CN106119990A - The electrostatic spinning nozzle of face of cylinder equilateral hexagon array and electrospinning process - Google Patents

The electrostatic spinning nozzle of face of cylinder equilateral hexagon array and electrospinning process Download PDF

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Publication number
CN106119990A
CN106119990A CN201610657662.5A CN201610657662A CN106119990A CN 106119990 A CN106119990 A CN 106119990A CN 201610657662 A CN201610657662 A CN 201610657662A CN 106119990 A CN106119990 A CN 106119990A
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CN
China
Prior art keywords
cylinder
face
nozzle
equilateral hexagon
electrostatic spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610657662.5A
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Chinese (zh)
Inventor
朱自明
黄泽峰
郭杰庄
杨晓林
温尊伟
梅晨
谢壁衡
王新力
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FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Original Assignee
FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
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Publication date
Application filed by FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd filed Critical FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Priority to CN201610657662.5A priority Critical patent/CN106119990A/en
Publication of CN106119990A publication Critical patent/CN106119990A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0069Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

The invention discloses electrostatic spinning nozzle and the electrospinning process of a kind of face of cylinder equilateral hexagon array, including body, described body has the face of cylinder being positioned at top and is provided with at least two group export structures, each group export structure is arranged along the axis direction linearly array on the face of cylinder, adjacent export structure is spaced a distance, each group export structure includes six connecting holes being opened on the face of cylinder, needle nozzle all it is connected on each connecting hole, each needle nozzle extends and contour along the normal direction on the face of cylinder, in same group of export structure, the projection in the horizontal plane of each connecting hole is respectively on the end points of equilateral hexagon, two adjacent equilateral hexagon are zhou duicheng tuxing, and its axis of symmetry is parallel to the limit of equilateral hexagon.The present invention each needle nozzle electric field intensity difference is less, and the most advanced and sophisticated electric field of each nozzle is more uniform.Present invention can apply to electrostatic spinning.

Description

The electrostatic spinning nozzle of face of cylinder equilateral hexagon array and electrospinning process
Technical field
The present invention relates to electrostatic spinning field, particularly relate to the electrostatic spinning spray of a kind of face of cylinder equilateral hexagon array Head and electrospinning process.
Background technology
The patent of invention of Application No. 200910031948.2 discloses a kind of array multi-nozzle electrospinning device, utilizes Multiple shower nozzles that the most linearly rectangular array is arranged carry out spinning, can realize the production in enormous quantities of electrospun fiber membrane material.
But after using for a long time, technical staff finds to postpone in array cloth in the plane when shower nozzle, each shower nozzle Most advanced and sophisticated electric field can influence each other, disturb so that between different shower nozzles, electric field differs greatly and causes spinning uneven.
Summary of the invention
In order to solve the problems referred to above, it is an object of the invention to provide the Static Spinning of a kind of face of cylinder equilateral hexagon array Silk shower nozzle, the most advanced and sophisticated electric field of its nozzle is the most uniform.
The technical solution adopted in the present invention is:
The electrostatic spinning nozzle of a kind of face of cylinder equilateral hexagon array, including body, described body has one and is positioned at top The face of cylinder and be provided with at least two group export structures, each group export structure arranges along the axis direction linearly array on the face of cylinder, Adjacent sets export structure is spaced a distance, and each group export structure includes six connecting holes being opened on the face of cylinder, Mei Gelian Meeting Kong Shangjun and be connected to needle nozzle, each needle nozzle extends and contour along the normal direction on the face of cylinder, respectively connects in same group of export structure Connecing hole projection in the horizontal plane to be respectively on the end points of equilateral hexagon, two adjacent equilateral hexagon are axial symmetry figure Shape, and its axis of symmetry is parallel to the limit of equilateral hexagon.
As a further improvement on the present invention, in same group of export structure, the projection in the horizontal plane of each connecting hole is located respectively On orthohexagonal end points.
As a further improvement on the present invention, the spacing of adjacent sets export structure is equal with the orthohexagonal length of side.
The present invention also provides for a kind of electrospinning process, and it the technical scheme is that
Using above-mentioned electrostatic spinning nozzle, be coated on by spinning liquid on each needle nozzle, spinning liquid is at needle nozzle, collection dress Putting generation induced jet under formed induction electric field, induced jet is induced to collection device and forms fiber.
It addition, the electrostatic spinning nozzle of the present invention can also use following structure:
Described needle nozzle has the sap cavity that of hollow, and described body surface has inlet, and body interior has solution channel, Described go out sap cavity by corresponding connecting hole, solution channel connection inlet.
The electrospinning process of this electrostatic spinning nozzle is as follows:
In injecting sap cavity by spinning liquid by solution channel and arrive needle nozzle top, spinning liquid is in needle nozzle, collection Producing induced jet under the induction electric field that device is formed, induced jet is induced to collection device and forms fiber.
The invention has the beneficial effects as follows: the present invention respectively organizes the export structure axis direction linearly array cloth along the face of cylinder Putting, the projection in the horizontal plane of six connecting holes of each group export structure is respectively on the end points of equilateral hexagon, then each Connecting hole subpoint line on the projection surface forms the track of equilateral hexagon axial symmetry array, and between each equilateral hexagon Every a segment distance, this arrangement, for prior art in the nozzle of array arranged in tracks in the plane, respectively sprays Mouth electric field intensity difference is less, and the most advanced and sophisticated electric field of each nozzle is more uniform.
Accompanying drawing explanation
The present invention is further described with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is the front view of electrostatic spinning nozzle;
Fig. 2 is the side view of electrostatic spinning nozzle;
Fig. 3 is the top view of electrostatic spinning nozzle;
Fig. 4 is the schematic diagram of electrostatic spinning process;
Fig. 5 is schematic diagram in three row's arranged in linear arrays shower nozzles in the plane;
Fig. 6 is the schematic diagram that the most hexagonal axial symmetry spaced array arranges shower nozzle;
Fig. 7 is the Electric Field Simulation result schematic diagram of arrangement in Fig. 5;
Fig. 8 is the Electric Field Simulation result schematic diagram of arrangement in Fig. 6;
Fig. 9 is Electric Field Simulation result schematic diagram of the present invention.
Detailed description of the invention
The electrostatic spinning nozzle of face of cylinder equilateral hexagon array as shown in Figure 1 to Figure 3, including body 1, body 1 has Having the face of cylinder being positioned at top and be provided with at least two group export structures, described export structure is for collecting and jet spinning Liquid.
Often group export structure is by six connecting holes being opened on the face of cylinder and the pin type being connected on connecting hole Nozzle 2 forms, and the connecting hole in accompanying drawing overlaps with needle nozzle 2, and therefore connecting hole does not the most indicate.Such as Fig. 3 Shown in, these six connecting holes project on the end points being respectively at equilateral hexagon, namely by subpoint line in the horizontal plane The track of rear composition equilateral hexagon.In this described equilateral hexagon, the line of relative two of which end points is parallel to cylinder The axis in face, is positioned on the top line on the face of cylinder for the two of which connecting hole in this export structure, and four additional connecting hole is with circle The top line of cylinder is the both sides that axis of symmetry lays respectively at face of cylinder top line.
In embodiment, each group export structure along the axis on the face of cylinder linearly array arrange, later group export structure phase For previous group export structure axial symmetry being spaced a distance on the axis direction on the face of cylinder, thus, all export structures Projection in the horizontal plane i.e. constitutes the linear array figure of the equilateral hexagon at multiple interval.Specifically, with reference to Fig. 3, The most adjacent above-mentioned equilateral hexagon is zhou duicheng tuxing, and its axis of symmetry is perpendicular to the axis on the face of cylinder, and axis of symmetry is also simultaneously It is respectively parallel to the limit 31,32 of two equilateral hexagon.Article two, spacing d on limit 31,32 is the spacing of adjacent sets output mechanism.
Above-mentioned needle nozzle 2 is needle point structure away from the end of connecting hole, and this kind of needle nozzle 2 is commonly used in the art Nozzle structure, is not explained in detail at this.The needle nozzle 2 often organizing export structure is all contour, and different group output Each needle nozzle 2 of structure is also contour, namely all of needle nozzle 2 is both with respect to contour for the face of cylinder.These pins Formula nozzle 2 extends along the normal direction on the face of cylinder.
Above-mentioned body 1 can be complete cylindrical structure thus its surface is the face of cylinder, it is also possible to be only one Part has the structure on the face of cylinder.
Have above-mentioned connecting hole, the electrostatic spinning nozzle of needle nozzle track can greatly reduce in each needle nozzle electric field Influence each other so that the most advanced and sophisticated electric field of each needle nozzle is more uniform.
Preferably, in same group of export structure, the projection in the horizontal plane of each connecting hole is respectively at orthohexagonal end points On, namely the track that six connecting holes are on the projection surface constitutes a regular hexagon.This arrangement is more beneficial for ensureing point Hold the uniform of electric field.
It is furthermore preferred that the spacing of adjacent sets export structure (the most above-mentioned spacing d) is equal with the orthohexagonal length of side, this Arrangement is more beneficial for ensureing the uniform of most advanced and sophisticated electric field.
The electrospinning process of above-described embodiment is as follows:
As shown in Figure 4, being evenly applied on each needle nozzle 2 by outside coating unit by spinning liquid, body 1 is relative to receipts Acquisition means 4 is fixed, and needle nozzle 2 is towards collection device 4, and spinning liquid is in needle nozzle 2, collection device 4 institute Producing induced jet under the induction electric field formed, induced jet is induced to collection device 4 and forms fiber.
In other embodiments of electrostatic spinning nozzle, what needle nozzle 2 can have hollow goes out sap cavity, and this goes out sap cavity and passes through Before and after logical needle nozzle 2, having inlet on body 1 surface, body 1 is internal has solution channel, goes out sap cavity by correspondence Connecting hole, solution channel connection inlet.Now, connecting hole may be considered a spray orifice.
The electrospinning process using the preferred embodiment is as follows:
As shown in Figure 4, body 1 is fixed relative to collection device 4, and needle nozzle 2 is towards collection device 4, will Spinning liquid injects in sap cavity by solution channel and arrives needle nozzle 2 top, and spinning liquid is at needle nozzle 2, collection device 4 Producing induced jet under the induction electric field formed, induced jet is induced to collection device 4 and forms fiber.This spinning process Can continue with spun structure and carry out spinning incessantly.
Below by way of Electric Field Simulation the electrostatic spinning nozzle in embodiment and the most linearly array arranged with And the shower nozzle that hexagonal shaft symmetry spaced array is arranged contrasts.
Simulation parameter is as follows: needle nozzle 2 diameter 2mm, and the height of nozzle-end to the face of cylinder is 15mm, such as Fig. 3 institute In the top view (floor projection) shown, the spacing of adjacent nozzle subpoint is 20mm, and nozzle material is rustless steel, the face of cylinder straight Footpath is 100mm, a length of 220mm, and material is rustless steel.Face of cylinder top line distance collection device distance is 115mm, collection device A width of 180mm, a length of 240mm, thickness is 2mm, and material is aluminum.Simulation software is comsol, and emulation voltage is 50kv.Institute's power taking field It is electric field at nozzle tip 1mm.
The nozzle 61 of contrast simulation becomes three row's arranged in linear arrays in plane 6, as shown in Figure 5.Nozzle 61 diameter 2mm, Nozzle-end is 15mm to the height of plane 6, and adjacent nozzle spacing is 20mm, and material is rustless steel.The top of nozzle 61 is from also Not shown collection device distance is 100mm, a width of 180mm of collection device, a length of 240mm, and thickness is 2mm, and material is aluminum.Emulation Software is comsol, and emulation voltage is 50kv;Institute's power taking field is electric field at nozzle tip 1mm.
As shown in Figure 6, the nozzle 51 of contrast simulation becomes hexagonal shaft symmetry spaced array to arrange in plane 5, this layout Formed figure connecting hole each with this electrostatic spinning nozzle project on horizontal plane on formed figure consistent.Nozzle 51 Diameter 2mm, the height of nozzle-end to plane 5 is 15mm, and adjacent nozzle spacing is 20mm, and material is rustless steel.Nozzle 51 Top from and not shown collection device distance be 100mm, a width of 180mm of collection device, a length of 240mm, thickness is 2mm, material For aluminum.Simulation software is comsol, and emulation voltage is 50kv;Institute's power taking field is electric field at nozzle tip 1mm.
Comparison diagram 7, Fig. 8 and Fig. 9 are simulation result, and in Fig. 9, the electric field intensity difference of adjacent needle nozzle is less, and often The electric field intensity difference in individual region (each two or three crests are one group of curve formed) is less;And shown in Fig. 7 and Fig. 8, The electric field intensity gap of adjacent nozzle substantially big than in Fig. 9.Therefore the electric field using this electrostatic spinning nozzle to be obtained is more equal Even.
The above is the preferred embodiment of the present invention, and it is not intended that limiting the scope of the invention.

Claims (6)

1. an electrostatic spinning nozzle for face of cylinder equilateral hexagon array, including body (1), it is characterised in that: described body (1) having the face of cylinder being positioned at top and be provided with at least two group export structures, each group export structure is along the axis on the face of cylinder Direction linearly array is arranged, adjacent sets export structure is spaced a distance, and each group export structure includes being opened on the face of cylinder Six connecting holes, each connecting hole is all connected to needle nozzle (2), each needle nozzle (2) along the face of cylinder normal direction extend and Contour, in same group of export structure, the projection in the horizontal plane of each connecting hole is respectively on the end points of equilateral hexagon, adjacent Two equilateral hexagon be zhou duicheng tuxing, and its axis of symmetry is parallel to the limit of equilateral hexagon.
The electrostatic spinning nozzle of the face of cylinder the most according to claim 1 equilateral hexagon array, it is characterised in that: same group In export structure, the projection in the horizontal plane of each connecting hole is respectively on orthohexagonal end points.
The electrostatic spinning nozzle of the face of cylinder the most according to claim 2 equilateral hexagon array, it is characterised in that: adjacent sets The spacing of export structure is equal with the orthohexagonal length of side.
4. according to the electrostatic spinning nozzle of the face of cylinder equilateral hexagon array described in claim 1 or 2 or 3, it is characterised in that: Described needle nozzle (2) has the sap cavity that of hollow, and described body (1) surface has inlet, and body (1) is internal has solution Passage, described in go out sap cavity by corresponding connecting hole, solution channel connection inlet.
5. an electrospinning process, it is characterised in that: use the electrostatic spinning nozzle described in claim 1 or 2 or 3, will spin Silk liquid is coated on each needle nozzle (2), and spinning liquid produces under the induction electric field that needle nozzle (2), collection device are formed Induced jet, induced jet is induced to collection device and forms fiber.
6. an electrospinning process, it is characterised in that: use the electrostatic spinning nozzle described in claim 4, spinning liquid is led to Crossing in solution channel injects sap cavity and arrive needle nozzle (2) top, spinning liquid is in needle nozzle (2), collection device institute shape Producing induced jet under the induction electric field become, induced jet is induced to collection device and forms fiber.
CN201610657662.5A 2016-08-11 2016-08-11 The electrostatic spinning nozzle of face of cylinder equilateral hexagon array and electrospinning process Pending CN106119990A (en)

Priority Applications (1)

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CN201610657662.5A CN106119990A (en) 2016-08-11 2016-08-11 The electrostatic spinning nozzle of face of cylinder equilateral hexagon array and electrospinning process

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Application Number Priority Date Filing Date Title
CN201610657662.5A CN106119990A (en) 2016-08-11 2016-08-11 The electrostatic spinning nozzle of face of cylinder equilateral hexagon array and electrospinning process

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1435515A (en) * 2002-01-30 2003-08-13 韩国科学技术研究院 Polymer fibre web mfg. device and method
CN101077474A (en) * 2007-01-12 2007-11-28 张爱华 Centrifugal force auxiliary using spinning jet electrofluid mechanics method and uses thereof
CN101215762A (en) * 2008-01-03 2008-07-09 东华大学 Device and method for preparing highly effective continuous electrostatic spinning nano fibre felt
KR20110041839A (en) * 2009-10-16 2011-04-22 전북대학교산학협력단 Electrospinning nozzle block with united nozzle
CN103194805A (en) * 2013-04-15 2013-07-10 厦门大学 Claw multi-nozzle electrospinning jet device with auxiliary air flow
CN103334163A (en) * 2013-06-18 2013-10-02 清华大学 Electrospinning sprayer unit, electrospinning liquid filamentation device and electrostatic spinning machine
CN104451910A (en) * 2014-11-10 2015-03-25 厦门大学 Electrostatic spinning device with jet flow induced at fixed point

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1435515A (en) * 2002-01-30 2003-08-13 韩国科学技术研究院 Polymer fibre web mfg. device and method
CN101077474A (en) * 2007-01-12 2007-11-28 张爱华 Centrifugal force auxiliary using spinning jet electrofluid mechanics method and uses thereof
CN101215762A (en) * 2008-01-03 2008-07-09 东华大学 Device and method for preparing highly effective continuous electrostatic spinning nano fibre felt
KR20110041839A (en) * 2009-10-16 2011-04-22 전북대학교산학협력단 Electrospinning nozzle block with united nozzle
CN103194805A (en) * 2013-04-15 2013-07-10 厦门大学 Claw multi-nozzle electrospinning jet device with auxiliary air flow
CN103334163A (en) * 2013-06-18 2013-10-02 清华大学 Electrospinning sprayer unit, electrospinning liquid filamentation device and electrostatic spinning machine
CN104451910A (en) * 2014-11-10 2015-03-25 厦门大学 Electrostatic spinning device with jet flow induced at fixed point

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Application publication date: 20161116

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