CN106147333A - A kind of dubbin paint - Google Patents

A kind of dubbin paint Download PDF

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Publication number
CN106147333A
CN106147333A CN201610571823.9A CN201610571823A CN106147333A CN 106147333 A CN106147333 A CN 106147333A CN 201610571823 A CN201610571823 A CN 201610571823A CN 106147333 A CN106147333 A CN 106147333A
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Prior art keywords
parts
resin
resistant
chemicals
dubbin
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Pending
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CN201610571823.9A
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Chinese (zh)
Inventor
黎红波
毛璞
李冬冬
刘晶晶
王昱伟
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Xinxiang University
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Xinxiang University
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Priority to CN201610571823.9A priority Critical patent/CN106147333A/en
Publication of CN106147333A publication Critical patent/CN106147333A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06Artists' paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of dubbin paint, it is prepared from by the raw material of following weight portion: polyester urethane resin 30~44 parts, core-shell acrylic elastic emulsion 33~43 parts, AS resin 3~8 parts, paraffin 15~20 parts, natural chitosan inorganic metal ion coordination compound 0.3~0.6 part, heat-resistant agent 3~6 parts, chemicals-resistant modifying agent 0.8~2.2 parts, heat filling 10~25 parts, infrared external reflection titanium dioxide 1.25~2.75 parts, light stabilizer 0.6~1 part, polymerization oleum lini 2.3~4.7 parts, siritch 31~39 parts, Oleum Terebinthinae 1.4~3.6 parts, polystyrene glycol 4~8 parts, mill base 7~13 parts;The weight average molecular weight of described AS resin is 3~10W, and AN content is 20~35%.Good water-proof effect of the present invention, adhesive force is strong, and weatherability and good corrosion resistance have certain anti-microbial property, and the most easy to crack.

Description

A kind of dubbin paint
Technical field
The present invention relates to painting supply field, be specifically related to a kind of dubbin paint.
Background technology
Oil colour is a kind of special drawing pigment of oil painting, pigment powder refuel and glue agitation grinding forms, oil colour Basis as other drawing pigment by colorant, extender pigment, vehicle and the such as plastotype agent of some adjuvant, stabilizer, Slow dry agent or drier etc. are constituted.Period deposited after paintings complete by existing oil colour can be by moisture vapor in air Impact, causes color and luster dim, loses original gloss, the texture that impact is overall, and corrosion resistance, weatherability and antibiotic property are relatively Difference.
Summary of the invention
For solving the problems referred to above, the invention provides a kind of dubbin paint, good water-proof effect, adhesive force is strong, weather-proof Property and good corrosion resistance, there is certain anti-microbial property, and the most easy to crack, peel off.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of dubbin paint, is prepared from by the raw material of following weight portion:
Polyester urethane resin 30~44 parts, core-shell acrylic elastic emulsion 33~43 parts, AS resin 3~8 parts, stone Wax 15~20 parts, natural chitosan-inorganic metal ion coordination compound 0.3~0.6 part, heat-resistant agent 3~6 parts, chemicals-resistant modification Agent 0.8~2.2 parts, heat filling 10~25 parts, infrared external reflection titanium dioxide 1.25~2.75 parts, light stabilizer 0.6~1 part, Polymerization oleum lini 2.3~4.7 parts, siritch 31~39 parts, Oleum Terebinthinae 1.4~3.6 parts, polystyrene glycol 4~8 parts, mill base 7 ~13 parts;
The weight average molecular weight of described AS resin is 3~10W, and AN content is 20~35%, described chemicals-resistant modifying agent For fluorinated additive.
Preferably, the raw material of following weight portion it is prepared from:
Polyester urethane resin 37 parts, core-shell acrylic elastic emulsion 38 parts, AS resin 5.5 parts, 17.5 parts of paraffin, Natural chitosan-inorganic metal ion coordination compound 0.45 part, heat-resistant agent 4.5 parts, chemicals-resistant modifying agent 1.5 parts, heat filling 17.5 parts, infrared external reflection titanium dioxide 2 parts, light stabilizer 0.8 part, polymerization oleum lini 3.5 parts, siritch 35 parts, Oleum Terebinthinae 2.5 Part, polystyrene glycol 6 parts, mill base 10 parts.
Preferably, described chemicals-resistant modifying agent is the acrylic acid series additive of perfluoroalkyl.
Preferably, described light stabilizer be salicylate, benzophenone, the UV absorbent of triazines and hindered amines from By the base agent for capturing mixing gained of 2:1 in mass ratio.
Preferably, described infrared external reflection titanium dioxide particle diameter is 1000nm-1200nm, TiO2Content is 80%-90%, Surface coating layer SiO2With Al2O3Content be 10-20%.
Preferably, described heat filling is magnesium oxide, zinc oxide, boron nitride, aluminium nitride 3:1:2:1 in mass ratio mixing Gained, the particle diameter of described heat filling is more than 95% in 0.5um-1.0um, purity.
Preferably, described heat-resistant agent is copolymer or the copolymer of-methyl styrene of N-phenylmaleimide.
The method have the advantages that
By select Ultra-low molecular weight AS resin, improve mobility, reduce in pigment dry run produce interior Stress, is simultaneously introduced the acrylic acid series additive of perfluoroalkyl as chemicals-resistant modifying agent, the transport efficiency pole of this additive Height, can being completely migrating to surface in preparation process, to form a kind of protecting film, this layer of protecting film and water incompatible and have relatively The performance of strong acid and alkali-resistance, can greatly reduce cracking situation, improves spraying yield;Use infrared external reflection titanium dioxide, Ke Yi great The visible ray of amplitude reflection sunlight and infrared part energy, the collaborative contribution of the heat release of heat filling, can make relatively in addition The surface temperature of oil painting is greatly reduced, thus substantially increases the weatherability of oil painting;Natural chitosan-inorganic metal ion Coordination compound works in coordination with the interpolation of core-shell acrylic elastic emulsion so that the pigment of gained is further while having preferable antibiotic property Improve the performances such as the water proofing property of oil colour, weatherability, resistance to dirt retention and UV resistant.Gained oil colour of the present invention is waterproof Effective, adhesive force is strong, and weatherability and good corrosion resistance have certain anti-microbial property, and the most easy to crack.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out further Describe in detail.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit this Bright.
The acrylic acid series additive that chemicals-resistant modifying agent is perfluoroalkyl that following example are used;The light used Stabilizer is that salicylate, benzophenone, the UV absorbent of triazines and hindered amines free radical scavenger 2:1 in mass ratio are mixed Close gained;The infrared external reflection titanium dioxide particle diameter used is 1000nm-1200nm, TiO2Content is 80%-90%, and surface is wrapped Coating SiO2With Al2O3Content be 10-20%;The heat filling used be magnesium oxide, zinc oxide, boron nitride, aluminium nitride by Mass ratio 3:1:2:1 mixing gained, the particle diameter of described heat filling is more than 95% in 0.5um-1.0um, purity;Used is resistance to Thermit powder is copolymer or the copolymer of-methyl styrene of N-phenylmaleimide.
Embodiment 1
A kind of dubbin paint, is prepared from by the raw material of following weight portion:
Polyester urethane resin 30 parts, core-shell acrylic elastic emulsion 33 parts, AS resin 3 parts, 15 parts of paraffin, natural Chitosan-inorganic metal ion coordination compound 0.3 part, heat-resistant agent 3 parts, chemicals-resistant modifying agent 0.8 part, heat filling 10 parts, red External reflectance titanium dioxide 1.25 parts, light stabilizer 0.6 part, polymerization oleum lini 2.3 parts, siritch 31 parts, Oleum Terebinthinae 1.4 parts, poly- Styrene glycol 4 parts, mill base 7 parts;
The weight average molecular weight of described AS resin is 3~10W, and AN content is 20~35%.
Embodiment 2
A kind of dubbin paint, is prepared from by the raw material of following weight portion:
Polyester urethane resin 44 parts, core-shell acrylic elastic emulsion 43 parts, AS resin 8 parts, 20 parts of paraffin, natural Chitosan-inorganic metal ion coordination compound 0.6 part, heat-resistant agent 6 parts, chemicals-resistant modifying agent 2.2 parts, heat filling 25 parts, red External reflectance titanium dioxide 2.75 parts, light stabilizer 1 part, polymerization oleum lini 4.7 parts, siritch 31~39 parts, Oleum Terebinthinae 3.6 parts, Polystyrene glycol 8 parts, mill base 13 parts;
The weight average molecular weight of described AS resin is 3~10W, and AN content is 20~35%.
Embodiment 3
A kind of dubbin paint, is prepared from by the raw material of following weight portion:
Polyester urethane resin 37 parts, core-shell acrylic elastic emulsion 38 parts, AS resin 5.5 parts, 17.5 parts of paraffin, Natural chitosan-inorganic metal ion coordination compound 0.45 part, heat-resistant agent 4.5 parts, chemicals-resistant modifying agent 1.5 parts, heat filling 17.5 parts, infrared external reflection titanium dioxide 2 parts, light stabilizer 0.8 part, polymerization oleum lini 3.5 parts, siritch 35 parts, Oleum Terebinthinae 2.5 Part, polystyrene glycol 6 parts, mill base 10 parts.
The weight average molecular weight of described AS resin is 3~10W, and AN content is 20~35%.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (7)

1. a dubbin paint, it is characterised in that be prepared from by the raw material of following weight portion:
Polyester urethane resin 30~44 parts, core-shell acrylic elastic emulsion 33~43 parts, AS resin 3~8 parts, paraffin 15 ~20 parts, natural chitosan-inorganic metal ion coordination compound 0.3~0.6 part, heat-resistant agent 3~6 parts, chemicals-resistant modifying agent 0.8 ~2.2 parts, heat filling 10~25 parts, infrared external reflection titanium dioxide 1.25~2.75 parts, light stabilizer 0.6~1 part, polymerization Asia Oleum Sesami 2.3~4.7 parts, siritch 31~39 parts, Oleum Terebinthinae 1.4~3.6 parts, polystyrene glycol 4~8 parts, mill base 7~13 Part;
The weight average molecular weight of described AS resin is 3~10W, and AN content is 20~35%, and described chemicals-resistant modifying agent is for containing Fluorine class additive.
A kind of dubbin paint the most according to claim 1, it is characterised in that by the raw material preparation of following weight portion Become:
Polyester urethane resin 37 parts, core-shell acrylic elastic emulsion 38 parts, AS resin 5.5 parts, 17.5 parts of paraffin, natural Chitosan-inorganic metal ion coordination compound 0.45 part, heat-resistant agent 4.5 parts, chemicals-resistant modifying agent 1.5 parts, heat filling 17.5 Part, infrared external reflection titanium dioxide 2 parts, light stabilizer 0.8 part, polymerization oleum lini 3.5 parts, siritch 35 parts, Oleum Terebinthinae 2.5 parts, Polystyrene glycol 6 parts, mill base 10 parts.
A kind of dubbin paint the most according to claim 1, it is characterised in that described chemicals-resistant modifying agent is perfluor The acrylic acid series additive of alkyl.
A kind of dubbin paint the most according to claim 1, it is characterised in that described light stabilizer is salicylic acid Ester, benzophenone, the UV absorbent of triazines and the hindered amines free radical scavenger mixing gained of 2:1 in mass ratio.
A kind of dubbin paint the most according to claim 1, it is characterised in that described infrared external reflection titanium dioxide grain Footpath is 1000nm-1200nm, TiO2Content is 80%-90%, surface coating layer SiO2With Al2O3Content be 10-20%.
A kind of dubbin paint the most according to claim 1, it is characterised in that described heat filling be magnesium oxide, Zinc oxide, boron nitride, the aluminium nitride mixing gained of 3:1:2:1 in mass ratio, the particle diameter of described heat filling at 0.5um-1.0um, Purity is more than 95%.
A kind of dubbin paint the most according to claim 1, it is characterised in that described heat-resistant agent is N-phenyl maleoyl The copolymer of imines or the copolymer of-methyl styrene.
CN201610571823.9A 2016-07-20 2016-07-20 A kind of dubbin paint Pending CN106147333A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106928830A (en) * 2017-03-29 2017-07-07 江西科技学院 A kind of architectural decoration coating material
CN107227084A (en) * 2017-07-03 2017-10-03 河南工程学院 A kind of waterproof art painting of dilutable water and preparation method thereof
CN107573736A (en) * 2017-09-07 2018-01-12 代晓蕾 A kind of art painting and preparation method thereof
CN107699056A (en) * 2017-11-16 2018-02-16 湖北工程学院 Environmentally friendly art painting and preparation method thereof
CN110903687A (en) * 2019-12-13 2020-03-24 珠海闲云艺术有限公司 Water-based oil painting pigment and preparation method thereof
CN111791641A (en) * 2019-11-04 2020-10-20 江苏辰宇文化艺术品有限公司 Manufacturing process of waterproof oil painting
CN113816773A (en) * 2021-11-09 2021-12-21 铜川市耀州窑唐宋陶业有限公司 High-quality color-filling artistic ceramic and manufacturing process thereof

Citations (4)

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CN102757702A (en) * 2012-08-01 2012-10-31 南宁亚多制漆有限公司 Water-based natural biological composite antibacterial coating and preparation method thereof
CN104004310A (en) * 2014-05-05 2014-08-27 上海锦湖日丽塑料有限公司 High-weatherability white ASA resin applied to extrusion molding and preparation method thereof
CN105061966A (en) * 2015-08-15 2015-11-18 辽宁石油化工大学 Antistatic composite and preparation method thereof
CN105131484A (en) * 2015-09-07 2015-12-09 王璐 Waterproof flame retardant anti-microbial mildew-resistant pigment

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN102757702A (en) * 2012-08-01 2012-10-31 南宁亚多制漆有限公司 Water-based natural biological composite antibacterial coating and preparation method thereof
CN104004310A (en) * 2014-05-05 2014-08-27 上海锦湖日丽塑料有限公司 High-weatherability white ASA resin applied to extrusion molding and preparation method thereof
CN105061966A (en) * 2015-08-15 2015-11-18 辽宁石油化工大学 Antistatic composite and preparation method thereof
CN105131484A (en) * 2015-09-07 2015-12-09 王璐 Waterproof flame retardant anti-microbial mildew-resistant pigment

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* Cited by examiner, † Cited by third party
Title
任思源: "《西方绘画学习宝典》", 30 June 2015, 中国华侨出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106928830A (en) * 2017-03-29 2017-07-07 江西科技学院 A kind of architectural decoration coating material
CN107227084A (en) * 2017-07-03 2017-10-03 河南工程学院 A kind of waterproof art painting of dilutable water and preparation method thereof
CN107573736A (en) * 2017-09-07 2018-01-12 代晓蕾 A kind of art painting and preparation method thereof
CN107699056A (en) * 2017-11-16 2018-02-16 湖北工程学院 Environmentally friendly art painting and preparation method thereof
CN111791641A (en) * 2019-11-04 2020-10-20 江苏辰宇文化艺术品有限公司 Manufacturing process of waterproof oil painting
CN110903687A (en) * 2019-12-13 2020-03-24 珠海闲云艺术有限公司 Water-based oil painting pigment and preparation method thereof
CN113816773A (en) * 2021-11-09 2021-12-21 铜川市耀州窑唐宋陶业有限公司 High-quality color-filling artistic ceramic and manufacturing process thereof

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Application publication date: 20161123