CN106192377A - 一种防霉防蛀帆布帐篷面料及其制备方法 - Google Patents
一种防霉防蛀帆布帐篷面料及其制备方法 Download PDFInfo
- Publication number
- CN106192377A CN106192377A CN201610680575.1A CN201610680575A CN106192377A CN 106192377 A CN106192377 A CN 106192377A CN 201610680575 A CN201610680575 A CN 201610680575A CN 106192377 A CN106192377 A CN 106192377A
- Authority
- CN
- China
- Prior art keywords
- mould
- moth
- canvas
- colloidal sol
- tent fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/1845—Aromatic mono- or polycarboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/236—Esters of carboxylic acids; Esters of carbonic acid containing halogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
本发明公开了一种防霉防蛀帆布帐篷面料,其是由下述重量份的原料制得:涤纶纤维30‑40,竹炭纤维10‑15,***纤维10‑15,硅藻土3‑5,苯丙乳液5‑10,十二烷基三甲基氯化铵0.2‑0.4,月桂酸单甘油酯1‑2,苯甲酸钠0.1‑0.2,联苯菊酯0.1‑0.2,双乙酸钠2‑4,改性淀粉溶胶5‑10。本发明的帆布帐篷面料既符合基本的使用要求,又具有良好的透湿透气性,涂层稳定性和均匀度高,不易脱落、开裂,防水效果和外观品质好,并且具有防霉防蛀性能,附加价值高。
Description
技术领域
本发明涉及帐篷面料技术领域,尤其涉及一种防霉防蛀帆布帐篷面料及其制备方法。
背景技术
帐篷是一种具有建筑材料功能的纺织品,用于在野外环境中隔离出一个独立安全的空间。帐篷具有简便、轻巧的特点,需要具有防风、防雨、防雪、防寒、防蚊虫的基本功能。近年来随着旅游业的发展,帐篷的销量得到大幅度增长,市场进一步扩大,人们对帐篷外观、性能的需求也进一步提高。帐篷面料由基布经表面整理制成,它的性能很大程度上影响了帐篷的使用性能。目前应用最广泛的帐篷面料是涤纶帆布,其透气透湿性能差,使用性能和附加价值不高,无法满足市场对中高档产品的潜在需求。帐篷面料在使用、存放过程中容易发生霉变、虫蛀,改善其防霉防蛀效果有利于提升其使用性能和清洁性。
发明内容
本发明目的就是为了弥补已有技术的缺陷,提供一种防霉防蛀帆布帐篷面料及其制备方法。
本发明是通过以下技术方案实现的:
一种防霉防蛀帆布帐篷面料,其是由下述重量份的原料制得:
涤纶纤维30-40,竹炭纤维10-15,***纤维10-15,硅藻土3-5,苯丙乳液5-10,十二烷基三甲基氯化铵0.2-0.4,月桂酸单甘油酯1-2,苯甲酸钠0.1-0.2,联苯菊酯0.1-0.2,双乙酸钠2-4,改性淀粉溶胶5-10;
其中改性淀粉溶胶由下列重量份的原料制成:玉米淀粉30-40,石墨粉10-15,硝酸钠1-2,高锰酸钾2-4,丙烯酸3-5,甲基丙烯酸甲酯6-8,15-20%浓度双氧水水溶液10-15,过硫酸铵0.5-1,十二烷基硫酸钠0.5-1,水200-300;改性淀粉溶胶的制备方法是将石墨粉按固液重量比1:1.5-1:2与质量分数为98%的浓硫酸混合后加入硝酸钠、高锰酸钾,40-50℃反应0.5-1h后依次加入水、玉米淀粉和15-20%浓度双氧水水溶液60-80℃搅拌3-4h,将pH调至中性后加入其余原料70-80℃反应1-2h,冷却后即得。
一种防霉防蛀帆布帐篷面料的制备方法,包括以下步骤:
(1)将涤纶纤维、竹炭纤维和***纤维按比例混纺编织,得帆布基布;
(2)将苯丙乳液、改性淀粉溶胶、月桂酸单甘油酯与十二烷基三甲基氯化铵混合后40-50℃搅拌1-2h,冷却后加入其余原料共同研磨至细度≤50μm,得涂覆剂;
(3)将(2)中的涂覆剂均匀涂覆于(1)中的帆布基布表面,先于80-90℃干燥4-6h,再于120-140℃热处理10-20min,冷却后即得防霉防蛀帆布帐篷面料。
本发明的优点是:
本发明通过改性淀粉溶胶与苯丙乳液等原料复配,合成的涂覆剂与帐篷帆布基布具有良好的结合性,在基布上生成具有良好粘着牢度、透湿透气性和力学性能的涂膜,使最终得到的帆布帐篷面料既符合基本的使用要求,又具有良好的透湿透气性,涂层稳定性和均匀度高,不易脱落、开裂,防水效果和外观品质好,并且具有防霉防蛀性能,附加价值高。
具体实施方式
一种防霉防蛀帆布帐篷面料,其是由下述重量份的原料制得:
涤纶纤维30,竹炭纤维10,***纤维10,硅藻土3,苯丙乳液5,十二烷基三甲基氯化铵0.2,月桂酸单甘油酯1,苯甲酸钠0.1,联苯菊酯0.1,双乙酸钠2,改性淀粉溶胶5;
其中改性淀粉溶胶由下列重量份的原料制成:玉米淀粉30,石墨粉10,硝酸钠1,高锰酸钾2,丙烯酸3,甲基丙烯酸甲酯6,15%浓度双氧水水溶液10,过硫酸铵0.5,十二烷基硫酸钠0.5,水200;改性淀粉溶胶的制备方法是将石墨粉按固液重量比1:1.5与质量分数为98%的浓硫酸混合后加入硝酸钠、高锰酸钾,40℃反应0.5h后依次加入水、玉米淀粉和15%浓度双氧水水溶液60℃搅拌3h,将pH调至中性后加入其余原料70℃反应1h,冷却后即得。
一种防霉防蛀帆布帐篷面料的制备方法,包括以下步骤:
(1)将涤纶纤维、竹炭纤维和***纤维按比例混纺编织,得帆布基布;
(2)将苯丙乳液、改性淀粉溶胶、月桂酸单甘油酯与十二烷基三甲基氯化铵混合后40℃搅拌1h,冷却后加入其余原料共同研磨至细度≤50μm,得涂覆剂;
(3)将(2)中的涂覆剂均匀涂覆于(1)中的帆布基布表面,先于80℃干燥4h,再于120℃热处理10min,冷却后即得防霉防蛀帆布帐篷面料。
上述制得的帆布帐篷面料性能指标测试结果如下:
项目 | 单位 | 指标 |
断裂强力(经向) | N | 2090 |
断裂强力(纬向) | N | 1870 |
透湿量 | g/m2d | 1642 |
Claims (2)
1.一种防霉防蛀帆布帐篷面料,其特征在于,其是由下述重量份的原料制得:
涤纶纤维30-40,竹炭纤维10-15,***纤维10-15,硅藻土3-5,苯丙乳液5-10,十二烷基三甲基氯化铵0.2-0.4,月桂酸单甘油酯1-2,苯甲酸钠0.1-0.2,联苯菊酯0.1-0.2,双乙酸钠2-4,改性淀粉溶胶5-10;
所述的改性淀粉溶胶由下列重量份的原料制成:玉米淀粉30-40,石墨粉10-15,硝酸钠1-2,高锰酸钾2-4,丙烯酸3-5,甲基丙烯酸甲酯6-8,15-20%浓度双氧水水溶液10-15,过硫酸铵0.5-1,十二烷基硫酸钠0.5-1,水200-300;改性淀粉溶胶的制备方法是将石墨粉按固液重量比1:1.5-1:2与质量分数为98%的浓硫酸混合后加入硝酸钠、高锰酸钾,40-50℃反应0.5-1h后依次加入水、玉米淀粉和15-20%浓度双氧水水溶液60-80℃搅拌3-4h,将pH调至中性后加入其余原料70-80℃反应1-2h,冷却后即得。
2.根据权利要求1所述的一种防霉防蛀帆布帐篷面料的制备方法,其特征在于,包括以下步骤:
(1)将涤纶纤维、竹炭纤维和***纤维按比例混纺编织,得帆布基布;
(2)将苯丙乳液、改性淀粉溶胶、月桂酸单甘油酯与十二烷基三甲基氯化铵混合后40-50℃搅拌1-2h,冷却后加入其余原料共同研磨至细度≤50μm,得涂覆剂;
(3)将(2)中的涂覆剂均匀涂覆于(1)中的帆布基布表面,先于80-90℃干燥4-6h,再于120-140℃热处理10-20min,冷却后即得防霉防蛀帆布帐篷面料。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610680575.1A CN106192377A (zh) | 2016-08-17 | 2016-08-17 | 一种防霉防蛀帆布帐篷面料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610680575.1A CN106192377A (zh) | 2016-08-17 | 2016-08-17 | 一种防霉防蛀帆布帐篷面料及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106192377A true CN106192377A (zh) | 2016-12-07 |
Family
ID=57522289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610680575.1A Pending CN106192377A (zh) | 2016-08-17 | 2016-08-17 | 一种防霉防蛀帆布帐篷面料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106192377A (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106884326A (zh) * | 2017-04-24 | 2017-06-23 | 江苏阳光股份有限公司 | 多功能全毛装饰面料的生产方法 |
CN111254520A (zh) * | 2020-03-14 | 2020-06-09 | 揭东巴黎万株纱华纺织有限公司 | 一种具有驱蚊功能的复合纤维材料制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104178011A (zh) * | 2014-08-27 | 2014-12-03 | 句容市石狮冲压件厂 | 一种户外帐篷用复合涂料及其制备方法 |
CN104859231A (zh) * | 2015-05-04 | 2015-08-26 | 湖州丝葳纺织有限公司 | 一种帐篷面料及其制备方法 |
CN105129901A (zh) * | 2015-09-22 | 2015-12-09 | 陕西科技大学 | 用于制革污水的接枝改性淀粉絮凝吸附剂及其制备方法 |
-
2016
- 2016-08-17 CN CN201610680575.1A patent/CN106192377A/zh active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104178011A (zh) * | 2014-08-27 | 2014-12-03 | 句容市石狮冲压件厂 | 一种户外帐篷用复合涂料及其制备方法 |
CN104859231A (zh) * | 2015-05-04 | 2015-08-26 | 湖州丝葳纺织有限公司 | 一种帐篷面料及其制备方法 |
CN105129901A (zh) * | 2015-09-22 | 2015-12-09 | 陕西科技大学 | 用于制革污水的接枝改性淀粉絮凝吸附剂及其制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106884326A (zh) * | 2017-04-24 | 2017-06-23 | 江苏阳光股份有限公司 | 多功能全毛装饰面料的生产方法 |
CN111254520A (zh) * | 2020-03-14 | 2020-06-09 | 揭东巴黎万株纱华纺织有限公司 | 一种具有驱蚊功能的复合纤维材料制备方法 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106192391A (zh) | 一种防水阻燃帆布帐篷面料及其制备方法 | |
CN106149394A (zh) | 一种高强度耐磨帆布帐篷面料及其制备方法 | |
CN105131174B (zh) | 通用于棉和涤纶的持久抗紫外线整理剂及其制备方法 | |
CN104499290B (zh) | 一种织物涂层剂、超薄防风透湿抗紫外线面料及其制备方法 | |
CN106192377A (zh) | 一种防霉防蛀帆布帐篷面料及其制备方法 | |
CN106337238A (zh) | 一种防蚊虫帆布帐篷面料及其制备方法 | |
CN106192387A (zh) | 一种防污抗皱帆布帐篷面料及其制备方法 | |
CN107558175B (zh) | 一种玻纤/氧化锌的制备方法 | |
CN108342116A (zh) | 一种内墙保温隔音腻子膏及其制备方法 | |
CN106283690A (zh) | 一种保暖透气帆布帐篷面料及其制备方法 | |
CN110331595A (zh) | 一种改良型卷帘面料及其制造方法 | |
CN107217495A (zh) | 一种中空尼龙涤纶混纺轻量化推拉篷涂层布的制备方法 | |
CN106149392A (zh) | 一种耐低温抗寒帆布帐篷面料及其制备方法 | |
CN106149393A (zh) | 一种高韧性耐撕裂帆布帐篷面料及其制备方法 | |
CN106010034A (zh) | 一种耐候性高的太阳能吸热涂料 | |
CN103924442B (zh) | 钛酸四丁酯及染料对涤棉混纺织物改性染色复合整理方法 | |
CN108997768A (zh) | 一种家具用的阻燃环保型面板的制备方法 | |
CN106283676A (zh) | 一种防紫外、防辐射帆布帐篷面料及其制备方法 | |
CN103571286A (zh) | 一种彩色粉末涂料的制备方法 | |
CN104480235B (zh) | 改性二氧化钛/琥珀酸酯磺酸化氢化蓖麻复合材料及其制备方法 | |
CN106245345A (zh) | 一种耐高温防老化帆布帐篷面料及其制备方法 | |
CN103015179A (zh) | 一种防水棉锦混纺织物的生产方法 | |
CN108505348A (zh) | 一种背胶防水喷绘油画布及其生产方法 | |
CN108409284A (zh) | 一种新型氯氧镁板材 | |
CN104448952A (zh) | 具有光催化性能的膨润土无机凝胶的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
|
RJ01 | Rejection of invention patent application after publication |