CN106195984B - Novel coal supercritical carbon dioxide Brayton cycle single-stage shunts electricity generation system - Google Patents

Novel coal supercritical carbon dioxide Brayton cycle single-stage shunts electricity generation system Download PDF

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Publication number
CN106195984B
CN106195984B CN201610507083.2A CN201610507083A CN106195984B CN 106195984 B CN106195984 B CN 106195984B CN 201610507083 A CN201610507083 A CN 201610507083A CN 106195984 B CN106195984 B CN 106195984B
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China
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outlet
carbon dioxide
generation system
electricity generation
supercritical carbon
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CN106195984A (en
Inventor
白文刚
李红智
姚明宇
张帆
张一帆
杨玉
王月明
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Xian Thermal Power Research Institute Co Ltd
Huaneng Group Technology Innovation Center Co Ltd
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Xian Thermal Power Research Institute Co Ltd
Huaneng Group Technology Innovation Center Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B31/00Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus
    • F22B31/08Installation of heat-exchange apparatus or of means in boilers for heating air supplied for combustion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K11/00Plants characterised by the engines being structurally combined with boilers or condensers
    • F01K11/02Plants characterised by the engines being structurally combined with boilers or condensers the engines being turbines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • F23J2215/101Nitrous oxide (N2O)

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

The invention discloses a kind of novel coal supercritical carbon dioxide Brayton cycle single-stages to shunt electricity generation system, including boiler and supercritical carbon dioxide Brayton cycle electricity generation system, boiler includes being sequentially connected logical burner hearth, horizontal flue and back-end ductwork, direction in burner hearth along flue gas circulation has been sequentially arranged water-cooling wall, wall reheater and pendant superheater, high temperature reheater is disposed in horizontal flue, direction in back-end ductwork along flue gas circulation has been sequentially arranged low-temperature reheater, secondary air preheater and main air preheater, low temperature superheater is disposed in back-end ductwork, low-temperature reheater is arranged side by side with low temperature superheater, the system can reduction exhaust gas temperature, improve the thermal efficiency of boiler and the efficiency of electricity generation system.

Description

Novel coal supercritical carbon dioxide Brayton cycle single-stage shunts electricity generation system
Technical field
The invention belongs to advanced efficient field of thermal power, it is related to a kind of novel coal supercritical carbon dioxide Bretton and follows Ring single-stage shunts electricity generation system.
Background technique
The efficiency that generating set is continuously improved is the eternal theme and target of power industry research.For electricity power enterprise Speech, the cycle efficieny of system is higher, and the energy consumption of unit generated energy is lower, and corresponding energy-output ratio and pollutant discharge amount are just It is lower.For traditional using steam Rankine cycle as the generating set of energy conversion system, if improving generating efficiency to 50% left side The right side then needs to improve main steam condition to 700 DEG C, this, which means that, needs to spend high economic cost and time cost to grind Send out nickel base superalloy novel.In order to avoid the technical bottleneck in terms of material, sight is transferred to novel dynamic by scholars one after another The power circulatory system, to realize the promotion of generating efficiency.By a large amount of early-stage study of scholars and demonstration, generally recognize at present Can supercritical carbon dioxide Brayton cycle be great potential new concept advanced power systems.This is mainly due to overcritical Carbon dioxide has the characteristics that energy density is big, heat transfer efficiency is high, supercritical carbon dioxide Brayton cycle efficient power generation system The efficiency that 700 DEG C of conventional steam Rankine cycle can be reached in 620 DEG C of temperature ranges, does not need novel high temperature nickel of redeveloping Based alloy, and equipment size is less than the steam unit of same parameter, economy is very good.
The characteristics of China's energy natural endowment, determines that coal fired power generation is still the master of China's electric structure in the following very long-term Body, therefore, exploitation novel coal supercritical carbon dioxide Brayton cycle electricity generation system meet the fundamental realities of the country in China, tool very much There is very wide application prospect.
Although being in the world public technology about supercritical carbon dioxide Brayton cycle generation technology, at present It is to be directed to the new energy such as solar energy, and be directed to tradition mostly about supercritical carbon dioxide Brayton cycle electricity generation system both at home and abroad The novel system of fossil energy, especially coal fired power generation, which rarely has, to be related to.Coal-fired supercritical carbon dioxide Brayton cycle is sent out For electric system, due to including a large amount of heat regenerative systems, boiler inlet supercritical carbon dioxide Temperature of Working in the entire circulatory system It generally will be more than 500 DEG C.For supercritical carbon dioxide boiler, if still according to the heating surface cloth of conventional vapor boiler Method is set, arranges conventional economizer in boiler tail, then temperature and pressure are small, and working medium temperature rise is usually only several to take the photograph due to conducting heat at economizer Family name's degree, so that heating surface arrangement is unreasonable, less economical.In addition, coal-fired supercritical carbon dioxide Brayton cycle electricity generation system Since working medium entrances temperature is high, boiler tail exhaust gas temperature is also higher, therefore how to reduce the row of supercritical carbon dioxide boiler Smoke temperature degree, improving boiler thermal efficiency is also the coal-fired vital technology ring of supercritical carbon dioxide Brayton cycle electricity generation system Section.
Summary of the invention
It is an object of the invention to overcome the above-mentioned prior art, a kind of overcritical titanium dioxide of novel coal is provided Carbon Brayton cycle single-stage shunt electricity generation system, the system can reduction exhaust gas temperature, improve boiler the thermal efficiency and The efficiency of electricity generation system.
In order to achieve the above objectives, novel coal supercritical carbon dioxide Brayton cycle single-stage of the present invention shunts hair Electric system includes boiler and supercritical carbon dioxide Brayton cycle electricity generation system, and boiler includes being sequentially connected logical burner hearth, water Flat flue and back-end ductwork, the interior direction along flue gas circulation of burner hearth have been sequentially arranged water-cooling wall, wall reheater and screen formula overheat Device, is disposed with high temperature reheater in horizontal flue, in back-end ductwork along the direction of flue gas circulation be sequentially arranged low-temperature reheater, Secondary air preheater and main air preheater are disposed with low temperature superheater, low-temperature reheater and low temperature mistake in back-end ductwork Hot device is arranged side by side;
The hot side outlet of cryogenic regenerator is divided into two-way in supercritical carbon dioxide Brayton cycle electricity generation system, wherein one Road is connected with the entrance of forecooler in supercritical carbon dioxide Brayton cycle electricity generation system, another way and overcritical titanium dioxide The entrance that machine is recompressed in carbon Bretton cycle generating system is connected, in supercritical carbon dioxide Brayton cycle electricity generation system The cold side outlet port of high temperature regenerator is connected with the entrance of water-cooling wall;
The outlet of water-cooling wall is connected with the entrance of low temperature superheater, the outlet of low temperature superheater and entering for pendant superheater Mouth is connected, the outlet of pendant superheater and the entrance of the high pressure turbine in supercritical carbon dioxide Brayton cycle electricity generation system It is connected;
The outlet and the entrance phase of wall reheater of supercritical carbon dioxide Brayton cycle electricity generation system mesohigh turbine Connection, the outlet of wall reheater is connected with the entrance of low-temperature reheater, the outlet of low-temperature reheater through high temperature reheater with Low pressure turbine in supercritical carbon dioxide Brayton cycle electricity generation system is connected;
The air outlet slit of main air preheater is connected with the air intake of secondary air preheater, secondary air preheating The air outlet slit of device is connected with the air intake of boiler.
Supercritical carbon dioxide Brayton cycle electricity generation system includes forecooler, main compressor, recompression machine, low temperature backheat Device, high temperature regenerator, boiler, high pressure turbine, low pressure turbine and generator;
The hot side outlet of cryogenic regenerator is divided into two-way, wherein pre-cooled device is connected with the entrance of main compressor all the way, The outlet of main compressor is connected with the cold side input port of cryogenic regenerator, and another way is connected with the entrance of recompression machine, then presses The outlet of contracting machine is connected with the cold side outlet port of cryogenic regenerator by the cold side input port of pipeline and Guan Houyu high temperature regenerator, low The outlet of pressure turbine is connected with the hot side entrance of high temperature regenerator, the hot side outlet of high temperature regenerator and the heat of cryogenic regenerator Side entrance is connected, and the output shaft of low pressure turbine is connected with the drive shaft of generator.
It there also is provided SCR denitration device in back-end ductwork, SCR denitration device is located at secondary air preheater and main air Between preheater.
The invention has the following advantages:
Novel coal supercritical carbon dioxide Brayton cycle single-stage of the present invention shunts the boiler tail of electricity generation system Main air preheater and secondary air preheater are disposed in portion's flue, flue-gas temperature is reduced to by secondary air preheater 350~400 DEG C of the preference temperature section of SCR denitration reaction, the flue gas after cooling enter SCR denitration device and carry out denitration reaction, Flue gas after completing denitration process enters back into main air preheater to exchange heat with air, and exhaust gas temperature is reduced to Certain level, on the one hand effectively on the other hand low exhaust gas temperature, raising boiler thermal efficiency can heat boiler auxiliary combustion air To 500 DEG C or more, the temperature of combustion air is improved, conducive to the kindling and burning of coal dust, while being conducive in boiler-burner region High temperature strong reducing property atmosphere is created, so that the generation of nitrogen oxides be greatly reduced, and then improves the generating efficiency of boiler. In addition, the hot side outlet of cryogenic regenerator is connected with forecooler and recompression machine import respectively, so that entire cycle generating system It is simplified.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Wherein, 1 it is forecooler, 2 be main compressor, 3 be recompression machine, 4 be cryogenic regenerator, 5 is high temperature regenerator, 6 It is high pressure turbine for boiler, 7,8 be low pressure turbine, 9 be generator, 61 be water-cooling wall, 62 be wall reheater, 63 is screen formula mistake Hot device, 64 be high temperature reheater, 65 be low-temperature reheater, 66 be low temperature superheater, 67 be secondary air preheater, 68 be SCR Denitrification apparatus, 69 are main air preheater.
Specific embodiment
The invention will be described in further detail with reference to the accompanying drawing:
With reference to Fig. 1, novel coal supercritical carbon dioxide Brayton cycle single-stage of the present invention shunts electricity generation system Including boiler 6 and supercritical carbon dioxide Brayton cycle electricity generation system, boiler 6 includes being sequentially connected logical burner hearth, horizontal cigarette Road and back-end ductwork, the interior direction along flue gas circulation of burner hearth have been sequentially arranged water-cooling wall 61, wall reheater 62 and screen formula overheat Device 63, is disposed with high temperature reheater 64 in horizontal flue, has been sequentially arranged low temperature again along the direction of flue gas circulation in back-end ductwork Hot device 65, secondary air preheater 67 and main air preheater 69 are disposed with low temperature superheater 66 in back-end ductwork, and low temperature is again Hot device 65 is arranged side by side with low temperature superheater 66;Cryogenic regenerator 4 in supercritical carbon dioxide Brayton cycle electricity generation system Hot side outlet is divided into two-way, wherein the entrance phase with forecooler 1 in supercritical carbon dioxide Brayton cycle electricity generation system all the way Connection, another way are connected with the entrance for recompressing machine 3 in supercritical carbon dioxide Brayton cycle electricity generation system, and overcritical two The cold side outlet port of carbonoxide Brayton cycle electricity generation system high temperature regenerator 5 is connected with the entrance of water-cooling wall 61;Water-cooling wall 61 outlet is connected with the entrance of low temperature superheater 66, and the outlet of low temperature superheater 66 is connected with the entrance of pendant superheater 63 It is logical, the outlet and the entrance phase of the high pressure turbine 7 in supercritical carbon dioxide Brayton cycle electricity generation system of pendant superheater 63 Connection;The outlet and the entrance phase of wall reheater 62 of supercritical carbon dioxide Brayton cycle electricity generation system mesohigh turbine 7 Connection, the outlet of wall reheater 62 is connected with the entrance of low-temperature reheater 65, the outlet of low-temperature reheater 65 through high temperature again Hot device 64 is connected with the low pressure turbine 8 in supercritical carbon dioxide Brayton cycle electricity generation system;Main air preheater 69 Air outlet slit be connected with the air intake of secondary air preheater 67, the air outlet slit and boiler of secondary air preheater 67 6 air intake is connected.
Supercritical carbon dioxide Brayton cycle electricity generation system includes forecooler 1, main compressor 2, recompression machine 3, low temperature Regenerator 4, high temperature regenerator 5, boiler 6, high pressure turbine 7, low pressure turbine 8 and generator 9;The hot side outlet of cryogenic regenerator 4 It is divided into two-way, wherein pre-cooled device 1 is connected with the entrance of main compressor 2 all the way, the outlet of main compressor 2 and cryogenic regenerator 4 cold side input port is connected, and another way is connected with the entrance of recompression machine 3, recompresses outlet and the cryogenic regenerator 4 of machine 3 Cold side outlet port is by pipeline and the cold side input port of Guan Houyu high temperature regenerator 5 is connected, the outlet of low pressure turbine 8 and high temperature return The hot side entrance of hot device 5 is connected, and the hot side outlet of high temperature regenerator 5 is connected with the hot side entrance of cryogenic regenerator 4, low pressure The output shaft of turbine 8 is connected with the drive shaft of generator 9;It there also is provided SCR denitration device 68, SCR denitration in back-end ductwork Device 68 is between secondary air preheater 67 and main air preheater 69.
Specific works engineering of the invention are as follows:
The lack of gas that 4 hot side of cryogenic regenerator comes out are divided into two parts, and a part is by entering back into master after cooling in forecooler 1 Compressor 2 boosts, and the cold side for then entering back into cryogenic regenerator 4 carries out pre-heating temperature elevation, and another part directly passes through recompression machine 3 Enter in 5 cold side of high temperature regenerator after being converged after boosting with the cold side outlet port working medium of cryogenic regenerator 4, high temperature regenerator 5 The working medium of cold side output enters in water-cooling wall 61, then successively water cooled wall 61, low temperature superheater 66 and pendant superheater again 63;Pendant superheater 6 flows out working medium and enters 7 expansion work of high pressure turbine, and the exhaust after acting is successively through wall reheater 62, low Enter low pressure turbine 8 after warm reheater 65 and high temperature reheater 64 to do work, the lack of gas of low pressure turbine 8 are followed by high temperature regenerator 4 hot side of 5 hot sides and cryogenic regenerator, for heating the Biological process after being boosted by recompression machine 3.
In order to further decrease 6 exhaust gas temperature of boiler, 6 thermal efficiency of boiler is improved, the present invention is disposed in back-end ductwork Main air preheater 69 and secondary air preheater 67, wherein the smoke temperature drop of flue gas after the heat exchange of secondary air preheater 67 As low as the preference temperature section of SCR denitration reaction, i.e., 350 DEG C~400 DEG C, the flue gas after then cooling down enters SCR denitration device 68 carry out denitration process, and the flue gas after denitration process enters in main air preheater 69 to the air entered in boiler 6 It is heated, the temperature of air after heating is made to meet hearth combustion and thermal transmission requirement.
Above-described specific embodiment has carried out further the purpose of the present invention, technical scheme and beneficial effects It is described in detail, it should be understood that being not limited to this hair the foregoing is merely a specific embodiment of the invention Bright, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the present invention Protection scope within.

Claims (1)

1. a kind of novel coal supercritical carbon dioxide Brayton cycle single-stage shunts electricity generation system, which is characterized in that including pot Furnace (6) and supercritical carbon dioxide Brayton cycle electricity generation system ontology, boiler (6) include being sequentially connected logical burner hearth, level Flue and back-end ductwork, the interior direction along flue gas circulation of burner hearth have been sequentially arranged water-cooling wall (61), wall reheater (62) and screen Formula superheater (63) is disposed with high temperature reheater (64) in horizontal flue, along the direction of flue gas circulation successively cloth in back-end ductwork It is equipped with low-temperature reheater (65), secondary air preheater (67) and main air preheater (69), is disposed in back-end ductwork low Warm superheater (66), low-temperature reheater (65) are arranged side by side with low temperature superheater (66);
The cold side outlet port of supercritical carbon dioxide Brayton cycle electricity generation system ontology high temperature regenerator (5) and water-cooling wall (61) Entrance be connected;
The outlet of water-cooling wall (61) is connected with the entrance of low temperature superheater (66), the outlet and screen formula mistake of low temperature superheater (66) The entrance of hot device (63) is connected, the outlet and supercritical carbon dioxide Brayton cycle electricity generation system sheet of pendant superheater (63) The entrance of high pressure turbine (7) in body is connected;
The outlet of supercritical carbon dioxide Brayton cycle electricity generation system ontology mesohigh turbine (7) and wall reheater (62) Entrance is connected, and the outlet of wall reheater (62) is connected with the entrance of low-temperature reheater (65), low-temperature reheater (65) Outlet is connected through high temperature reheater (64) with the low pressure turbine (8) in supercritical carbon dioxide Brayton cycle electricity generation system ontology It is logical;
The air outlet slit of main air preheater (69) is connected with the air intake of secondary air preheater (67), secondary air The air outlet slit of preheater (67) is connected with the air intake of boiler (6);
Supercritical carbon dioxide Brayton cycle electricity generation system ontology includes forecooler (1), main compressor (2), recompression machine (3), cryogenic regenerator (4), high temperature regenerator (5), high pressure turbine (7), low pressure turbine (8) and generator (9);
The hot side outlet of cryogenic regenerator (4) is divided into two-way, wherein the entrance phase of pre-cooled device (1) and main compressor (2) all the way Connection, the outlet of main compressor (2) are connected with the cold side input port of cryogenic regenerator (4), and another way enters with recompression machine (3) Mouth is connected, and the cold side outlet port of the outlet and cryogenic regenerator (4) that recompress machine (3) passes through pipeline and Guan Houyu high temperature regenerator (5) cold side input port is connected, and the outlet of low pressure turbine (8) is connected with the hot side entrance of high temperature regenerator (5), high temperature backheat The hot side outlet of device (5) is connected with the hot side entrance of cryogenic regenerator (4), the output shaft of low pressure turbine (8) and generator (9) Drive shaft be connected;
There also is provided in back-end ductwork SCR denitration device (68), SCR denitration device (68) be located at secondary air preheater (67) with Between main air preheater (69).
CN201610507083.2A 2016-06-30 2016-06-30 Novel coal supercritical carbon dioxide Brayton cycle single-stage shunts electricity generation system Active CN106195984B (en)

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CN107420931B (en) * 2017-08-25 2023-04-25 西安热工研究院有限公司 Method and system for quality-classified and stage-classified utilization of flue gas energy and working medium energy generated by coal-fired supercritical carbon dioxide power generation
CN108613170A (en) * 2018-03-14 2018-10-02 西安交通大学 A kind of supercritical carbon dioxide coal generating system and operation method
CN110080848B (en) * 2019-05-08 2024-02-02 上海发电设备成套设计研究院有限责任公司 Supercritical carbon dioxide circulating coal-fired power generation system
CN110230523B (en) * 2019-07-01 2023-10-17 西安热工研究院有限公司 Supercritical CO2 power generation system and method for coupling seawater desalination
CN111810260B (en) * 2020-06-30 2021-10-22 上海发电设备成套设计研究院有限责任公司 Supercritical carbon dioxide split-flow recompression cycle power generation system
CN114592971B (en) * 2022-03-30 2024-01-19 西安热工研究院有限公司 Biomass micro-combustion engine and supercritical carbon dioxide coupling power generation system and method

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JP2000154733A (en) * 1998-11-19 2000-06-06 Mitsubishi Heavy Ind Ltd Closed brayton cycle gas turbine device
CN104728823B (en) * 2015-03-17 2016-08-03 西安热工研究院有限公司 A kind of Novel supercritical carbon dioxide coal-burning boiler
CN104832229A (en) * 2015-04-29 2015-08-12 南京瑞柯徕姆环保科技有限公司 Britten-organic Rankine type solar thermal power generation method and device
CN105526576B (en) * 2016-01-20 2017-11-17 西安热工研究院有限公司 A kind of coal base supercritical carbon dioxide Brayton cycle double split flow efficient power generation system

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