CN106192372A - A kind of Novel protective glove - Google Patents
A kind of Novel protective glove Download PDFInfo
- Publication number
- CN106192372A CN106192372A CN201610542095.9A CN201610542095A CN106192372A CN 106192372 A CN106192372 A CN 106192372A CN 201610542095 A CN201610542095 A CN 201610542095A CN 106192372 A CN106192372 A CN 106192372A
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- glove
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- tpe
- thermoplastic elastomer
- leather
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
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- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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Abstract
The present invention proposes a kind of Novel protective glove, the base fabric of these glove is looped fabric or flexible woven cloth, scrim surfaces makes glove form after glove coating is processed, subsequently at palm, the back of the hand of glove, and sew on surface before and after finger or use binding agent to be bonded with thermoplastic elastomer (TPE) glove leather, after described thermoplastic elastomer (TPE) glove leather is fixed to glove surface, sprays described glove coating to the outer surface of thermoplastic elastomer (TPE) glove leather, be finally made protective gloves finished product.These Novel protective glove have the anti-wear performance of excellence, tear resistance, fire protecting performance, shock resistance, and have the performances such as good antibiotic property, anticorrosive property, resistance to water, heat-resisting, weatherability, are better than existing like product, are suitable to popularization and application.
Description
Technical field
The present invention relates to labour protection articles for use field, particularly relate to a kind of Novel protective glove.
Background technology
In prior art, in using the work of General Purpose Rubber, latex safety and industrial gloves and motor process, there is glue in the relevant personnel
Skin easily tears the shortcoming separated with yarn matter glove core, and the shock resistance of glove is not enough with anti-collision, Authorization Notice No.
Chinese patent for CN202653224U discloses a kind of fire-proof high-temperature resistant glove, including glove bulk, described glove bulk bag
Including internal layer, outer layer, described outer layer is provided with thermoplastic elastomer layer, and described thermoplastic elastomer layer is embedded between internal layer and outer layer；Institute
Stating outer layer uses Silicone Rubber Coated glass fabric to make, and is provided with inner chamber between described internal layer and outer layer；Described interior intracavity is provided with
Extinguishing chemical；Described thermoplastic elastomer layer is provided with multiple bar-shaped trough；Described thermoplastic elastomer layer is provided with reflective band.This fire prevention is resistance to
Although it is preferable that high temperature glove have excellent resistance to elevated temperatures, effect of heat insulation, but it is wear-resisting, anti tear, impact resistance are poor, no
Be suitable to long-term machinery work use.Authorization Notice No. is that the Chinese patent of CN205106469U discloses a kind of thermal insulating and water-proof and prevents
Clashing into glove, the described glove back side is sewed with TPR anticollison block, described TPR anticollison block is sewed with in the position of the back of the hand with finger
Staircase cloth, described glove are sewed with one week Neil pool two-sided compound neoprene of woods around shirt-circuited end, and described glove palm is super fine, institute
Stating and be sewed with Kev bracing wire on super fibre, be provided with elastic cord at described palm wrist, described glove palm interlayer is provided with waterproof bag, institute
Stating waterproof bag and be provided with connection band in finger tip part, described connection band finger with shell, inner bag respectively is connected sewing.Above-mentioned anti-
Although water warming anticollision glove improve anticollision performance to a certain extent, but its wearability, anti-flammability, anti tear, resistance to
Hou Xing, resistance to elevated temperatures are poor, limit its popularization and application.Additionally, existing protective gloves product thick and heavy grasping dynamics is not strong, nothing
Method effectively alleviates the fatigue strength of hand, and uses the industrial chemicals such as toluene, methanol for not seep through in process of production, produces
Not only there is certain toxicity but also retain the biggest abnormal smells from the patient in product, not environmentally, existing product there is also cannot wash useful life
The shortcoming such as long.
Summary of the invention
In view of disadvantages described above present in above-mentioned prior art, the present invention proposes a kind of Novel protective glove.The present invention's
Protective gloves has the performances such as superpower wear-resisting, anti-tear, anticollision, superpower grip fire-retardant, waterproof, environmental protection odorlessness, has
The hand of effect protection staff, improves workman's work efficiency.
The invention provides a kind of Novel protective glove, by the following technical solutions:
A kind of Novel protective glove, the base fabric of these glove is looped fabric or flexible woven cloth, and scrim surfaces is through glove coating
Make glove form after being processed, sew or adopt on surface before and after the palm, the back of the hand, and finger of glove subsequently
It is bonded with thermoplastic elastomer (TPE) glove leather with binding agent, after described thermoplastic elastomer (TPE) glove leather is fixed to glove surface, to
The outer surface of thermoplastic elastomer (TPE) glove leather sprays described glove coating, is finally made protective gloves finished product.
Preferably, the processed step of described base fabric includes base fabric by glove coating, is submerged initially in glove coating, then
Pricking dry, dried by baking oven afterwards at 70-130 DEG C, the base fabric after drying subsequently makes glove form.
Preferably, in terms of parts by weight, the concrete composition of described glove coating is: poly-Hydroxypropyldimonium Chloride 32～
36 parts；Normal hexane diisocyanate 30-35 part；Silicone modified styrene-acrylate emulsion 23-25 part；Polyvinyl butyral resin 27-30 part；
Tripropylene glycol diacrylate 10-13 part；White mica 16-20 part；Octadecyl trichlorosilane alkane 13-15 part；Acrylate-benzene second
Alkene-vinyl acetate terpolymer 11-15 part；Vinyl acetate-ethylene copolymerization emulsions 11-13 part；Phthalic acid dibutyl ester 10-
16 parts；Nano-aluminum hydroxide 5-7 part；Zinc dibutyl dithiocaarbamate 15-19 part；Hydroxypropyl methyl cellulose 3-6 part；
Brominated polystyrene 2-3 part；Guar gum 3-5 part；Glycol phenyl ether 1-2 part；2-benzylimidazoline 1-2 part；Polyvinyl alcohol 2-3
Part；Perfluorocarbon 1-2 part；Deionized water 1200-1500 part.
Preferably, the particle diameter of described nano-aluminum hydroxide is 30-40nm.Preferably, described Acrylate-styrene bipolymer-vinegar
In acid ethylene-dien terpolymer, by weight percentage, acrylate accounts for 45%, and styrene accounts for 33%, and vinyl acetate accounts for 22%,
The weight average molecular weight of copolymer is 80000-100000, and has the hydroxyl value of 5mgKOH/g, and mean diameter is 0.7-1 μm.
Preferably, described octadecyl trichlorosilane alkane uses natural charged mineral material.
Preferably, described glove coating is prepared according to following preparation method:
(1) by poly-Hydroxypropyldimonium Chloride, normal hexane diisocyanate, silicone modified styrene-acrylate emulsion, polyethylene
Butyral, tripropylene glycol diacrylate, phthalic acid dibutyl ester, zinc dibutyl dithiocaarbamate, poly-bromination benzene
Ethylene, guar gum, polyvinyl alcohol, perfluorocarbon add in deionized water, and heated and stirred is uniform, keep temperature to be 90-105 DEG C, stir
Mixing speed controlling is 300-400rad/min, is cooled to room temperature after standing 2-2.5h, filters, and filtrate is standby；
(2) according to described parts by weight by Acrylate-styrene bipolymer-vinyl acetate terpolymer, white mica, octadecane
Base trichlorosilane, nano-aluminum hydroxide deliver to ball mill, and being milled to particle diameter is 30-50nm, then mix and blend, 100-120r/min
Speed stir 40-50 minute, be uniformly mixing to obtain mixture；
(3) mixture that step (2) prepares is added in the filtrate that step (1) prepares, ultrasonic high speed dispersion, ultrasound wave frequency
Rate is 20kHz, rate of dispersion 5500r/min, and jitter time is 55min；
(4) remaining vinyl acetate-ethylene copolymerization emulsions, hydroxypropyl methyl cellulose, glycol phenyl ether, 2-benzene are added
Base imidazoline, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 4800r/min, and jitter time is 40min,
Glove coating.
Preferably, the component including following parts by weight of described thermoplastic elastomer (TPE) glove leather:
Preferably, " EPDM " is formed by ethylene-propylene-non-conjugated diene hydrocarbon three kinds monomer copolymerization, and its strand is
Saturated, but due to the introducing of Third monomer, make the linear three block copolymer containing a small amount of unsaturated double-bond on side chain.
Preferably, the preparation method of described thermoplastic elastomer (TPE) glove leather comprises the steps:
(1) in the stirred tank equipped with mix and blend and cooling system that can heat, antioxidant, PUR, 6-8 are added
Part thinner, opens stirring, is warming up to 120-125 DEG C and stirs 1-1.5 hour, and speed of agitator 600r/min makes antioxidant and heat
Melten gel is completely dissolved；
(2) EPDM and tri trimellitate (2-ethylhexyl) ester TOTM is joined in stirred tank, puts into residue thinner,
After keeping temperature 110-115 DEG C stirring 25-30min, speed of agitator 600r/min；
(3) put into polymethylacrylic acid gadolinium, white carbon, keep 400-600r/min rotating speed stirring 2-2.5h, temperature 100-
105 DEG C, obtain dispensing, standing and defoaming；
(4) step (3) gained dispensing is put into the production of existing production line and obtains described thermoplastic elastomer (TPE) glove leather.
Visible, the present invention provide Novel protective glove have excellence anti-wear performance, tear resistance, fire protecting performance,
Shock resistance, and there is the performances such as good antibiotic property, anticorrosive property, resistance to water, heat-resisting, weatherability, it is better than existing similar
Product, is suitable to popularization and application.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, concrete below in conjunction with the present invention
Embodiment, is clearly and completely described the technical scheme of the embodiment of the present invention.Obviously, described embodiment is this
Bright a part of embodiment rather than whole embodiments.Based on described embodiments of the invention, ordinary skill
The every other embodiment that personnel are obtained on the premise of without creative work, broadly falls into the scope of protection of the invention.
The invention provides a kind of Novel protective glove, the base fabric of these glove is looped fabric or flexible woven cloth, base fabric table
Face is processed through glove coating.Being specially step is: by base fabric by glove coating, (be submerged initially in through leaching one bundle
Glove coating, then prick dry), to be dried at 70-130 DEG C by baking oven afterwards, the base fabric after drying subsequently makes glove.
The concrete composition of described glove coating is:
Poly-Hydroxypropyldimonium Chloride 32～36 parts；Normal hexane diisocyanate 30-35 part；Organosilicon-modified styrene-acrylic breast
Liquid 23-25 part；Polyvinyl butyral resin 27-30 part；Tripropylene glycol diacrylate 10-13 part；White mica 16-20 part；18
Alkyltrichlorosilanes 13-15 part；Acrylate-styrene bipolymer-vinyl acetate terpolymer 11-15 part；Vinyl acetate-ethylene
Copolymer emulsion 11-13 part；Phthalic acid dibutyl ester 10-16 part；Nano-aluminum hydroxide 5-7 part；Di-n-butyl dithiocarbamates first
Acid zinc 15-19 part；Hydroxypropyl methyl cellulose 3-6 part；Brominated polystyrene 2-3 part；Guar gum 3-5 part；Glycol phenyl ether 1-2
Part；2-benzylimidazoline 1-2 part；Polyvinyl alcohol 2-3 part；Perfluorocarbon 1-2 part；Deionized water 1200-1500 part.
Preferably, the particle diameter of described nano-aluminum hydroxide is 30-40nm.
Wherein, in described Acrylate-styrene bipolymer-vinyl acetate terpolymer, by weight percentage, acrylate
Accounting for 45%, styrene accounts for 33%, and vinyl acetate accounts for 22%, and the weight average molecular weight of copolymer is 80000-100000, and has
The hydroxyl value of 5mgKOH/g, mean diameter is 0.7-1 μm.
Described octadecyl trichlorosilane alkane uses natural charged mineral material, and adding octadecyl trichlorosilane alkane can show
Write the anti-microbial property improved escherichia coli and staphylococcus aureus etc..
In the present invention, Acrylate-styrene bipolymer-vinyl acetate terpolymer has the anti-flammability of excellence, and it is with organic
Si modification styrene-acrylic emulsion, the combination of vinyl acetate-ethylene copolymerization emulsions can improve well film compactness, anticorrosive property,
The performances such as resistance to water, heat-resisting, weatherability.Use vinyl acetate-ethylene copolymerization emulsions, it is also possible to be greatly enhanced that coating is anti-to be stained with
Viscosity energy, has good elasticity and toughness simultaneously, and its film is provided with good anti-cracking performance and stain resistance and scrubbing resistance
Performance.
The preparation method of described glove coating comprises the steps:
(1) by poly-Hydroxypropyldimonium Chloride, normal hexane diisocyanate, silicone modified styrene-acrylate emulsion, polyethylene
Butyral, tripropylene glycol diacrylate, phthalic acid dibutyl ester, zinc dibutyl dithiocaarbamate, poly-bromination benzene
Ethylene, guar gum, polyvinyl alcohol, perfluorocarbon add in deionized water, and heated and stirred is uniform, keep temperature to be 90-105 DEG C, stir
Mixing speed controlling is 300-400rad/min, is cooled to room temperature after standing 2-2.5h, filters, and filtrate is standby；
(2) according to described parts by weight by Acrylate-styrene bipolymer-vinyl acetate terpolymer, white mica, octadecane
Base trichlorosilane, nano-aluminum hydroxide deliver to ball mill, and being milled to particle diameter is 30-50nm, then mix and blend, 100-120r/min
Speed stir 40-50 minute, be uniformly mixing to obtain mixture；
(3) mixture that step (2) prepares is added in the filtrate that step (1) prepares, ultrasonic high speed dispersion, ultrasound wave frequency
Rate is 20kHz, rate of dispersion 5500r/min, and jitter time is 55min；
(4) remaining vinyl acetate-ethylene copolymerization emulsions, hydroxypropyl methyl cellulose, glycol phenyl ether, 2-benzene are added
Base imidazoline, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 4800r/min, and jitter time is 40min,
Glove coating.
In one embodiment, described glove coating includes the raw material of following parts by weight: poly-hydroxypropyl dimethyl chlorine
Change ammonium 32 parts；Normal hexane diisocyanate 30 parts；Silicone modified styrene-acrylate emulsion 23 parts；Polyvinyl butyral resin 30 parts；3 third
Omega-diol diacrylate 12 parts；White mica 18 parts；14 parts of octadecyl trichlorosilane alkane；Acrylate-styrene bipolymer-vinyl acetate three
Membered copolymer 15 parts；Vinyl acetate-ethylene copolymerization emulsions 13 parts；Phthalic acid dibutyl ester 16 parts；Nano-aluminum hydroxide 5 parts；Two
Normal-butyl zinc dithiocarbamate 15 parts；Hydroxypropyl methyl cellulose 6 parts；Brominated polystyrene 2 parts；Guar gum 5 parts；Glycol
Phenyl ether 1 part；2-benzylimidazoline 2 parts；Polyvinyl alcohol 2 parts；Perfluorocarbon 1 part；Deionized water 1200 parts.
In one embodiment, described glove coating includes the raw material of following parts by weight: poly-hydroxypropyl dimethyl chlorine
Change ammonium 32～36 parts；Normal hexane diisocyanate 35 parts；Silicone modified styrene-acrylate emulsion 24 parts；Polyvinyl butyral resin 27 parts；
Tripropylene glycol diacrylate 11 parts；White mica 17 parts；13 parts of octadecyl trichlorosilane alkane；Acrylate-styrene bipolymer-acetic acid second
Alkene terpolymer 11 parts；Vinyl acetate-ethylene copolymerization emulsions 11 parts；Phthalic acid dibutyl ester 10 parts；Nano-aluminum hydroxide 5
Part；Zinc dibutyl dithiocaarbamate 18 parts；Hydroxypropyl methyl cellulose 4 parts；Brominated polystyrene 3 parts；Guar gum 4
Part；Glycol phenyl ether 1-2 part；2-benzylimidazoline 1 part；Polyvinyl alcohol 2 parts；Perfluorocarbon 1 part；Deionized water 1500 parts.
In one embodiment, described glove coating includes the raw material of following parts by weight: poly-hydroxypropyl dimethyl chlorine
Change ammonium 36 parts；Normal hexane diisocyanate 32 parts；Silicone modified styrene-acrylate emulsion 25 parts；Polyvinyl butyral resin 28 parts；3 third
Omega-diol diacrylate 10 parts；White mica 16 parts；15 parts of octadecyl trichlorosilane alkane；Acrylate-styrene bipolymer-vinyl acetate three
Membered copolymer 14 parts；Vinyl acetate-ethylene copolymerization emulsions 12 parts；Phthalic acid dibutyl ester 13 parts；Nano-aluminum hydroxide 5 parts；Two
Normal-butyl zinc dithiocarbamate 19 parts；Hydroxypropyl methyl cellulose 5 parts；Brominated polystyrene 2.5 parts；Guar gum 4 parts；Two
Alcohol phenyl ether 1 part；2-benzylimidazoline 1 part；Polyvinyl alcohol 3 parts；Perfluorocarbon 1 part；Deionized water 1500 parts.
In one embodiment, described glove coating includes the raw material of following parts by weight: poly-hydroxypropyl dimethyl chlorine
Change ammonium 33 parts；Normal hexane diisocyanate 31 parts；Silicone modified styrene-acrylate emulsion 25 parts；Polyvinyl butyral resin 29 parts；3 third
Omega-diol diacrylate 13 parts；White mica 20 parts；15 parts of octadecyl trichlorosilane alkane；Acrylate-styrene bipolymer-vinyl acetate three
Membered copolymer 14 parts；Vinyl acetate-ethylene copolymerization emulsions 13 parts；Phthalic acid dibutyl ester 14 parts；Nano-aluminum hydroxide 7 parts；Two
Normal-butyl zinc dithiocarbamate 16 parts；Hydroxypropyl methyl cellulose 3 parts；Brominated polystyrene 2 parts；Guar gum 3 parts；Glycol
Phenyl ether 1 part；2-benzylimidazoline 1.5 parts；Polyvinyl alcohol 3 parts；Perfluorocarbon 2 parts；Deionized water 1300 parts.
In one embodiment, described glove coating includes the raw material of following parts by weight: poly-hydroxypropyl dimethyl chlorine
Change ammonium 35 parts；Normal hexane diisocyanate 34 parts；Silicone modified styrene-acrylate emulsion 23 parts；Polyvinyl butyral resin 27 parts；3 third
Omega-diol diacrylate 11 parts；White mica 18 parts；13 parts of octadecyl trichlorosilane alkane；Acrylate-styrene bipolymer-vinyl acetate three
Membered copolymer 12 parts；Vinyl acetate-ethylene copolymerization emulsions 12 parts；Phthalic acid dibutyl ester 14 parts；Nano-aluminum hydroxide 6 parts；Two
Normal-butyl zinc dithiocarbamate 15 parts；Hydroxypropyl methyl cellulose 3 parts；Brominated polystyrene 2 parts；Guar gum 4 parts；Glycol
Phenyl ether 1.5 parts；2-benzylimidazoline 1 part；Polyvinyl alcohol 2.5 parts；Perfluorocarbon 2 parts；Deionized water 1400-1500 part.
Subsequently, sew on surface before and after the palm, the back of the hand, and finger of glove or use binding agent to be bonded with thermoplastic
Property elastomeric glove leather, the component including following parts by weight of described thermoplastic elastomer (TPE) glove leather:
In this specification, term EPDM refers to mainly by ethylene-propylene-non-conjugated diene hydrocarbon three kinds monomer copolymerization
Becoming, its strand is also saturated, but due to the introducing of Third monomer, makes on side chain containing a small amount of unsaturated double-bond
Linear three block copolymer.
Described PUR is preferably Dupont EBA34035.Described thinner is preferably Porous deproteinized bone solvent.Described
Antioxidant is preferably BHT, or WingStay L antioxidant.
The preparation method of described thermoplastic elastomer (TPE) glove leather comprises the steps:
(1) in the stirred tank equipped with mixing and stirring system that can heat, antioxidant, PUR, 6-8 part viscosity reduction are added
Agent, opens stirring, is warming up to 120-125 DEG C and stirs 1-1.5 hour, and speed of agitator 600r/min makes antioxidant and PUR complete
CL；
(2) EPDM and tri trimellitate (2-ethylhexyl) ester TOTM is joined in stirred tank, puts into residue thinner,
After keeping temperature 110-115 DEG C stirring 25-30min, speed of agitator 600r/min；
(3) put into polymethylacrylic acid gadolinium, white carbon, keep 400-600r/min rotating speed stirring 2-2.5h, temperature 100-
105 DEG C, obtain dispensing, standing and defoaming；
(4) step (3) gained dispensing is put into the production of existing production line and obtains described thermoplastic elastomer (TPE) glove leather.
In a preferred embodiment, the component including following parts by weight of described thermoplastic elastomer (TPE) glove leather:
In a preferred embodiment, the component including following parts by weight of described thermoplastic elastomer (TPE) glove leather:
In a preferred embodiment, the component including following parts by weight of described thermoplastic elastomer (TPE) glove leather:
In a preferred embodiment, the component including following parts by weight of described thermoplastic elastomer (TPE) glove leather:
After thermoplastic elastomer (TPE) glove leather is fixed to glove surface, preferably glove are heated to 45-55 degree Celsius, and to
The outer surface of thermoplastic elastomer (TPE) glove leather sprays described glove coating, is finally made protective gloves finished product.
After tested, the Novel protective glove hot strength of the present invention is up to 24.85-28.68MPa, elongation at break 617-
632%, cut resistant index reaches 3, wear-resisting amount (mg/1000 time) 0.38-0.4, and fire protection flame retarding rank V-0, humidity is more than 60%
Rate of corrosion (25 DEG C) 2.7%-4.1%, pH=3.5 acid environment rate of corrosion 4.7%-5.6%, pH=8.5 alkali environmental corrosion rate
4.1%-4.6%, escherichia coli mycete survival rate 2.5%-3.1%, resistance to impact/(kg cm) 151-155, high temperature resistant (500
DEG C) 22-25 hour unchanged, benzene class material detect: be not detected by originate SGS test.The product of the visible present invention has excellent
Anti-wear performance, shock resistance, antibiotic property, anticorrosive property, resistance to water, the performance such as heat-resisting, weatherability, be better than existing similar product
Product, are suitable to popularization and application.
Above example is merely to illustrate the present invention, and not limitation of the present invention, about the common skill of technical field
Art personnel, without departing from the spirit and scope of the present invention, it is also possible to make a variety of changes and modification, the most all etc.
Same technical scheme falls within scope of the invention, and the scope of patent protection of the present invention should be defined by the claims.
Claims (8)
1. Novel protective glove, it is characterised in that the base fabric of these glove is looped fabric or flexible woven cloth, scrim surfaces warp
Glove coating makes glove form after being processed, subsequently before and after the palm, the back of the hand, and finger of glove on surface
Sewing or employing binding agent are bonded with thermoplastic elastomer (TPE) glove leather, and described thermoplastic elastomer (TPE) glove leather is fixed to glove surface
Afterwards, spray described glove coating to the outer surface of thermoplastic elastomer (TPE) glove leather, be finally made protective gloves finished product.
A kind of Novel protective glove the most according to claim 1, it is characterised in that the processed step bag of described base fabric
Include base fabric by glove coating, be submerged initially in glove coating, then prick dry, dried at 70-130 DEG C, subsequently by baking oven afterwards
Base fabric after drying makes glove form.
A kind of Novel protective glove the most according to claim 1, it is characterised in that in terms of parts by weight, described glove are coated with
The concrete composition of material is: poly-Hydroxypropyldimonium Chloride 32～36 parts；Normal hexane diisocyanate 30-35 part；Organosilicon changes
Property styrene-acrylic emulsion 23-25 part；Polyvinyl butyral resin 27-30 part；Tripropylene glycol diacrylate 10-13 part；White mica 16-20
Part；Octadecyl trichlorosilane alkane 13-15 part；Acrylate-styrene bipolymer-vinyl acetate terpolymer 11-15 part；Acetic acid second
Alkene-ethylene copolymerization emulsions 11-13 part；Phthalic acid dibutyl ester 10-16 part；Nano-aluminum hydroxide 5-7 part；Di-n-butyl two sulfur
For carbaminate 15-19 part；Hydroxypropyl methyl cellulose 3-6 part；Brominated polystyrene 2-3 part；Guar gum 3-5 part；Glycol
Phenyl ether 1-2 part；2-benzylimidazoline 1-2 part；Polyvinyl alcohol 2-3 part；Perfluorocarbon 1-2 part；Deionized water 1200-1500 part.
A kind of Novel protective glove the most according to claim 3, it is characterised in that the particle diameter of described nano-aluminum hydroxide is
30-40nm.Preferably, in described Acrylate-styrene bipolymer-vinyl acetate terpolymer, by weight percentage, acrylic acid
Ester accounts for 45%, and styrene accounts for 33%, and vinyl acetate accounts for 22%, and the weight average molecular weight of copolymer is 80000-100000, and has
Having the hydroxyl value of 5mgKOH/g, mean diameter is 0.7-1 μm.Preferably, described octadecyl trichlorosilane alkane uses natural charged
Mineral material.
A kind of Novel protective glove the most according to claim 3, it is characterised in that described glove coating is according to following preparation
Method is prepared:
(1) by poly-Hydroxypropyldimonium Chloride, normal hexane diisocyanate, silicone modified styrene-acrylate emulsion, polyvinyl alcohol contracting
Butyraldehyde, tripropylene glycol diacrylate, phthalic acid dibutyl ester, zinc dibutyl dithiocaarbamate, brominated polystyrene,
Guar gum, polyvinyl alcohol, perfluorocarbon add in deionized water, and heated and stirred is uniform, keep temperature to be 90-105 DEG C, mixing speed
Controlling is 300-400rad/min, is cooled to room temperature after standing 2-2.5h, filters, and filtrate is standby；
(2) according to described parts by weight by Acrylate-styrene bipolymer-vinyl acetate terpolymer, white mica, octadecyl three
Chlorosilane, nano-aluminum hydroxide deliver to ball mill, and being milled to particle diameter is 30-50nm, then mix and blend, the speed of 100-120r/min
Degree stirring 40-50 minute, is uniformly mixing to obtain mixture；
(3) being added in the filtrate that step (1) prepares by the mixture that step (2) prepares, ultrasonic high speed dispersion, ultrasonic frequency is
20kHz, rate of dispersion 5500r/min, jitter time is 55min；
(4) remaining vinyl acetate-ethylene copolymerization emulsions, hydroxypropyl methyl cellulose, glycol phenyl ether, 2-phenyl miaow are added
Oxazoline, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion 4800r/min, and jitter time is 40min, obtains glove
Coating.
A kind of Novel protective glove the most according to claim 1, it is characterised in that described thermoplastic elastomer (TPE) glove leather
Component including following parts by weight:
A kind of Novel protective glove the most according to claim 6, it is characterised in that EPDM is by ethylene-propylene-non-conjugated
Three kinds of monomer copolymerizations of alkadienes, its strand is saturated, but due to the introducing of Third monomer, makes to contain on side chain
The linear three block copolymer of a small amount of unsaturated double-bond.
A kind of Novel protective glove the most according to claim 1, it is characterised in that described thermoplastic elastomer (TPE) glove leather
Preparation method comprises the steps:
(1) in the stirred tank equipped with mix and blend and cooling system that can heat, add antioxidant, PUR, 6-8 part fall
Stick, opens stirring, is warming up to 120-125 DEG C and stirs 1-1.5 hour, and speed of agitator 600r/min makes antioxidant and PUR
It is completely dissolved；
(2) EPDM and tri trimellitate (2-ethylhexyl) ester TOTM is joined in stirred tank, put into residue thinner, keep
After temperature 110-115 DEG C stirring 25-30min, speed of agitator 600r/min；
(3) put into polymethylacrylic acid gadolinium, white carbon, keep 400-600r/min rotating speed stirring 2-2.5h, temperature 100-105
DEG C, obtain dispensing, standing and defoaming；
(4) step (3) gained dispensing is put into the production of existing production line and obtains described thermoplastic elastomer (TPE) glove leather.
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| CN201610542095.9A CN106192372A (en) | 2016-07-11 | 2016-07-11 | A kind of Novel protective glove |
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| CN201610542095.9A CN106192372A (en) | 2016-07-11 | 2016-07-11 | A kind of Novel protective glove |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106723481A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | A kind of Novel abrasion-proof sport kneecap |
| CN106758210A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | A kind of preparation method of Novel abrasion-proof sport kneecap |
| CN106758140A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | Outer barrel making cloth is protected in a kind of elbow protector for sports |
| CN106752465A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | The outer barrel preparation method for making cloth is protected in a kind of elbow protector for sports |
| CN106868885A (en) * | 2017-03-16 | 2017-06-20 | 江苏工程职业技术学院 | A kind of processing method of polyamide fibre Graphene white dipped gloves |
| CN110396825A (en) * | 2019-08-08 | 2019-11-01 | 邦威防护科技股份有限公司 | A kind of preparation method of fireproof facing material |
| WO2024077722A1 (en) * | 2022-10-10 | 2024-04-18 | 南通强生新材料科技股份有限公司 | Light, thin and shock-resistant graphene glove and preparation method therefor |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106723481A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | A kind of Novel abrasion-proof sport kneecap |
| CN106758210A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | A kind of preparation method of Novel abrasion-proof sport kneecap |
| CN106758140A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | Outer barrel making cloth is protected in a kind of elbow protector for sports |
| CN106752465A (en) * | 2017-01-20 | 2017-05-31 | 青岛瑞诚铭机械设计有限公司 | The outer barrel preparation method for making cloth is protected in a kind of elbow protector for sports |
| CN106868885A (en) * | 2017-03-16 | 2017-06-20 | 江苏工程职业技术学院 | A kind of processing method of polyamide fibre Graphene white dipped gloves |
| CN110396825A (en) * | 2019-08-08 | 2019-11-01 | 邦威防护科技股份有限公司 | A kind of preparation method of fireproof facing material |
| CN110396825B (en) * | 2019-08-08 | 2022-03-11 | 邦威防护科技股份有限公司 | Preparation method of fireproof fabric |
| WO2024077722A1 (en) * | 2022-10-10 | 2024-04-18 | 南通强生新材料科技股份有限公司 | Light, thin and shock-resistant graphene glove and preparation method therefor |
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Address after: 266000 No. 2008 Kunlunshan South Road, Huangdao District, Qingdao City, Shandong Province Applicant after: Qingdao Yinshida Protection Technology Co., Ltd. Address before: 266000 Huangdao Economic and Technological Development Zone, Qingdao City, Shandong Province Applicant before: Qingdao Yinshida Plastic Co., Ltd. |
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