperature liquid state industrial slag produces pottery glaze - Google Patents
Utilize the method that high-temperature liquid state industrial slag produces pottery glaze Download PDFInfo
- Publication number
- CN106277781A CN106277781A CN201510290413.2A CN201510290413A CN106277781A CN 106277781 A CN106277781 A CN 106277781A CN 201510290413 A CN201510290413 A CN 201510290413A CN 106277781 A CN106277781 A CN 106277781A
- Authority
- CN
- China
- Prior art keywords
- liquid state
- temperature liquid
- glaze
- slag
- industrial slag
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The present invention relates to a kind of method utilizing high-temperature liquid state industrial slag to produce pottery glaze, using high-temperature liquid state industrial slag as raw material, high temperature heat that slag self has, chemical composition is utilized directly to prepare the frit of ceramic glaze, it comprises the following steps: high-temperature liquid state industrial slag 20～90 weight portion is added high temperature kiln by (1), add the quenched material of 10～95 weight portions, heat at a temperature of 1300 DEG C～1600 DEG C, make quenched material melt, and be sufficiently mixed the melt becoming clarification homogenizing with slag；(2) melt is discharged in high temperature kiln and shrend becomes frit granule, frit granule is dried, prepares pottery glaze after broken, screening.Production technology of the present invention is simple, and clinker quality is excellent, and decreases the raw material needed for pottery glaze produces and the energy.
Description
Technical field:
The present invention relates to a kind of method utilizing high-temperature liquid state industrial slag to produce pottery glaze.
Background technology
Ore residue after ore dressing or smelting is referred to as slag.Pyrometallurgy produces, such as smelting iron and steel, Copper making, aluminum
Smelt production all can produce a large amount of high-temperature liquid state industrial slag.It addition, some nonmetal raw material of industry, such as yellow phosphorus etc.,
Also being produced by high-temperature technology by natural minerals, its production process also can produce substantial amounts of high-temperature liquid state industrial slag.High-temperature liquid
The composition of state industrial slag is typically based on silicate, and chemical composition is with production technology, Ore kind and the difference of smelting auxiliary agent
Variant.The representative slag main component of part is shown in Table 1.
Table 1
Shrend and heat vexed be the conventional processing method of current slag.Slag part after process can be used as building aggregate, aggregate of building the road
Deng, it is widely used as cement admixture after blast furnace granulated slag is levigate.But the value that generally speaking, slag is exploited is the highest.Slag
In the sensible heat that contains the most also be difficult by；And in hot slag shrend and hot vexed processing procedure, substantial amounts of water need to be consumed, and
Produce corrosive vapor and waste water, cause environmental pollution.If hot slag can be utilized to produce high added value material, then can greatly carry
Rise the value of hot slag, be highly significant to preserving the ecological environment.
Production of Ceramics be unable to do without glaze.Glaze refers to cover the glassy state of the thin layer on ceramic body surface or glassy state and crystalline state
The material combined, has the raising effect such as product properties, decoration, can be divided into clear frit, opaque glaze, crystallization by barment tag
The kinds such as glaze, can be divided into fritted glaze, part fritted glaze, raw glaze by raw material composition.Fritted glaze is that raw material is first melt into glass
After liquid, shrend becomes granule, i.e. frit, re-grading, and ingredient groups synthesis glaze uses.Part fritted glaze be by frit and its
His material mixing and water adding grinds what slurrying used, and the glaze slip made has more stable suspension and the good adhesion to base substrate.
Due to fritted glaze have relative to raw glaze can stablize glaze character, expand glaze firing range, to improve glaze quality etc. many excellent
Point, has obtained increasingly being widely applied in recent years in glazed ceramic produces.But frit produces and there is the problems such as energy consumption is higher.
Some glaze and Production of Ceramics enterprise add the industrial slag of a small amount of cold conditions in the formula of frit, and such as, patent is " a kind of
Industrial slag is utilized to carry out the preparation method of split-phase black fancy glaze " (number of patent application: CN201210087100.3) propose one
Planting the preparation method utilizing industrial slag to carry out split-phase black fancy glaze, the parvafacies mechanism that during utilizing glaze to burn till, melt produces combines
Slag coloring oxide colours, and makes a small amount of coloring oxide produce bigger colorability, thus invented a kind of low cost,
The preparation method of the black fancy glaze that stability is high, decorative pattern is abundant；Patent " utilizes aluminium section bar industrial slag to prepare the side of preparing ceramic clinker
Method " (number of patent application: CN201210510902.0) disclose a kind of side utilizing aluminium section bar industrial slag to prepare preparing ceramic clinker
Method, this invention adds the batch of necessity in pretreated industrial aluminum profile slag, prepares preparing ceramic clinker.These are for cold
The production pottery glaze research work that state slag is carried out, make use of the mineral resources of slag, but is not directed to utilize high-temperature liquid state
The high temperature energy of industrial slag.
Limited to by the various kiln efficiencies of heating surface, found the equivalent glass melt with slag identical component according to raw mineral materials, need to disappear
Consumption mass energy, theoretically, if utilizing high-temperature liquid state industrial slag for raw material production frit, can economize in raw materials and adding heat fusing
The required energy.Meanwhile, also can reduce the flux consumption needed for frit produces, can reduce accordingly because flux decomposes discharge
The adverse effect that environment is caused by all kinds of pollution gas.
Summary of the invention
It is an object of the invention to provide a kind of high temperature heat of utilizing high-temperature liquid state industrial slag self to have, chemical composition is directly made
The method of standby pottery glaze, decreases the raw mineral materials needed for pottery glaze produces and the energy.
The present invention is to add a certain proportion of quenched material in high-temperature liquid state industrial slag, adds heat mixture, make mixing in kiln
Material is melted, clarification, homogenizing, then shrend becomes frit granule, is dried by frit granule, prepares pottery after broken, screening
Porcelain glaze.
The present invention provides a kind of method utilizing high-temperature liquid state industrial slag to produce pottery glaze, and it comprises the following steps:
(1) high-temperature liquid state industrial slag 20～90 weight portion is added high temperature kiln, adds the quenched material of 10～95 weight portions,
Heat at a temperature of 1300 DEG C～1600 DEG C, make the fusing of quenched material and be mixed into the melt of clarification homogenizing with slag；
(2) melt is discharged in high temperature kiln and shrend becomes frit granule, frit granule is dried, prepares after broken, screening
Pottery glaze.
Preferential, the quenched material described in above-mentioned steps (1) can be according to target frit composition and industrial slag composition, by 5～65 weights
Amount the quartz sand of part, quartzite, silica sand, sandstone, Kaolin, clay, flyash, pyrophyllite, aluminium oxide, aluminium hydroxide,
Magnesia, zircon sand, Anhydrite, potassium feldspar, albite, calcium oxide, limestone, dolomite, Talcum, magnesite, basalt
With flux, Nucleating Agent, clarifier, coloring agent and the decolorising agent of one or more and 5～30 weight portions of cullet one
Plant or multiple prepared.
The most preferential, in above-mentioned steps (1), high-temperature liquid state industrial slag is 50～80 weight portions, and quenched material is 45～65
The quartz sand of weight portion, quartzite, silica sand, sandstone, Kaolin, clay, flyash, pyrophyllite, aluminium oxide, hydroxide
Aluminum, magnesia, zircon sand, Anhydrite, potassium feldspar, albite, calcium oxide, limestone, dolomite, Talcum, magnesite, profound
One or more and flux, Nucleating Agent, clarifier, coloring agent and the decolorising agent of 10～26 weight portions of Wu Yan and cullet
One or more.
Preferential, the quenched material described in above-mentioned steps (1) can be made into the solid powder of mix homogeneously or adds the liquid material of heat fusing.
Preferential, the quenched material described in above-mentioned steps (1) can be directly added in high temperature kiln, it is also possible to is accessing high-temperature liquid state
Add during industrial slag.
Preferential, the flux described in above-mentioned steps (1) is selected from sodium carbonate, potassium carbonate, sodium nitrate, potassium nitrate, Natrii Sulfas, firefly
Stone, prodan, cryolite, boric acid, Borax, lithium oxide, lead oxide, zinc oxide, sodium phosphate etc.；Described Nucleating Agent selects
Autoxidation ferrum, titanium oxide, zirconium oxide, chromium oxide, carbon, sulfur, carborundum, metal sulfide, Si, Zn, Au, Ag, Fe,
The metal powders such as Mn, Cu；Described clarifier selected from arsenic trioxide, antimony oxide, Sodium antimonite., nitrate, sulfate,
Ceria, fluoride, Sal；Described coloring agent is selected from gold such as Ag, Ti, V, Cr, Mn, Fe, Cu, Ni, Co, Sb
Belong to or metal ion compound, sulfur, arsenic and methyl seleninic acid etc.；Described decolorising agent is selected from Se, arsenic trioxide, three oxidations
Two antimony, Sodium antimonite., Na2S, ceria, arsenic oxide, antimony pentoxide, carbon, nitrate, fluoride, chlorination
Thing etc..
Preferential, SiO in the high-temperature liquid state industrial slag described in above-mentioned steps (1)2、Al2O3Add up to more than 60% with CaO content.
Preferential, the high-temperature liquid state industrial slag described in above-mentioned steps (1) is the height of 900～1600 DEG C of discharge in smelting process
The industrial slag of temperature liquid, is specifically as follows blast furnace scum, Corex direct melting reduction iron-making furnace slag, slag, lead skim, aluminum
Slag, copper ashes or phosphorus slag.
Wherein,
The composition of the blast furnace scum of high-temperature liquid state is generally (weight portion): SiO228～38, Al2O35～18, CaO 30～48,
T.Fe 0～1.5, MgO 0～6, P2O50～2.
The composition of high-temperature liquid state Corex direct melting reduction iron-making furnace slag is generally (weight portion): SiO227～37, Al2O36～
19, CaO 30～45, T.Fe 0.1～1.8, MgO 0～9, P2O50～2.
The composition of high-temperature liquid state slag is generally (weight portion): SiO28～20, Al2O32～5, CaO 40～60, T.Fe 3～
18, MgO 0～6, P2O50～2.
The composition of high-temperature liquid state phosphorus slag is generally (weight portion): SiO235～45, Al2O33～7, CaO 45～55, T.Fe 0～
3, MgO 0～3, P2O51～6.
Preferential, the high temperature kiln described in above-mentioned steps (1) is the burning kilns such as combustion gas, fire coal, fuel oil, electric arc heated or electricity
The kiln that pole heating or the electric melting furnace of resistance heating or burning kiln are combined with electric melting furnace.
Preferential, the high temperature kiln equipment described in above-mentioned steps (1) includes 1～3 kiln.
Preferential, the ceramic glaze described in step (2) is crystallization glaze, crystallite frit, milkiness glaze or saturating
Bright glaze.
Term " shrend " in step (2), refers to the high temp glass liquid that compound formed after high-temperature fusion and flows slowly into water
In rapidly cooling make the process of its quenching.
After step (2) prepares pottery glaze, it is also possible to discharge the metal of precipitation in high temperature kiln further, carry out back
Receive and utilize.
The present invention proposes a kind of method utilizing high-temperature liquid state industrial slag to produce pottery glaze, has an advantage in that:
1. high-temperature liquid state industrial slag directly obtains effectively utilization in the condition of high temperature, reduces frit energy consumption, and economic benefit is bright
Show and be conducive to preserving the ecological environment.
2. the frit granule prepared by has firing temperature width, the coefficient of expansion is suitable, intensity is high, the advantage such as wear-resisting.
3. prepare ceramic glaze be crystallite frit, milkiness glaze or transparent glaze, can be directly used as ceramic glaze,
Vitreous enamel or the raw material of devitrified glass composite ceramic slab.
4. the metal contained by high-temperature liquid state industrial slag, discharges after can precipitating gathering, can be used as metallurgical production in high temperature kiln
Raw material.
Detailed description of the invention
Embodiment 1
To be according to parts by weight in advance: 5 parts of flyash, quartz sand 45 parts, sodium carbonate 20 parts, sodium nitrate 5 parts, three oxygen
Change 1 part of mix homogeneously of two antimony, prepare solid state q-switched material standby.
The high-temperature liquid state Corex direct melting reduction iron-making furnace slag that parts by weight are 80 parts is entered in glass melting kiln, adds simultaneously
Enter the quenched material of above-mentioned preparation, heat 6 hours at a temperature of 1450 DEG C in fusing kiln, make the fusing of quenched material and mix with slag
Uniformly, clarified, the melt of homogenizing.
Melt is discharged in fusing kiln, rushes melt with cold water simultaneously, make melt shrend become frit granule, frit granule is dried,
Preparing ceramic transparent glaze product after broken, screening, frit thermal coefficient of expansion (0～600 DEG C) is (6.4～6.6) xl0-6/
DEG C, the ceramic veneer surface Mohs' hardness prepared with this frit reaches 4 grades.
Consisting of of described high-temperature liquid state Corex direct melting reduction iron-making furnace slag: CaO 40%, SiO233%, Al2O317%,
MgO 9%.
Embodiment 2
According to parts by weight it is in advance: by zircon sand 5 parts, quartz sand 20 parts, Anhydrite 20 parts, 8 parts of magnesia, Borax 10 parts
Mix homogeneously, prepares solid state q-switched material standby.
The high-temperature liquid state Phosphorus Slag that parts by weight are 50 parts is accessed in electric arc furnace, is simultaneously introduced the quenched material of above-mentioned preparation, at electricity
In arc stove, heating 1 hour, makes quenched material melt.
Melt is poured in tank furnace, heat 4 hours at a temperature of 1430 DEG C in tank furnace, the clarification obtained, homogenizing melt.
Melt is discharged in tank furnace, rushes melt with cold water simultaneously, make melt shrend become frit granule, frit granule is dried,
Preparing ceramic microcrystalline glaze product after broken, screening, frit thermal coefficient of expansion (0～600 DEG C) is (6.5～6.7) xl0-6/
DEG C, the devitrified glass composite ceramic slab surface Mohs' hardness prepared with this frit reaches 5 grades.
Described consisting of high-temperature liquid state Phosphorus Slag: CaO 50%, SiO239.5%, Al2O36.5%, P2O54%.
Claims (9)
1. one kind utilizes the method that high-temperature liquid state industrial slag produces pottery glaze, it is characterised in that comprise the following steps:
(1) high-temperature liquid state industrial slag 20～90 weight portion is added high temperature kiln, adds the quenched material of 10～95 weight portions,
Heat at a temperature of 1300 DEG C～1600 DEG C, make the fusing of quenched material and be mixed into the melt of clarification homogenizing with slag；
(2) melt is discharged in high temperature kiln and shrend becomes frit granule, frit granule is dried, prepares after broken, screening
Pottery glaze.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
Quenched material described in step (1) is by the quartz sand of 5～65 weight portions, quartzite, silica sand, sandstone, Kaolin, clay, powder
Coal ash, pyrophyllite, aluminium oxide, aluminium hydroxide, magnesia, zircon sand, Anhydrite, potassium feldspar, albite, calcium oxide, Calx
One or more and the flux of 5～30 weight portions, crystalline substance of stone, dolomite, Talcum, magnesite, basalt and cullet
One or more of core agent, clarifier, coloring agent and decolorising agent prepare.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
The solid powder that quenched material is mix homogeneously described in step (1) or add the liquid material of heat fusing.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
SiO in described high-temperature liquid state industrial slag2、Al2O3Add up to more than 60% with CaO content.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
Described high temperature kiln equipment is the kiln that burning kiln, electric melting furnace or burning kiln are combined with electric melting furnace.
Utilize the method that high-temperature liquid state industrial slag produces pottery glaze, its feature the most according to claim 1 or 5
It is: described high temperature kiln equipment includes 1～3 kiln.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
Ceramic glaze described in step (2) is crystallization glaze, crystallite frit, milkiness glaze or transparent glaze.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
Quenched material described in step (1) can be directly added in high temperature kiln, it is also possible to during accessing high-temperature liquid state industrial slag
Add.
The method utilizing high-temperature liquid state industrial slag to produce pottery glaze the most according to claim 1, it is characterised in that:
High-temperature liquid state industrial slag described in step (1) is the industrial slag of the high-temperature liquid state of 900～1600 DEG C discharged in smelting process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510290413.2A CN106277781A (en) | 2015-05-29 | 2015-05-29 | Utilize the method that high-temperature liquid state industrial slag produces pottery glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510290413.2A CN106277781A (en) | 2015-05-29 | 2015-05-29 | Utilize the method that high-temperature liquid state industrial slag produces pottery glaze |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106277781A true CN106277781A (en) | 2017-01-04 |
Family
ID=57655233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510290413.2A Pending CN106277781A (en) | 2015-05-29 | 2015-05-29 | Utilize the method that high-temperature liquid state industrial slag produces pottery glaze |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106277781A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107352803A (en) * | 2017-07-25 | 2017-11-17 | 平顶山学院 | A kind of ceramic glaze, preparation method and its application process |
| CN108558212A (en) * | 2018-05-25 | 2018-09-21 | 万玉梅 | A kind of preparation method of anti-skidding glazed tile |
| CN110482861A (en) * | 2019-09-16 | 2019-11-22 | 陕西理工大学 | The method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze |
| CN110550937A (en) * | 2019-09-18 | 2019-12-10 | 上海宝田新型建材有限公司 | Method for producing ceramic blank by using blast furnace slag powder |
| CN111036371A (en) * | 2019-12-31 | 2020-04-21 | 耒阳市焱鑫有色金属有限公司 | Harmless treatment method for reducing arsenic leaching of water of byproduct arsenic-iron alloy of lead smelting oxygen-enriched side-blown converter |
| CN111393027A (en) * | 2020-03-13 | 2020-07-10 | 蒙娜丽莎集团股份有限公司 | White crystal flower frit, white crystal flower decorative ceramic tile and preparation method thereof |
| CN112624613A (en) * | 2020-12-23 | 2021-04-09 | 山东硅元新型材料股份有限公司 | Spherical three-dimensional cracking copper blue glaze and preparation method thereof |
| CN112645689A (en) * | 2021-01-05 | 2021-04-13 | 福建省德化鑫东宝瓷业有限公司 | Ceramic flowerpot prepared from waste raw materials and preparation process thereof |
| CN113942668A (en) * | 2020-07-16 | 2022-01-18 | 广西艾陶新型材料科技有限公司 | Method and device for using potassium carbonate as solvent in ceramic dissolving block |
| CN114573227A (en) * | 2022-03-22 | 2022-06-03 | 洛阳理工学院 | Calendered photovoltaic glass clarifying agent and application thereof |
| CN114735936A (en) * | 2022-05-17 | 2022-07-12 | 山东理工大学 | Steel slag-based ceramic glaze opacifier and preparation method thereof |
| CN116177887A (en) * | 2021-11-26 | 2023-05-30 | 山东鲁阳玄武岩纤维有限公司 | Rock wool product and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188153A (en) * | 1997-11-08 | 1998-07-22 | 周洪志 | Process for treatment of slag and scum and its application method |
| CN101914639A (en) * | 2010-09-08 | 2010-12-15 | 北京科技大学 | Method for recycling iron on line from iron-containing industrial slag and preparing glass ceramics frit |
| CN103922808A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature green antique glaze by utilizing iron-ore slag |
-
2015
- 2015-05-29 CN CN201510290413.2A patent/CN106277781A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1188153A (en) * | 1997-11-08 | 1998-07-22 | 周洪志 | Process for treatment of slag and scum and its application method |
| CN101914639A (en) * | 2010-09-08 | 2010-12-15 | 北京科技大学 | Method for recycling iron on line from iron-containing industrial slag and preparing glass ceramics frit |
| CN103922808A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature green antique glaze by utilizing iron-ore slag |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107352803B (en) * | 2017-07-25 | 2020-10-30 | 平顶山学院 | Ceramic glaze, preparation method and application method thereof |
| CN107352803A (en) * | 2017-07-25 | 2017-11-17 | 平顶山学院 | A kind of ceramic glaze, preparation method and its application process |
| CN108558212A (en) * | 2018-05-25 | 2018-09-21 | 万玉梅 | A kind of preparation method of anti-skidding glazed tile |
| CN110482861A (en) * | 2019-09-16 | 2019-11-22 | 陕西理工大学 | The method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze |
| CN110550937A (en) * | 2019-09-18 | 2019-12-10 | 上海宝田新型建材有限公司 | Method for producing ceramic blank by using blast furnace slag powder |
| CN111036371A (en) * | 2019-12-31 | 2020-04-21 | 耒阳市焱鑫有色金属有限公司 | Harmless treatment method for reducing arsenic leaching of water of byproduct arsenic-iron alloy of lead smelting oxygen-enriched side-blown converter |
| CN111393027A (en) * | 2020-03-13 | 2020-07-10 | 蒙娜丽莎集团股份有限公司 | White crystal flower frit, white crystal flower decorative ceramic tile and preparation method thereof |
| CN111393027B (en) * | 2020-03-13 | 2021-12-03 | 蒙娜丽莎集团股份有限公司 | White crystal flower frit, white crystal flower decorative ceramic tile and preparation method thereof |
| CN113942668A (en) * | 2020-07-16 | 2022-01-18 | 广西艾陶新型材料科技有限公司 | Method and device for using potassium carbonate as solvent in ceramic dissolving block |
| CN112624613A (en) * | 2020-12-23 | 2021-04-09 | 山东硅元新型材料股份有限公司 | Spherical three-dimensional cracking copper blue glaze and preparation method thereof |
| CN112645689A (en) * | 2021-01-05 | 2021-04-13 | 福建省德化鑫东宝瓷业有限公司 | Ceramic flowerpot prepared from waste raw materials and preparation process thereof |
| CN116177887A (en) * | 2021-11-26 | 2023-05-30 | 山东鲁阳玄武岩纤维有限公司 | Rock wool product and preparation method thereof |
| CN114573227A (en) * | 2022-03-22 | 2022-06-03 | 洛阳理工学院 | Calendered photovoltaic glass clarifying agent and application thereof |
| CN114573227B (en) * | 2022-03-22 | 2024-02-20 | 洛阳理工学院 | Calendaring photovoltaic glass clarifying agent and application thereof |
| CN114735936A (en) * | 2022-05-17 | 2022-07-12 | 山东理工大学 | Steel slag-based ceramic glaze opacifier and preparation method thereof |
| CN114735936B (en) * | 2022-05-17 | 2023-10-17 | 山东理工大学 | Steel slag-based ceramic glaze opacifier and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106277781A (en) | Utilize the method that high-temperature liquid state industrial slag produces pottery glaze | |
| Toya et al. | Preparation and properties of CaO–MgO–Al2O3–SiO2 glass-ceramics from kaolin clay refining waste (Kira) and dolomite | |
| CN103539357B (en) | A kind of Silicon-slag microcrystalline glass and preparation method thereof | |
| CN102942303B (en) | A kind of utilize granite waste material to prepare high-strength wearable engineering devitrified glass and preparation method | |
| CN106277789A (en) | A kind of method utilizing steel slag preparation pottery glaze | |
| CN100567412C (en) | Prevent coated material of carbon deposition of coke oven and preparation method thereof | |
| CN101439932B (en) | Low-expansion glass-ceramics with lithia ore tailings as principal raw material and manufacturing method thereof | |
| CN105417950B (en) | A kind of fluxing nucleator of micro crystal material and preparation method thereof | |
| CN101914639A (en) | Method for recycling iron on line from iron-containing industrial slag and preparing glass ceramics frit | |
| CN101759368B (en) | Green glass-ceramic plate made from lead-zinc smelting slag and manufacturing method thereof | |
| CN103395995A (en) | Production method for producing microcrystalline glass by using waste glass and smelting waste | |
| Toya et al. | Glass-ceramics prepared from sludge generated by a water purification plant | |
| CN105293908B (en) | The method for directly preparing devitrified glass using hot steel slag | |
| CN102795772A (en) | Method for preparing microcrystalline glass from kaolin-type coal gangue or fly ash and carbide slag | |
| CN1246454A (en) | Process for preparing decorative devitrified glass tile and its products | |
| CN103771712A (en) | Process for preparing glass ceramics from granite tailings by float process and special tin bath for same | |
| CN102491640A (en) | Method for preparing microcrystalline glass by synergetically processing municipal sludge through utilizing metallurgical slag | |
| CN105731808A (en) | Method for preparing glass ceramics | |
| CN105152536B (en) | A kind of method that microcrystal glass material is synthesized using ferrochrome slag | |
| CN105884200A (en) | Method for producing microcrystalline glass-ceramic composite material from industrial fly ash and vitrification slag | |
| CN104108882A (en) | Float microcrystalline glass and preparation method thereof | |
| CN101967043A (en) | Glass ceramics made from high silicon iron tailings and manufacturing method thereof | |
| CN106316118B (en) | Using liquid blast furnace cinder as brown ambetti of primary raw material and preparation method thereof | |
| CN110217995A (en) | Molten blast furnace slag and flyash coordinate system for devitrified glass method | |
| CN1024652C (en) | Nucleated glass made from tungsten slag and prep. thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170104 |