CN106219516A - A kind of method that solution left standstill method prepares oriented alignment single armed CNT - Google Patents
A kind of method that solution left standstill method prepares oriented alignment single armed CNT Download PDFInfo
- Publication number
- CN106219516A CN106219516A CN201610604496.2A CN201610604496A CN106219516A CN 106219516 A CN106219516 A CN 106219516A CN 201610604496 A CN201610604496 A CN 201610604496A CN 106219516 A CN106219516 A CN 106219516A
- Authority
- CN
- China
- Prior art keywords
- swcn
- solution
- left standstill
- oriented alignment
- solution left
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
- B82B3/0061—Methods for manipulating nanostructures
- B82B3/0066—Orienting nanostructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
Abstract
The invention discloses a kind of method that solution left standstill method prepares oriented alignment SWCN, by surface is rested on SWCN with the substrate tilting of parallel pole, in colloidal liquid that deionized water, surfactant, organic polymer are mixed to prepare, owing to parallel pole enables CNT oriented alignment between parallel pole to the dimensional effect of CNT.This method is compared traditional chemical vapour deposition technique and is prepared aligned carbon nanotube arranged vertically, simple to operate, is prepared for the CNT of horizontal orientation arrangement, can apply in scene effect pipe, field emission device and chemical sensor.
Description
Technical field
The present invention relates to function film preparation method, belong to nano film material field and field of nanometer devices, specifically relate to
And a kind of method that novel solution left standstill method prepares oriented alignment SWCN.
Background technology
Carbon nano-tube material is as a kind of new functional material enjoying various countries to pay close attention in recent years, and it has good current-carrying
The features such as transport factor and electric current transport ability, good mechanical property, good optical property make its scene effect pipe, field send out
The devices such as emitter, semiconductor probe, chemical sensor possesses good application prospect.
For many years, SWCN is silica-based owing to its good electric property and ultra-thin structure are seen as replacing
The new material of TFT.The method preparing SWCN TFT is divided into two kinds: chemical vapour deposition technique and solution Filtration.
Chuan Wang in 2009 etc. utilize solution Filtration method to be prepared for high performance SWCN TFT, and electric current density reaches
10uA/ m, on-off ratio is more than 104.(Chuan Wang etc Wafer～Scale Fabrication of Separated
Carbon Nanotube Thin～Film Transistors for Display Applications, Nano Letters,
2009,Vol.9,No.12)。
S.J Wind in 2002 etc. utilize chemical vapour deposition technique to be prepared for SWCN TFT, and electric current density reaches
2100 uA/um.(S.J Wind etc Vertical scaling of carbon nanotube field～effect
transistors using top gate electrodes, Applied physics Letters,2002,Vol.80,
No.20) but the CNT TFT for preparing of these methods is owing to the density of CNT is low and non-directional characteristic, its electrical property
Application demand can not reached.In order to solve problem above, Hyunhyub Ko etc. proposes one can allow carbon nano-tube oriented alignment
Method.And when using solution Filtration, the polymer solution of CNT is fixed in certain area coverage when film forming,
And by self-assembled film Parallel Growth on silicon chip, at silicon chip plated film again, CNT can be directional trend arrangement due to dimensional effect
(due to the length being smaller than CNT of self-assembled film).(Hyunhyub Ko etc Liquid～Crystalline
Processing of Highly Oriented Carbon Nanotube Arrays for Thin～Film
Transistors, Nano Letters, 2006, Vol.6, No.7) but this method is owing to obtaining the thin film aligned
After plated electrode again, may have residue when removing self-assembled film, affect structural behaviour, and be difficult to determine the CNT of orientation
Region, operation complexity, it is not easy to prepare intact device.
Summary of the invention
It is an object of the invention to how to overcome prepare CNT high cost, preparation is complicated, carbon nanotube concentration is too low
And the shortcoming such as do not have directionality, electric property poor, improves existing CNT and prepares method, simplify preparation method, it is thus achieved that
High performance CNT.
Proposed by the invention technical problem is that so solution: provide a kind of novel solution left standstill method preparation orientation row
The method of cloth SWCN, it is characterised in that have steps of:
(1) by SWCN, deionized water, surfactant mix homogeneously, solution 1 is obtained;
(2) in solution 1, add organic polymer, mix homogeneously, obtain black colloidal liquid, ie in solution 2;
(3) substrate tilting with parallel pole is rested in solution 2, prepare wet film；
(4), under room temperature, normal atmospheric conditions makes the thin film spontaneous nucleation in step (3), is formed in parallel with substrate and aligns
SWCN figure；
(5) unnecessary part is removed in photoetching, obtains complete aligned carbon nanotube figure.
Further, described SWCN is 1:5～10 with the mass ratio of surfactant.
Further, described SWCN is 1:10～20 with the mass ratio of organic polymer.
Further, described surfactant and organic polymer can allow SWCN be suspended in solution surface.
Described prepares environment for requirements such as general room environment, inert free gas protection, adiabatic dryings.
Described surfactant is Dodecyl trimethyl ammonium chloride, cetyl trimethylammonium bromide, dodecyl
One or more in benzene sulfonic acid sodium salt, cetyl benzenesulfonic acid sodium, preferably dodecylbenzene sodium sulfonate；
Described organic polymer is many peptides or protein, such as polystyrene Sulfonate, polyvinyl alcohol, polyvinylpyrrolidone
Deng, preferably polyvinylpyrrolidone.
Further, the thickness of described substrate does not has particular/special requirement, is provided with 300～500nm insulating barriers above it, absolutely
Being provided with the metal level of 100～300nm in edge layer, metal layer lithography goes out parallel pole.
As preferably, described insulating barrier is SiO2Insulating barrier, a length of the 0.1 of described parallel pole～5mm, electrode
Between spacing be 3～30 m.Distribution CNT in-between the electrodes can be played orientation by parallel pole figure.
Further, described step (3) tilts to stand to refer to be 3～20 ° of cultivations favoured equipped with solution 2 by substrate
In ware, and making the long limit of parallel pole horizontal by 3～20 ° of angles, in described step (3), time of repose is 24～72 little
Time.
Further, described step (1) all uses ultrasonic mixing with the mixing in step (2).
As preferably, described step (1) or step (2) can be combined with magnetic agitation while using ultrasonic mixing,
The magnetic agitation temperature of described step (1) is 60～80 DEG C, and the time is 3～6 hours, the magnetic agitation temperature of described step (2)
Being 60～80 DEG C for temperature, the time is 10～30min.
The CNT using method of the present invention to prepare, has the advantage that
A. orientating products is good, stable electrical properties, Stability Analysis of Structures, uniform, smooth；
The most first carrying out interdigital electrode, recycle the interdigital electrode orientation to CNT, whole technological operation is simple；
C. normal-temperature reaction, and to environment without particular/special requirement, equipment requirements is low, need small investment, product cost low；
D. reactant is nontoxic, does not pollutes the environment and affects health.
Accompanying drawing explanation
Fig. 1 is the inventive method flow chart；
Fig. 2 is the orientation SEM figure of SWCN between embodiment 1 products obtained therefrom parallel pole；
Fig. 3 is the non-directional SEM figure of the outer SWCN of embodiment 1 products obtained therefrom parallel pole；
Fig. 4 is the inventive method schematic diagram (cross section)；
Wherein, 1 be substrate, 2 for SiO2Insulating barrier, 3 be parallel pole, 4 for oriented alignment SWCN.
Detailed description of the invention
Below in conjunction with embodiment and accompanying drawing the present invention done and further describes:
Embodiment 1: a kind of method that solution left standstill method prepares oriented alignment SWCN, comprises the following steps:
(1) take 20mL deionized water to load in beaker, weigh CNT 15mg, weigh dodecylbenzene sodium sulfonate 100mg and add
Entering in beaker, put into magnet rotor in beaker, put into by beaker in magnetic stirrer, regulation temperature is 70 DEG C, and rotating speed is 12rad/
S, magnetic agitation 3 hours, carry out ultrasonic mixing simultaneously, make dodecylbenzene sodium sulfonate and CNT be dispersed in deionization
In water, obtain solution 1；
(2) taking polyvinylpyrrolidone 150mg and join in solution 1, regulation temperature is 70 DEG C, and rotating speed 12rad/s, magnetic force stirs
Mix 10 minutes, carry out ultrasonic mixing simultaneously, obtain black colloidal liquid, ie in solution 2；
(3) use solution left standstill method to prepare wet film, the substrate with parallel pole is rested in solution 2 with 5 ° of overturning angles and prepares
Wet film, stands crystallization in 24 hours；
(4) excess carbon nanotubes outside raceway groove is fallen in photoetching, obtains product.
Use field emission scanning electron microscope (SEM) that product is tested, obtain Fig. 2, Fig. 3, Fig. 2, Fig. 3 contrast,
Orientating products performance is good, even structure, smooth, stable.
Embodiment 2: a kind of method that solution left standstill method prepares oriented alignment SWCN, comprises the following steps:
(1) take 20mL deionized water to load in beaker, weigh CNT 15mg, weigh Dodecyl trimethyl ammonium chloride
75mg, cetyl trimethylammonium bromide 75mg add in beaker, ultrasonic mixing, make ten behenyl ammonium bromide,
Cetyl trimethylammonium bromide and CNT are dispersed in deionized water, obtain solution 1；
(2) take polystyrene Sulfonate 150mg, polyvinyl alcohol 150mg joins in solution 1, obtains black glue after ultrasonic mix homogeneously
Shape liquid, ie in solution 2；
(3) use solution left standstill method to prepare wet film, the substrate with parallel pole is rested in solution 2 with 2 ° of overturning angles and prepares
Wet film, stands crystallization in 72 hours；
(4) excess carbon nanotubes outside raceway groove is fallen in photoetching, obtains product.
Embodiment 3: a kind of method that solution left standstill method prepares oriented alignment SWCN, comprises the following steps:
(1) take 20mL deionized water to load in beaker, weigh CNT 15mg, weigh cetyl trimethylammonium bromide
40mg, dodecylbenzene sodium sulfonate 60mg add in beaker, put into magnet rotor, put into by beaker in magnetic stirrer in beaker,
Regulation temperature is 80 DEG C, and rotating speed is 12rad/s, magnetic agitation 5 hours, carries out ultrasonic mixing simultaneously, makes DBSA
Sodium and CNT are dispersed in deionized water, obtain solution 1；
(2) taking polyvinyl alcohol 200mg and join in solution 1, regulation temperature is 80 DEG C, rotating speed 12rad/s, magnetic agitation 20 points
Clock, carries out ultrasonic mixing simultaneously, obtains black colloidal liquid, ie in solution 2；
(3) use solution left standstill method to prepare wet film, the substrate with parallel pole is rested in solution 2 with 30 ° of overturning angles and makes
Standby wet film, stands crystallization in 48 hours；
(4) excess carbon nanotubes outside raceway groove is fallen in photoetching, obtains product.
Embodiment 4: a kind of method that solution left standstill method prepares oriented alignment SWCN, comprises the following steps:
(1) take 20mL deionized water to load in beaker, weigh CNT 15mg, weigh dodecylbenzene sodium sulfonate 75mg and add
Entering in beaker, put into magnet rotor in beaker, put into by beaker in magnetic stirrer, regulation temperature is 60 DEG C, and rotating speed is 12rad/
S, magnetic agitation 6 hours, carry out ultrasonic mixing simultaneously, make dodecylbenzene sodium sulfonate and CNT be dispersed in deionization
In water, obtain solution 1；
(2) taking the protein 300mg that SWCN can be allowed to be suspended in solution surface and join in solution 1, regulation temperature is
60 DEG C, rotating speed 12rad/s, magnetic agitation 30 minutes, carry out ultrasonic mixing simultaneously, obtain black colloidal liquid, ie in solution 2；
(3) use solution left standstill method to prepare wet film, the substrate with parallel pole is rested in solution 2 with 5 ° of overturning angles and prepares
Wet film, stands crystallization in 72 hours；
(4) excess carbon nanotubes outside raceway groove is fallen in photoetching, obtains product.
Embodiment 5: a kind of method that solution left standstill method prepares oriented alignment SWCN, comprises the following steps:
(1) take 20mL deionized water to load in beaker, weigh CNT 15mg, weigh dodecylbenzene sodium sulfonate 80mg and add
Enter in beaker, carry out ultrasonic mixing, make dodecylbenzene sodium sulfonate and CNT dispersed in deionized water, obtain molten
Liquid 1；
(2) take the polypeptides matter 250mg that SWCN can be allowed to be suspended in solution surface to join in solution 1, surpass
Sound mixes, and obtains black colloidal liquid, ie in solution 2；
(3) use solution left standstill method to prepare wet film, the substrate with parallel pole is rested in solution 2 with 12 ° of overturning angles and makes
Standby wet film, stands crystallization in 36 hours；
(4) excess carbon nanotubes outside raceway groove is fallen in photoetching, obtains product.
As it has been described above, only present pre-ferred embodiments, therefore appoint all without departing from this programme technology contents, according to this
Above example is made any simple change, equivalent variations and modification by bright technical spirit, all still falls within the technology of the present invention
The scope of scheme.
Claims (10)
1. the method that a solution left standstill method prepares oriented alignment SWCN, it is characterised in that comprise the following steps:
(1) by SWCN, deionized water, surfactant mix homogeneously, solution 1 is obtained;
(2) in solution 1, add organic polymer, mix homogeneously, obtain black colloidal liquid, ie in solution 2;
(3) substrate tilting with parallel pole is rested in solution 2, prepare wet film；
(4), under room temperature, normal atmospheric conditions makes the thin film spontaneous nucleation in step (3), is formed in parallel with substrate and aligns
SWCN figure；
(5) unnecessary part is removed in photoetching, obtains complete aligned carbon nanotube figure.
The method that a kind of solution left standstill method the most according to claim 1 prepares oriented alignment SWCN, its feature
It is: in described step (1), SWCN is 1:5～10 with the mass ratio of surfactant.
The method that a kind of solution left standstill method the most according to claim 1 prepares oriented alignment SWCN, its feature
It is: in described step (2), SWCN and organic polymer mass ratio are 1:10～20.
4. the side of oriented alignment SWCN is prepared according to the arbitrary described a kind of solution left standstill method of claim 1,2,3
Method, it is characterised in that: described surfactant and organic polymer can allow SWCN float over solution surface.
The method that a kind of solution left standstill method the most according to claim 4 prepares oriented alignment SWCN, its feature
It is: described surfactant is Dodecyl trimethyl ammonium chloride, cetyl trimethylammonium bromide, detergent alkylate sulphur
One or more in acid sodium, cetyl benzenesulfonic acid sodium, preferably dodecylbenzene sodium sulfonate；Described organic polymer is
Many peptides or protein, preferably polyvinylpyrrolidone.
6. the method preparing oriented alignment SWCN according to a kind of solution left standstill method described in claim 1, it is special
Levy and be: described substrate is provided above the insulating barrier of 300～500nm, insulating barrier is provided with the metal of 100～300nm
Layer, metal layer lithography goes out parallel pole figure.
The method that a kind of solution left standstill method the most according to claim 6 prepares oriented alignment SWCN, its feature
It is: described insulating barrier is SiO2Insulating barrier, described parallel pole a length of 0.1～5mm, interelectrode spacing be 3～
30 µm。
The method that a kind of solution left standstill method the most according to claim 1 prepares oriented alignment SWCN, its feature
It is: described step (3) tilts standing and refers to that will be 3～20 ° by substrate favours in the culture dish equipped with solution 2, and
Making the long limit of parallel pole horizontal by 3～20 ° of angles, time of repose is 24～72 hours.
The method that a kind of solution left standstill method the most according to claim 1 prepares oriented alignment SWCN, its feature
It is: described step (1) uses ultrasonic mixing with the mixing in step (2).
The method that a kind of solution left standstill method the most according to claim 1 prepares oriented alignment SWCN, its feature
It is: described step (1) or step (2) can be combined with magnetic agitation while using ultrasonic mixing, described step (1)
Magnetic agitation temperature is 60～80 DEG C, and the time is 3～6 hours, the magnetic agitation temperature of described step (2) be temperature be 60～80
DEG C, the time is 10～30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610604496.2A CN106219516B (en) | 2016-07-28 | 2016-07-28 | A kind of method that solution left standstill method prepares oriented alignment single-walled carbon nanotube |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610604496.2A CN106219516B (en) | 2016-07-28 | 2016-07-28 | A kind of method that solution left standstill method prepares oriented alignment single-walled carbon nanotube |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106219516A true CN106219516A (en) | 2016-12-14 |
| CN106219516B CN106219516B (en) | 2018-12-25 |
Family
ID=57533830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610604496.2A Active CN106219516B (en) | 2016-07-28 | 2016-07-28 | A kind of method that solution left standstill method prepares oriented alignment single-walled carbon nanotube |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106219516B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106904598A (en) * | 2017-04-20 | 2017-06-30 | 国家纳米科学中心 | A kind of CNT magnet and its preparation method and application |
| CN109534317A (en) * | 2017-09-21 | 2019-03-29 | 中国科学院物理研究所 | A kind of preparation method of carbon nano-tube film |
| CN109761222A (en) * | 2017-11-09 | 2019-05-17 | 北京华碳元芯电子科技有限责任公司 | The method for removing carbon nano tube surface dispersing agent using being evaporated in vacuo |
| CN110282974A (en) * | 2019-06-28 | 2019-09-27 | 华南理工大学 | Oriented alignment magnetic carbon fiber graphene composite film and its preparation method and application |
| CN114149001A (en) * | 2021-12-22 | 2022-03-08 | 浙江大学 | Preparation, transfer and orientation determination method of self-assembled carbon nanotube array for terahertz |
| CN115340085A (en) * | 2022-05-12 | 2022-11-15 | 中山大学 | Carbon nanotube film with controllable surface density and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531822A (en) * | 2009-01-06 | 2009-09-16 | 华东理工大学 | Polymer carbon nano tube compound structure and preparation method thereof |
| CN102110489A (en) * | 2010-12-24 | 2011-06-29 | 中国科学院苏州纳米技术与纳米仿生研究所 | Ultrathin film of transparent high-strength and high-conductivity electrical self-supporting carbon nano-tube and preparation method thereof |
| CN102627409A (en) * | 2011-12-14 | 2012-08-08 | 京东方科技集团股份有限公司 | Method for preparing carbon nanotube film |
| CN102634249A (en) * | 2012-04-10 | 2012-08-15 | 中国科学院苏州纳米技术与纳米仿生研究所 | Preparation method of carbon nanotube ink and preparation method of transistor device |
| CN103000816A (en) * | 2012-09-07 | 2013-03-27 | 天津工业大学 | Organic light emitting diode based on flexible carbon nanotube films |
| CN103196965A (en) * | 2013-03-18 | 2013-07-10 | 北京科技大学 | Method for preparing carbon nanotube composite conductive hydrogel coating modified electrode |
| CN105084342A (en) * | 2015-08-13 | 2015-11-25 | 海门市明阳实业有限公司 | Preparing method for carbon nano tube thin film |
-
2016
- 2016-07-28 CN CN201610604496.2A patent/CN106219516B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531822A (en) * | 2009-01-06 | 2009-09-16 | 华东理工大学 | Polymer carbon nano tube compound structure and preparation method thereof |
| CN102110489A (en) * | 2010-12-24 | 2011-06-29 | 中国科学院苏州纳米技术与纳米仿生研究所 | Ultrathin film of transparent high-strength and high-conductivity electrical self-supporting carbon nano-tube and preparation method thereof |
| CN102627409A (en) * | 2011-12-14 | 2012-08-08 | 京东方科技集团股份有限公司 | Method for preparing carbon nanotube film |
| CN102634249A (en) * | 2012-04-10 | 2012-08-15 | 中国科学院苏州纳米技术与纳米仿生研究所 | Preparation method of carbon nanotube ink and preparation method of transistor device |
| CN103000816A (en) * | 2012-09-07 | 2013-03-27 | 天津工业大学 | Organic light emitting diode based on flexible carbon nanotube films |
| CN103196965A (en) * | 2013-03-18 | 2013-07-10 | 北京科技大学 | Method for preparing carbon nanotube composite conductive hydrogel coating modified electrode |
| CN105084342A (en) * | 2015-08-13 | 2015-11-25 | 海门市明阳实业有限公司 | Preparing method for carbon nano tube thin film |
Non-Patent Citations (1)
| Title |
|---|
| HYUNHYUB KO ETC.: ""Liquid-crystalline Processing of Highly Oriented Carbon Nanotube Arrays for thin-film Transistors"", 《NANO LETTERS》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106904598A (en) * | 2017-04-20 | 2017-06-30 | 国家纳米科学中心 | A kind of CNT magnet and its preparation method and application |
| CN109534317A (en) * | 2017-09-21 | 2019-03-29 | 中国科学院物理研究所 | A kind of preparation method of carbon nano-tube film |
| CN109534317B (en) * | 2017-09-21 | 2021-11-23 | 中国科学院物理研究所 | Preparation method of carbon nanotube film |
| CN109761222A (en) * | 2017-11-09 | 2019-05-17 | 北京华碳元芯电子科技有限责任公司 | The method for removing carbon nano tube surface dispersing agent using being evaporated in vacuo |
| CN110282974A (en) * | 2019-06-28 | 2019-09-27 | 华南理工大学 | Oriented alignment magnetic carbon fiber graphene composite film and its preparation method and application |
| CN110282974B (en) * | 2019-06-28 | 2020-12-29 | 华南理工大学 | Oriented magnetic carbon fiber graphene composite membrane and preparation method and application thereof |
| CN114149001A (en) * | 2021-12-22 | 2022-03-08 | 浙江大学 | Preparation, transfer and orientation determination method of self-assembled carbon nanotube array for terahertz |
| CN115340085A (en) * | 2022-05-12 | 2022-11-15 | 中山大学 | Carbon nanotube film with controllable surface density and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106219516B (en) | 2018-12-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106219516A (en) | A kind of method that solution left standstill method prepares oriented alignment single armed CNT | |
| Xu et al. | Preparation of CdS single‐crystal nanowires by electrochemically induced deposition | |
| Yun et al. | Ferroelectric properties of individual barium titanate nanowires investigated by scanned probe microscopy | |
| Huang et al. | Oxidation rate effect on the direction of metal-assisted chemical and electrochemical etching of silicon | |
| Zheng et al. | Growth of Prussian blue microcubes under a hydrothermal condition: possible nonclassical crystallization by a mesoscale self-assembly | |
| Chen et al. | Controlling kink geometry in nanowires fabricated by alternating metal-assisted chemical etching | |
| Minelli et al. | Micrometer-long gold nanowires fabricated using block copolymer templates | |
| Samal et al. | Room-temperature chemical synthesis of silver telluride nanowires | |
| Huang et al. | Preparation and electrical properties of ultrafine Ga2O3 nanowires | |
| Martín et al. | Relaxations and relaxor-ferroelectric-like response of nanotubularly confined poly (vinylidene fluoride) | |
| KR101438184B1 (en) | Large-area Films Using Interfacial Self-assembly of Microparticles and Method Manufacturing the Same | |
| Tzeng et al. | Stacked silicon nanowires with improved field enhancement factor | |
| Bai et al. | Wafer-scale fabrication of uniform Si nanowire arrays using the Si wafer with UV/Ozone pretreatment | |
| Zheng et al. | Chemical Synthesis and Integration of Highly Conductive PdTe2 with Low‐Dimensional Semiconductors for p‐Type Transistors with Low Contact Barriers | |
| Gao et al. | Graphene Membranes for Multi‐Dimensional Electron Microscopy Imaging: Preparation, Application, and Prospect | |
| He et al. | Preparation of low dimensional antimonene oxides and their application in Cu: NiOx based planar pin perovskite solar cells | |
| Lv et al. | Well-aligned NiSi/Si heterostructured nanowire arrays as field emitters | |
| Wu et al. | Synthesis and dispersion of isolated high aspect ratio gold nanowires | |
| Ouyang et al. | Tuning Morphologies and Field-Emission Properties of CuTCNQF4 and AgTCNQF4 Nanostructures | |
| JP2006298715A (en) | Method for manufacturing carbon nanotube thin film, method for manufacturing electronic element, method for manufacturing thin film, method for manufacturing structure, and method for forming bubble | |
| Larsen et al. | Self-assembled peptide nanotubes as an etching material for the rapid fabrication of silicon wires | |
| Bai et al. | Porosification-induced back-bond weakening in chemical etching of n-Si (111) | |
| Lv et al. | Tunable field emission properties of well-aligned silicon nanowires with controlled aspect ratio and proximity | |
| Youn et al. | Vertical alignment of carbon nanotubes using the magneto-evaporation method | |
| Chen et al. | Mechanisms for formation of a one-dimensional horizontal anodic aluminum oxide nanopore array on a Si substrate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |