CN106147672A - A kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof - Google Patents
A kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof Download PDFInfo
- Publication number
- CN106147672A CN106147672A CN201510173718.5A CN201510173718A CN106147672A CN 106147672 A CN106147672 A CN 106147672A CN 201510173718 A CN201510173718 A CN 201510173718A CN 106147672 A CN106147672 A CN 106147672A
- Authority
- CN
- China
- Prior art keywords
- aqueous
- binding agent
- initiator
- agent
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof, it is characterized in that, this binding agent is polymerized through emulsion by double acrylic compounds polyurethane, acrylic monomer, styrene, emulsifying agent, initiator, polymerization inhibitor, pH value regulator, aqueous wetting agent, aqueous defoamer, deionized water.Use homemade reactive emulsifier and double acrylic compounds polyurethane, double bond is all contained at molecule two ends, the aqueous binder of preparation in film forming procedure can self-crosslinking, the network structure of cross-linking type in being formed, there is good resistance to water, solvent resistance and cohesive strength.This binding agent is to having extremely strong bonding force and good resistance to water between the low surface tension materials such as polyethylene, polypropylene, polyester, nylon, aluminium foil.It is widely used in flexible package and moulds/mould compound mechanization production process, the advantage with high efficiency, high-quality, environmental protection.
Description
Technical field
The present invention relates to polymer binder preparation field, be specifically related to a kind of poly-for moulding/mould compound aqueous
Urethane acrylate binding agent and preparation method thereof.
Background technology
Chinese patent ZL201010252736.X reports the poly-ammonia containing ionic group of a kind of uV curable
Ester acrylate adhesive and preparation method thereof, by macromolecular polyol adds carboxylic acid compound or sulfonate,
Add diisocyanate and catalyst after dehydration, add after intensification the monohydric alcohol containing acrylate group and from
By base polymerization inhibitor, temperature control reaction obtains the mixed of urethane acrylate polymer, addition diluent and initiator
Compound i.e. obtains product.This diluent is iso-bornyl acrylate or trimethylolpropane trimethacrylate,
Belong to organic solvent, environment and operator will certainly be brought certain harm.
Patent ZL201010280182.4 of our company reports a kind of flexible package composite membrane ultraviolet cured water-based
Adhesive and preparation method thereof, with epoxide modified polyester polyurethane acrylate water-base resin as adhesive
Primary resins, although be green environment protection water adhesive, but preparation method is more complicated.
Patent ZL201010280190.9 of our company reports a kind of novel reaction type emulsifying agent and preparation side thereof
Method, is used this kind of homemade reactive emulsifier and double acrylic compounds polyurethane, is polymerized by simple emulsion
Reaction has i.e. been invented a kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof.
This aqueous binder does not contains poisonous and harmful substance, can self-crosslinking in film forming procedure, it is not necessary to ultraviolet light irradiates
I.e. can solidify, and there is good resistance to water, solvent resistance and cohesive strength.
Summary of the invention
The problem run into for current aqueous binder industry prior art, the invention provides a kind of for moulding/
Mould compound aqueous polyurethane acrylate binding agent and preparation method thereof.
Technical scheme is as described below: a kind of viscous for moulding/mould compound aqueous polyurethane acrylate
Mixture, it is characterised in that this binding agent by double acrylic compounds polyurethane, acrylic monomer, styrene,
Emulsifying agent, initiator, polymerization inhibitor, pH value regulator, aqueous wetting agent, aqueous defoamer, deionized water
It is polymerized through emulsion.The low surfaces such as polyethylene, polypropylene, polyester, nylon, aluminium foil are opened by this binding agent
There is between dead-wood material extremely strong bonding force and good resistance to water.
In described aqueous polyurethane acrylate binding agent, the consumption of each raw material is by weight percentage:
The structural formula of described double acrylic compounds polyurethane is as follows:
N=1 in formula～5, A are polyester group or polyether group, R1And R2For carbon number 1～18 straight chain or
Branched paraffin, R3For hydrogen atom or methyl, R4For any one in following structural formula:
Described acrylic monomer be acrylic acid, butyl acrylate, ethyl acrylate, Isooctyl acrylate monomer,
Any one or more in 2-(Acryloyloxy)ethanol, Hydroxypropyl acrylate, methacrylic acid；
Described emulsifying agent is homemade reactive emulsifier；
Described initiator is the one in Ammonium persulfate., potassium peroxydisulfate, sodium peroxydisulfate；
Described polymerization inhibitor is 4-methoxyphenol；
Described pH value regulator is ammonia；
Described aqueous wetting agent is polyether-modified polydimethylsiloxane type wetting agent；
Described aqueous defoamer is butine diones defoamer.
Described a kind of preparation method for moulding/mould compound aqueous polyurethane acrylate binding agent, it is special
Levy and be, comprise the following steps:
Weigh each raw material by proportioning, in emulsifying kettle, add and account for whole deionized water gross weight 10～20% go
Ionized water, opens stirring, adds and accounts for whole emulsifying agent gross weight 80～the emulsifying agent of 90%, is subsequently adding double third
Olefin(e) acid class polyurethane, acrylic monomer, styrene, stir formation emulsion；
Add account for ionized water gross weight 70～the deionized water of 80% in a kettle., open stirring, be warming up to
80 DEG C, add remaining emulsifying agent and whole polymerization inhibitor；First the initiator deionized water of about 20 times of weight
Dissolved and form initiator solution, join in reactor the 70～80% of whole initiator solutions, take complete
The 10 of portion's emulsion～15% are added drop-wise in reactor, time for adding about 30 minutes, reaction temperature control 79～
81 DEG C, continue insulation reaction 30 minutes；
In insulating process, remaining initiator solution being joined in emulsifying kettle, the formation that stirs contains
The emulsion of initiator, is added to the emulsion droplet containing initiator in reactor, drips off at 3.5～4 hours
Finishing, reaction temperature controls at 79～81 DEG C；Drip complete follow-up continuous insulation reaction 30～60 minutes, then drop
Temperature, to less than 40 DEG C, regulates pH value 6.0～7.0 by pH value regulator, adds aqueous wetting agent and aqueous disappears
Infusion, stirs, and i.e. obtains aqueous polyurethane acrylate binding agent.
The beneficial effects of the present invention is: use homemade reactive emulsifier and double acrylic compounds polyurethane,
All contain double bond at molecule two ends, the aqueous binder of preparation in film forming procedure can self-crosslinking, formed in
The network structure of cross-linking type, has good resistance to water, solvent resistance and cohesive strength.This binding agent is to poly-
Have between the low surface tension materials such as ethylene, polypropylene, polyester, nylon, aluminium foil extremely strong bonding force and
Well resistance to water.It is widely used in flexible package and moulds/mould compound mechanization production process, there is high efficiency, height
Quality, the advantage of environmental protection.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail:
Embodiment 1
In emulsifying kettle, add deionized water 3000g, open stirring, add homemade reactive emulsifier
250g, be subsequently adding double acrylic compounds polyurethane 1200g, acrylic acid 500g, ethyl acrylate 12000g,
Butyl acrylate 2500g, 2-(Acryloyloxy)ethanol 2000g, styrene 5000g, stir formation emulsion；
In a kettle. add deionized water 15600g, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 50g and polymerization inhibitor 4-methoxyphenol 5g；First 120g Ammonium persulfate. 2400g go from
Sub-water dissolution forms initiator solution, then 2000g initiator solution is joined in reactor；Take 3000g
Emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C, continues
Insulation reaction 30 minutes；
In insulating process, remaining 520g initiator solution being joined in emulsifying kettle, stir formation
Containing the emulsion of initiator, the emulsion droplet containing initiator is added in reactor, at 3.5～4 hours
Dripping complete, reaction temperature controls at 79～81 DEG C；Drip complete follow-up continuous insulation reaction 30～60 minutes,
Then it is cooled to less than 40 DEG C, regulates pH value 6.72 with 350g ammonia, add 80g aqueous wetting agent and 50g
Aqueous defoamer, stirs, and i.e. obtains aqueous polyurethane acrylate binding agent.
Embodiment 2
In emulsifying kettle, add deionized water 4500g, open stirring, add homemade reactive emulsifier
400g, be subsequently adding double acrylic compounds polyurethane 1800g, methacrylic acid 1000g, butyl acrylate 10000g,
Isooctyl acrylate monomer 2000g, Hydroxypropyl acrylate 3000g, styrene 7500g, stir formation emulsifying
Liquid；
In a kettle. add deionized water 16500g, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 50g and polymerization inhibitor 4-methoxyphenol 5g；First 100g sodium peroxydisulfate 2000g go from
Sub-water dissolution forms initiator solution, then takes 1500g initiator solution and join in reactor；Take 4000g
Emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C, continues
Insulation reaction 30 minutes；
In insulating process, remaining 600g initiator solution being joined in emulsifying kettle, stir formation
Containing the emulsion of initiator, the emulsion droplet containing initiator is added in reactor, at 3.5～4 hours
Dripping complete, reaction temperature controls at 79～81 DEG C；
Drip complete follow-up continuous insulation reaction 30～60 minutes, be then cooled to less than 40 DEG C, use 250g ammonia
Water regulation pH value 6.57, adds 120g aqueous wetting agent and 50g aqueous defoamer, stirs, to obtain final product
To aqueous polyurethane acrylate binding agent.
Embodiment 3
In emulsifying kettle, add deionized water 2000g, open stirring, add homemade reactive emulsifier
65g, is subsequently adding double acrylic compounds polyurethane 1300g, butyl acrylate 9000g, styrene 12500g,
Stir formation emulsion；Add deionized water 14000g in a kettle., open stirring, be warming up to 80 DEG C,
Add homemade reactive emulsifier 15g and polymerization inhibitor 4-methoxyphenol 5g；First 200g potassium peroxydisulfate
Form initiator solution with 4000g deionized water dissolving, then take 3000g initiator solution and join instead
Answer in still；Taking 3000g emulsion droplet to be added in reactor, time for adding about 30 minutes, reaction temperature controls
At 79～81 DEG C, continue insulation reaction 30 minutes；
In insulating process, remaining 1200g initiator solution being joined in emulsifying kettle, stir shape
Become the emulsion containing initiator, the emulsion droplet containing initiator is added in reactor, little in 3.5～4
In time, drip complete, and reaction temperature controls at 79～81 DEG C；
Drip complete follow-up continuous insulation reaction 30～60 minutes, be then cooled to less than 40 DEG C, use 300g ammonia
Water regulation pH value 6.83, adds 200g aqueous wetting agent and 80g aqueous defoamer, stirs, to obtain final product
To aqueous polyurethane acrylate binding agent.
Embodiment 4
In emulsifying kettle, add deionized water 3500g, open stirring, add homemade reactive emulsifier
180g, be subsequently adding double acrylic compounds polyurethane 500g, methacrylic acid 1000g, ethyl acrylate 8000g,
Butyl acrylate 2000,2-(Acryloyloxy)ethanol 1000g, styrene 8000g, stir formation emulsion；
In a kettle. add deionized water 14500g, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 20g and polymerization inhibitor 4-methoxyphenol 5g；First 100g Ammonium persulfate. 2000g go from
Sub-water dissolution forms initiator solution, then takes 1500g initiator solution and join in reactor；Take 3000g
Emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C, continues
Insulation reaction 30 minutes；
In insulating process, remaining 600g initiator solution being joined in emulsifying kettle, stir formation
Containing the emulsion of initiator, the emulsion droplet containing initiator is added in reactor, at 3.5～4 hours
Dripping complete, reaction temperature controls at 79～81 DEG C；Drip complete follow-up continuous insulation reaction 30～60 minutes,
Then be cooled to less than 40 DEG C, with 400g ammonia regulate pH value 6.97, add 250g aqueous wetting agent and
50g aqueous defoamer, stirs, and i.e. obtains aqueous polyurethane acrylate binding agent.
Embodiment 5
In emulsifying kettle, add deionized water 3000g, open stirring, add homemade reactive emulsifier
170g, be subsequently adding double acrylic compounds polyurethane 1000g, acrylic acid 1000g, methacrylic acid 10000g,
Ethyl acrylate 500g, butyl acrylate 1500g, Isooctyl acrylate monomer 3000g, 2-(Acryloyloxy)ethanol 1000g,
Hydroxypropyl acrylate 2000g, styrene 5000g, stir formation emulsion；
In a kettle. add deionized water 18000g, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 30g and polymerization inhibitor 4-methoxyphenol 5g；First 100g sodium peroxydisulfate 2000g go from
Sub-water dissolution forms initiator solution, then takes 1500g initiator solution and join in reactor；Take 3000g
Emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C, continues
Insulation reaction 30 minutes；
In insulating process, remaining 600g initiator solution being joined in emulsifying kettle, stir formation
Containing the emulsion of initiator, the emulsion droplet containing initiator is added in reactor, at 3.5～4 hours
Dripping complete, reaction temperature controls at 79～81 DEG C；
Drip complete follow-up continuous insulation reaction 30～60 minutes, be then cooled to less than 40 DEG C, use 800g ammonia
Water regulation pH value 6.96, adds 300g aqueous wetting agent and 60g aqueous defoamer, stirs, to obtain final product
To aqueous polyurethane acrylate binding agent.
Embodiment 6
In emulsifying kettle, add deionized water 2800g, open stirring, add homemade reactive emulsifier
160g, be subsequently adding double acrylic compounds polyurethane 800g, butyl acrylate 10000g, Hydroxypropyl acrylate 500g,
2-(Acryloyloxy)ethanol 1000g, methacrylic acid 500g, styrene 10000g, stir formation emulsion；
In a kettle. add deionized water 18200g, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 40g and polymerization inhibitor 4-methoxyphenol 5g；First 200g Ammonium persulfate. 4000g go from
Sub-water dissolution forms initiator solution, then takes 3000g initiator solution and join in reactor；Take 3000g
Emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C, continues
Insulation reaction 30 minutes；
In insulating process, remaining 1200g initiator solution being joined in emulsifying kettle, stir shape
Become the emulsion containing initiator, the emulsion droplet containing initiator is added in reactor, little in 3.5～4
In time, drip complete, and reaction temperature controls at 79～81 DEG C；
Drip complete follow-up continuous insulation reaction 30～60 minutes, be then cooled to less than 40 DEG C, use 250g ammonia
Water regulation pH value 6.29, adds 100g aqueous wetting agent and 60g aqueous defoamer, stirs, to obtain final product
To aqueous polyurethane acrylate binding agent.
Embodiment 7
In emulsifying kettle, add deionized water 500kg, open stirring, add homemade reactive emulsifier
70kg, be subsequently adding double acrylic compounds polyurethane 100kg, methacrylic acid 200kg, ethyl acrylate 200kg,
Butyl acrylate 1800kg, Isooctyl acrylate monomer 300kg, 2-(Acryloyloxy)ethanol 300kg, Hydroxypropyl acrylate
200kg, styrene 2000kg, stir formation emulsion；
In a kettle. add deionized water 3600kg, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 10kg and polymerization inhibitor 4-methoxyphenol 1kg；First 20kg sodium peroxydisulfate 400kg is gone
Ionized water dissolves and forms initiator solution, then takes 300kg initiator solution and join in reactor；Take
700kg emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C,
Continue insulation reaction 30 minutes；In insulating process, remaining 120kg initiator solution is joined emulsifying
In still, stir and form the emulsion containing initiator, the emulsion droplet containing initiator is added to reaction
In still, complete dropping in 3.5～4 hours, reaction temperature controls at 79～81 DEG C；
Drip complete follow-up continuous insulation reaction 30～60 minutes, be then cooled to less than 40 DEG C, use 80kg ammonia
Water regulation pH value 6.56, adds 20kg aqueous wetting agent and 10kg aqueous defoamer, stirs, to obtain final product
To aqueous polyurethane acrylate binding agent.
Embodiment 8
In emulsifying kettle, add deionized water 800kg, open stirring, add homemade reactive emulsifier
40kg, is subsequently adding double acrylic compounds polyurethane 200kg, butyl acrylate 1000kg, Hydroxypropyl acrylate
500kg, 2-(Acryloyloxy)ethanol 1000kg, styrene 1000kg, stir formation emulsion；
In a kettle. add deionized water 4100kg, open stirring, be warming up to 80 DEG C, add homemade instead
Answer type emulsifying agent 10kg and polymerization inhibitor 4-methoxyphenol 1kg；First 30kg Ammonium persulfate. 600kg is gone
Ionized water dissolves and forms initiator solution, then takes 480kg initiator solution and join in reactor；Take
500kg emulsion droplet is added in reactor, time for adding about 30 minutes, and reaction temperature controls at 79～81 DEG C,
Continue insulation reaction 30 minutes；
In insulating process, remaining 150kg initiator solution being joined in emulsifying kettle, stir shape
Become the emulsion containing initiator, the emulsion droplet containing initiator is added in reactor, little in 3.5～4
In time, drip complete, and reaction temperature controls at 79～81 DEG C；
Drip complete follow-up continuous insulation reaction 30～60 minutes, be then cooled to less than 40 DEG C, use 100kg ammonia
Water regulation pH value 6.81, adds 30kg aqueous wetting agent and 10kg aqueous defoamer, stirs, to obtain final product
To aqueous polyurethane acrylate binding agent.
The patented product that homemade reactive emulsifier is our company in above-described embodiment 1～8, refers to patent
ZL201010280190.9, aqueous wetting agent is polyether-modified polydimethylsiloxane type wetting agent, and aqueous disappears
Infusion is butine diones defoamer.
The foregoing is only presently preferred embodiments of the present invention, all equalizations done according to scope of the invention as claimed
Change and modification, all should belong to the covering scope of the claims in the present invention.
Claims (2)
1. one kind is used for moulding/mould compound aqueous polyurethane acrylate binding agent, it is characterised in that this binding agent
By double acrylic compounds polyurethane, acrylic monomer, styrene, emulsifying agent, initiator, polymerization inhibitor, pH
Value regulator, aqueous wetting agent, aqueous defoamer, deionized water are polymerized through emulsion.This binding agent pair
Between the low surface tension materials such as polyethylene, polypropylene, polyester, nylon, aluminium foil, there is extremely strong bonding force
And good resistance to water.
In described aqueous polyurethane acrylate binding agent, the consumption of each raw material is by weight percentage:
The structural formula of described double acrylic compounds polyurethane is as follows:
N=1 in formula～5, A are polyester group or polyether group, R1And R2For carbon number 1～18 straight chain or
Branched paraffin, R3For hydrogen atom or methyl, R4For any one in following structural formula:
Described acrylic monomer be acrylic acid, butyl acrylate, ethyl acrylate, Isooctyl acrylate monomer,
Any one or more in 2-(Acryloyloxy)ethanol, Hydroxypropyl acrylate, methacrylic acid；
Described emulsifying agent is homemade reactive emulsifier；
Described initiator is the one in Ammonium persulfate., potassium peroxydisulfate, sodium peroxydisulfate；
Described polymerization inhibitor is 4-methoxyphenol；
Described pH value regulator is ammonia；
Described aqueous wetting agent is polyether-modified polydimethylsiloxane type wetting agent；
Described aqueous defoamer is butine diones defoamer.
A kind of system for moulding/mould compound aqueous polyurethane acrylate binding agent
Preparation Method, it is characterised in that comprise the following steps:
Weigh each raw material by proportioning, in emulsifying kettle, add and account for whole deionized water gross weight 10～20% go
Ionized water, opens stirring, adds and accounts for whole emulsifying agent gross weight 80～the emulsifying agent of 90%, is subsequently adding double third
Olefin(e) acid class polyurethane, acrylic monomer, styrene, stir formation emulsion；
Add account for ionized water gross weight 70～the deionized water of 80% in a kettle., open stirring, be warming up to
80 DEG C, add remaining emulsifying agent and whole polymerization inhibitor；First the initiator deionized water of about 20 times of weight
Dissolved and form initiator solution, join in reactor the 70～80% of whole initiator solutions, take complete
The 10 of portion's emulsion～15% are added drop-wise in reactor, time for adding about 30 minutes, reaction temperature control 79～
81 DEG C, continue insulation reaction 30 minutes；
In insulating process, remaining initiator solution being joined in emulsifying kettle, the formation that stirs contains
The emulsion of initiator, was added to the emulsion droplet containing initiator in reactor, dropping in 3.5～4 hours
Complete, reaction temperature controls at 79～81 DEG C；Drip complete follow-up continuous insulation reaction 30～60 minutes, then
It is cooled to less than 40 DEG C, regulates pH value 6.0～7.0 by pH value regulator, add aqueous wetting agent and aqueous
Defoamer, stirs, and i.e. obtains aqueous polyurethane acrylate binding agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510173718.5A CN106147672B (en) | 2015-04-07 | 2015-04-07 | It is a kind of to be used to moulding/moulding compound aqueous polyurethane acrylate adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510173718.5A CN106147672B (en) | 2015-04-07 | 2015-04-07 | It is a kind of to be used to moulding/moulding compound aqueous polyurethane acrylate adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106147672A true CN106147672A (en) | 2016-11-23 |
| CN106147672B CN106147672B (en) | 2018-06-19 |
Family
ID=57336879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510173718.5A Active CN106147672B (en) | 2015-04-07 | 2015-04-07 | It is a kind of to be used to moulding/moulding compound aqueous polyurethane acrylate adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106147672B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106674437A (en) * | 2016-12-31 | 2017-05-17 | 佛山市顺德区巴德富实业有限公司 | Polyurethane-acrylate hybrid emulsion and preparation method thereof |
| CN106810647A (en) * | 2016-12-27 | 2017-06-09 | 东莞市浩彩油墨科技有限公司 | A kind of water-based ink resin binding material and preparation method thereof |
| CN109705278A (en) * | 2018-12-26 | 2019-05-03 | 广东衡光新材料科技有限公司 | Aqueous acrylic emulsion and preparation method thereof for automobile electrophoresis finish |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101704923A (en) * | 2009-11-18 | 2010-05-12 | 北京高盟化工有限公司 | Water-based acrylic acid emulsion, water-based adhesive for aluminum-plating film composite material and preparation method thereof |
| CN101864025A (en) * | 2010-06-21 | 2010-10-20 | 东莞市凯迪克高分子材料有限公司 | Preparation method of polyacrylate microgel emulsion and application thereof |
| CN102618193A (en) * | 2012-04-16 | 2012-08-01 | 广州荣域实业有限公司 | Water-based composite adhesive |
| CN103059784A (en) * | 2013-02-01 | 2013-04-24 | 东莞市星宇高分子材料有限公司 | Water-based plastic-plastic compound adhesive for food and drug flexible package and preparation method thereof |
| CN103275653A (en) * | 2013-05-13 | 2013-09-04 | 浙江科冠聚合物有限公司 | Acrylic plastic-plastic composite latex |
| CN103865448A (en) * | 2014-03-27 | 2014-06-18 | 山东华诚高科胶粘剂有限公司 | Aqueous composite adhesive and preparation method for same |
-
2015
- 2015-04-07 CN CN201510173718.5A patent/CN106147672B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101704923A (en) * | 2009-11-18 | 2010-05-12 | 北京高盟化工有限公司 | Water-based acrylic acid emulsion, water-based adhesive for aluminum-plating film composite material and preparation method thereof |
| CN101864025A (en) * | 2010-06-21 | 2010-10-20 | 东莞市凯迪克高分子材料有限公司 | Preparation method of polyacrylate microgel emulsion and application thereof |
| CN102618193A (en) * | 2012-04-16 | 2012-08-01 | 广州荣域实业有限公司 | Water-based composite adhesive |
| CN103059784A (en) * | 2013-02-01 | 2013-04-24 | 东莞市星宇高分子材料有限公司 | Water-based plastic-plastic compound adhesive for food and drug flexible package and preparation method thereof |
| CN103275653A (en) * | 2013-05-13 | 2013-09-04 | 浙江科冠聚合物有限公司 | Acrylic plastic-plastic composite latex |
| CN103865448A (en) * | 2014-03-27 | 2014-06-18 | 山东华诚高科胶粘剂有限公司 | Aqueous composite adhesive and preparation method for same |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810647A (en) * | 2016-12-27 | 2017-06-09 | 东莞市浩彩油墨科技有限公司 | A kind of water-based ink resin binding material and preparation method thereof |
| CN106810647B (en) * | 2016-12-27 | 2020-08-11 | 东莞市浩彩油墨科技有限公司 | Water-based ink resin binder and preparation method thereof |
| CN106674437A (en) * | 2016-12-31 | 2017-05-17 | 佛山市顺德区巴德富实业有限公司 | Polyurethane-acrylate hybrid emulsion and preparation method thereof |
| CN109705278A (en) * | 2018-12-26 | 2019-05-03 | 广东衡光新材料科技有限公司 | Aqueous acrylic emulsion and preparation method thereof for automobile electrophoresis finish |
| CN109705278B (en) * | 2018-12-26 | 2021-10-08 | 广东衡光新材料科技有限公司 | Water-based acrylic emulsion for automobile electrophoresis finish paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106147672B (en) | 2018-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103360561B (en) | Polyurethane modified acrylic emulsion, preparation method of acrylic emulsion and prepared artificial stone | |
| CN106147672A (en) | A kind of for moulding/mould compound aqueous polyurethane acrylate binding agent and preparation method thereof | |
| CN102134292B (en) | Preparation method for polyvinylidene fluoride with high molten fluidity | |
| CN101864025B (en) | Preparation method of polyacrylate microgel emulsion and application thereof | |
| CN105086857B (en) | A kind of environment-friendly type aqueous rubber protective film and preparation method thereof | |
| CN103626910A (en) | Solid ethylene-vinyl acetate copolymer and preparation method thereof | |
| CN109651569A (en) | A kind of aqueous epoxy resins modifying agent of emulsified asphalt and its preparation method and application method | |
| CN103275260B (en) | Preparation method of acrylic plastic-plastic composite latex | |
| CN104559853A (en) | Composition and preparation method of multipurpose environment-friendly aqueous laminating adhesive | |
| CN105439852B (en) | A kind of synthetic method of the single-ended ether-ether series compound of polyalkylene glycol acrylate | |
| CN101676347A (en) | 60% high solid content pressure-sensitive adhesive and preparation method thereof | |
| CN106632791B (en) | One kind resisting fresh cement accumulation of salt in the surface soil priming paint styrene-acrylic emulsion and preparation method thereof | |
| CN106188420B (en) | Anti- bleeding type water-reducing agent and preparation method thereof | |
| CN102040697B (en) | Method for preparing adhesive purpose chloroprene rubber | |
| CN103865448B (en) | A kind of water-based composite gum and preparation method thereof | |
| CN102993353A (en) | Acrylic ester waterproof paint copolymerization emulsion and preparation method thereof | |
| CN105331213A (en) | Epoxy modified acrylate copolymerization emulsion used for preparing two-component latex paint | |
| CN106147659A (en) | A kind of for moulding/mould compound phosphoric acrylic ester binding agent and preparation method thereof | |
| CN105585658A (en) | Normal-temperature self-crosslinking fluorine-containing acrylate emulsion for woodware and preparation method thereof | |
| CN106674437A (en) | Polyurethane-acrylate hybrid emulsion and preparation method thereof | |
| CN102617866A (en) | Preparation method of nonionic polyethylene wax emulsion | |
| CN103497622B (en) | A kind of environment-friendly type contains interpenetrating polymer network anticorrosion paint of inorganic particulate and preparation method thereof | |
| CN104744632A (en) | Preparation method of low-molecular-weight cationic polyacrylamide hydrophilic coating | |
| CN107459605A (en) | A kind of high-speed coating paper-plastic stick high solid content and low viscosity acrylic pressure sensitive adhesives preparation method | |
| CN103694402B (en) | A kind of water-soluble colloidality polyacrylic ester filling resin for leather and preparation technology thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |