CN106147297A - Far ultrared paint and its preparation method and application - Google Patents
Far ultrared paint and its preparation method and application Download PDFInfo
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- CN106147297A CN106147297A CN201510153476.3A CN201510153476A CN106147297A CN 106147297 A CN106147297 A CN 106147297A CN 201510153476 A CN201510153476 A CN 201510153476A CN 106147297 A CN106147297 A CN 106147297A
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Abstract
The invention provides far ultrared paint and its preparation method and application, wherein far ultrared paint includes: silica；Carborundum；Aluminum oxide；Melanizing agent；Anion powder；And binding agent.The far ultrared paint of the present invention has the function of efficient far infrared transmission efficiency and good antibiotic and sterilizing and health care.
Description
Technical field
The present invention relates to technical field of coatings, in particular it relates to far ultrared paint and its preparation method and application,
Preparing far infrared heater more particularly, to far ultrared paint and preparation method thereof, far ultrared paint
In purposes, and far infrared heater.
Background technology
Far ultrared paint is the high-temperature coatings commonly using on current far-infrared heater.Recently, Chinese patent
Disclosing related coating in document, patent application CN1552779A discloses a kind of high-temp. far infrared and applies
Material, this coating mainly comprises as zirconium oxide, chromium oxide, iron oxide, carborundum, clay, bentonite, titanium
White powder, Brown Alundum；Patent application CN1361209A discloses a kind of efficient far ultrared paint, and it is main
Composition is wanted to be zirconium oxide, iron oxide, silica, manganese oxide, Suzhou soil etc.；Patent CN1493626A
Disclose a kind of far ultrared paint, its be mainly composed of carborundum, iron oxide, cobalt oxide, manganese oxide,
Aluminum oxide, chromium oxide, nickel oxide etc..Patent application CN1097780A discloses a kind of tobacco-roasting chamber
Coating, it is mainly composed of carborundum and iron oxide.Above-mentioned related far ultrared paint, is all with metal oxygen
Compound or carborundum are raw material, and therefore, it is relatively costly；In addition, its instability when high temperature causes launching
Rate is unstable, and particularly when high-temperature region, the emissivity of coating is unstable especially.
Thus, the correlative study with regard to far ultrared paint still needs deeply.
Content of the invention
It is contemplated that one of technical problem solving at least to a certain extent in correlation technique.To this end, this
One purpose of invention is to propose the far ultrared paint that a kind of emissivity is stable, have antibiotic and sterilizing function.
In the first aspect of the invention, the invention provides a kind of far ultrared paint.Reality according to the present invention
Executing example, described far ultrared paint includes: silica；Carborundum；Aluminum oxide；Melanizing agent；Anion powder；
And binding agent.Inventor finds, the far ultrared paint of the present invention has efficient far infrared transmission efficiency,
Normal direction is launched entirely can be up to more than 90%, the addition of anion powder simultaneously so that this coating also has anti-
Bacterium sterilization and the function of health care, this far ultrared paint is suitable to pottery and the metal applying to use Far-infrared Heating
Spraying etc. various utensils, device, it is possible to increase the thermal efficiency of Far-infrared Heating, economizes on resources.In addition,
Use the carborundum of black and melanizing agent, it is to avoid existing far ultrared paint reduces blackness when high temperature and leads
The problem of emissivity induced reduction, it is ensured that the stability of far infrared transmission.
According to embodiments of the invention, according to mass percent, described far ultrared paint includes: 30-40wt%
Described silica；The described carborundum of 15%-20wt%；The described aluminum oxide of 10%-20wt%；10-15
The described melanizing agent of wt%；The described anion powder of 5-10wt%；And the described binding agent of surplus.
According to embodiments of the invention, described melanizing agent is cobalt black pigment.
According to embodiments of the invention, according to mass percent, described cobalt black pigment includes: 45.4wt%'s
Cr-Cu-Co；The CoO of 15.6wt%；And the Fe of 39wt%3O4。
According to embodiments of the invention, according to mass percent, described anion powder includes: 35.10wt%
Al2O3；The SiO of 34.81wt%2；The B of 11.02wt%2O3；The MgO of 4.70wt%；10.18wt%
Fe2O3；The Na of 0.91wt%2O；The K of 0.04wt%2O；The CaO of 0.01wt%～0.05wt%；0.22
The P of wt%2O5；The TiO of 0.26wt%2；And the FeO of 1.35wt%.
According to embodiments of the invention, the granularity of described anion powder is 1500 mesh～4000 mesh.
According to embodiments of the invention, the color of described anion powder is ecru.
According to embodiments of the invention, described binding agent is waterglass.
According to embodiments of the invention, according to mass percent, described far ultrared paint includes: 20wt%'s
Described carborundum；The described aluminum oxide of 20wt%；The described silica of 30wt%；The described increasing of 15wt%
Black dose；The described negative ion powder of 5wt%；And the described binding agent of 10wt%.
According to embodiments of the invention, according to mass percent, described far ultrared paint includes: 15wt%'s
Described carborundum；The described aluminum oxide of 10wt%；The described silica of 40wt%；The described increasing of 10wt%
Black dose；The described negative ion powder of 10wt%；And the described binding agent of 15wt%.
According to embodiments of the invention, according to mass percent, described far ultrared paint includes: 20wt%'s
Described carborundum；The described aluminum oxide of 10wt%；The described silica of 30wt%；The described increasing of 10wt%
Black dose；The described negative ion powder of 10wt%；And the described binding agent of 20wt%.
In a second aspect of the present invention, the invention provides a kind of side preparing foregoing far ultrared paint
Method, it is characterised in that include: by silica, carborundum, aluminum oxide, melanizing agent, anion powder,
And binding agent mixing, in order to obtain described far ultrared paint.Utilize the method for the present invention, can be quick
Effectively prepare foregoing far ultrared paint, and simple, convenient fast, it is easy to accomplish big
Large-scale production.
In a third aspect of the present invention, the invention provides foregoing far ultrared paint in preparation far infrared
Purposes in heater.
In a fourth aspect of the present invention, the invention provides a kind of far infrared heater.According to the present invention's
Embodiment, this far infrared heater includes: housing, limits Far-infrared Heating space in described housing；
Far infrared coating, described far infrared coating forms the inner surface with described housing；Wherein, described far infrared applies
Layer is formed by foregoing far ultrared paint.Inventor finds, is formed by the inner surface at housing
Described coating, has efficient far infrared transmission efficiency, and normal direction is launched entirely can be up to more than 90%, simultaneously
This coating also has the function of antibiotic and sterilizing and health care, and far infrared transmissivity will not drop under the high temperature conditions
Low, keep stable far infrared transmissivity.
According to embodiments of the invention, described far infrared heater for selected from pan, baking box, bread producing machine,
At least one in electric cooker, heating furnace, tobacco flue-curing house.
Relative to prior art, the present invention at least has the advantages that
1. far ultrared paint according to embodiments of the present invention has selected the carbonization of high temperature cobalt black pigment and black
Silicon, this pigment coloring is strong, it is to avoid common far ultrared paint reduces blackness when high temperature and causes emissivity
The problem reducing, it is ensured that the stability of far infrared transmission.
2. far ultrared paint according to embodiments of the present invention, owing to adding anion powder, has excellent
Far infrared transmission characteristic and antibiotic and sterilizing function, purify activated water and air function.
3. coating can be sprayed by far ultrared paint according to embodiments of the present invention by conventional spraying method
It is applied to the surface of workpiece, utensil, through high temperature sintering after spraying, formed and firmly there is antibacterial functions and height
The coating of efficiency infrared emission efficiency.The advantage with low cost and energy-saving environment protection health, tool is widely used
Potentiality.
Detailed description of the invention
Embodiments of the invention are described below in detail.The embodiments described below is exemplary, is only used for solving
Release the present invention, and be not considered as limiting the invention.Unreceipted concrete technology or condition in embodiment,
Carry out according to the technology described by the document in this area or condition or according to product description.Agents useful for same
Or instrument unreceipted production firm person, be can by city available from conventional products.
In the first aspect of the invention, the invention provides a kind of far ultrared paint.Reality according to the present invention
Executing example, described far ultrared paint includes: silica；Carborundum；Aluminum oxide；Melanizing agent；Anion powder；
And binding agent.Inventor finds, the far ultrared paint of the present invention has efficient far infrared transmission efficiency,
Normal direction is launched entirely can be up to more than 90%, the addition of anion powder simultaneously so that this coating also has anti-
Bacterium sterilization and the function of health care, this far ultrared paint is suitable to pottery and the metal applying to use Far-infrared Heating
Spraying etc. various utensils, device, it is possible to increase the thermal efficiency of Far-infrared Heating, economizes on resources.In addition,
Use the carborundum of black and melanizing agent, it is to avoid existing far ultrared paint reduces blackness when high temperature and leads
The problem of emissivity induced reduction, it is ensured that the stability of far infrared transmission.
According to embodiments of the invention, according to mass percent, described far ultrared paint includes: 30-40wt%
Described silica；The described carborundum of 15%-20wt%；The described aluminum oxide of 10%-20wt%；10-15
The described melanizing agent of wt%；The described anion powder of 5-10wt%；And the described binding agent of surplus.By
This, described far ultrared paint has the far infrared transmission efficiency being better than other ratios, and far infrared transmission is steady
Qualitative preferably.
According to embodiments of the invention, the species of described melanizing agent is not particularly limited, as long as having stronger
Tinting strength, tinting power, the blackness that can keep coating during high temperature is stable, and those skilled in the art can select flexibly.Root
According to a specific example of the present invention, described melanizing agent is cobalt black pigment.Thus, the far infrared of the present invention applies
Material will cause emissivity to reduce when high temperature because reducing blackness, can effectively ensure that the steady of far infrared transmission
Qualitative.
According to embodiments of the invention, according to mass percent, described cobalt black pigment includes: 45.4wt%'s
Cr-Cu-Co；The CoO of 15.6wt%；And the Fe of 39wt%3O4.Thus, described cobalt black pigment coloring
By force so that the far ultrared paint of present invention blackness when high temperature is stable, and then ensures far infrared transmission during high temperature
Stability.
It should be noted that the expression way " Cr-Cu-Co " used in the present invention refer to Cr, Cu,
The alloy powder pigment that Co is formed according to mass ratio 1:1:1.
According to embodiments of the invention, the composition of described anion powder be characterized with boracic aluminium, sodium,
Iron, the silicate material of lithium circulus, its middle rare earth account for more than 60%.Specifically, according to quality
Percentage, described anion powder includes: the Al of 35.10wt%2O3；The SiO of 34.81wt%2；11.02
The B of wt%2O3；The MgO of 4.70wt%；The Fe of 10.18wt%2O3；The Na of 0.91wt%2O；0.04wt%
K2O；The CaO of 0.01wt%～0.05wt%；The P of 0.22wt%2O5；The TiO of 0.26wt%2；And
The FeO of 1.35wt%.It will be understood by those skilled in the art that anion powder according to embodiments of the present invention
The impurity component of trace can be contained.Inventor finds, this anion powder has excellent far infrared transmission
Characteristic and antibiotic and sterilizing function, purify activated water and air function, the far ultrared paint of the present invention select bear from
Sub-powder can give its excellent sterilization antibacterial functions.
According to embodiments of the invention, the granularity of described anion powder is 1500 mesh～4000 mesh.Thus,
The emissivity of far ultrared paint is higher, and sterilization antibacterial effect is preferable.
According to embodiments of the invention, the color of described anion powder is ecru.Thus, be conducive to carrying
The emissivity of high far ultrared paint is higher and strengthens sterilization antibacterial functions.
According to embodiments of the invention, the species of described binding agent is not particularly limited, as long as can be effectively viscous
While knot, do not affect emission effciency and far infrared transmission stability, the people in the art of far ultrared paint
Member can select flexibly.According to some embodiments of the present invention, described binding agent is waterglass.Thus, protect
While card bond effect is preferable, the emission effciency of far ultrared paint is higher, and launch stability is preferable.
According to one specific example of the present invention, according to mass percent, described far ultrared paint includes: 20wt%
Described carborundum；The described aluminum oxide of 20wt%；The described silica of 30wt%；15wt%'s is described
Melanizing agent；The described negative ion powder of 5wt%；And the described binding agent of 10wt%.Thus, far infrared applies
The emissivity of material is higher, emissivity will be caused to reduce because blackness reduces, have good transmitting during high temperature
Stability.
According to another specific example of the present invention, according to mass percent, described far ultrared paint includes:
The described carborundum of 15wt%；The described aluminum oxide of 10wt%；The described silica of 40wt%；10wt%
Described melanizing agent；The described negative ion powder of 10wt%；And the described binding agent of 15wt%.Thus,
The emissivity of far ultrared paint is higher, emissivity will be caused to reduce because blackness reduces, have good during high temperature
Good launch stability.
According to another specific example of the present invention, according to mass percent, described far ultrared paint includes:
The described carborundum of 20wt%；The described aluminum oxide of 10wt%；The described silica of 30wt%；10wt%
Described melanizing agent；The described negative ion powder of 10wt%；And the described binding agent of 20wt%.Thus,
The emissivity of far ultrared paint is higher, emissivity will be caused to reduce because blackness reduces, have good during high temperature
Good launch stability.
According to a particular embodiment of the invention, emissivity measurement result shows that the far ultrared paint of the present invention is formed
Coating when 300-500 degree Celsius full infrared emittance reach 93-95%, particularly temperature reaches
When more than 1000 degrees Celsius, full infrared emittance still reaches 90-92%, and emissivity is higher, and during high temperature
Emissivity will not substantially reduce, and emissivity stability is preferable, relative to existing far ultrared paint at high temperature
When emissivity typically at about 80-85%, the emissivity during far ultrared paint high temperature of the present invention significantly carries
High.
In a second aspect of the present invention, the invention provides a kind of side preparing foregoing far ultrared paint
Method, it is characterised in that include: by silica, carborundum, aluminum oxide, melanizing agent, anion powder,
And binding agent mixing, in order to obtain described far ultrared paint.Utilize the method for the present invention, can be quick
Effectively prepare foregoing far ultrared paint, and simple, convenient fast, it is easy to accomplish big
Large-scale production.
In a third aspect of the present invention, the invention provides foregoing far ultrared paint in preparation far infrared
Purposes in heater.Inventor finds, the inner wall surface at far infrared heater is formed by above institute
The coating that the far ultrared paint stated is formed, this coating has high efficiency infrared emission efficiency and antibiotic and sterilizing work(
Can, the advantage with low cost and energy-saving environment protection health, and make the heat utilization of far infrared heater
Rate is higher, and heater internal temperature is evenly.
It should be noted that term used in the present invention " far infrared heater " should broadly understood,
Far infrared is not its unique thermal source, and far infrared heater of the present invention can pass through naked light, fuel
Burning, the mode such as electrical heating heats, as long as one of thermal source is far infrared.According to the present invention one
A little embodiments, far infrared heater of the present invention include but is not limited to pan, baking box, bread producing machine,
Electric cooker, heating furnace, tobacco flue-curing house etc..
In a fourth aspect of the present invention, the invention provides a kind of far infrared heater.According to the present invention's
Embodiment, this far infrared heater includes: housing, limits Far-infrared Heating space in described housing；
Far infrared coating, described far infrared coating forms the inner surface with described housing；Wherein, described far infrared applies
Layer is formed by foregoing far ultrared paint.Inventor finds, is formed by the inner surface at housing
Described coating, has efficient far infrared transmission efficiency, and normal direction is launched entirely can be up to more than 90%, simultaneously
This coating also has the function of antibiotic and sterilizing and health care, and far infrared transmissivity will not drop under the high temperature conditions
Low, keep stable far infrared transmissivity.
According to embodiments of the invention, described far infrared heater for selected from pan, baking box, bread producing machine,
At least one in electric cooker, heating furnace, tobacco flue-curing house.According to embodiments of the invention, heating furnace concrete
Species is not limited by especially, including but not limited to industry rotary furnace, reacting furnace etc..
The specific embodiment of the present invention is described below in detail, it should be noted that institute in example below
The composition of the cobalt black pigment using is: the Cr-Cu-Co of 45.4wt%；The CoO of 15.6wt%；And 39
The Fe of wt%3O4.The anion powder being used is the powder that ecru, granularity are 1500 mesh～4000 mesh
Body, its concrete composition is: the Al of 35.10wt%2O3；The SiO of 34.81wt%2；The B of 11.02wt%2O3；
The MgO of 4.70wt%；The Fe of 10.18wt%2O3；The Na of 0.91wt%2O；The K of 0.04wt%2O；
The CaO of 0.01wt%～0.05wt%；The P of 0.22wt%2O5；The TiO of 0.26wt%2；And 1.35wt%
FeO.
Embodiment 1:
Raw material: carborundum: 20wt%, aluminum oxide 20wt%, silica 30wt%, cobalt black pigment
15wt%, negative ion powder 5wt%, waterglass 10wt%.
Experimental procedure:
Weigh raw material according to aforementioned proportion, and the raw material of precise is mixed, then applied
Overlaying on stainless steel pan surface, then, the stainless steel pan being coated with coating carries out high temperature sintering,
In 2 hours, it is slowly warmed up to 700 degree from low temperature, and is incubated at least half an hour, it is thus achieved that surface
There is the stainless steel pan of far infrared coating, through detection, film adhesion hundred lattice 4B.
Utilizing IR-2 two waveband emissivity measurement instrument to detect, the coating that this coating is formed is taken the photograph at 300-500
When family name spends, full infrared emittance reaches 95%, when particularly temperature reaches more than 1000 degrees Celsius, and Quan Hong
Emission rate still reaches 92%.The coating that the far ultrared paint of the result explanation present invention is formed has higher
Emissivity, and during high temperature, emissivity is stable.And send out when high temperature relative to existing far ultrared paint
Penetrating rate typically at about 80-85%, the emissivity during far ultrared paint high temperature of the present invention significantly improves.
Embodiment 2:
Raw material: carborundum: 15wt%, aluminum oxide 10wt%, silica 40wt%, cobalt black pigment
10wt%, negative ion powder 10wt%, waterglass 15wt%.
Experimental procedure:
Weigh raw material according to aforementioned proportion, and the raw material of precise is mixed, then applied
Overlaying on ceramic cooker surface, then, the ceramic cooker being coated with coating carries out high temperature sintering, 2
In little Shi, it is slowly warmed up to 700 degree from low temperature, and is incubated at least half an hour, it is thus achieved that surface has
The ceramic cooker of far infrared coating, through detection, film adhesion hundred lattice 5B.
Utilizing IR-2 two waveband emissivity measurement instrument to detect, the coating that this coating is formed is taken the photograph at 300-500
When family name spends, full infrared emittance reaches 93%, when particularly temperature reaches more than 1000 degrees Celsius, and Quan Hong
Emission rate still reaches 92%.The coating that the far ultrared paint of the result explanation present invention is formed has higher
Emissivity, and during high temperature, emissivity is stable.
Embodiment 3:
Raw material: carborundum: 20wt%, aluminum oxide 10wt%, silica 30wt%, cobalt black pigment
10wt%, negative ion powder 10wt%, waterglass 20wt%.
Experimental procedure:
Weigh raw material according to aforementioned proportion, and the raw material of precise is mixed, then applied
Overlay on ceramic cooker surface, then, be coated with coating ceramic cooker and carry out high temperature sintering, little 2
When interior it is slowly warmed up to 700 degree from low temperature, and be incubated at least half an hour, it is thus achieved that surface has far
The ceramic cooker of infrared coating, through detection, film adhesion hundred lattice 5B.
Utilizing IR-2 two waveband emissivity measurement instrument to detect, the coating that this coating is formed is taken the photograph at 300-500
When family name spends, far infrared transmissivity reaches 93%, when particularly temperature reaches more than 1000 degrees Celsius, far red
Emission rate still reaches 90%, and the coating that the far ultrared paint of the result explanation present invention is formed has higher
Emissivity, and during high temperature, emissivity is stable.
In the description of this specification, reference term " embodiment ", " some embodiments ", " example ", " tool
The description of body example " or " some examples " etc. means to combine this embodiment or example describes specific features,
Structure, material or feature are contained at least one embodiment or the example of the present invention.In this manual,
Identical embodiment or example are necessarily directed to the schematic representation of above-mentioned term.And, description
Specific features, structure, material or feature can with in one or more embodiments in office or example with suitably
Mode combines.Additionally, in the case of not conflicting, those skilled in the art can be by this specification
Described in different embodiment or the feature of example and different embodiment or example be combined and combine.
Although above it has been shown and described that embodiments of the invention, it is to be understood that above-described embodiment
It is exemplary, it is impossible to being interpreted as limitation of the present invention, those of ordinary skill in the art is the present invention's
In the range of above-described embodiment can be changed, change, replace and modification.
Claims (10)
1. a far ultrared paint, it is characterised in that include:
Silica；
Carborundum；
Aluminum oxide；
Melanizing agent；
Anion powder；And
Binding agent.
2. far ultrared paint according to claim 1, it is characterised in that according to mass percent,
Described far ultrared paint includes:
The described silica of 30-40wt%；
The described carborundum of 15%-20wt%；
The described aluminum oxide of 10%-20wt%；
The described melanizing agent of 10-15wt%；
The described anion powder of 5-10wt%；And
The described binding agent of surplus.
3. far ultrared paint according to claim 1, it is characterised in that described melanizing agent is cobalt black
Pigment,
Optionally, according to mass percent, described cobalt black pigment includes:
The Cr-Cu-Co of 45.4wt%；
The CoO of 15.6wt%；And
The Fe of 39wt%3O4。
4. far ultrared paint according to claim 1, it is characterised in that according to mass percent,
Described anion powder includes:
The Al of 35.10wt%2O3；
The SiO of 34.81wt%2；
The B of 11.02wt%2O3；
The MgO of 4.70wt%；
The Fe of 10.18wt%2O3；
The Na of 0.91wt%2O；
The K of 0.04wt%2O；
The CaO of 0.01wt%～0.05wt%；
The P of 0.22wt%2O5；
The TiO of 0.26wt%2；And
The FeO of 1.35wt%,
Optionally, the granularity of described anion powder is 1500 mesh～4000 mesh,
Optionally, the color of described anion powder is ecru.
5. far ultrared paint according to claim 1, it is characterised in that described binding agent is water glass
Glass.
6. far ultrared paint according to claim 1, it is characterised in that according to mass percent,
Described far ultrared paint includes one of following:
The described carborundum of 20wt%；
The described aluminum oxide of 20wt%；
The described silica of 30wt%；
The described melanizing agent of 15wt%；
The described negative ion powder of 5wt%；And
The described binding agent of 10wt%,
The described carborundum of 15wt%；
The described aluminum oxide of 10wt%；
The described silica of 40wt%；
The described melanizing agent of 10wt%；
The described negative ion powder of 10wt%；And
The described binding agent of 15wt%,
The described carborundum of 20wt%；
The described aluminum oxide of 10wt%；
The described silica of 30wt%；
The described melanizing agent of 10wt%；
The described negative ion powder of 10wt%；And
The described binding agent of 20wt%.
7. the method preparing the far ultrared paint described in any one in claim 1-6, its feature
It is, comprising:
Silica, carborundum, aluminum oxide, melanizing agent, anion powder and binding agent are mixed, with
Just described far ultrared paint is obtained.
8. in claim 1-6 the far ultrared paint described in any one in preparing far infrared heater
Purposes.
9. a far infrared heater, it is characterised in that include:
Housing, limits Far-infrared Heating space in described housing；
Far infrared coating, described far infrared coating is formed at the inner surface of described housing；
Wherein, described far infrared coating is by the far ultrared paint shape described in any one in claim 1-6
Become.
10. far infrared heater according to claim 9, it is characterised in that described far infrared adds
Hot charging is set at least one in pan, baking box, bread producing machine, electric cooker, heating furnace, tobacco flue-curing house.
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| CN111020483A (en) * | 2019-12-13 | 2020-04-17 | 南京大学 | Infrared heat absorption coating, preparation method and application thereof, non-contact infrared heating substrate and application thereof |
| CN111826058A (en) * | 2020-06-30 | 2020-10-27 | 亚士漆(上海)有限公司 | Environment-friendly oily epoxy resin coating and preparation method and application thereof |
| CN111849357A (en) * | 2020-07-28 | 2020-10-30 | 苏州达万塑胶电子有限公司 | Heat-curing and light-curing anion coating and manufacturing process thereof |
| CN112898812A (en) * | 2021-02-05 | 2021-06-04 | 东莞市中科智恒新材料有限公司 | Far infrared quartz tube applied to electronic cigarette heater and preparation method thereof |
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| CN111020483A (en) * | 2019-12-13 | 2020-04-17 | 南京大学 | Infrared heat absorption coating, preparation method and application thereof, non-contact infrared heating substrate and application thereof |
| CN111826058A (en) * | 2020-06-30 | 2020-10-27 | 亚士漆(上海)有限公司 | Environment-friendly oily epoxy resin coating and preparation method and application thereof |
| CN111849357A (en) * | 2020-07-28 | 2020-10-30 | 苏州达万塑胶电子有限公司 | Heat-curing and light-curing anion coating and manufacturing process thereof |
| CN112898812A (en) * | 2021-02-05 | 2021-06-04 | 东莞市中科智恒新材料有限公司 | Far infrared quartz tube applied to electronic cigarette heater and preparation method thereof |
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