CN106142767A - A kind of gasket seal for biochemical equipment - Google Patents

A kind of gasket seal for biochemical equipment Download PDF

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Publication number
CN106142767A
CN106142767A CN201610516844.0A CN201610516844A CN106142767A CN 106142767 A CN106142767 A CN 106142767A CN 201610516844 A CN201610516844 A CN 201610516844A CN 106142767 A CN106142767 A CN 106142767A
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China
Prior art keywords
parts
gasket seal
layer
biochemical equipment
stabilizer
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Pending
Application number
CN201610516844.0A
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Chinese (zh)
Inventor
马荣华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU BEIKAI BIOCHEMICAL EQUIPMENT Co Ltd
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SUZHOU BEIKAI BIOCHEMICAL EQUIPMENT Co Ltd
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Priority to CN201610516844.0A priority Critical patent/CN106142767A/en
Publication of CN106142767A publication Critical patent/CN106142767A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/042Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/285Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2581/00Seals; Sealing equipment; Gaskets

Landscapes

  • Gasket Seals (AREA)
  • Sealing Material Composition (AREA)

Abstract

The present invention provides a kind of gasket seal for biochemical equipment, described gasket seal is multi-layer compound structure, described multi-layer compound structure includes that basic unit, the front and back of described basic unit are respectively equipped with expansion buffer layer, flame-retardant layer, anticorrosive coat, high-temperature-resistant layer and outer layer the most successively;The described gasket seal for biochemical equipment, possesses good anti-flammability, anti-corrosive properties and resistance to elevated temperatures, can be widely used in the biochemical equipment environment of various complexity;Secondly, described gasket seal substantially increases the dilatancy of product, makes product possess good mechanical strength and elasticity;Additionally, a kind of gasket seal for biochemical equipment that the present invention provides is also equipped with certain Water-proof and oil-proof, dust-proof, the function of antistatic.

Description

A kind of gasket seal for biochemical equipment
Technical field
The present invention relates to biochemical equipment field, be specifically related to a kind of gasket seal for biochemical equipment.
Background technology
Gasket seal, is a kind of internal for machinery, equipment, pipeline etc., the material sealed.The most conventional is close Gasket mainly includes asbestos seal gasket and rubber sheet gasketing from material.
Gasket seal is very important on biochemical equipment.The production process of biochemical equipment often has equipment fault, The accidents such as interruption, inventory disposal that produce occur, and trace it to its cause and are no lack of potted component (including gasket seal) damage initiation sealing skill Art Failure Factors.Potted component (including gasket seal) in a set of biochemical equipment in addition to ensureing accurately to perform technological parameter, it Another function be exactly to avoid the three of electromechanical equipment to leak (water, gas, oil etc.), it to ensure the safe and highly efficient operation of equipment, joint About energy conservation environment, ensure produce product quality have very important effect, countries in the world all pay much attention to it Research and application.
For the gasket seal in biochemical equipment, place, the environment applied due to biochemical equipment are the most special, because of This, the requirement to gasket seal is the strictest.
Current biochemical equipment great majority are for fields such as biochemical industry pharmacy, sewage disposal, oilfield exploitations.We know Road, biochemical equipment is typically used for the making of some bio-chemical, can usually touch some biochemical reagents, these reagent Of a great variety, different properties, the damage to equipment is the biggest, and therefore, for these fields, sealing gasket is except requiring it Beyond sealing, for production safety, for the sealing gasket of this equipment, the requirement of its anticorrosive property to be far longer than common close Gasket.Meanwhile, in Workplace, fireproof requires to be significantly larger than the most common working space, so, fire-retardant to gasket seal Property, the fire line secure context such as temperature tolerance require the highest.
Therefore, for socioeconomic development, also for production safety, it is necessary to develop a kind of for biochemical equipment Multiple-effect gasket seal.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of gasket seal for biochemical equipment, Described gasket seal is multi-layer compound structure, and described multi-layer compound structure includes basic unit, and the front and back of described basic unit is from inner Outwards it is respectively equipped with expansion buffer layer, flame-retardant layer, anticorrosive coat, high-temperature-resistant layer and outer layer successively;Described close for biochemical equipment Gasket, possesses good anti-flammability, anti-corrosive properties and resistance to elevated temperatures, and the biochemistry that can be widely used in various complexity sets In standby environment;Secondly, described gasket seal substantially increases the dilatancy of product, makes product possess good mechanical strength and bullet Property;Additionally, a kind of gasket seal for biochemical equipment that the present invention provides is also equipped with certain Water-proof and oil-proof, dust-proof, anti-quiet The function of electricity.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
A kind of gasket seal for biochemical equipment, described gasket seal is multi-layer compound structure, and described MULTILAYER COMPOSITE is tied Structure include basic unit, the front and back of described basic unit be respectively equipped with the most successively expansion buffer layer, flame-retardant layer, anticorrosive coat, High-temperature-resistant layer and outer layer;The thickness of described flame-retardant layer is 0.2~0.4mm, and described flame-retardant layer includes following weight proportion raw material:
EVA resin: 60~90 parts, brominated isobutylene-p-methylstyrene copolymer rubber: 15~25 parts, expanded graphite: 2~8 parts, aluminium hydroxide: 8~12 parts, red phosphorus: 1~2 part, ceramic fibre: 3~5 parts, nickel oxide: 5~8 parts, impact modification Agent: 3~5 parts, plasticizer: 4~8 parts, stabilizer: 2~3 parts, coupling agent: 0.1~0.5 part, n-butyl alcohol: 10~20 parts;
The thickness of described anticorrosive coat is 0.1~0.2mm, and described anticorrosive coat includes following weight proportion raw material:
Polyphenylene sulfide: 50~80 parts, Oppanol: 10~15 parts, ceramic fibre: 2~5 parts, epoxy resin: 8~ 12 parts, silicon powder: 1~3 part;White carbon black: 1~2 part, Pulvis Talci: 1~2 part, coupling agent: 0.1~1 part, plasticizer: 3~5 parts, surely Determine agent: 1~2 part, n-butyl alcohol: 10~20 parts.
Preferably, described flame-retardant layer includes following weight proportion raw material:
EVA resin: 65~85 parts, brominated isobutylene-p-methylstyrene copolymer rubber: 16~23 parts, expanded graphite: 3~7 parts, aluminium hydroxide: 8.5~11 parts, red phosphorus: 1.2~1.96 parts, ceramic fibre: 3.5~4.8 parts, nickel oxide: 5.5~ 7.5 parts, anti-impact modifier: 3.4~4.6 parts, plasticizer: 4.6~7.5 parts, stabilizer: 2.1~2.98 parts, coupling agent: 0.15~0.45 part, n-butyl alcohol: 11~19 parts;
Described anticorrosive coat includes following weight proportion raw material:
Polyphenylene sulfide: 55~75 parts, Oppanol: 11~14.5 parts, ceramic fibre: 2.5~4.5 parts, asphalt mixtures modified by epoxy resin Fat: 8.5~11 parts, silicon powder: 1.6~2.7 parts;White carbon black: 1.1~1.9 parts, Pulvis Talci: 1.15~1.96 parts, coupling agent: 0.15~0.95 part, plasticizer: 3.4~4.7 parts, stabilizer: 1.25~1.97 parts, n-butyl alcohol: 11~19 parts.
Preferably, described flame-retardant layer includes following weight proportion raw material:
EVA resin: 75 parts, brominated isobutylene-p-methylstyrene copolymer rubber: 20 parts, expanded graphite: 5.5 parts, hydrogen Aluminium oxide: 9.65 parts, red phosphorus: 1.56 parts, ceramic fibre: 4 parts, nickel oxide: 6.8 parts, anti-impact modifier: 4.2 parts, plasticising Agent: 6.6 parts, stabilizer: 2.52 parts, coupling agent: 0.34 part, n-butyl alcohol: 15 parts;
Described anticorrosive coat includes following weight proportion raw material:
Polyphenylene sulfide: 64 parts, Oppanol: 13 parts, ceramic fibre: 3.85 parts, epoxy resin: 10.5 parts, silicon is micro- Powder: 2 parts;White carbon black: 1.54 parts, Pulvis Talci: 1.56 parts, coupling agent: 0.58 part, plasticizer: 4 parts, stabilizer: 1.6 parts, positive fourth Alcohol: 16 parts.
Further, described basic unit is brominated isobutylene-p-methylstyrene copolymer rubber, and the thickness of described basic unit is 1 ~2mm, described outer layer is politef, and the thickness of described outer layer is 0.3~0.5mm.
Further, described expansion buffer layer is butadiene rubber, and the thickness of described expansion buffer layer is 0.2~0.3mm.
Separately, described high-temperature-resistant layer is Parylene, and the thickness of described high-temperature-resistant layer is 0.3~0.5mm.
Separately having, described anti-impact modifier is acrylonitrile-butadiene-styrene copolymer.
Again, described plasticizer is SA dioctyl ester, and described stabilizer is calcium-zinc composite stabilizing agent and tetramethylolmethane weight Component ratio is the mixture of 1:2.
Further, described coupling agent is gamma-aminopropyl-triethoxy-silane, γ-methacryloxypropyl trimethoxy One in silane, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane.
The beneficial effects of the present invention is:
(1) the described gasket seal for biochemical equipment, arranges multi-layer compound structure, product combination property can be made more excellent More so that it is be more widely used in the production equipment that the environment such as biochemical equipment are extremely complex.
(2) the described gasket seal for biochemical equipment, possesses good anti-flammability, anti-corrosive properties and resistance to elevated temperatures, It is highly resistant to the corrosion of chemical reagent and surrounding, can still keep good performance in high temperature environments, raw at equipment Produce in running, also will not be on fire because of reasons such as frictions, there is good anti-flammability, be especially suitable for applying various multiple In miscellaneous biochemical equipment environment.
(3) described gasket seal substantially increases the dilatancy of product, makes product possess good mechanical strength and elasticity, Possess good shock resistance and crocking resistance, extend the service life of described gasket seal.
(4) a kind of gasket seal for biochemical equipment that the present invention provides, by new compound proportioning, also makes it have Standby certain Water-proof and oil-proof, dust-proof, the function of antistatic.
Accompanying drawing explanation
The structural representation of a kind of gasket seal for biochemical equipment that Fig. 1 provides for the present invention;
Wherein, 1 is basic unit, and 2 is expansion buffer layer, and 3 is flame-retardant layer, and 4 is anticorrosive coat, and 5 is high-temperature-resistant layer, and 6 is outer layer.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be carried out clear, complete description below, it is clear that described enforcement Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained on the premise of not making creative work, broadly falls into present invention protection Scope.
Table 1 is flame-retardant layer by weight ratio former in the gasket seal of biochemical equipment a kind of described in the embodiment of the present invention Material list.
Table 2 is anticorrosive coat by weight ratio former in the gasket seal of biochemical equipment a kind of described in the embodiment of the present invention Material list.
Row implemented by table 1, and described a kind of in the gasket seal of biochemical equipment, flame-retardant layer is by weight
The raw material (unit: part) of proportioning
Row described anticorrosive coat raw material (unit: part) by weight ratio implemented by table 2
The gasket seal of above-described embodiment, the material of each composite bed is prepared (such as flame-retardant layer 3, corrosion-resistant coating 4), so respectively After be combined again, compound after the product that obtains can reprocess according to actual use, Production requirement, be processed into spy Fixed shape.
A kind of gasket seal for biochemical equipment that the present invention provides, the described gasket seal for biochemical equipment, if Put multi-layer compound structure, product combination property can be made more superior so that it is be more widely used in the environment poles such as biochemical equipment For in complicated production equipment.The described gasket seal for biochemical equipment, possesses good anti-flammability, anti-corrosive properties and resistance to height Warm nature energy, is highly resistant to the corrosion of chemical reagent and surrounding, can still keep good performance in high temperature environments, During equipment production run, also will not be on fire because of reasons such as frictions, there is good anti-flammability, be especially suitable for applying In the biochemical equipment environment of various complexity.Secondly, described gasket seal substantially increases the dilatancy of product, makes product possess very Good mechanical strength and elasticity, possess good shock resistance and crocking resistance, extend the use of described gasket seal Life-span.Additionally, a kind of gasket seal for biochemical equipment that the present invention provides, by new compound proportioning, it is also made to have Standby certain Water-proof and oil-proof, dust-proof, the function of antistatic.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention In profit claimed range.

Claims (9)

1. the gasket seal for biochemical equipment, it is characterised in that described gasket seal is multi-layer compound structure, described Multi-layer compound structure includes that basic unit, the front and back of described basic unit are respectively equipped with expansion buffer layer, fire-retardant the most successively Layer, anticorrosive coat, high-temperature-resistant layer and outer layer;The thickness of described flame-retardant layer is 0.2~0.4 mm, and described flame-retardant layer includes following weight Proportioning raw material:
EVA resin: 60~90 parts, brominated isobutylene-p-methylstyrene copolymer rubber: 15~25 parts, expanded graphite: 2~8 Part, aluminium hydroxide: 8~12 parts, red phosphorus: 1~2 part, ceramic fibre: 3~5 parts, nickel oxide: 5~8 parts, anti-impact modifier: 3 ~5 parts, plasticizer: 4~8 parts, stabilizer: 2~3 parts, coupling agent: 0.1~0.5 part, n-butyl alcohol: 10~20 parts;
The thickness of described anticorrosive coat is 0.1~0.2 mm, and described anticorrosive coat includes following weight proportion raw material:
Polyphenylene sulfide: 50~80 parts, Oppanol: 10~15 parts, ceramic fibre: 2~5 parts, epoxy resin: 8~12 parts, Silicon powder: 1~3 part;White carbon black: 1~2 part, Pulvis Talci: 1~2 part, coupling agent: 0.1~1 part, plasticizer: 3~5 parts, stabilizer: 1~2 part, n-butyl alcohol: 10~20 parts.
A kind of gasket seal for biochemical equipment the most according to claim 1, it is characterised in that described flame-retardant layer Including following weight proportion raw material:
EVA resin: 65~85 parts, brominated isobutylene-p-methylstyrene copolymer rubber: 16~23 parts, expanded graphite: 3~7 Part, aluminium hydroxide: 8.5~11 parts, red phosphorus: 1.2~1.96 parts, ceramic fibre: 3.5~4.8 parts, nickel oxide: 5.5~7.5 parts, Anti-impact modifier: 3.4~4.6 parts, plasticizer: 4.6~7.5 parts, stabilizer: 2.1~2.98 parts, coupling agent: 0.15~ 0.45 part, n-butyl alcohol: 11~19 parts;
Described anticorrosive coat includes following weight proportion raw material:
Polyphenylene sulfide: 55~75 parts, Oppanol: 11~14.5 parts, ceramic fibre: 2.5~4.5 parts, epoxy resin: 8.5~11 parts, silicon powder: 1.6~2.7 parts;White carbon black: 1.1~1.9 parts, Pulvis Talci: 1.15~1.96 parts, coupling agent: 0.15~ 0.95 part, plasticizer: 3.4~4.7 parts, stabilizer: 1.25~1.97 parts, n-butyl alcohol: 11~19 parts.
A kind of gasket seal for biochemical equipment the most according to claim 1, it is characterised in that described flame-retardant layer Including following weight proportion raw material:
EVA resin: 75 parts, brominated isobutylene-p-methylstyrene copolymer rubber: 20 parts, expanded graphite: 5.5 parts, hydroxide Aluminum: 9.65 parts, red phosphorus: 1.56 parts, ceramic fibre: 4 parts, nickel oxide: 6.8 parts, anti-impact modifier: 4.2 parts, plasticizer: 6.6 Part, stabilizer: 2.52 parts, coupling agent: 0.34 part, n-butyl alcohol: 15 parts;
Described anticorrosive coat includes following weight proportion raw material:
Polyphenylene sulfide: 64 parts, Oppanol: 13 parts, ceramic fibre: 3.85 parts, epoxy resin: 10.5 parts, silicon powder: 2 Part;White carbon black: 1.54 parts, Pulvis Talci: 1.56 parts, coupling agent: 0.58 part, plasticizer: 4 parts, stabilizer: 1.6 parts, n-butyl alcohol: 16 Part.
A kind of gasket seal for biochemical equipment the most according to claim 1, it is characterised in that described basic unit is bromine Changing isobutene .-p-methylstyrene copolymer rubber, the thickness of described basic unit is 1~2 mm, and described outer layer is politef, The thickness of described outer layer is 0.3~0.5 mm.
A kind of gasket seal for biochemical equipment the most according to claim 1, it is characterised in that described expansion buffer Layer is butadiene rubber, and the thickness of described expansion buffer layer is 0.2~0.3 mm.
A kind of gasket seal for biochemical equipment the most according to claim 1, it is characterised in that described high-temperature-resistant layer For Parylene, the thickness of described high-temperature-resistant layer is 0.3~0.5 mm.
7. according to a kind of gasket seal for biochemical equipment described in claim 1 or 2 or 3, it is characterised in that described anti-impact Hitting modifying agent is acrylonitrile-butadiene-styrene copolymer.
8. according to a kind of gasket seal for biochemical equipment described in claim 1 or 2 or 3, it is characterised in that described plasticising Agent is SA dioctyl ester, and described stabilizer is calcium-zinc composite stabilizing agent and tetramethylolmethane composition by weight ratio is the mixing of 1:2 Thing.
9. according to a kind of gasket seal for biochemical equipment described in claim 1 or 2 or 3, it is characterised in that described coupling Agent be gamma-aminopropyl-triethoxy-silane, γ-methacryloxypropyl trimethoxy silane, N-(β-aminoethyl)-γ- One in aminopropyl trimethoxysilane.
CN201610516844.0A 2016-07-04 2016-07-04 A kind of gasket seal for biochemical equipment Pending CN106142767A (en)

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CN107718831A (en) * 2017-11-08 2018-02-23 佛山市顺德区宝丽马彩膜板业科技有限公司 A kind of decorating film easy to use

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107718831A (en) * 2017-11-08 2018-02-23 佛山市顺德区宝丽马彩膜板业科技有限公司 A kind of decorating film easy to use

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