CN106242118A - Boracic treatment of Phosphorus Containing Waste Water system - Google Patents

Boracic treatment of Phosphorus Containing Waste Water system Download PDF

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Publication number
CN106242118A
CN106242118A CN201610786120.8A CN201610786120A CN106242118A CN 106242118 A CN106242118 A CN 106242118A CN 201610786120 A CN201610786120 A CN 201610786120A CN 106242118 A CN106242118 A CN 106242118A
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CN
China
Prior art keywords
waste water
treatment
tank
boracic
phosphorus containing
Prior art date
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Pending
Application number
CN201610786120.8A
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Chinese (zh)
Inventor
张志�
刘鹏飞
匡波
范云良
王亮亮
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Shanghai Jiaotong University
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Shanghai Jiaotong University
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Publication date
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Priority to CN201610786120.8A priority Critical patent/CN106242118A/en
Publication of CN106242118A publication Critical patent/CN106242118A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/108Boron compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention provides a kind of boracic treatment of Phosphorus Containing Waste Water system, including: regulating reservoir, coagulating tank, sedimentation tank, sludge concentration tank, filtration system;Waste water enters sedimentation tank after sequentially passing through regulating reservoir, coagulating tank, and the supernatant of sedimentation tank is delivered to filtration system and filters, and lower floor's mud of sedimentation tank is delivered to sludge concentration tank and carries out concentration;Filtration system is by the waste water discharge through filtering and meet discharge standard.Waste Water Treatment in the present invention passes through regulating reservoir, coagulating tank, sedimentation tank, sludge concentration tank, filtration system etc., it is achieved the quick process carrying out waste water so that the waste water after process reaches discharge standard;Being monitored the processing procedure of whole waste water additionally, the present invention is also provided with robot control system(RCS), automaticity is high, and system stability is reliable.

Description

Boracic treatment of Phosphorus Containing Waste Water system
Technical field
The present invention relates to technical field of sewage, in particular it relates to a kind of boracic treatment of Phosphorus Containing Waste Water system.
Background technology
Major pollutants in industrial wastewater are boric acid, and boron is one of required element of organism, but there are some researches show, high The boron of content has negative effect to the reproductive function of animal;The boron mass concentration irrigation water higher than 0.3-0.5mg/L is to some agriculture Crop also has certain toxicity.In the sanitary standard for drinking water of China, boron is as unconventional index, and its limit value is 0.5mg/ L。
Similar with boron, phosphorus is one of main nutrient elements needed for plant growth, but in water body, phosphorus mass concentration exceedes 20mg/L will accelerate algal grown in water, consumes oxygen in water, causes body eutrophication, water quality deterioration.If by height The boracic phosphorus-containing wastewater of concentration directly discharges, and natural water necessarily causes certain pollution.Accordingly, it would be desirable to the most effectively give up Water processes so that and limit value that boric acid and phosphate concentration specify less than integrated wastewater discharge standard (in terms of B and P, respectively 5mg/ L, 1mg/L), the most just can discharge.
Summary of the invention
For defect of the prior art, it is an object of the invention to provide a kind of boracic treatment of Phosphorus Containing Waste Water system.
The boracic treatment of Phosphorus Containing Waste Water system provided according to the present invention, including: regulating reservoir, coagulating tank, sedimentation tank, dirt Mud thickener, filtration system;Waste water enters sedimentation tank, the supernatant of sedimentation tank after sequentially passing through regulating reservoir, coagulating tank Being delivered to filtration system filter, lower floor's mud of sedimentation tank is delivered to sludge concentration tank and carries out concentration;Filtration system By the waste water discharge through filtering and meet discharge standard.
Preferably, described filtration system includes: sand filtering device, ultrafiltration apparatus and reverse osmosis unit, the upper strata of sedimentation tank Clear liquid sequentially passes through: enters reverse osmosis unit after sand filtering device, ultrafiltration apparatus, and is discharged treated giving up by reverse osmosis unit Water.
Preferably, described sand filtering device includes: more medium filter, active carbon filter.
Preferably, described sedimentation tank is: tube settler, and the lower section of inclined tube is provided with the drainage system of inverted cone;Tiltedly The supernatant of pipe sedimentation tank is delivered to filtration system by pipeline, the drain by inverted cone of the lower floor's mud of tube settler Device imports sludge concentration tank.
Preferably, described boracic treatment of Phosphorus Containing Waste Water system also includes: robot control system(RCS), and described robot control system(RCS) is used for controlling to give up The whole process that water processes;Described robot control system(RCS) includes: data processing module, water level detecting sensor, excessively stream/overload/short circuit Protection module, fault alarm module and multiple control valve.
Preferably, described water level detecting sensor, for monitoring the water level in regulating reservoir, and send monitoring signal to data Processing module, is controlled closedown and the unlatching of intake pump by data processing module;When the water level of regulating reservoir is less than lower threshold, close Close intake pump;When the water level of regulating reservoir is higher than lower threshold, open intake pump;When the water level of regulating reservoir is higher than upper limit threshold, When i.e. rising above the warning line, send alarm signal.
Preferably, described crossing stream/overload/short circuit protection module, for when crossing stream/overload/short-circuit conditions, cut-out is electric Source, the safety of protection Waste Water Treatment electrical equipment;
Described data processing module, for the monitoring letter to water level detecting sensor, excessively stream/overload/short circuit protection module Number it is analyzed processing, controls intake pump and the closedown of multiple control valve and unlatching;
Described fault alarm module, for carrying out alarm to fault.Compared with prior art, the present invention has as follows Beneficial effect:
1, the boracic treatment of Phosphorus Containing Waste Water system that the present invention provides is by regulating reservoir, coagulating tank, and sedimentation tank, mud are dense Contracting pond, filtration system etc., it is achieved the quick process that waste water is carried out so that the waste water after process reaches discharge standard;Additionally, this Invention is also provided with robot control system(RCS) and is monitored the processing procedure of whole waste water, and automaticity is high, and system stability is reliable.
2, the sedimentation tank in the present invention uses tube settler, and the lower section of inclined tube is provided with the drainage system of inverted cone; Make waste water can active layered, and base sludge is imported in time sludge concentration tank, whole apparatus structure is simple, layering effect The best.
Accompanying drawing explanation
By the detailed description non-limiting example made with reference to the following drawings of reading, the further feature of the present invention, Purpose and advantage will become more apparent upon:
The wastewater treatment process schematic diagram of the boracic treatment of Phosphorus Containing Waste Water system that Fig. 1 provides for the present invention;
The structural representation of the boracic treatment of Phosphorus Containing Waste Water system that Fig. 2 provides for the present invention;
Fig. 3 is the structural representation in Fig. 2 after the amplification of RO system.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following example will assist in the technology of this area Personnel are further appreciated by the present invention, but limit the present invention the most in any form.It should be pointed out that, the ordinary skill to this area For personnel, without departing from the inventive concept of the premise, it is also possible to make some changes and improvements.These broadly fall into the present invention Protection domain.
The boracic treatment of Phosphorus Containing Waste Water system provided according to the present invention, including: regulating reservoir, coagulating tank, sedimentation tank, dirt Mud thickener, filtration system;Waste water enters sedimentation tank, the supernatant of sedimentation tank after sequentially passing through regulating reservoir, coagulating tank Being delivered to filtration system filter, lower floor's mud of sedimentation tank is delivered to sludge concentration tank and carries out concentration;Filtration system By the waste water discharge through filtering and meet discharge standard.
Described filtration system includes: sand filtering device, ultrafiltration apparatus and reverse osmosis unit, and the supernatant of sedimentation tank is successively Through: enter reverse osmosis unit after sand filtering device, ultrafiltration apparatus, and discharged treated waste water by reverse osmosis unit.
Described sand filtering device includes: more medium filter, active carbon filter.
Described sedimentation tank is: tube settler, and the lower section of inclined tube is provided with the drainage system of inverted cone;Tube settler The supernatant be delivered to filtration system by pipeline, lower floor's mud of tube settler is imported by the drainage system of inverted cone Sludge concentration tank.
Described boracic treatment of Phosphorus Containing Waste Water system also includes: robot control system(RCS), and described robot control system(RCS) is used for controlling waste water and processes Whole process;Described robot control system(RCS) includes: data processing module, water level detecting sensor, excessively stream/overload/short-circuit protection mould Block, fault alarm module and multiple control valve;
Described water level detecting sensor, for monitoring the water level in regulating reservoir, and sends monitoring signal and processes mould to data Block, is controlled closedown and the unlatching of intake pump by data processing module;When the water level of regulating reservoir is less than lower threshold, close water inlet Pump;When the water level of regulating reservoir is higher than lower threshold, open intake pump;When the water level of regulating reservoir is higher than upper limit threshold, i.e. exceed During warning line, send alarm signal;
Described cross stream/overload/short circuit protection module, for cross stream/overload/short-circuit conditions time, cut off the electricity supply, protect give up The safety of water treatment system electrical equipment;
Described data processing module, for the monitoring letter to water level detecting sensor, excessively stream/overload/short circuit protection module Number it is analyzed processing, controls intake pump and the closedown of multiple control valve and unlatching;
Described fault alarm module, for carrying out alarm to fault.
Such as: about boron mass concentration 18300mg/L;Sodium phosphate, concentration is the waste water of about 6000mg/L, the waste water water yield For 20t/d.The limit value that the target that waste water processes is boric acid and phosphate concentration to be specified less than integrated wastewater discharge standard is (with B and P Meter, respectively 5mg/L, 1mg/L).
Influent waste water water quality is as shown in table 1:
Table 1 designs influent quality leading indicator catalog
After process, water outlet will be emitted into municipal wastewater and process pipe network, according to " Shanghai City integrated wastewater discharge standard " (DB31/ 199-1997) primary standard, determines that sewage discharge index is as shown in table 2.
Table 2 designs effluent quality leading indicator catalog
Note: in bracket, numerical value is water temperature Con trolling index when being less than 12 DEG C.
Further, as in figure 2 it is shown, a kind of Waste Water Treatment, including: regulating reservoir, coagulating tank, sloping plate deposition Pond, sludge concentration tank, sand filtration, ultrafiltration, reverse osmosis unit and robot control system(RCS).Wherein:
Coagulating tank
Dischargeable capacity: 1m3;
Peaking variation factor: 1.2 times;
The time of staying: 15min;
Material: PP material
Major function: coagulating water sample mesoboric acid, sodium phosphate.
Inclined-plate clarifying basin
Material: carbon steel anticorrosion, containing inclined tube filler;
Model: 1500*1000*2000mm;
Quantity: 1;
Major function: mud-water separation.
Sand filtration+whole process equipment of ultrafiltration+reverse osmosis one
Sand filter+automatic multi-path valve: model 18 " × 65 ";
Ultrafiltration apparatus: 4040 × 3PCS;
RO system: ESPA-2 4040 × 1PCS 5;
It is mainly used in Sewage advanced treatment boron and the whole process system of phosphorus one.
Pipeline
Major function: the connection of waste water difference in functionality processing unit.
Robot control system(RCS)
This robot control system(RCS) is independent development, and main feature has:
1) possess Automatic Control and Non-follow control function;
2) intake pump stops when low water level, arrives and starts when setting high water level, sends alarm signal during super warning line;
3) be provided with stream, transship, disconnected phase, short-circuit protection, fault automatically switches and opens audible-visual annunciator;
4) whole system is reliable, and service life is long.
Above the specific embodiment of the present invention is described.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make a variety of changes within the scope of the claims or revise, this not shadow Ring the flesh and blood of the present invention.In the case of not conflicting, the feature in embodiments herein and embodiment can any phase Combination mutually.

Claims (7)

1. a boracic treatment of Phosphorus Containing Waste Water system, it is characterised in that including: regulating reservoir, coagulating tank, sedimentation tank, mud Concentration basin, filtration system;Waste water enters sedimentation tank after sequentially passing through regulating reservoir, coagulating tank, and the supernatant of sedimentation tank is defeated Delivering to filtration system filter, lower floor's mud of sedimentation tank is delivered to sludge concentration tank and carries out concentration;Filtration system will Through filtering and meet the waste water discharge of discharge standard.
Boracic treatment of Phosphorus Containing Waste Water system the most according to claim 1, it is characterised in that described filtration system includes: sand Filter device, ultrafiltration apparatus and reverse osmosis unit, the supernatant of sedimentation tank sequentially passes through: sand filtering device, ultrafiltration apparatus are laggard Enter reverse osmosis unit, and discharged treated waste water by reverse osmosis unit.
Boracic treatment of Phosphorus Containing Waste Water system the most according to claim 2, it is characterised in that described sand filtering device includes: many Medium filter, active carbon filter.
Boracic treatment of Phosphorus Containing Waste Water system the most according to claim 1, it is characterised in that described sedimentation tank is: inclined tube sinks Pond, shallow lake, and the lower section of inclined tube is provided with the drainage system of inverted cone;The supernatant of tube settler was delivered to by pipeline Filter system, lower floor's mud of tube settler imports sludge concentration tank by the drainage system of inverted cone.
Boracic treatment of Phosphorus Containing Waste Water system the most according to claim 1, it is characterised in that described boracic treatment of Phosphorus Containing Waste Water System also includes: robot control system(RCS), and described robot control system(RCS) is for controlling the whole process that waste water processes;Described robot control system(RCS) includes: Data processing module, water level detecting sensor, excessively stream/overload/short circuit protection module, fault alarm module and multiple control Valve.
Boracic treatment of Phosphorus Containing Waste Water system the most according to claim 5, it is characterised in that described water level detecting sensor, Water level in monitoring regulating reservoir, and send monitoring signal to data processing module, data processing module control intake pump Closedown and unlatching;When the water level of regulating reservoir is less than lower threshold, close intake pump;When the water level of regulating reservoir is higher than lower limit threshold During value, open intake pump;When the water level of regulating reservoir is higher than upper limit threshold, when i.e. rising above the warning line, send alarm signal.
Boracic treatment of Phosphorus Containing Waste Water system the most according to claim 5, it is characterised in that described mistake flows/overload/short circuit guarantor Protect module, for when crossing stream/overload/short-circuit conditions, cutting off the electricity supply, the safety of protection Waste Water Treatment electrical equipment;
Described data processing module, for entering water level detecting sensor, excessively the monitoring signal of stream/overload/short circuit protection module Row analyzing and processing, controls intake pump and the closedown of multiple control valve and unlatching;
Described fault alarm module, for carrying out alarm to fault.
CN201610786120.8A 2016-08-30 2016-08-30 Boracic treatment of Phosphorus Containing Waste Water system Pending CN106242118A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109368943A (en) * 2018-12-12 2019-02-22 黑龙江省九0四环境工程勘察设计院 A kind of bathing geothermal tail water combined treatment device
CN112624247A (en) * 2020-11-27 2021-04-09 南昌航空大学 Method for removing boron and phosphorus in wastewater by coupling shell powder

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11319851A (en) * 1998-05-12 1999-11-24 Nippon Light Metal Co Ltd Treatment of water containing boron and phosphorus
US20060194303A1 (en) * 2004-12-21 2006-08-31 Novozymes Biologicals, Inc. Wastewater treatment compositions
CN101597119A (en) * 2008-06-03 2009-12-09 新疆德蓝科技有限公司 Integrating technology of water supplying and saving and sewage reusing technology system in petroleum and petrochemical industry
CN101781049A (en) * 2010-03-03 2010-07-21 北京桑德环境工程有限公司 System and method for treating water recycled from straw pulp papermaking wastewater
CN102120668A (en) * 2010-09-26 2011-07-13 东南大学 Printed circuit board integrated wastewater resource utilization method
CN202144468U (en) * 2011-04-01 2012-02-15 深圳恒通源水处理科技有限公司 Fluoride-containing wastewater recycling system
CN102730871A (en) * 2011-04-01 2012-10-17 深圳恒通源水处理科技有限公司 Recycling process of fluorine-containing wastewater
CN105174580A (en) * 2015-08-25 2015-12-23 天津市华通寰昊水务科技有限公司 Desulphurization waste-water zero discharge processing system and technology
CN204897590U (en) * 2015-08-25 2015-12-23 天津市华通寰昊水务科技有限公司 Desulfurization waste water zero release processing system

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11319851A (en) * 1998-05-12 1999-11-24 Nippon Light Metal Co Ltd Treatment of water containing boron and phosphorus
US20060194303A1 (en) * 2004-12-21 2006-08-31 Novozymes Biologicals, Inc. Wastewater treatment compositions
CN101597119A (en) * 2008-06-03 2009-12-09 新疆德蓝科技有限公司 Integrating technology of water supplying and saving and sewage reusing technology system in petroleum and petrochemical industry
CN101781049A (en) * 2010-03-03 2010-07-21 北京桑德环境工程有限公司 System and method for treating water recycled from straw pulp papermaking wastewater
CN102120668A (en) * 2010-09-26 2011-07-13 东南大学 Printed circuit board integrated wastewater resource utilization method
CN202144468U (en) * 2011-04-01 2012-02-15 深圳恒通源水处理科技有限公司 Fluoride-containing wastewater recycling system
CN102730871A (en) * 2011-04-01 2012-10-17 深圳恒通源水处理科技有限公司 Recycling process of fluorine-containing wastewater
CN105174580A (en) * 2015-08-25 2015-12-23 天津市华通寰昊水务科技有限公司 Desulphurization waste-water zero discharge processing system and technology
CN204897590U (en) * 2015-08-25 2015-12-23 天津市华通寰昊水务科技有限公司 Desulfurization waste water zero release processing system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109368943A (en) * 2018-12-12 2019-02-22 黑龙江省九0四环境工程勘察设计院 A kind of bathing geothermal tail water combined treatment device
CN112624247A (en) * 2020-11-27 2021-04-09 南昌航空大学 Method for removing boron and phosphorus in wastewater by coupling shell powder

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