CN106221115A - Blooming tubing - Google Patents
Blooming tubing Download PDFInfo
- Publication number
- CN106221115A CN106221115A CN201610656070.1A CN201610656070A CN106221115A CN 106221115 A CN106221115 A CN 106221115A CN 201610656070 A CN201610656070 A CN 201610656070A CN 106221115 A CN106221115 A CN 106221115A
- Authority
- CN
- China
- Prior art keywords
- tubing
- blooming
- kinds
- mixing
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of blooming tubing, including following component: ABS, PVC, engineering plastics, MTES, methyl methacrylate, stabilizer, bulking agent, lubricant, nano material, impact modifier, cross-linking agent and antioxidant.A kind of blooming tubing that the present invention provides, this tubing has preferable physics, mechanical integrated performance, and the quality index such as its hot strength, bending strength, notch impact strength and hot modification temperature reaches the requirement of high intensity blooming winding pipe.
Description
Technical field
The present invention relates to a kind of tubing, it is more particularly related to a kind of blooming tubing.
Background technology
The many employings of blooming tubing with polyethylene (PE) as raw material, through be wound around fusion molding tubing, but this pipe
Material is as hollow spiral tube material, and its tubing intensity and toughness still do not reach requirement, and service life, also ratio was relatively low.
Tubing prepared by ABS material because of its have lightweight, impact strength is high, toughness is good and the advantage of good corrosion resistance,
It is widely used, may be used for the winding of blooming.ABS is acrylonitrile, butadiene and cinnamic terpolymer, and A represents
Acrylonitrile, B represents butadiene, and S represents styrene.ABS resin has excellent processing characteristics, and impact strength is high, but
There is the shortcomings such as inflammable, loss of properties on aging, most importantly ABS price is relatively costly, has bigger shadow to entreprise cost
Ringing, therefore, research one can reduce ABS resin usage amount, ABS tubing yield does not produce the ideal substitute of impact, is
At present the focus studied.
Summary of the invention
It is an object of the invention to solve at least the above, and provide a kind of blooming tubing, this tubing has
Preferably physics, mechanical integrated performance, the quality such as its hot strength, bending strength, notch impact strength and hot modification temperature refers to
Mark reaches the requirement of high intensity blooming winding pipe.
In order to realize according to object of the present invention and further advantage, it is provided that a kind of blooming tubing, including such as
The component of lower weight portion:
Preferably, described engineering plastics are polyformaldehyde, acrylonitrile-butadiene-styrene copolymer, Merlon and gather
The mixing of one or two or more kinds in amide.
Preferably, described bulking agent be acrylonitrile-butadiene-styrene (ABS) graft, ethylene-vinyl acetate copolymer,
Glycidyl methacrylate radiation grafting thing, styrene-maleic anhydride copolymer, polycthylene grafted thing and styrene-horse
The mixing of one or two or more kinds in maleic anhydride grafted thing.
Preferably, the chlorinity of described PVC is 54～68%, and the degree of polymerization is 800～1200.
Preferably, described stabilizer is calcium zinc stabilizer, rare-earth stabilizer, complex salt stabilizer and organic tin stabilizer
In the mixing of one or two or more kinds.
Preferably, described nano material is nano level silicon dioxide, titanium dioxide, calcium carbonate, Pulvis Talci, silica flour
With the mixing of one or two or more kinds in sea urchin roe paste powder.
Preferably, described impact modifier be ethylene propylene diene rubber, butadiene-styrene rubber, nitrile rubber, styrene-butylene-
Styrol copolymer, ethylene-vinyl acetate copolymer, acrylonitrile-butadiene-styrene copolymer, styrene-butadiene-benzene
The mixing of one or two or more kinds in ethylene copolymer and chlorinated polyethylene.
Preferably, described lubricant be OPE, Tissuemat E, high melting-point wax, octadecanol, glycerol, white oil,
The mixing of one or two or more kinds in monoglyceride, stearic acid, paraffin and stearic amide.
Preferably, described cross-linking agent is 2,5-dimethyl-2,5-di-t-butyl peroxyhexane, cumyl peroxide,
The mixing of one or two or more kinds in benzoyl peroxide and di-isopropylbenzene hydroperoxide.
The present invention at least includes following beneficial effect: the present invention is by optimization further to formula so that at ABS tubing
The course of processing can promote the dispersion of nano material, improve the mobility of ABS melt, moreover it is possible to promote hot strength and extension at break
Rate, changes ABS goods toughness low, the shortcoming that hardness is low；At compositions such as use impact modifier, resins in inventive formulation
After, the cold-bending property of the tubing produced, impact resistance all increases；By adding engineering plastics and its component being carried out
Optimized choice, prepares that anti-impact is good, fire-retardant, resistance to ag(e)ing is good, excellent in mechanical performance and the high ABS tubing of cost performance.
Part is embodied by the further advantage of the present invention, target and feature by description below, and part also will be by this
Invention research and practice and be understood by the person skilled in the art.
Detailed description of the invention
The present invention is described further below, to make those skilled in the art can be real according to this with reference to description word
Execute.
A kind of blooming tubing, including the component of following weight portion:
As one embodiment of the present invention, described engineering plastics are that polyformaldehyde, acrylonitrile-butadiene-styrene (ABS) are common
The mixing of one or two or more kinds in polymers, Merlon and polyamide.
As one embodiment of the present invention, described bulking agent be acrylonitrile-butadiene-styrene (ABS) graft, ethylene-
Acetate ethylene copolymer, glycidyl methacrylate radiation grafting thing, styrene-maleic anhydride copolymer, polyethylene connect
The mixing of one or two or more kinds in branch thing and phenylethylene-maleic anhydride graft.Described bulking agent can reduce melt polymerization
Molecular force between thing, makes strand Relative sliding and rotation, reduces intermolecular internal friction, improves mobility.With
Time at polymer melt and equipment interface, form the lubricant layer that aligns, play buffer action, reduce between the two
Friction, improves stripping result.
As one embodiment of the present invention, the chlorinity of described PVC is 54～68%, and the degree of polymerization is 800～1200.
As one embodiment of the present invention, described stabilizer is that calcium zinc stabilizer, rare-earth stabilizer, complex salt are stable
The mixing of one or two or more kinds in agent and organic tin stabilizer.Described stabilizer can shield or absorb the energy of ultraviolet,
Quenching singlet oxygen and hydroperoxide decomposition is become inert matter, makes high molecular polymer under the radiation of light, can get rid of
Or slow down photochemical reaction probability, stop or postpone the process of photoaging, thus improve weatherability.Reach to extend polyphosphazene polymer
The purpose in compound goods service life.
As one embodiment of the present invention, described nano material is nano level silicon dioxide, titanium dioxide, carbonic acid
The mixing of one or two or more kinds in calcium, Pulvis Talci, silica flour and sea urchin roe paste powder.Described nano material has the function of enhancing,
It is filled in network structure, utilizes its structure, particle diameter difference, dense packing effect, improve product strength and elastic modelling quantity.
As one embodiment of the present invention, described impact modifier is ethylene propylene diene rubber, butadiene-styrene rubber, butyronitrile rubber
Glue, styrene-butylene-styrene copolymer, ethylene-vinyl acetate copolymer, acrylonitrile-butadiene-styrene copolymer, benzene
The mixing of one or two or more kinds in ethylene-butadiene-styrene copolymer and chlorinated polyethylene.
As one embodiment of the present invention, described lubricant be OPE, Tissuemat E, high melting-point wax,
The mixing of one or two or more kinds in octadecanol, glycerol, white oil, monoglyceride, stearic acid, paraffin and stearic amide.
As one embodiment of the present invention, described cross-linking agent is 2,5-dimethyl-2,5-di-t-butyl peroxyhexane,
The mixing of one or two or more kinds in cumyl peroxide, benzoyl peroxide and di-isopropylbenzene hydroperoxide.
Table 1 lists different embodiment and the concrete component of comparative example and content thereof.
Table 1 embodiment 1～3 and the concrete component of comparative example 1～4
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| ABS | 10 | 20 | 30 | 15 | 5 | 40 | 30 |
| PVC | 5 | 10 | 15 | 7 | 3 | 10 | 15 |
| Engineering plastics | 1 | 5 | 10 | 8 | 0.5 | 15 | 0 |
| MTES | 2 | 8 | 15 | 12 | 1 | 20 | 15 |
| Methyl methacrylate | 5 | 10 | 15 | 8 | 2 | 20 | 15 |
| Stabilizer | 1 | 2 | 3 | 3 | 0.5 | 5 | 3 |
| Bulking agent | 0.1 | 0.5 | 1 | 1 | 0.05 | 3 | 1 |
| Lubricant | 1 | 1.5 | 2 | 1 | 0.5 | 5 | 2 |
| Nano material | 1 | 1.5 | 2 | 1.5 | 0.5 | 5 | 2 |
| Impact modifier | 0.1 | 0.3 | 0.6 | 0.6 | 0.05 | 1 | 0.6 |
| Cross-linking agent | 0.1 | 1.5 | 2 | 2 | 0.05 | 5 | 2 |
| Oxidant | 0 | 0.5 | 1 | 1 | 0 | 3 | 1 |
Table 2 lists embodiment 1～4 and the test result of comparative example 1～3.
Table 2 embodiment 1～4 and the test result of comparative example 1～3
Although embodiment of the present invention are disclosed as above, but it is not restricted in description and embodiment listed
Using, it can be applied to various applicable the field of the invention completely, for those skilled in the art, and can be easily
Realizing other amendment, therefore under the general concept limited without departing substantially from claim and equivalency range, the present invention does not limit
In specific details with shown here as the legend with description.
Claims (9)
1. a blooming tubing, it is characterised in that include the component of following weight portion:
2. blooming tubing as claimed in claim 1, it is characterised in that described engineering plastics are polyformaldehyde, acrylic nitrile-butadiene
The mixing of one or two or more kinds in diene-styrene copolymer, Merlon and polyamide.
3. blooming tubing as claimed in claim 1, it is characterised in that described bulking agent is acrylonitrile-butadiene-benzene second
Alkene graft, ethylene-vinyl acetate copolymer, glycidyl methacrylate radiation grafting thing, phenylethylene-maleic anhydride are common
The mixing of one or two or more kinds in polymers, polycthylene grafted thing and phenylethylene-maleic anhydride graft.
4. blooming tubing as claimed in claim 1, it is characterised in that the chlorinity of described PVC is 54～68%, polymerization
Degree is 800～1200.
5. blooming tubing as claimed in claim 1, it is characterised in that described stabilizer is that calcium zinc stabilizer, rare earth are steady
Determine the mixing of one or two or more kinds in agent, complex salt stabilizer and organic tin stabilizer.
6. blooming tubing as claimed in claim 1, it is characterised in that described nano material is nano level titanium dioxide
The mixing of one or two or more kinds in silicon, titanium dioxide, calcium carbonate, Pulvis Talci, silica flour and sea urchin roe paste powder.
7. blooming tubing as claimed in claim 1, it is characterised in that described impact modifier be ethylene propylene diene rubber,
Butadiene-styrene rubber, nitrile rubber, styrene-butylene-styrene copolymer, ethylene-vinyl acetate copolymer, acrylonitrile-butadiene-
The mixing of one or two or more kinds in styrol copolymer, styrene-butadiene-styrene and chlorinated polyethylene.
8. blooming tubing as claimed in claim 1, it is characterised in that described lubricant is OPE, poly-second
One in alkene wax, high melting-point wax, octadecanol, glycerol, white oil, monoglyceride, stearic acid, paraffin and stearic amide or two kinds with
On mixing.
9. blooming tubing as claimed in claim 1, it is characterised in that described cross-linking agent is 2,5-dimethyl-2,5-bis-
One in t-butyl-peroxyhexane, cumyl peroxide, benzoyl peroxide and di-isopropylbenzene hydroperoxide or two kinds with
On mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610656070.1A CN106221115A (en) | 2016-08-11 | 2016-08-11 | Blooming tubing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610656070.1A CN106221115A (en) | 2016-08-11 | 2016-08-11 | Blooming tubing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221115A true CN106221115A (en) | 2016-12-14 |
Family
ID=57547126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610656070.1A Pending CN106221115A (en) | 2016-08-11 | 2016-08-11 | Blooming tubing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221115A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115044146A (en) * | 2022-07-15 | 2022-09-13 | 江苏中科睿赛污染控制工程有限公司 | High-performance PVC/ABS alloy material and preparation method thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107487A (en) * | 1994-10-31 | 1995-08-30 | 南开大学 | Sanitary and flame-retardant ABS/PVC injection moulding alloy |
| CN101096448A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | Modified formula for PC-ABS resin with high surface hardness |
| CN102134366A (en) * | 2010-01-25 | 2011-07-27 | 王广武 | Polycarbonate (PC)/acrylonitrile-butadiene-styrene (ABS) or polyvinyl chloride (PVC)/ABS alloy with low linear expansion coefficient and preparation method thereof |
| CN102417671A (en) * | 2010-09-27 | 2012-04-18 | 上海远洲管业有限公司 | Preparation technology of high strength PVC non-excavation pipe fitting |
| CN102634132A (en) * | 2012-04-19 | 2012-08-15 | 新疆蓝山屯河型材有限公司 | Heat-proof PVC (polyvinyl chloride) profiled bar |
| CN102731926A (en) * | 2012-06-08 | 2012-10-17 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN102875920A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | High-gloss scratch-resistant ABS/PVC (acrylonitrile-butadiene-styrene/polyvinyl chloride) alloy and preparation method thereof |
| CN102911454A (en) * | 2012-09-24 | 2013-02-06 | 冠益实业股份有限公司 | PVC (polyvinyl chloride)/ABS (acrylonitrile butadiene styrene copolymer)/CPE (chlorinated polyethylene) pipe with high impact resistance and method for preparing same |
| CN103232648A (en) * | 2013-03-31 | 2013-08-07 | 青岛永卓真塑料制品有限公司 | High strength textile bobbin PVC/ABS alloy material |
| CN103509289A (en) * | 2013-09-30 | 2014-01-15 | 广东聚石化学股份有限公司 | Injection molding grade flame retardant PVC/ABS alloy material and preparation method thereof |
| CN104558971A (en) * | 2015-02-10 | 2015-04-29 | 苏州科胜仓储物流设备有限公司 | Anti-corrosion PVC profile for experiment table top and treatment process of anti-corrosion PVC profile |
-
2016
- 2016-08-11 CN CN201610656070.1A patent/CN106221115A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107487A (en) * | 1994-10-31 | 1995-08-30 | 南开大学 | Sanitary and flame-retardant ABS/PVC injection moulding alloy |
| CN101096448A (en) * | 2006-06-30 | 2008-01-02 | 佛山市顺德区汉达精密电子科技有限公司 | Modified formula for PC-ABS resin with high surface hardness |
| CN102134366A (en) * | 2010-01-25 | 2011-07-27 | 王广武 | Polycarbonate (PC)/acrylonitrile-butadiene-styrene (ABS) or polyvinyl chloride (PVC)/ABS alloy with low linear expansion coefficient and preparation method thereof |
| CN102417671A (en) * | 2010-09-27 | 2012-04-18 | 上海远洲管业有限公司 | Preparation technology of high strength PVC non-excavation pipe fitting |
| CN102634132A (en) * | 2012-04-19 | 2012-08-15 | 新疆蓝山屯河型材有限公司 | Heat-proof PVC (polyvinyl chloride) profiled bar |
| CN102731926A (en) * | 2012-06-08 | 2012-10-17 | 佛山市顺德区圆融新材料有限公司 | Environment-friendly low-cost composite material capable of substituting flame retardant ABS |
| CN102911454A (en) * | 2012-09-24 | 2013-02-06 | 冠益实业股份有限公司 | PVC (polyvinyl chloride)/ABS (acrylonitrile butadiene styrene copolymer)/CPE (chlorinated polyethylene) pipe with high impact resistance and method for preparing same |
| CN102875920A (en) * | 2012-10-08 | 2013-01-16 | 合肥杰事杰新材料股份有限公司 | High-gloss scratch-resistant ABS/PVC (acrylonitrile-butadiene-styrene/polyvinyl chloride) alloy and preparation method thereof |
| CN103232648A (en) * | 2013-03-31 | 2013-08-07 | 青岛永卓真塑料制品有限公司 | High strength textile bobbin PVC/ABS alloy material |
| CN103509289A (en) * | 2013-09-30 | 2014-01-15 | 广东聚石化学股份有限公司 | Injection molding grade flame retardant PVC/ABS alloy material and preparation method thereof |
| CN104558971A (en) * | 2015-02-10 | 2015-04-29 | 苏州科胜仓储物流设备有限公司 | Anti-corrosion PVC profile for experiment table top and treatment process of anti-corrosion PVC profile |
Non-Patent Citations (3)
| Title |
|---|
| 卓昌明 主编: "《塑料应用技术手册》", 31 May 2013, 机械工业出版社 * |
| 吴培熙 等编著: "《塑料制品生产工艺手册》", 31 October 2004, 化学工业出版社 * |
| 齐贵亮 编著: "《塑料改性配方工艺速查360例》", 31 January 2016, 文化发展出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115044146A (en) * | 2022-07-15 | 2022-09-13 | 江苏中科睿赛污染控制工程有限公司 | High-performance PVC/ABS alloy material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103030917B (en) | Cracking-resistant thermoplastic low-smoke halogen-free flame-retardant polyolefin cable material | |
| CN103421240B (en) | The square single-wall corrugated pipe material of a kind of electric power | |
| US20110094772A1 (en) | Method for producing water tree-resistant, trxlpe-type cable sheath | |
| CN107082977A (en) | A kind of high-impact high fluidity PVC injected plastics materials formula and preparation method thereof | |
| CN106609000A (en) | Polyethylene combination, preparation method thereof and modified crosslinked polyethylene | |
| CN105153528B (en) | A kind of soft, wear-resisting cross-linking radiation environment-friendly polyolefin CABLE MATERIALS and preparation method thereof | |
| CN102585338A (en) | Anti-wear halogen-free flame-retardant cable material | |
| CN106604965B (en) | Polyacetal resin composite and sliding component | |
| CN107236166A (en) | Preparation technology for LSZH heat proof cable material | |
| CN102276913A (en) | Polypropylene material for MPP (modified polypropylene) jacking pipe | |
| CN101029154A (en) | Halogen free flame retardant resin composition and wire cable using same | |
| CN106317668B (en) | A kind of acrylate resin composition and preparation method thereof of high petrol-resistance | |
| Ahmed et al. | Effects of electron beam irradiation and multi-functional monomer/co-agents on the mechanical and thermal properties of ethylene-vinyl acetate copolymer/polyamide blends | |
| KR101439382B1 (en) | Nontoxic Synthetic Resin Composition Having Improved Impact Resistance, Synthetic Resin Pipe Using the Composition and manufacturing method thereof | |
| CN106221115A (en) | Blooming tubing | |
| CN108610763A (en) | A kind of polyethylene powder coating and preparation method thereof of plastic-coated composite pipe high adhesion force and good leveling property | |
| CN102153830B (en) | ACS (acrylonitrile-chlorinated polyethylene-styrene) resin composition and method for preparing same | |
| JP2017014447A (en) | Pc/abs resin composition and resin molded article | |
| CN104804356B (en) | A kind of flame-retardant and anti-static composition and preparation method thereof | |
| CN107418038A (en) | Electric cable with large cross-section resistance to cracking low-smoke halogen-free polyolefin protective cover material and preparation method thereof | |
| CN110283387A (en) | A kind of PP/HDPE furniture composite material and preparation method | |
| JP2021515831A (en) | A core-shell copolymer, a method for producing the same, and a thermoplastic resin composition containing the same. | |
| CN104177804B (en) | A kind of PC anti-stress cracking agent, preparation method and its usage | |
| JP6684434B2 (en) | ABS resin composition and resin molded product | |
| CN109161118A (en) | A kind of acrylate resin composition of strong weatherability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161214 |