CN106265168A - A kind of preparation method of natural composite plant mosquito-driving liquid antibacterial, antipruritic - Google Patents
A kind of preparation method of natural composite plant mosquito-driving liquid antibacterial, antipruritic Download PDFInfo
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- CN106265168A CN106265168A CN201610885929.6A CN201610885929A CN106265168A CN 106265168 A CN106265168 A CN 106265168A CN 201610885929 A CN201610885929 A CN 201610885929A CN 106265168 A CN106265168 A CN 106265168A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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Abstract
The invention discloses the preparation method of a kind of natural composite plant mosquito-driving liquid antibacterial, antipruritic, it is characterised in that with Cera Flava as corrosion inhibiter, Mentholum and thymol are antibacterial, and plants essential oil is anophelifuge.In the reactor, add by following composition concentration expressed in percentage by volume and order, Oleum Pelargonii Graveolentis: 22 ~ 26%, Oleum Cinnamomi: 22 ~ 26%, eucalyptus citriodora oil: 18 ~ 23%, Oleum menthae: 15 ~ 20%, Herba Artemisiae Annuae oil: 6 ~ 10%, Litsea cubeba oil: 6 ~ 10%, it is subsequently adding the ethanol solution of Cera Flava, adding the ethanol solution of Mentholum and thymol, obtaining yellow transparent liquid is natural composite plant mosquito-driving liquid antibacterial, antipruritic.This mosquito-driving liquid distributes nature faint scent, and has antibacterial, slow releasing function, has no side effect human body, easy to use, and the persistent period, repelling effect was averagely more than 90% at 10 to 12 hours.
Description
Technical field
The present invention relates to a kind of mosquito repellent, particularly to the preparation of a kind of natural composite plant mosquito-driving liquid antibacterial, antipruritic
Method and the application in cosmetics thereof, belong to cosmetic technical field.
Background technology
Plants essential oil be mainly composed of monoterpene, sesquiterpene, aliphatic compound and aromatic hydrocarbon derivative, have a variety of
Biological activity.At present, plants essential oil has formed a new field at the aspect such as antibacterial, antioxidation, parasite killing.Especially for
The vegetable source pesticide active substances such as the preventing and treating of sanitary insect pest, natural pyrethrum, plants essential oil have person poultry safety, delay evil
Worm Drug resistance, do not pollute the advantages such as living environment, in hygienic biocide field, there is huge potentiality to be exploited and using value.?
There are some researches show that plants essential oil can kill by the way of fumigating or tagging or weaken mosquitos and flies.It is generally acknowledged the effect of fumigant
Mechanism is that the steam of fumigant enters respiratory system by epidermis or the valve of insect, thus penetrates into blood and make insect death by poisoning
Die.
Mosquito sucks human blood, spreads disease, serious harm human health.For a long time, people use multiple method to control
Mosquito, preferably and the persistent period is longer to the prevention effect of mosquito for all kinds of chemical insecticides, and the mosquito matchmaker's disease in certain areas controls
In preventing and treating in play an important role.But organic synthesis insecticide has also left over many problems while efficient insecticide.Real
Trampling proof, along with the use that chemical insecticide is the most long-term, the Drug resistance of mosquito is increasingly stronger, and spreads rapid, pollution ring
Border affects ecological balance.Therefore, find environmentally safe, safe to the human body, be prone to degraded, there is selectivity mosquito repellent enjoy
Pay close attention to.
Anophelifuge technology is a kind of wide variety of technology at China's cosmetic field, traditional cosmetic with repelling effect
Product mainly with the addition of the repellant of chemosynthesis, such as diethyltoluamide (DEET), mosquitofugal oil (DMP) or citronellal etc., spread upon
On skin, form protecting film, make the mosquito dare not be close.But, the repellant of this interpolation chemical composition is likely to result in skin
Allergy, has certain toxicity, pollutes environment etc..
The most also have plant extract as the research report of human body mosquito-repellent, such as: Flos Chrysanthemi Indici, Herba Pelargonii Graveolentis
Oil, lonicera oil, Herba Artemisiae Annuae oil, Herba Schizonepetae oil, the grey oil in mountain, retinal, wintergreen oil, Indian oil of verbena, eucalyptus citriodora oil, citronella oil, smoke clothing
Grass oil, Oleum Caryophylli etc., but the time of these mosquito-repellent effects with plant volatile oil as main component is the shortest, typically exists
1 ~ 2 hour.And single plants essential oil mosquito repellent effect is the most preferable, screening several plant quintessence oil carries out composite mosquito repelling to be had
Synergism.Permitted the light of spring etc., carried out compound plant essential oil repelling effect studying (light of spring etc. perhaps, compound plant essential oil anophelifuge
The research of effect, China's hygienic biocide medical instruments, volume 2014,20, the 3rd phase)；Chinese Patent Application No. is:
201310267797.7 patent in disclose a kind of mosquito-expelling and antipruritic floral water and preparation method thereof；Chinese Patent Application No. is:
201510747775.X patent in disclose a kind of herbaceous plant essential oil composition with repelling effect；Chinese patent application
Number it is: the patent of 201410379082.5 discloses a kind of mosquito repellent incense quintessence oil；Chinese Patent Application No. is:
201610342621.7 patent in disclose a kind of pure natural quintessence oil mosquito-driving liquid and preparation method thereof；Chinese Patent Application No.
For: disclosing one in the patent of 201210098867.6 can direct acting anophelifuge natural plant essential oil composition.
Research finds that plants essential oil mostly has sterilization or bacteriostasis to multiple pathogenic bacteria.As Mentholum external can disappear
Inflammation, pain relieving, antipruritic, expelling mosquito, blood circulation promoting, detumescence etc.；The bactericidal action of thymol is stronger than phenol, and toxicity
Low, oral cavity pharyngolaryngeal mucosa there are sterilization, fungicidal action, there are anticorrosion, local anesthetic action in dental caries chamber, for oral cavity, the disappearing of throat
Sterilization, tinea, actinomycosis and otitis.The secretion of tra cheo-oesophageal voice, beneficially tracheal mucus, Yi Qi can be promoted
Phlegm-dispelling functions, then added with bactericidal action, therefore can be used for treating tracheitis, pertussis etc..There is the strongest acaricidal action.Cubeb litsen tree essence
Oil have antidepressant, antibacterial, restrain, sterilize, flatulence of dispelling, promote galactopoiesis, parasite killing, encourage, mend body effect.
Its main component of Cera Flava Cera Flava has: acids, free fatty, free alkyl alcohol and carbohydrate.Additionally, also have
Carotenoid, vitamin A, aromatic substance etc., the additionally volatile oil containing trace and pigment, Cera Flava has in industrial and agricultural production
Have been widely used.There is removing toxic substances, sore, granulation promoting, effect of pain relieving.Being usually used in ulcer being unable to heal, ecthyma is rotten to the corn, wound ulceration,
Burn and scald.Removing toxic substances, sore, granulation promoting, pain relieving, there is faint scent.In natural composite plant mosquito-driving liquid, add Cera Flava can carry
The repelling effect of high plants essential oil, can also make the effect of the volatile slow release of plants essential oil simultaneously.
Having the active substance contained by different types of plants essential oil different, the repelling effect of single plants essential oil is undesirable,
And duration is short, the application is by means such as the compounding interpolation corrosion inhibiter to plants essential oil, it is thus achieved that a kind of antibacterial, antipruritic
Natural composite plant mosquito-driving liquid so that it is there is higher anophelifuge rate, persistent period at 10 to 12 hours.
Summary of the invention
An object of the present invention is to provide the preparation method of a kind of natural composite plant mosquito-driving liquid antibacterial, antipruritic, is
The retention time solving the existence of existing anophelifuge is short, adds the problems such as chemical insecticide, repelling effect difference.A kind of raw material is provided
Source is extensive, with low cost, repelling effect is notable, safety non-toxic, with having slow-release natural composite plant mosquito-driving liquid.
The purpose of the present invention is achieved through the following technical solutions.
The preparation method of a kind of natural composite plant mosquito-driving liquid antibacterial, antipruritic, it is characterised in that the method has following work
Skill step:
(1) A liquid preparation: be placed in reactor by Cera Flava, adds dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, and stirring reaction 2 is little
Time, it is cooled to room temperature, places 36 hours, being made into quality concentration expressed in percentage by volume is 5 ~ 10% ethanol solution, is filtered to remove insoluble matter, filter
Liquid is A liquid, standby；
(2) B liquid preparation: Mentholum and thymol are dissolved in dehydrated alcohol, are made into quality concentration expressed in percentage by volume, containing Herba Menthae
Brain: 2 ~ 5%, thymol: the ethanol solution of 0.15 ~ 0.5%, room temperature is placed 24 hours, is obtained B liquid, standby；
(3) C liquid preparation: in the reactor, is added by following composition concentration expressed in percentage by volume and order, Oleum Pelargonii Graveolentis: 22 ~ 26%, Cortex Cinnamomi
Oil: 22 ~ 26%, eucalyptus citriodora oil: 18 ~ 23%, Oleum menthae: 15 ~ 20%, Herba Artemisiae Annuae oil: 6 ~ 10%, Litsea cubeba oil: 6 ~ 10%, each component it
With for absolutely, stirring and evenly mixing, obtain C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, by A liquid: B liquid: C: the body of Arlacel-60 liquid
Long-pending ratio mixes for 1:1:1:0.1 ~ 0.15 ratio, and after mix homogeneously, it is antibacterial, antipruritic natural multiple for obtaining yellow transparent liquid
Close Botanical mosquito repellent, stand overnight, be distributed in container.
It is optimum in the mass ratio of the Mentholum described in step (2) and thymol at 10:1.
It is plant extract in the Mentholum described in step (2) and thymol.
It is plant in the Oleum Pelargonii Graveolentis described in step (3), Oleum Cinnamomi, eucalyptus citriodora oil, Oleum menthae, Herba Artemisiae Annuae oil, Litsea cubeba oil
Extract.
Using method: natural composite plant mosquito-driving liquid antibacterial, antipruritic can directly be smeared or be sprayed on human body skin.
The present invention compared with the prior art, has the advantage that and beneficial effect:
(1) present invention obtain antibacterial, antipruritic natural composite plant mosquito-driving liquid be use natural plant essential oils be main component, no
Containing chemical insecticide, environmental protection, safety non-toxic, having good mosquito repellent function, repelling effect is averagely more than 90%；
(2) antibacterial, the antipruritic natural composite plant mosquito-driving liquid that the present invention obtains can directly smear or be sprayed at human body skin when using
On skin, natural essential oil compositions gives out nature fragrant, and thymol has bactericidal action, and has antibacterial, antipruritic, skin moistening
Deng effect, human body is had no side effect, easy to use；
(3) present invention obtain antibacterial, antipruritic natural composite plant mosquito-driving liquid owing to the addition of Cera Flava, crazy in containing acids,
Free fatty, free alkyl alcohol and carbohydrate have slow releasing function to plants essential oil so that it is anophelifuge retention time is long, holds
The continuous time was at 10 to 12 hours.
Detailed description of the invention
Embodiment 1
(1) A liquid preparation: be placed in reactor by 8g Cera Flava, adds 100mL dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, stirring
Reacting 2 hours, be cooled to room temperature, place 36 hours, be filtered to remove insoluble matter, filtrate is A liquid, standby；
(2) B liquid preparation: 4g Mentholum and 0.4g thymol are dissolved in 100mL dehydrated alcohol, room temperature is placed 24 hours,
Obtain B liquid, standby；
(3) C liquid preparation: in the reactor, be separately added into, Oleum Pelargonii Graveolentis: 24mL, Oleum Cinnamomi: 24mL, eucalyptus citriodora oil: 20mL, Herba Menthae
Oil: 18mL, Herba Artemisiae Annuae oil: 7mL, Litsea cubeba oil: 7mL, stirring and evenly mixing, obtains C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, is separately added into A liquid: 100mL, B liquid:
100mL, C:100mL, Arlacel-60: 10mL, after mix homogeneously, obtaining yellow transparent liquid is natural composite plant antibacterial, antipruritic
Mosquito-driving liquid, stands overnight, and is distributed in container.
Embodiment 2
(1) A liquid preparation: be placed in reactor by 10g Cera Flava, adds 100mL dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, stirring
Reacting 2 hours, be cooled to room temperature, place 36 hours, be filtered to remove insoluble matter, filtrate is A liquid, standby；
(2) B liquid preparation: 5g Mentholum and 0.5g thymol are dissolved in 100mL dehydrated alcohol, room temperature is placed 24 hours,
Obtain B liquid, standby；
(3) C liquid preparation: in the reactor, be separately added into, Oleum Pelargonii Graveolentis: 25mL, Oleum Cinnamomi: 26mL, eucalyptus citriodora oil: 15mL, Herba Menthae
Oil: 20mL, Herba Artemisiae Annuae oil: 6mL, Litsea cubeba oil: 10mL, stirring and evenly mixing, obtains C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, is separately added into A liquid: 50mL, B liquid:
50mL, C:50mL, Arlacel-60: 6mL, after mix homogeneously, obtaining yellow transparent liquid is that natural composite plant antibacterial, antipruritic drives
Mosquito liquid, stands overnight, and is distributed in container.
Embodiment 3
(1) A liquid preparation: be placed in reactor by 5g Cera Flava, adds 100mL dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, stirring
Reacting 2 hours, be cooled to room temperature, place 36 hours, be filtered to remove insoluble matter, filtrate is A liquid, standby；
(2) B liquid preparation: 3g Mentholum and 0.3g thymol are dissolved in 100mL dehydrated alcohol, room temperature is placed 24 hours,
Obtain B liquid, standby；
(3) C liquid preparation: in the reactor, be separately added into, Oleum Pelargonii Graveolentis: 22mL, Oleum Cinnamomi: 22mL, eucalyptus citriodora oil: 23mL, Herba Menthae
Oil: 15mL, Herba Artemisiae Annuae oil: 10mL, Litsea cubeba oil: 8mL, stirring and evenly mixing, obtains C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, is separately added into A liquid: 100mL, B liquid:
100mL, C:100mL, Arlacel-60: 15mL, after mix homogeneously, obtaining yellow transparent liquid is natural composite plant antibacterial, antipruritic
Mosquito-driving liquid, stands overnight, and is distributed in container.
Embodiment 4
(1) A liquid preparation: be placed in reactor by 7g Cera Flava, adds 100mL dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, stirring
Reacting 2 hours, be cooled to room temperature, place 36 hours, be filtered to remove insoluble matter, filtrate is A liquid, standby；
(2) B liquid preparation: 2g Mentholum and 0.2g thymol are dissolved in 100mL dehydrated alcohol, room temperature is placed 24 hours,
Obtain B liquid, standby；
(3) C liquid preparation: in the reactor, be separately added into, Oleum Pelargonii Graveolentis: 26mL, Oleum Cinnamomi: 25mL, eucalyptus citriodora oil: 18mL, Herba Menthae
Oil: 17mL, Herba Artemisiae Annuae oil: 8mL, Litsea cubeba oil: 6mL, stirring and evenly mixing, obtains C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, is separately added into A liquid: 100mL, B liquid:
100mL, C:100mL, Arlacel-60: 11mL, after mix homogeneously, obtaining yellow transparent liquid is natural composite plant antibacterial, antipruritic
Mosquito-driving liquid, stands overnight, and is distributed in container.
Embodiment 5
(1) A liquid preparation: be placed in reactor by 9g Cera Flava, adds 100mL dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, stirring
Reacting 2 hours, be cooled to room temperature, place 36 hours, be filtered to remove insoluble matter, filtrate is A liquid, standby；
(2) B liquid preparation: 3.5g Mentholum and 0.15g thymol being dissolved in 100mL dehydrated alcohol, it is little that room temperature places 24
Time, obtain B liquid, standby；
(3) C liquid preparation: in the reactor, be separately added into, Oleum Pelargonii Graveolentis: 23mL, Oleum Cinnamomi: 23mL, eucalyptus citriodora oil: 17mL, Herba Menthae
Oil: 18mL, Herba Artemisiae Annuae oil: 9mL, Litsea cubeba oil: 9mL, stirring and evenly mixing, obtains C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, is separately added into A liquid: 100mL, B liquid:
100mL, C:100mL, Arlacel-60: 13mL, after mix homogeneously, obtaining yellow transparent liquid is natural composite plant antibacterial, antipruritic
Mosquito-driving liquid, stands overnight, and is distributed in container.
Using method: a kind of natural composite plant mosquito-driving liquid antibacterial, antipruritic can directly be smeared or be sprayed at human body when using
On skin, natural essential oil compositions gives out nature fragrant, and has the effects such as antibacterial, detumescence, long-acting, anophelifuge, to human body
Have no side effect, easy to use；Persistent period, repelling effect was averagely more than 90% at 10 to 12 hours.
Claims (5)
1. the preparation method of a natural composite plant mosquito-driving liquid antibacterial, antipruritic, it is characterised in that the method has following technique
Step:
(1) A liquid preparation: be placed in reactor by Cera Flava, adds dehydrated alcohol, heating in water bath to 60 ± 2 DEG C, and stirring reaction 2 is little
Time, it is cooled to room temperature, places 36 hours, being made into quality concentration expressed in percentage by volume is 5 ~ 10% ethanol solution, is filtered to remove insoluble matter, filter
Liquid is A liquid, standby；
(2) B liquid preparation: Mentholum and thymol are dissolved in dehydrated alcohol, are made into quality concentration expressed in percentage by volume, containing Herba Menthae
Brain: 2 ~ 5%, thymol: the ethanol solution of 0.15 ~ 0.5%, room temperature is placed 24 hours, is obtained B liquid, standby；
(3) C liquid preparation: in the reactor, is added by following composition concentration expressed in percentage by volume and order, Oleum Pelargonii Graveolentis: 22 ~ 26%, Cortex Cinnamomi
Oil: 22 ~ 26%, eucalyptus citriodora oil: 18 ~ 23%, Oleum menthae: 15 ~ 20%, Herba Artemisiae Annuae oil: 6 ~ 10%, Litsea cubeba oil: 6 ~ 10%, each component it
With for absolutely, stirring and evenly mixing, obtain C liquid；
(4) preparation of natural composite plant mosquito-driving liquid antibacterial, antipruritic: in the reactor, by A liquid: B liquid: C: the body of Arlacel-60 liquid
Long-pending ratio mixes for 1:1:1:0.1 ~ 0.15 ratio, and after mix homogeneously, it is antibacterial, antipruritic natural multiple for obtaining yellow transparent liquid
Close Botanical mosquito repellent, stand overnight, be distributed in container.
2., according to the preparation method of a kind of antibacterial, the antipruritic natural composite plant mosquito-driving liquid described in claim 1, its feature exists
In, Mentholum and the mass ratio of thymol described in step (2) are optimum at 10:1.
3., according to the preparation method of a kind of antibacterial, the antipruritic natural composite plant mosquito-driving liquid described in claim 1, its feature exists
In, Mentholum and thymol described in step (2) are plant extract.
4., according to the preparation method of a kind of antibacterial, the antipruritic natural composite plant mosquito-driving liquid described in claim 1, its feature exists
In, the Oleum Pelargonii Graveolentis described in step (3), Oleum Cinnamomi, eucalyptus citriodora oil, Oleum menthae, Herba Artemisiae Annuae oil, Litsea cubeba oil are plant extract.
5. according to prepared by the preparation method of a kind of antibacterial, the antipruritic natural composite plant mosquito-driving liquid described in claim 1
Natural composite plant mosquito-driving liquid antibacterial, antipruritic.
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| CN107260593A (en) * | 2017-05-27 | 2017-10-20 | 江西科技师范大学 | Compound pair of wormwood artemisia mosquito repellent liquid and preparation method thereof of external application |
| CN107518012A (en) * | 2017-09-06 | 2017-12-29 | 杨俊奇 | A kind of efficient mosquito repelling Chinese medicine compound prescription essential oil |
| CN112043629A (en) * | 2020-09-29 | 2020-12-08 | 湛江市丰睿香料有限公司 | Plant essential oil itching-relieving mosquito-repellent liquid |
| CN112999120A (en) * | 2021-03-26 | 2021-06-22 | 福建宸润生物科技有限公司 | Composition for repelling mosquitoes and relieving itching of children and preparation method thereof |
| CN116268012A (en) * | 2022-12-21 | 2023-06-23 | 西藏纽伟仕生物科技有限公司 | Natural plant essential oil mosquito-repellent spray and preparation method thereof |
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| CN104824046A (en) * | 2014-02-12 | 2015-08-12 | 上海中华药业有限公司 | Natural mosquito-repellent aromatic plant essential oil composition and preparation method thereof |
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| CN112999120A (en) * | 2021-03-26 | 2021-06-22 | 福建宸润生物科技有限公司 | Composition for repelling mosquitoes and relieving itching of children and preparation method thereof |
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