CN106191343A - One plays haze wax and preparation method thereof - Google Patents
One plays haze wax and preparation method thereof Download PDFInfo
- Publication number
- CN106191343A CN106191343A CN201610756538.4A CN201610756538A CN106191343A CN 106191343 A CN106191343 A CN 106191343A CN 201610756538 A CN201610756538 A CN 201610756538A CN 106191343 A CN106191343 A CN 106191343A
- Authority
- CN
- China
- Prior art keywords
- parts
- oil
- present
- haze wax
- chlorination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C14C9/02—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention provides one and play haze wax, in parts by weight, including: the high-grade aliphatic ester of 100～150 parts；The neat's foot oil of 80～120 parts；The polyunsaturated vegetable oil of 80～120 parts；The chlorination Oleum Glycines of 20～40 parts；The chlorination methyl ester of 20～40 parts；The epoxy soybean oil of 150～250 parts；250 parts～the lanoline of 350 parts；The mineral oil of 80～120 parts；The lecithin of 80～120 parts；The emulsifying agent of 5～10 parts；The penetrating agent of 10～30 parts；The correctives of 1～5 part；The preservative of 1～5 part.The oil of kicking a ball making the present invention provide under the comprehensive function of various raw materials in playing haze wax has preferable abnormal smells from the patient, long-term preserves not stratified, and the softness using rear skin is preferable and resistance to storage.Present invention also offers a kind of above-mentioned preparation method playing haze wax.
Description
Technical field
The invention belongs to leather processing technique field, particularly relate to one and play haze wax and preparation method thereof.
Background technology
Playing haze wax is the special important chemical materials of fur coat fatting agent, has complementarity oil and rubs effect.During stuffing,
Beat by playing skin machine, allow and play haze wax and fully penetrate into Intradermal, wash on fleece with cleaning machine and oils and fats that flesh noodles is superfluous,
Improve the feel on fur coat surface.At present, market is sold the haze wax of playing of multiple different brands, but these play haze wax abnormal smells from the patient difficulty
Hear, long-term existence is easily layered, use after the softness of skin poor and be weak to storage.
Summary of the invention
In view of this, it is an object of the invention to provide one and play haze wax, it is preferable, long that what the present invention provided plays haze wax abnormal smells from the patient
Phase exist not stratified, use after skin softness preferably and resistance to storage.
The invention provides one and play haze wax, in parts by weight, including:
The high-grade aliphatic ester of 100～150 parts；
The neat's foot oil of 80～120 parts；
The polyunsaturated vegetable oil of 80～120 parts；
The chlorination Oleum Glycines of 20～40 parts；
The chlorination methyl ester of 20～40 parts；
The epoxy soybean oil of 150～250 parts；
250 parts～the lanoline of 350 parts；
The mineral oil of 80～120 parts；
The lecithin of 80～120 parts；
The emulsifying agent of 5～10 parts；
The penetrating agent of 10～30 parts；
The correctives of 1～5 part；
The preservative of 1～5 part.
Preferably, described high-grade aliphatic ester is prepared by oleic acid and fatty alcohol are reacted.
Preferably, described fatty alcohol be carbon number be the fatty alcohol of 10～18.
Preferably, the acid number of described high-grade aliphatic ester is less than 1mgKOH/g.
Preferably, the mol ratio of described oleic acid and fatty alcohol is 1:(0.5～1.5).
Preferably, the kinematic viscosity of described mineral oil is 24～28mm2/s。
The invention provides the preparation method playing haze wax described in a kind of technique scheme, including:
By high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean oil, Pilus Caprae seu Ovis
Fat, mineral oil, lecithin, emulsifying agent, penetrating agent, correctives and preservative mixing, obtain playing haze wax.
Preferably, play the preparation method of haze wax described in and specifically include following steps:
(1) by high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean oil, sheep
Hair fat, mineral oil, lecithin and emulsifying agent mixing, obtain mixture；
(2) described mixture, penetrating agent, correctives and preservative are mixed, obtain playing haze wax.
Preferably, in described step (1), the temperature of mixing is 60～65 DEG C；
In described step (2), the temperature of mixing is 35～40 DEG C.
Preferably, the preparation method of described high-grade aliphatic ester includes:
Under the effect of p-methyl benzenesulfonic acid, oleic acid and fatty alcohol are reacted, obtains high-grade aliphatic ester.
The present invention under the comprehensive function of above-mentioned various raw materials, make to prepare play haze wax abnormal smells from the patient preferably, long-term existence
Not stratified, use after skin softness preferably and resistance to storage.
Detailed description of the invention
The invention provides one and play haze wax, in parts by weight, including:
The high-grade aliphatic ester of 100～150 parts；
The neat's foot oil of 80～120 parts；
The polyunsaturated vegetable oil of 80～120 parts；
The chlorination Oleum Glycines of 20～40 parts；
The chlorination methyl ester of 20～40 parts；
The epoxy soybean oil of 150～250 parts；
250 parts～the lanoline of 350 parts；
The mineral oil of 80～120 parts；
The lecithin of 80～120 parts；
The emulsifying agent of 5～10 parts；
The penetrating agent of 10～30 parts；
The correctives of 1～5 part；
The preservative of 1～5 part.
What the present invention provided plays the high-grade aliphatic ester that haze wax includes 100～150 parts.In the present invention, described senior fat
The parts by weight of fat acid esters are preferably 110～140 parts, more preferably 115～135 parts, most preferably 120～130 parts.At this
In bright, described high-grade aliphatic ester is preferably prepared by oleic acid and fatty alcohol are reacted.In the present invention, described fatty alcohol is excellent
Electing the fatty alcohol that carbon number is 10～18, more preferably carbon number as is the fatty alcohol of 12～16, most preferably carbon atom
Number is the fatty alcohol of 13～15.In the present invention, the mol ratio of described oleic acid and fatty alcohol is preferably 1:(0.5～1.5), more excellent
Elect 1:(0.8～1.2 as), most preferably 1:1.The present invention does not has special restriction to the source of described oleic acid and fatty alcohol, can
Bought by market and obtain, it is possible to prepare.
In the present invention, the preparation method of described high-grade aliphatic ester is preferably:
Under the effect of p-methyl benzenesulfonic acid, oleic acid and fatty alcohol are reacted, obtains high-grade aliphatic ester.
In the present invention, the temperature of described reaction is preferably 100～105 DEG C.In the present invention, the pressure of described reaction is excellent
Elect 0.09～0.1MPa as.In the present invention, the time of described reaction is preferably 2～4 hours, and more preferably 2.5～3.5 is little
Time, most preferably 3 hours.In the present invention, the product acid number preferably controlling in described course of reaction to obtain is less than
1mgKOH/g, more preferably 0～0.5mgKOH/g.In the present invention, described oleic acid and the kind of fatty alcohol, source and mol ratio
Consistent with oleic acid described in technique scheme and the kind of fatty alcohol, source and mol ratio, do not repeat them here.In the present invention
In, the consumption of described p-methyl benzenesulfonic acid accounts for the 0.3% of high-grade aliphatic ester.In the present invention, described high-grade aliphatic ester is for long
Chain structure, it is possible to penetrate between the fiber of leather, increases fiber and fibre lubrication, improves the pliability of resultant Leather.
What the present invention provided plays the neat's foot oil that haze wax includes 80～120 parts.In the present invention, the weight portion of described neat's foot oil
Number is preferably 85～115 parts, more preferably 90～110 parts, most preferably 95～105 parts.In the present invention, described neat's foot oil
Fusing point is preferably 6 DEG C.In the present invention, the iodine number of described neat's foot oil be preferably 75～89gI/100g, more preferably 80～
85gI/100g.In the present invention, described Ungula Bovis seu Bubali oil saponification value (KOH) be preferably 190～205mg/g, more preferably 195～
200mg/g.The present invention does not has special restriction to the source of described neat's foot oil, can be bought by market and obtain, as used Shanghai
The neat's foot oil that grain rice International Trading Company Ltd provides.In the present invention, described neat's foot oil act as improve fur coat surface
Oil sense.
What the present invention provided plays the polyunsaturated vegetable oil that haze wax includes 80～120 parts.In the present invention, described unsaturation is planted
The parts by weight of thing oil are preferably 85～115 parts, more preferably 90～110 parts, most preferably 95～105 parts.In the present invention,
The composition of described polyunsaturated vegetable oil is preferably Oleum Brassicae campestris.The present invention does not has special limit to the source of described polyunsaturated vegetable oil
System, can be bought by market and obtain, it is possible to prepare.Such as the Lv Yuanjing that Jiangxi Lvyuan Oil Industrial Co., Ltd. can be used to provide
The Oleum Brassicae campestris of ridge model.In the present invention, described polyunsaturated vegetable oil carbon chain length, skin to be moistened, flexibility is good.
What the present invention provided plays the chlorination Oleum Glycines that haze wax includes 20～40 parts.In the present invention, the weight of described chlorination Oleum Glycines
Amount number is preferably 25～35 parts, more preferably 28～32 parts.In the present invention, the chlorinty of described chlorination Oleum Glycines is about
18%, density is preferably 1.03～1.05g/mL.The present invention does not has special restriction to the source of described chlorination Oleum Glycines, can be by city
Field is bought and is obtained.As Xin Yuan chemical plant, Shifang City company can be used to provide chlorination Oleum Glycines.In the present invention, described chlorination Oleum Glycines
It act as improving the lubrication sense between fur coat fiber, increase the softness of fur coat.
What the present invention provided plays the chlorination methyl ester that haze wax includes 20～40 parts.In the present invention, the weight of described chlorination methyl ester
Amount number is preferably 25～35 parts, more preferably 28～32 parts.In the present invention, the density of described chlorination methyl ester is preferably 1.08
～1.02g/mL.In the present invention, the chlorinity of described chlorination methyl ester is preferably greater than or equal to 25.0%.In the present invention,
The pH of described chlorination methyl ester is preferably 1.0～3.0.In the present invention, described chlorination methyl ester working substance content is preferably greater than
99.5%.The present invention does not has special restriction to the source of described chlorination methyl ester, can be bought by market and obtain, as used Shifang
The chlorination methyl ester that Xin Yuan chemical plant, city company provides.In the present invention, described chlorination methyl ester act as increase hide fiber soft
Degree, improves the softness of fur coat.
What the present invention provided plays the epoxy soybean oil that haze wax includes 150～250 parts.In the present invention, described epoxy soybean
The parts by weight of oil are preferably 160～230 parts, more preferably 180～220 parts, most preferably 190～210 parts.In the present invention
In, the acid number of described epoxy soybean oil is preferably less than or equal to 0.5mgKOH/g.In the present invention, described epoxy soybean oil
Colourity is preferably less than or equal to 100PT-CO.In the present invention, the epoxide number of described epoxy soybean oil be preferably greater than or etc.
In 6.0%.In the present invention, described epoxy soybean oil flash is preferably greater than equal to 280 DEG C.In the present invention, described ring
The density of oxygen soybean oil is preferably 0.985～0.995g/cm3.In the present invention, the iodine number of described epoxy soybean oil is the least
In or equal to 6gI/100g.The present invention does not has special restriction to the source of described epoxy soybean oil, can be bought by market and obtain,
Such as the epoxy soybean oil that Guangzhou Zhong Ye Chemical Co., Ltd. can be used to provide.In the present invention, the work of described epoxy soybean oil
With the oil sense for increasing fur coat surface.
What the present invention provided plays the lanoline that haze wax includes 250～350 parts.In the present invention, the weight of described lanoline
Number is preferably 270～330 parts, more preferably 280～310 parts, most preferably 290～300 parts.In the present invention, described sheep
Hair fat is preferably one-level lanoline.In the present invention, the saponification number (potassium hydroxide) of described lanoline is preferably 92～106mg/
G, more preferably 96～100mg/g.In the present invention, the acid number of described lanoline is preferably not greater than 35mgKOH/g.At this
In bright, the working substance content of described lanoline is preferably greater than or equal to 99.0%.The source of described lanoline is not had by the present invention
There is special restriction, can be bought by market and obtain, as the Pilus Caprae seu Ovis of A model that Wujiang Dragon Lord oils and fats company limited provides can be used
Fat.In the present invention, the softness acting as increase fur coat of described lanoline, improves the mercerising sense on fur coat surface.
What the present invention provided plays the mineral oil that haze wax includes 80～120 parts.In the present invention, the weight portion of described mineral oil
Number is preferably 85～115 parts, more preferably 90～110 parts, most preferably 95～105 parts.In the present invention, described mineral oil
Kinematic viscosity is preferably 24～28mm2/s.In the present invention, the density (20 DEG C) of described mineral oil is preferably 830～840Kg/
m3.In the present invention, the pour point of described mineral oil is preferably-8～-12 DEG C.In the present invention, described mineral oil flash (closes
Mouthful) it is preferably 170～180 DEG C.In the present invention, described mineral oil is preferably 26# mineral oil.The present invention is to described mineral oil
Source does not has special restriction, can be bought by market and obtain, such as the 26# that Wuxi City Fu Min lubricating oil company limited can be used to provide
Number mineral oil.In the present invention, the softness acting as raising fur coat leather of described mineral oil.
What the present invention provided plays the lecithin that haze wax includes 80～120 parts.In the present invention, the weight portion of described lecithin
Number is preferably 85～115 parts, more preferably 90～110 parts, most preferably 95～105 parts.In the present invention, described lecithin
Acetone insoluble matter is preferably greater than or equal to 60%.The present invention does not has special restriction to kind and the source of described lecithin,
Use lecithin well known to those skilled in the art, can be commercially available by market.In the present invention, described lecithin is preferred
For soybean lecithin.The soybean lecithin that Fu Hong bio tech ltd, Zhengzhou provides can be used.In the present invention, described ovum
The softness acting as increase fur coat of phospholipid.
What the present invention provided plays the emulsifying agent that haze wax includes 5～10 parts.In the present invention, the parts by weight of described emulsifying agent
It is preferably 6～9 parts, more preferably 7～8 parts.The present invention does not has special restriction to kind and the source of described emulsifying agent, uses
Emulsifying agent well known to those skilled in the art, can be commercially available by market.In the present invention, described emulsifying agent is preferably fat
Fat polyoxyethylenated alcohol.The emulsifying agent of the AEO-9 model that BASF AG provides can be used.In the present invention, described emulsifying agent
Act as improving the emulsifying penetrating power of the fatting agent playing haze wax.
What the present invention provided plays the penetrating agent that haze wax includes 10～30 parts.In the present invention, the weight portion of described penetrating agent
Number is preferably 12～28 parts, more preferably 15～25 parts, most preferably 18～22 parts.The present invention to the kind of described penetrating agent and
Source does not has special restriction, uses penetrating agent well known to those skilled in the art, can be commercially available by market.At this
In bright, described penetrating agent is preferably dodecylbenzene sodium sulfonate.The infiltration of 5511 models that Sichuan Da Wei company provides can be used
Agent.In the present invention, described penetrating agent act as improve the penetrating power playing haze wax in fur coat.
What the present invention provided plays the correctives that haze wax includes 1～5 part.In the present invention, the parts by weight of described correctives
It is preferably 2～4 parts, more preferably 2.5～3.5 parts.The present invention does not has special restriction to kind and the source of described correctives,
Use correctives well known to those skilled in the art, can be commercially available by market.In the present invention, described correctives is preferred
Banana aldehyde for natural perfume material Yu synthetic perfume.Rectifying of the YJ1070-2 model that Shanghai company of Ya Jia essence factory provides can be used
Taste agent.In the present invention, described correctives act as hiding lanoline, the abnormal flavour that the oils and fats such as chlorination Oleum Glycines produces, make stuffing
After fur coat there is suitable abnormal smells from the patient.
What the present invention provided plays the preservative that haze wax includes 1～5 part.In the present invention, the parts by weight of described preservative
It is preferably 2～4 parts, more preferably 2.5～3.5 parts.The present invention does not has special restriction to kind and the source of described preservative,
Use preservative well known to those skilled in the art, can be commercially available by market.In the present invention, described preservative is preferred
For the organic compound preservative without pentachlorophenol.The Da Weilite MT type that Sichuan Dowell Technology Co., Ltd. provides can be used
Number preservative.In the present invention, described preservative act as bacteria growing inhibiting, prevent from playing haze wax and rot, acid is smelly.
The invention provides the preparation method playing haze wax described in a kind of technique scheme, including:
By high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean oil, Pilus Caprae seu Ovis
Fat, mineral oil, lecithin, emulsifying agent, penetrating agent, correctives and preservative mixing, obtain playing haze wax.
In the present invention, described high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, ring
The kind of oxygen soybean oil, lanoline, mineral oil, lecithin, emulsifying agent, penetrating agent, correctives and preservative, source and mass ratio
With high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean described in technique scheme
Oil, lanoline, mineral oil, lecithin, emulsifying agent, penetrating agent, correctives and the kind of preservative, source are consistent with mass ratio,
Do not repeat them here.In the present invention, play the preparation method of haze wax described in and preferably include following steps:
(1) by high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean oil, sheep
Hair fat, mineral oil, lecithin and emulsifying agent mixing, obtain mixture；
(2) described mixture, penetrating agent, correctives and preservative are mixed, obtain playing haze wax.
In the present invention, the temperature that described step (1) mixes is preferably 60～65 DEG C, more preferably 61～64 DEG C, optimum
Elect 62～63 DEG C as.In the present invention, the incorporation time in described step (1) is preferably 1～3 hour, more preferably 1.5～
2.5 hours, most preferably 2 hours.In the present invention, the temperature that described step (2) mixes is preferably 35～40 DEG C, more preferably
36～39 DEG C, most preferably 37～38 DEG C.In the present invention, to be preferably 0.5～1.5 little for the incorporation time in described step (2)
Time, more preferably 0.8～1.2 hour, most preferably 1 hour.
Play in haze wax under the comprehensive function of various raw materials above-mentioned, make that the present invention provides play haze wax abnormal smells from the patient preferably, long-term
Exist not stratified, use after skin softness preferably and resistance to storage.
The technique of fur coat stuffing is preferably by the haze wax of playing using the present invention to provide:
Pickling fur is carried out 35 DEG C of pre-tanning: first using the salt of 40g/L and the peace Alumen of 40g/L to control pH is 3.5, tan
Make 60 minutes；The aluminium tanningagent using 2g/L again turns and stops combining tanning 3 hours；Finally use sodium bicarbonate to adjust pH to 3.6～3.8, go out
Skin dries；
The above-mentioned leather dried is played skin 2～3 hours playing Pi Jizhong by the haze wax of playing using that the present invention provides；Skin is played in investigation
Oil permeance property in fur, observes and plays haze wax permeability in fur, and test result plays haze wax for what the present invention provided
Can quickly penetrate into inside fur.
Leather after the playing skin skin that dries in the air was dry-cleaned 1～2 minute after 12 hours, obtained playing the fur after skin processes.
The above-mentioned pliability playing the fur after skin prepared of the test present invention, method particularly includes:
Dried fur is put into and falls soft rotary drum, rotate 8 hours, judged the flexibility of fur by feel, survey
Test result is, what the present invention provided plays the most soft of the fur after skin.
The above-mentioned color inhibition situation playing the fur after skin prepared of the test present invention, according to HG/T3698-2014 " footwear
Class non-yellowing test method " standard testing, test result is, what the present invention provided plays the surface color inhibition journey of the fur after skin
Degree: ultraviolet xanthochromia UB (level) 4.24 (4 grades), sun bulb xanthochromia UA (level) 3.96 (4 grades).
According to test result above it can be seen that the fur coat after haze wax processes of playing that the present invention provides absorbs infiltration relatively
Good, leather softness, surface does not has yellowing in 1 year, have preferable stuffing effect.Additionally, the system playing haze wax that the present invention provides
Preparation Method is simple, environmental protection, cheap.
By the present invention provide play in the vial that haze wax is contained in 50mL specification, 45 DEG C transfer set to 0 sky, 3 months, 6
The moon, 9 months, 12 months, observe the outward appearance playing haze wax of different time.Observed result is, what the present invention provided play haze wax 0～
December outer is sample and stablizes, is not layered, and the haze wax of playing that the present invention provides has preferable stability.
The source of the raw material used described in following example of the present invention is:
The vegetable oil acid that oleic acid provides for Guangzhou company of Gong Qing Chemical Co., Ltd.；
C16～the C18 mixed fatty alcohol that fatty alcohol provides for Qingdao excellent rope chemistry Science and Technology Ltd.；
The neat's foot oil that neat's foot oil provides for Shanghai grain rice International Trading Company Ltd；
The Oleum Brassicae campestris of the green Yuan Jing ridge model that polyunsaturated vegetable oil provides for Jiangxi Lvyuan Oil Industrial Co., Ltd.；
Chlorination Oleum Glycines provides chlorination Oleum Glycines product for Xin Yuan chemical plant, Shifang City company；
The chlorination methyl ester product that chlorination methyl ester provides for Xin Yuan chemical plant, Shifang City company；
The epoxy soybean oil that epoxy soybean oil provides for Guangzhou Zhong Ye Chemical Co., Ltd.；
The lanoline product that one-level lanoline provides for Wujiang Dragon Lord oils and fats company limited；
The mineral oil product of provide for Wuxi City Fu Min lubricating oil company limited No. 26# of 26# mineral oil；
The soy lecithin product that lecithin provides for Fu Hong bio tech ltd, Zhengzhou；
The emulsifier production of the AEO-9 model that emulsifying agent provides for BASF AG；
The penetrating agent product of 5511 models that penetrating agent provides for Sichuan Da Wei company；
The correctives product of the YJ1070-2 model that correctives provides for Shanghai company of Ya Jia essence factory；
The Da Weilite MT efficient sterilizing preservative product that preservative provides for Sichuan Dowell Technology Co., Ltd..
Embodiment 1
Add oleic acid and the C of 67g according to the amount that mol ratio is 1:1 in reactor16～C18Mixed fatty alcohol, with to first
Benzenesulfonic acid is catalyst, reacts at 100 DEG C, evacuation, and vacuum degree control, at 0.09MPa, is reacted 3 hours, controls acid number
Less than 1mgKOH/g, obtain high-grade aliphatic ester.Be cooled to 60 DEG C standby.
Embodiment 2
Add oleic acid and the C of 67g according to the amount that mol ratio is 1:1 in reactor16～C18Mixed fatty alcohol, with to first
Benzenesulfonic acid is catalyst, reacts at 105 DEG C, evacuation, and vacuum degree control, at 0.1MPa, is reacted 3 hours, controls acid number little
In 0.5mgKOH/g, obtain high-grade aliphatic ester.Be cooled to 65 DEG C standby.
Embodiment 3
Add oleic acid and the C of 67g according to the amount that mol ratio is 1:1.05 in reactor16～C18Mixed fatty alcohol, with right
Toluenesulfonic acid is catalyst, reacts at 95 DEG C, evacuation, and vacuum degree control, at 0.09MPa, is reacted 4 hours, controls acid number
Less than 0.5mgKOH/g, obtain high-grade aliphatic ester.Be cooled to 62 DEG C standby.
Embodiment 4
Add oleic acid and the C of 70g according to the amount that mol ratio is 1:1.05 in reactor16～C18Mixed fatty alcohol, with right
Toluenesulfonic acid is catalyst, reacts at 100 DEG C, evacuation, and vacuum degree control, at 0.09MPa, is reacted 4.5 hours, controls
Acid number is less than 0.5mgKOH/g, obtains high-grade aliphatic ester.Be cooled to 63 DEG C standby.
Embodiment 5
High-grade aliphatic ester that 120g embodiment 1 prepares, 100g neat's foot oil, 100g is added unsaturated in reactor
Vegetable oil, 25g chlorination Oleum Glycines, 25g chlorination methyl ester, 150g epoxy soybean oil, 300g one-level lanoline, 100g 26# mineral oil,
80g lecithin and 5g emulsifying agent, be incubated 2 hours at 60 DEG C, obtain mixture；
Described mixture is cooled to 35 DEG C, adds 5g penetrating agent, 5g correctives and 4g preservative, be incubated mixing in 1 hour,
Obtain playing haze wax.
According to the method described in technique scheme, fur is entered by the haze wax of playing using the embodiment of the present invention 5 to prepare
Row is played skin and is processed.
According to the method described in technique scheme, after what the test embodiment of the present invention 5 prepared play skin, play haze wax
Stuffing permeability, the pliability of fur coat, the color inhibition situation of fur coat, test result is, what the embodiment of the present invention 5 prepared plays
The stuffing good penetrability of the fur after skin, the most soft, ultraviolet xanthochromia UB (level) 4.11 (4 grades), sun bulb xanthochromia UA (level)
3.91 (4 grades).
Embodiment 6
High-grade aliphatic ester that 100g embodiment 2 prepares, 80g neat's foot oil, 100g is added unsaturated in reactor
Vegetable oil, 25g chlorination Oleum Glycines, 25g chlorination methyl ester, 150g epoxy soybean oil, 250g one-level lanoline, 100g 26# mineral oil,
100g lecithin and 5g emulsifying agent, be incubated 2 hours at 65 DEG C, obtain mixture；
Described mixture is cooled to 40 DEG C, adds 5g penetrating agent, 5g correctives and 4g preservative, be incubated mixing in 1 hour,
Obtain playing haze wax.
According to the method described in technique scheme, fur is entered by the haze wax of playing using the embodiment of the present invention 6 to prepare
Row is played skin and is processed.
According to the method described in technique scheme, after what the test embodiment of the present invention 6 prepared play skin, play haze wax
Stuffing permeability, the pliability of fur coat, the color inhibition situation of fur coat, test result is, what the embodiment of the present invention 6 prepared plays
The stuffing good penetrability of the fur after skin, the most soft, ultraviolet xanthochromia UB (level) 4.15 (4 grades), sun bulb xanthochromia UA (level)
3.95 (4 grades).
Embodiment 7
High-grade aliphatic ester that 110g embodiment 3 prepares, 120g neat's foot oil, 80g is added unsaturated in reactor
Vegetable oil, 25g chlorination Oleum Glycines, 25g chlorination methyl ester, 200g epoxy soybean oil, 350g one-level lanoline, 100g 26# mineral oil,
100g lecithin and 5g emulsifying agent, be incubated 2 hours at 60 DEG C, obtain mixture；
Described mixture is cooled to 42 DEG C, adds 5g penetrating agent, 5g correctives and 4g preservative, be incubated mixing in 1 hour,
Obtain playing haze wax.
According to the method described in technique scheme, fur is entered by the haze wax of playing using the embodiment of the present invention 7 to prepare
Row is played skin and is processed.
According to the method described in technique scheme, after what the test embodiment of the present invention 7 prepared play skin, play haze wax
Stuffing permeability, the pliability of fur coat, the color inhibition situation of fur coat, test result is, what the embodiment of the present invention 7 prepared plays
The stuffing good penetrability of the fur after skin, the most soft 10 points, ultraviolet xanthochromia UB (level) 4.19 (4 grades), sun bulb xanthochromia UA
(level) 3.93 (4 grades).
Embodiment 8
Add high-grade aliphatic ester that 105g embodiment 4 prepares in reactor, 80g neat's foot oil, 80g unsaturation are planted
Thing oil, 25g chlorination Oleum Glycines, 25g chlorination methyl ester, 150g epoxy soybean oil, 300g one-level lanoline, 80g 26# mineral oil, 80g
Lecithin and 5g emulsifying agent, be incubated 2 hours at 62 DEG C, obtain mixture；
Described mixture is cooled to 38 DEG C, adds 4g penetrating agent, 4g correctives and 5g preservative, be incubated mixing in 1 hour,
Obtain playing haze wax.
According to the method described in technique scheme, fur is entered by the haze wax of playing using the embodiment of the present invention 8 to prepare
Row is played skin and is processed.
According to the method described in technique scheme, after what the test embodiment of the present invention 8 prepared play skin, play haze wax
Stuffing permeability, the pliability of fur coat, the color inhibition situation of fur coat, test result is, what the embodiment of the present invention 8 prepared plays
The stuffing good penetrability of the fur after skin, the most soft, ultraviolet xanthochromia UB (level) 4.21 (4 grades), sun bulb xanthochromia UA (level)
3.98 (4 grades).
Comparative example 1
Use that commercially available Lao Ensitan company of the U.S. provides play haze wax TP model play haze wax.
According to the method described in technique scheme, fur is played skin by the haze wax of playing using the present invention to compare 1 offer
Process.
According to the method described in technique scheme, test that comparative example 1 of the present invention prepares play skin after play haze wax
Stuffing permeability, the pliability of fur coat, the color inhibition situation of fur coat, test result is, what comparative example 1 of the present invention prepared plays
The stuffing infiltration of the fur after skin is slower, it is impossible to completely penetrating inside fur, permeability is general；Relatively soft, pliability is general；
Ultraviolet xanthochromia UB (level) 3.25 (3 grades), sun bulb xanthochromia UA (level) 3.45 (3 grades).Compared with comparative example 1 prepared by the present invention
Play haze wax excellent performance, stable.
As seen from the above embodiment, the invention provides one and play haze wax, in parts by weight, including: 100～150 parts
High-grade aliphatic ester；The neat's foot oil of 80～120 parts；The polyunsaturated vegetable oil of 80～120 parts；The chlorination Oleum Glycines of 20～40 parts；20
～the chlorination methyl ester of 40 parts；The epoxy soybean oil of 150～250 parts；250 parts～the lanoline of 350 parts；The mineral of 80～120 parts
Oil；The lecithin of 80～120 parts；The emulsifying agent of 5～10 parts；The penetrating agent of 10～30 parts；The correctives of 1～5 part；1～5 part
Preservative.The oil of kicking a ball making the present invention provide under the comprehensive function of various raw materials in playing haze wax has preferable abnormal smells from the patient, length
Phase preserves not stratified, and the softness using rear skin is preferable and resistance to storage.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
1. play a haze wax, in parts by weight, including:
The high-grade aliphatic ester of 100～150 parts；
The neat's foot oil of 80～120 parts；
The polyunsaturated vegetable oil of 80～120 parts；
The chlorination Oleum Glycines of 20～40 parts；
The chlorination methyl ester of 20～40 parts；
The epoxy soybean oil of 150～250 parts；
250 parts～the lanoline of 350 parts；
The mineral oil of 80～120 parts；
The lecithin of 80～120 parts；
The emulsifying agent of 5～10 parts；
The penetrating agent of 10～30 parts；
The correctives of 1～5 part；
The preservative of 1～5 part.
The most according to claim 1 play haze wax, it is characterised in that described high-grade aliphatic ester by oleic acid and fatty alcohol through anti-
Should prepare.
The most according to claim 2 play haze wax, it is characterised in that described fatty alcohol be carbon number be the fat of 10～18
Alcohol.
The most according to claim 3 play haze wax, it is characterised in that the acid number of described high-grade aliphatic ester is less than 1mgKOH/
g。
The most according to claim 2 play haze wax, it is characterised in that the mol ratio of described oleic acid and fatty alcohol be 1:(0.5～
1.5)。
The most according to claim 1 play haze wax, it is characterised in that the kinematic viscosity of described mineral oil is 24～28mm2/s。
7. the preparation method playing haze wax described in any one in claim 1～6, including:
By high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean oil, lanoline, ore deposit
Thing oil, lecithin, emulsifying agent, penetrating agent, correctives and preservative mixing, obtain playing haze wax.
Method the most according to claim 7, it is characterised in that described in play the preparation method of haze wax and specifically include following step
Rapid:
(1) by high-grade aliphatic ester, neat's foot oil, polyunsaturated vegetable oil, chlorination Oleum Glycines, chlorination methyl ester, epoxy soybean oil, Pilus Caprae seu Ovis
Fat, mineral oil, lecithin and emulsifying agent mixing, obtain mixture；
(2) described mixture, penetrating agent, correctives and preservative are mixed, obtain playing haze wax.
Method the most according to claim 8, it is characterised in that in described step (1), the temperature of mixing is 60～65 DEG C；
In described step (2), the temperature of mixing is 35～40 DEG C.
Method the most according to claim 7, it is characterised in that the preparation method of described high-grade aliphatic ester includes:
Under the effect of p-methyl benzenesulfonic acid, oleic acid and fatty alcohol are reacted, obtains high-grade aliphatic ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756538.4A CN106191343B (en) | 2016-08-29 | 2016-08-29 | One kind kicking skin oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756538.4A CN106191343B (en) | 2016-08-29 | 2016-08-29 | One kind kicking skin oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106191343A true CN106191343A (en) | 2016-12-07 |
| CN106191343B CN106191343B (en) | 2018-07-17 |
Family
ID=58088216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610756538.4A Active CN106191343B (en) | 2016-08-29 | 2016-08-29 | One kind kicking skin oil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106191343B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082487A (en) * | 2018-09-12 | 2018-12-25 | 车井涛 | A kind of oiling method of environmental protection and energy saving standard mink skin |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040107504A1 (en) * | 2002-12-05 | 2004-06-10 | Blangiforti Anna Carner | Leather therapy treatment |
| CN101603102A (en) * | 2009-06-30 | 2009-12-16 | 陕西科技大学 | A kind of preparation method of composite water-proof leather fat-liquoring agent |
| CN103088169A (en) * | 2013-02-07 | 2013-05-08 | 浙江传化股份有限公司 | Leather comprehensive fat liquor and preparation method of the same |
| CN103789465A (en) * | 2012-11-05 | 2014-05-14 | 中国石油化工股份有限公司 | Leather greasing treatment agent and preparation method thereof |
| CN104032049A (en) * | 2014-06-19 | 2014-09-10 | 梁晓 | Multifunctional leather fatliquoring agent |
-
2016
- 2016-08-29 CN CN201610756538.4A patent/CN106191343B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040107504A1 (en) * | 2002-12-05 | 2004-06-10 | Blangiforti Anna Carner | Leather therapy treatment |
| CN101603102A (en) * | 2009-06-30 | 2009-12-16 | 陕西科技大学 | A kind of preparation method of composite water-proof leather fat-liquoring agent |
| CN103789465A (en) * | 2012-11-05 | 2014-05-14 | 中国石油化工股份有限公司 | Leather greasing treatment agent and preparation method thereof |
| CN103088169A (en) * | 2013-02-07 | 2013-05-08 | 浙江传化股份有限公司 | Leather comprehensive fat liquor and preparation method of the same |
| CN104032049A (en) * | 2014-06-19 | 2014-09-10 | 梁晓 | Multifunctional leather fatliquoring agent |
Non-Patent Citations (3)
| Title |
|---|
| 宋小平、韩长日主编: "《实用化学品配方手册》", 31 March 1996, 四川科学技术出版社 * |
| 李东光主编: "《皮革造纸添加剂生产与应用技术》", 31 July 2010, 化学工业出版社 * |
| 马建中主编: "《皮革化学品的合成原理与应用技术》", 31 August 2009, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082487A (en) * | 2018-09-12 | 2018-12-25 | 车井涛 | A kind of oiling method of environmental protection and energy saving standard mink skin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106191343B (en) | 2018-07-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101690514B (en) | Preparation method for honey peach fresh-keeping emulsion and application of honey peach fresh-keeping emulsion | |
| CN104365220B (en) | A kind of processing method of blue or green money willow seed | |
| CN107854326A (en) | A kind of hirudin moistens face moisturizing maintenance Essence | |
| CN104942937A (en) | Mulberry bark treatment method | |
| CN106234178A (en) | A kind of camellia seedling dedicated substrate | |
| CN104924381A (en) | Cornhusk mildew-proof insect-proof treatment method | |
| Livingston et al. | Dietary potassium and available phosphorous on broiler growth performance, carcass characteristics, and wooden breast | |
| CN106572683A (en) | Feed additive composition for reducing methane production of ruminants | |
| CN204015305U (en) | The anion bacteriostasis, and deodorization footwear of a kind of anion cloth and making thereof | |
| CN106279744A (en) | A kind of controlled release biocidal property eats composite membrane and preparation method thereof | |
| CN106191343A (en) | One plays haze wax and preparation method thereof | |
| CN101603102B (en) | Preparation method of composite water-proof leather fat-liquoring agent | |
| CN104726001A (en) | Leather surface treatment agent | |
| CN109498485A (en) | A kind of water-based nail polish | |
| CN105994372A (en) | Efficient mildew preventive | |
| CA2973894A1 (en) | Probiotic compositions and methods of use | |
| Andrade et al. | Dynamics of the chemical composition and productivity of composts for the cultivation of Agaricus bisporus strains | |
| CN105820695B (en) | Fire-retardant, antibacterial, waterproof graphene modified acrylic ester resin preparation method for coating | |
| CN105944521A (en) | Biologic mould inhibitor | |
| CN102309086A (en) | Silver-bearing antibacterial deodorizing shoe | |
| CN107299007A (en) | A kind of biological fruit-vegetable cleaning agent and preparation method | |
| CN105368608B (en) | One kind Chinese mugwort wax handmade soap and preparation method thereof | |
| KR20160068416A (en) | Manufacturing method of mineral water with increased mineral content | |
| CN104472060B (en) | A kind of method improving Flemingia philippinensis percentage of seedgermination | |
| CN108866258B (en) | Osmanthus-fragrance leather fatting agent and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |