CN106189530A - 一种金属用铁红防锈涂料 - Google Patents

一种金属用铁红防锈涂料 Download PDF

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CN106189530A
CN106189530A CN201610581403.9A CN201610581403A CN106189530A CN 106189530 A CN106189530 A CN 106189530A CN 201610581403 A CN201610581403 A CN 201610581403A CN 106189530 A CN106189530 A CN 106189530A
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沈旭源
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Abstract

本发明公开了一种金属用铁红防锈涂料，原料为：铁红、碳酸钙、硫酸钡、邻苯二甲酸二丁酯、乙基纤维素、硬脂酸铝、二苯胺、苯并三氮唑、氧化锌和磷酸三丁酯；涂膜外观平整光亮，粘度80‑100s，遮盖力240‑280g/cm2；耐水和防锈性能优异，附着力一级，耐盐雾15‑55d无异常，耐盐水性10‑30d不起泡、不脱落；表干1‑5h，实干12‑16h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。

Description

一种金属用铁红防锈涂料
技术领域
本发明涉及金属用材料技术领域，尤其涉及一种金属用铁红防锈涂料。
背景技术
铁红防锈漆是一种可保护金属表面免受大气、海水等的化学或电化学腐蚀的涂料。主要分为物理性和化学性铁红防锈漆两大类。前者靠颜料和漆料的适当配合，形成致密的漆膜以阻止腐蚀性物质的侵入，如铁红、铝粉、石墨铁红防锈漆等；后者靠铁红防锈颜料的化学抑锈作用，如红丹、锌黄铁红防锈漆等。用于桥梁、船舶、管道等金属的铁红防锈。
使用的铁红防锈漆大致为油性和水性两种。油性铁红防锈漆使材料表面油腻去除困难，已很少使用。油性铁红防锈漆使用方便，价格低廉，但因含有亚硝酸盐、铬酸盐等有毒物质，对操作人员危害较大，国家已限制使用，且此类产品性能单一，不能满足磁性合金材料的铁红防锈要求。
水性金属铁红防锈漆选用金属强力螯合剂肌醇六磷酸酯为主要成分，与其他几种水性助剂复配而成。肌醇六磷酸酯是从粮食作物中提取的天然无毒有机化工产品，当它作为磁性材料铁红防锈剂使用时，能在表面与金属迅速螯合，形成一层致密的单分子络合物保护膜，可有效抑制金属的腐蚀。经该产品处理后的材料表面保持原色，不必水洗即可进入涂装等下道工序。
铁红防锈颜料是铁红防锈漆的重要组成部分.物理铁红防锈颜料是一类本身化学性质较为稳定的颜料,它们是靠本身的物理性能,化学性能稳定,质地坚硬,颗粒细微,优良的填充性,提高漆膜的致密度,降低漆膜的可渗性从而起到铁红防锈的作用.氧化铁红就属这类物质.而金属铝粉的铁红防锈性是由于铝粉具有鳞片状结构,形成漆膜紧密,还有较强的反射紫外线光的能力,可提高漆膜抗老化的能力。
铁红防锈漆的主要成分是铁红防锈颜料和成膜物质。通常以铁红防锈颜料的名称而命名，如：红丹铁红防锈油漆、铁红铁红防锈油漆等等。如果以它的铁红防锈作用来分，大致可分为四大类：物理作用铁红防锈油漆、化学作用铁红防锈油漆、电化学作用铁红防锈油漆、综合作用铁红防锈油漆。
发明内容
本发明提供一种干燥快、强度高的金属用铁红防锈涂料，解决现有金属用涂料干燥慢和不耐盐雾等技术问题。
本发明采用以下技术方案：一种金属用铁红防锈涂料，其原料按质量份数配比如下：铁红100份，碳酸钙40-60份，硫酸钡15-55份，邻苯二甲酸二丁酯10-50份，乙基纤维素5-45份，硬脂酸铝10-30份，二苯胺5-25份，苯并三氮唑1-5份，氧化锌2-6份，磷酸三丁酯4-8份。
作为本发明的一种优选技术方案：所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙45-55份，硫酸钡25-45份，邻苯二甲酸二丁酯20-40份，乙基纤维素15-35份，硬脂酸铝15-25份，二苯胺10-20份，苯并三氮唑2-4份，氧化锌3-5份，磷酸三丁酯5-7份。
作为本发明的一种优选技术方案：所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙45份，硫酸钡25份，邻苯二甲酸二丁酯20份，乙基纤维素15份，硬脂酸铝15份，二苯胺10份，苯并三氮唑2份，氧化锌3份，磷酸三丁酯5份。
作为本发明的一种优选技术方案：所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙55份，硫酸钡45份，邻苯二甲酸二丁酯40份，乙基纤维素35份，硬脂酸铝25份，二苯胺20份，苯并三氮唑4份，氧化锌5份，磷酸三丁酯7份。
作为本发明的一种优选技术方案：所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙50份，硫酸钡35份，邻苯二甲酸二丁酯30份，乙基纤维素25份，硬脂酸铝20份，二苯胺15份，苯并三氮唑3份，氧化锌4份，磷酸三丁酯6份。
有益效果
本发明所述一种金属用铁红防锈涂料采用以上技术方案与现有技术相比，具有以下技术效果：1、涂膜外观平整光亮，粘度80-100s，遮盖力240-280g/cm2；2、耐水和防锈性能优异，附着力一级，耐盐雾15-55d无异常，耐盐水性10-30d不起泡、不脱落；3、表干1-5h，实干12-16h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。
具体实施方式
以下结合实例对本发明作进一步的描述，实施例仅用于对本发明进行说明，并不构成对权利要求范围的限制，本领域技术人员可以想到的其他替代手段，均在本发明权利要求范围内。
实施例1：
第一步：按照质量份数配比称取铁红100份，碳酸钙40份，硫酸钡15份，邻苯二甲酸二丁酯10份，乙基纤维素5份，硬脂酸铝10份，二苯胺5份，苯并三氮唑1份，氧化锌2份，磷酸三丁酯4份。
第二步：将铁红、碳酸钙、硫酸钡、邻苯二甲酸二丁酯和硬脂酸铝投入反应釜中，加热至140℃，以200r/min速度搅拌10min。
第三步：将搅拌均匀后的液体静置120min，加入乙基纤维素、二苯胺、苯并三氮唑、氧化锌和磷酸三丁酯，在170℃混合均匀后投入研磨机研磨16h,过滤后包装。
涂膜外观平整光亮，粘度80s，遮盖力240g/cm2；耐水和防锈性能优异，附着力一级，耐盐雾15d无异常，耐盐水性10d不起泡、不脱落；表干5h，实干16h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。
实施例2：
第一步：按照质量份数配比称取铁红100份，碳酸钙60份，硫酸钡55份，邻苯二甲酸二丁酯50份，乙基纤维素45份，硬脂酸铝30份，二苯胺25份，苯并三氮唑5份，氧化锌6份，磷酸三丁酯8份。
第二步：将铁红、碳酸钙、硫酸钡、邻苯二甲酸二丁酯和硬脂酸铝投入反应釜中，加热至160℃，以400r/min速度搅拌50min。
第三步：将搅拌均匀后的液体静置160min，加入乙基纤维素、二苯胺、苯并三氮唑、氧化锌和磷酸三丁酯，在190℃混合均匀后投入研磨机研磨20h,过滤后包装。
涂膜外观平整光亮，粘度85s，遮盖力250g/cm2；耐水和防锈性能优异，附着力一级，耐盐雾25d无异常，耐盐水性15d不起泡、不脱落；表干4h，实干15h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。
实施例3：
第一步：按照质量份数配比称取铁红100份，碳酸钙45份，硫酸钡25份，邻苯二甲酸二丁酯20份，乙基纤维素15份，硬脂酸铝15份，二苯胺10份，苯并三氮唑2份，氧化锌3份，磷酸三丁酯5份。
第二步：将铁红、碳酸钙、硫酸钡、邻苯二甲酸二丁酯和硬脂酸铝投入反应釜中，加热至140℃，以200r/min速度搅拌10min。
第三步：将搅拌均匀后的液体静置120min，加入乙基纤维素、二苯胺、苯并三氮唑、氧化锌和磷酸三丁酯，在170℃混合均匀后投入研磨机研磨16h,过滤后包装。
涂膜外观平整光亮，粘度90s，遮盖力260g/cm2；耐水和防锈性能优异，附着力一级，耐盐雾35d无异常，耐盐水性30d不起泡、不脱落；表干3h，实干14h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。
实施例4：
第一步：按照质量份数配比称取铁红100份，碳酸钙55份，硫酸钡45份，邻苯二甲酸二丁酯40份，乙基纤维素35份，硬脂酸铝25份，二苯胺20份，苯并三氮唑4份，氧化锌5份，磷酸三丁酯7份。
第二步：将铁红、碳酸钙、硫酸钡、邻苯二甲酸二丁酯和硬脂酸铝投入反应釜中，加热至160℃，以400r/min速度搅拌50min。
第三步：将搅拌均匀后的液体静置160min，加入乙基纤维素、二苯胺、苯并三氮唑、氧化锌和磷酸三丁酯，在190℃混合均匀后投入研磨机研磨20h,过滤后包装。
涂膜外观平整光亮，粘度95s，遮盖力270g/cm2；耐水和防锈性能优异，附着力一级，耐盐雾45d无异常，耐盐水性25d不起泡、不脱落；表干2h，实干13h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。
实施例5：
第一步：按照质量份数配比称取铁红100份，碳酸钙50份，硫酸钡35份，邻苯二甲酸二丁酯30份，乙基纤维素25份，硬脂酸铝20份，二苯胺15份，苯并三氮唑3份，氧化锌4份，磷酸三丁酯6份。
第二步：将铁红、碳酸钙、硫酸钡、邻苯二甲酸二丁酯和硬脂酸铝投入反应釜中，加热至150℃，以300r/min速度搅拌30min。
第三步：将搅拌均匀后的液体静置140min，加入乙基纤维素、二苯胺、苯并三氮唑、氧化锌和磷酸三丁酯，在180℃混合均匀后投入研磨机研磨18h,过滤后包装。
涂膜外观平整光亮，粘度100s，遮盖力280g/cm2；耐水和防锈性能优异，附着力一级，耐盐雾55d无异常，耐盐水性30d不起泡、不脱落；表干1h，实干12h，制备方法简单，原料简单易得，可以广泛生产并不断代替现有材料。

Claims (5)

1.一种金属用铁红防锈涂料，其特征在于，所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙40-60份，硫酸钡15-55份，邻苯二甲酸二丁酯10-50份，乙基纤维素5-45份，硬脂酸铝10-30份，二苯胺5-25份，苯并三氮唑1-5份，氧化锌2-6份，磷酸三丁酯4-8份。
2.根据权利要求1所述的一种金属用铁红防锈涂料，其特征在于，所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙45-55份，硫酸钡25-45份，邻苯二甲酸二丁酯20-40份，乙基纤维素15-35份，硬脂酸铝15-25份，二苯胺10-20份，苯并三氮唑2-4份，氧化锌3-5份，磷酸三丁酯5-7份。
3.根据权利要求1所述的一种金属用铁红防锈涂料，其特征在于，所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙45份，硫酸钡25份，邻苯二甲酸二丁酯20份，乙基纤维素15份，硬脂酸铝15份，二苯胺10份，苯并三氮唑2份，氧化锌3份，磷酸三丁酯5份。
4.根据权利要求2所述的一种金属用铁红防锈涂料，其特征在于，所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙55份，硫酸钡45份，邻苯二甲酸二丁酯40份，乙基纤维素35份，硬脂酸铝25份，二苯胺20份，苯并三氮唑4份，氧化锌5份，磷酸三丁酯7份。
5.根据权利要求1所述的一种金属用铁红防锈涂料，其特征在于：所述金属用铁红防锈涂料的原料按质量份数配比如下：铁红100份，碳酸钙50份，硫酸钡35份，邻苯二甲酸二丁酯30份，乙基纤维素25份，硬脂酸铝20份，二苯胺15份，苯并三氮唑3份，氧化锌4份，磷酸三丁酯6份。
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KR20080067700A (ko) * 2005-11-10 2008-07-21 시그마칼론 비.브이. 에폭시계 코팅
CN104927417A (zh) * 2015-06-30 2015-09-23 苏州乔纳森新材料科技有限公司 一种医用铁红防锈漆及其制备方法

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CN104927417A (zh) * 2015-06-30 2015-09-23 苏州乔纳森新材料科技有限公司 一种医用铁红防锈漆及其制备方法

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