CN106186699A - A kind of ceramic preparation with vivid image - Google Patents

A kind of ceramic preparation with vivid image Download PDF

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Publication number
CN106186699A
CN106186699A CN201610501034.8A CN201610501034A CN106186699A CN 106186699 A CN106186699 A CN 106186699A CN 201610501034 A CN201610501034 A CN 201610501034A CN 106186699 A CN106186699 A CN 106186699A
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China
Prior art keywords
image
color
ceramic preparation
vivid image
oxide
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CN201610501034.8A
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Chinese (zh)
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CN106186699B (en
Inventor
吴全发
宋江水
杨金华
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Hubei Xin Laili Chinaware Progression Co Ltd
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Hubei Xin Laili Chinaware Progression Co Ltd
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Priority to CN201610501034.8A priority Critical patent/CN106186699B/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Printing Methods (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The present invention provides a kind of ceramic preparation with vivid image, comprises the following steps: one, image procossing；Choose the monochromatic colour developing of at least one in image, prepare screen mesh printing plate；Two, stock is prepared；Three, at stock surface print pattern in the way of ink-jet；Four, in the way of silk screen printing, the colour developing chosen is printed on stock surface；Five, kiln-firing, obtains semi-finished product；Six, on semi-finished product, cover-coat enamel is coated；Seven, kiln-firing, obtains the pottery with vivid image.By using the scheme of Image semantic classification, combine the bright-colored advantage that can make complicated image with ink jet printing definition height of silk screen printing, it is thus achieved that there is the ceramic of vivid image.And production efficiency is high, equipment cost is low, and manufactured goods are bright-colored, natural color transition.

Description

A kind of ceramic preparation with vivid image
Technical field
The present invention relates to Production of Ceramics field, a kind of ceramic preparation with vivid image.
Background technology
Pattern many employings manual drawing on traditional ceramics surface, bright in luster attractive in appearance, liked by consumer.But it is traditional Pottery is higher to the requirement of mapper, when pattern is complicated, then production efficiency is low, and percent defective is high, and labor intensity is high.
Develop through technology, pottery silk-screen printing technique, such as Chinese patent literature CN104924789A occur, i.e. records A kind of pottery silk screen environmental protection printing technique, uses special stamp colorant, is covered on white embryo by silk screen, equal with spreading knife Even extruding is smeared and is made colorant penetrate the pattern on silk screen, throws off silk screen, and colorant is set on white embryo formation decalcomania, on Glaze, and put into high temperature kiln and form by a firing, obtain printed ceramic ceramic products.The ceramic product that the process that the present invention provides makes, The most bright-colored, carefully and neatly spend, and be complementary to one another painting the color advantage with applique.
Chinese patent literature CN 103351712A, describes a kind of ceramic wire silk screen printing ink, the adhesive force to pottery By force, difficult drop-off, strong coloring force, printing effect is excellent, is rich in third dimension.
But above-mentioned mode of printing has the biggest defect, i.e. silk screen printing to be affected by mode of printing, printing essence Spending the highest, definition is not enough, and can only print of the same colour every time, and chromatography difficulty between polychrome, intermediate color is beyond expression of words.
Along with further development, occur in that ceramic ink ink-jet printing process, utilize nozzle that ceramic ink is sprayed on pottery The surface of porcelain, thus obtain the image of fine definition.Such as Chinese patent literature CN102433044A i.e. describe a kind of for The ink of 3D digital ink-jet ceramic tile, has fine definition, third dimension and mirror effect.But ink-jetting process there is problems of, For guaranteeing ink jet precision, colorant and granules of accessories typically require the least particle diameter, and less particle diameter is non-in sintering procedure Chang Rongyi is because aoxidizing and variable color, thus causes the bright-coloured degree of color, i.e. color saturation cannot ensure, color is obscure, shadow Ring appearance.And more flaw easily occurs in ink-jetting process, the biggest color lump easily occurring, horizontal line, scarce ink cause disconnected Line, the problems such as intermediate color is uneven, and be difficult to be overcome by technological means, shower nozzle can only be changed, cause cost increase.
Also having decalcomia technique and cylinder printing process, wherein decalcomia technique is similar to caloric transfer printing technology, the most only Can be hand-manipulated, inefficient.And roll printing many employings intaglio printing, plate-making cost is much more expensive, and equipment cost is the most very Height, and operation complexity.
Summary of the invention
The technical problem to be solved is to provide a kind of ceramic preparation with vivid image, it is possible to become This relatively low mode mass-produces the ceramic with vivid image, in preferred scheme, and image can be made to have Glittering and translucent stereoeffect.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is: a kind of ceramic with vivid image Preparation Method, comprises the following steps:
One, image procossing；
Choose the monochromatic colour developing of at least one in image, prepare screen mesh printing plate；
Two, stock is prepared；
Three, at stock surface print pattern in the way of ink-jet；
Four, in the way of silk screen printing, the colour developing chosen is printed on stock surface；
Five, kiln-firing, obtains semi-finished product；
Six, on semi-finished product, cover-coat enamel is coated；
Seven, kiln-firing, obtains the pottery with vivid image.
Preferably in scheme, described colour developing is prominent color lump, the color lump of larger area of finger vision and needs bright-coloured face The color lump of color.
Preferably in scheme, the intermediate color in colour developing is fabricated to the form of reticulate pattern, and denseer part site is relatively big, thin Part site is less.
Preferably in scheme, in step 2, stock is dried through sintering.
Preferably in scheme, in step 3, before ink-jet, intermediate color is optimized, image is arranged and is converted to CMYK color pattern, intermediate color is to carry out transition less than three kinds of colors.
Preferably in scheme, intermediate color is to carry out transition less than two kinds of colors.
Preferably in scheme, in step 3, before ink-jet, is polished in stock surface, smooth to guarantee, and block Micropore.
Preferably in scheme, described cover-coat enamel is powder, is printed on the surface of semi-finished product in the way of silk screen printing.
Preferably in scheme, cover-coat enamel includes the following components remembered by weight:
Frit 40～50, potassium feldspar 10～20, clay 3～7,28～32 parts of quartz, titanium oxide 8～12, titanium dioxide 3～5 Part, ferrum oxide 3～7, lead oxide 3～6 parts, antimony oxide 5～6 parts, prodan 3～6 parts, Zirconium orthosilicate. is 3～6；High Ridge soil is 2～6；Colorant is 0.5～2,
Wherein: the constitutive material of frit is: silicon dioxide 64%, aluminium sesquioxide 7%, iron sesquioxide 1%, calcium oxide 8%, magnesium oxide 0.5%, potassium oxide 4%, sodium oxide 4%, diboron trioxide 11%, zinc oxide 0.5%.
Preferably in scheme, the reticulate pattern of cover-coat enamel is made according to image, and the position reticulate pattern of image vision projection is relatively big, recessed position Reticulate pattern is less.
A kind of ceramic preparation with vivid image that the present invention provides, by using the scheme of Image semantic classification, Combine the bright-colored advantage that can make complicated image with ink jet printing definition height of silk screen printing, it is thus achieved that have bright-coloured The ceramic of image.And production efficiency is high, equipment cost is low, and manufactured goods are bright-colored, natural color transition.Preferably scheme In, use the cover-coat enamel of powder, utilize the mode of silk screen printing, form scraggly surface texture according to image, highest point and Lowest part can reach 5mm, and the finished product after firing can form the coloured glaze layer with embossment stereoeffect, reflective due to light And refraction, coordinate the vivid image of bottom, there is the artistic effect of uniqueness.Cover-coat enamel of the present invention has good resistance to acids and bases, and Glaze smoothness is good, glaze slip performance is good, firing range width, the wear-resisting difficult drop-off of glaze；And also there is good thermal shock resistance.
Accompanying drawing explanation
The invention will be further described with embodiment below in conjunction with the accompanying drawings:
Fig. 1 is the original image of the present invention.
Fig. 2 is the plate-making picture of colour developing in the present invention.
Fig. 3 is the plate-making picture of another colour developing in the present invention.
Fig. 4 is the plate-making picture of another colour developing in the present invention.
Detailed description of the invention
A kind of ceramic preparation with vivid image, comprises the following steps:
One, image procossing；
Choose the monochromatic colour developing of at least one in image, prepare screen mesh printing plate；
Preferably in scheme, described colour developing is prominent color lump, the color lump of larger area of finger vision and needs bright-colored Color lump.
In Fig. 1 ~ 4, in FIG, the most red, golden and blue through comparing the colour developing of selection, wherein redness is The color lump that vision is prominent, as shown in Figure 2, and in the color that ink jet printing mode is formed, red and pink colour is difficult to ensure that fresh Gorgeous effect, through analyzing, it may be possible to colorant oxidation during high-temperature firing, and the colorant granularity in ink-jet ink and content mistake Low, it is difficult to the reasons such as color development.Therefore select red as one of colour developing.It is able to ensure that by silk screen printing and obtains bright-coloured i.e. color Accurate mutually, color saturation is high, the color that glossiness is high.Use the mode of silk screen printing, additionally it is possible to there is the effect of plastic relief Really.
Gold is then the color lump needing bright-colored, as shown in Figure 3, in the gold that ink jet printing mode is formed, Manufactured goods are shown as brown, poor effect, use the mode of silk screen printing, print gold in particular by the powder containing metal Color, has the most bright-coloured effect, and reflectance is high, and color is saturated, and can have the effect of plastic relief, and artistic effect is complete Beautiful.
Blueness is the color lump of larger area, as shown in Figure 4, it can be avoided that band occur, break in the way of silk screen printing The common flaw such as line, improves product appearance effect, rate of reducing the number of rejects and seconds.
Preferably in scheme, the intermediate color in colour developing is fabricated to the form of reticulate pattern, and denseer part site is relatively big, thin Part site is less.
Two, stock is prepared；
Preferably in scheme, in step 2, stock is dried through sintering.Being prepared as of stock is commonly used in the prior art, herein Repeat no more.
Three, at stock surface print pattern in the way of ink-jet；
Preferably in scheme, in step 3, before ink-jet, is polished in stock surface, smooth to guarantee, and block micro- Hole.Thus structure, makes stock surface keep smooth, is conducive to improving the precision of images, and is easy to ink attachment.Surface micropore is made to seal Stifled, it is possible to avoid ink too much to enter into stock surface, affect color development.The mode of closure micropore is to surface stock with polishing disk Surface is polished, and polishing time is shorter than normal polishing time.
Preferably in scheme, in step 3, before ink-jet, intermediate color is optimized, image is arranged and is converted to CMYK color pattern, intermediate color is to carry out transition less than three kinds of colors.
In further preferred scheme, intermediate color is to carry out transition less than two kinds of colors.
Such as pink colour intermediate color in Fig. 1, has partial color to be shown as C20M70Y20, and partial color is shown as C3M10Y5, in ink jet process, can spray the ink droplet of three kinds of colors, due to the error in ink jet process, easily be formed herein, The flaw of variegated point, the ink droplet of more polychrome, the probability forming variegated point is higher, affects the appearance of finished product.Intermediate color is excellent Turn to transit to M5Y1 from M75Y20, then make color transition the purest, form variegated point hardly, improve outward appearance effect Really.
Four, in the way of silk screen printing, the colour developing chosen is printed on stock surface；Step one such as obtain as Fig. 2 ~ Redness in 4, golden and blue.Trichroism print respectively, carry out chromatography with photoelectric sensor, print speed and use 20 ms/min.
Five, kiln-firing, obtains semi-finished product；Firing temperature is 1080 DEG C ~ 1250 DEG C.
Six, on semi-finished product, cover-coat enamel is coated；
Preferably in scheme, described cover-coat enamel is powder, is printed on the surface of semi-finished product in the way of silk screen printing.
Preferably in scheme, the stacking highest point height of cover-coat enamel is for 1 ~ 5mm.To form stereoeffect.
Preferably in scheme, cover-coat enamel includes the following components remembered by weight:
Frit 40～50, potassium feldspar 10～20, clay 3～7,28～32 parts of quartz, titanium oxide 8～12, titanium dioxide 3～5 Part, ferrum oxide 3～7, lead oxide 3～6 parts, antimony oxide 5～6 parts, prodan 3～6 parts, Zirconium orthosilicate. is 3～6；High Ridge soil is 2～6；Colorant is 0.5～2,
Wherein: the constitutive material of frit is: silicon dioxide 64%, aluminium sesquioxide 7%, iron sesquioxide 1%, calcium oxide 8%, magnesium oxide 0.5%, potassium oxide 4%, sodium oxide 4%, diboron trioxide 11%, zinc oxide 0.5%.
According to different effects, it is also possible to add SrO 2 ~ 3 parts, ZnO 4-6 part, K2O 4 ~ 5 parts, Na2O 3 ~ 5 parts, Li2O 3 ~ 5 parts, B2O3 8 ~ 12 parts.
Cover-coat enamel can be with thin color and luster, the most blue Co-Al-Zn that adds, and the partially red colorant Fe-Cr-Zn that adds is partially yellow Add colorant Zr-Fe-Si.
Preferably in scheme, the reticulate pattern of cover-coat enamel is made according to image, and the position reticulate pattern of image vision projection is relatively big, recessed Position reticulate pattern is less.Thus scheme obtains the pottery with embossment stereoeffect.
After firing, the three-dimensional cover-coat enamel of formation is curved surface, and highest point height is progressively transitioned into edge up to 5mm, in gap Position, can not have cover-coat enamel, the contrast being consequently formed on reflectance, forms unique artistic effect.
Seven, kiln-firing, firing temperature is 1080 DEG C ~ 1500 DEG C, obtains the pottery with vivid image.
The above embodiments are only the preferred technical solution of the present invention, and are not construed as the restriction for the present invention, this The technical scheme that bright protection domain should be recorded with claim, including technical characteristic in the technical scheme that claim is recorded Equivalents is protection domain.Equivalent the most in this range is improved, also within protection scope of the present invention.

Claims (10)

1. there is a ceramic preparation for vivid image, it is characterized in that comprising the following steps:
One, image procossing；
Choose the monochromatic colour developing of at least one in image, prepare screen mesh printing plate；
Two, stock is prepared；
Three, at stock surface print pattern in the way of ink-jet；
Four, in the way of silk screen printing, the colour developing chosen is printed on stock surface；
Five, kiln-firing, obtains semi-finished product；
Six, on semi-finished product, cover-coat enamel is coated；
Seven, kiln-firing, obtains the pottery with vivid image.
A kind of ceramic preparation with vivid image the most according to claim 1, is characterized in that: described colour developing is The prominent color lump of finger vision, the color lump of larger area and need the color lump of bright-colored.
A kind of ceramic preparation with vivid image the most according to claim 1, is characterized in that: the transition in colour developing Color is fabricated to the form of reticulate pattern, and denseer part site is relatively big, and thin part site is less.
A kind of ceramic preparation with vivid image the most according to claim 1, is characterized in that: in step 2, embryo Material is dried through sintering.
A kind of ceramic preparation with vivid image the most according to claim 1, is characterized in that: in step 3, Before ink-jet, being optimized for intermediate color, arranged by image and be converted to CMYK color pattern, intermediate color is with less than three kinds of face Color carries out transition.
A kind of ceramic preparation with vivid image the most according to claim 5, is characterized in that: intermediate color is not to surpass Cross two kinds of colors and carry out transition.
A kind of ceramic preparation with vivid image the most according to claim 1, is characterized in that: in step 3, Before ink-jet, is polished in stock surface, smooth to guarantee, and block micropore.
A kind of ceramic preparation with vivid image the most according to claim 1, is characterized in that: described cover-coat enamel is Powder, is printed on the surface of semi-finished product in the way of silk screen printing.
A kind of ceramic preparation with vivid image the most according to claim 8, is characterized in that cover-coat enamel includes by weight The following components of amount part note:
Frit 10～50, potassium feldspar 10～20, clay 3～7,28～50 parts of quartz, titanium oxide 0～12, titanium dioxide 3～5 Part, ferrum oxide 3～7, lead oxide 3～6 parts, antimony oxide 5～6 parts, prodan 3～6 parts, Zirconium orthosilicate. is 3～6；High Ridge soil is 2～6；Colorant is 0.5～2,
Wherein: the constitutive material of frit is: silicon dioxide 64%, aluminium sesquioxide 7%, iron sesquioxide 1%, calcium oxide 8%, magnesium oxide 0.5%, potassium oxide 4%, sodium oxide 4%, diboron trioxide 11%, zinc oxide 0.5%.
A kind of ceramic preparation with vivid image the most according to claim 8, is characterized in that the reticulate pattern root of cover-coat enamel Making according to image, the position reticulate pattern of image vision projection is relatively big, and recessed position reticulate pattern is less.
CN201610501034.8A 2016-06-30 2016-06-30 Preparation method for ceramic with bright-colored image Active CN106186699B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112888750A (en) * 2018-09-24 2021-06-01 地板工业有限公司 Ceramic inks for inkjet digital printing

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