CN106119985A - The electrostatic spinning nozzle of face of cylinder triangle center symmetric array and spinning process - Google Patents

The electrostatic spinning nozzle of face of cylinder triangle center symmetric array and spinning process Download PDF

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Publication number
CN106119985A
CN106119985A CN201610657313.3A CN201610657313A CN106119985A CN 106119985 A CN106119985 A CN 106119985A CN 201610657313 A CN201610657313 A CN 201610657313A CN 106119985 A CN106119985 A CN 106119985A
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CN
China
Prior art keywords
face
cylinder
nozzle
triangle
electrostatic spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610657313.3A
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Chinese (zh)
Inventor
朱自明
黄泽峰
郭杰庄
杨晓林
温尊伟
梅晨
谢壁衡
王新力
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Original Assignee
FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd filed Critical FOSHAN QINGZI PRECISION MEASUREMENT AND CONTROL TECHNOLOGY Co Ltd
Priority to CN201610657313.3A priority Critical patent/CN106119985A/en
Publication of CN106119985A publication Critical patent/CN106119985A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0069Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin

Abstract

The invention discloses electrostatic spinning nozzle and the spinning process of a kind of face of cylinder triangle center symmetric array, including body, described body has the face of cylinder being positioned at top and is provided with at least three group export structures, each group export structure includes three connecting holes being opened on the face of cylinder, needle nozzle all it is connected on each connecting hole, each needle nozzle extends and contour along the normal direction on the face of cylinder, three connecting holes are positioned on the end points of triangle, later group export structure is centrosymmetric on the axis direction on the face of cylinder relative to previous group export structure and from a distance, wherein limit of each triangle is on the same line and each parallel to the axis on the face of cylinder.The present invention each needle nozzle electric field intensity difference is less, and the most advanced and sophisticated electric field of each nozzle is more uniform.Present invention can apply to electrostatic spinning.

Description

The electrostatic spinning nozzle of face of cylinder triangle center symmetric array and spinning process
Technical field
The present invention relates to electrostatic spinning field, particularly relate to the Static Spinning of a kind of face of cylinder triangle center symmetric array Silk shower nozzle and spinning process.
Background technology
The patent of invention of Application No. 200910031948.2 discloses a kind of array multi-nozzle electrospinning device, utilizes Multiple shower nozzles that the most linearly rectangular array is arranged carry out spinning, can realize the production in enormous quantities of electrospun fiber membrane material.
But after using for a long time, technical staff finds to postpone in array cloth in the plane when shower nozzle, each shower nozzle Most advanced and sophisticated electric field can influence each other, disturb so that between different shower nozzles, electric field differs greatly and causes spinning uneven.
Summary of the invention
In order to solve the problems referred to above, it is an object of the invention to provide the quiet of a kind of face of cylinder triangle center symmetric array Electrospun shower nozzle, the most advanced and sophisticated electric field of its nozzle is the most uniform.
The technical solution adopted in the present invention is:
The electrostatic spinning nozzle of a kind of face of cylinder triangle center symmetric array, including body, described body has one and is positioned at top The face of cylinder in portion and be provided with at least three group export structures, each group export structure includes three connections being opened on the face of cylinder Hole, each connecting hole is all connected to needle nozzle, and each needle nozzle extends and contour along the normal direction on the face of cylinder, three connecting hole positions On the end points of triangle, later group export structure relative to previous group export structure at the axis direction Shang Cheng center on the face of cylinder Symmetrical and from a distance, wherein limit of each triangle is on the same line and each parallel to the axis on the face of cylinder.
As a further improvement on the present invention, in described triangle, the limit being parallel to face of cylinder axis is positioned at the face of cylinder On top line.
As a further improvement on the present invention, in same group of export structure, the projection in the horizontal plane of each connecting hole is located respectively On the end points of equilateral triangle.
As a further improvement on the present invention, the distance that adjacent sets export structure separates is equal with the length of side of equilateral triangle.
The present invention also provides for a kind of spinning process, and it the technical scheme is that
Using above-mentioned electrostatic spinning nozzle, be coated on by spinning liquid on each needle nozzle, spinning liquid is at needle nozzle, collection dress Putting generation induced jet under formed induction electric field, induced jet is induced to collection device and forms fiber.
It addition, the electrostatic spinning nozzle of the present invention can also use following structure:
Described needle nozzle has the sap cavity that of hollow, and described body surface has inlet, and body interior has solution channel, Described go out sap cavity by corresponding connecting hole, solution channel connection inlet.
The spinning process of this electrostatic spinning nozzle is as follows:
In injecting sap cavity by spinning liquid by solution channel and arrive needle nozzle top, spinning liquid is in needle nozzle, collection Producing induced jet under the induction electric field that device is formed, induced jet is induced to collection device and forms fiber.
The invention has the beneficial effects as follows: the present invention respectively organizes export structure and is centrosymmetric cloth along the axis direction on the face of cylinder Putting, the triangle track of line of three connecting holes of each group export structure, a wherein limit of each triangle is with always On line and each parallel to the axis on the face of cylinder, thus the subpoint that each connecting hole is on horizontal plane forms triangle center The track of symmetric array, this arrangement for prior art in the nozzle of array arranged in tracks in the plane, Each nozzle electric field intensity difference is less, and the most advanced and sophisticated electric field of each nozzle is more uniform.
Accompanying drawing explanation
The present invention is further described with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is the front view of electrostatic spinning nozzle;
Fig. 2 is the side view of electrostatic spinning nozzle;
Fig. 3 is the top view of electrostatic spinning nozzle;
Fig. 4 is the schematic diagram of electrostatic spinning process;
Fig. 5 is schematic diagram in three row's arranged in linear arrays shower nozzles in the plane;
Fig. 6 is the schematic diagram that centrosymmetry array the most triangular in shape arranges shower nozzle;
Fig. 7 is the Electric Field Simulation result schematic diagram of arrangement in Fig. 5;
Fig. 8 is the Electric Field Simulation result schematic diagram of arrangement in Fig. 6;
Fig. 9 is the Electric Field Simulation result schematic diagram of positioning means of the present invention.
Detailed description of the invention
The electrostatic spinning nozzle of face of cylinder triangle center symmetric array as shown in Figure 1 to Figure 3, including body 1, body 1 has the face of cylinder being positioned at top and is provided with at least three group export structures, and described export structure is used for collecting and spraying Spinning liquid.
Often group export structure is by three connecting holes being opened on the face of cylinder and the pin type being connected on connecting hole Nozzle 2 forms, and the connecting hole in accompanying drawing overlaps with needle nozzle 2, and therefore connecting hole does not the most indicate.These three The triangle track of line of connecting hole, namely these three connecting hole is on the end points of a triangle, wherein has two companies The line section connecing hole is parallel with the axis on the face of cylinder, in other words, and wherein of the triangle being made up of these three connecting hole While be parallel to the axis on the face of cylinder.
In embodiment, later group export structure relative to previous group export structure at the axis direction Shang Cheng center on the face of cylinder Symmetry is also spaced a distance, and thus, on the axis direction on the face of cylinder, each group export structure constitutes multiple triangle center The arrangement form of symmetric array.It addition, above-mentioned multiple trianglees are parallel to the limit of face of cylinder axis the most point-blank. The symmetrical centre of adjacent two trianglees is also on this straight line.
As it is shown on figure 3, often organize the projection in the horizontal plane of three connecting holes of export structure to be respectively at another one three On the end points of dihedral, namely by track triangle after three subpoint lines.From above-mentioned also, each export structure Connecting hole projection in the horizontal plane constitute the linear array figure of centrosymmetry triangle at multiple interval.Concrete next Saying, with reference to Fig. 3, triangle the most adjacent on above-mentioned horizontal plane is centrosymmetric knot in the horizontal plane relative to point 33 Structure, but adjacent two triangular compartments one distance, d, this spacing being two groups of export structures spaced apart.
Above-mentioned needle nozzle 2 is needle point structure away from the end of connecting hole, and this kind of needle nozzle 2 is commonly used in the art Nozzle structure, is not explained in detail at this.The needle nozzle 2 often organizing export structure is all contour, and different group output Each needle nozzle 2 of structure is also contour, namely all of needle nozzle 2 is both with respect to contour for the face of cylinder.These pins Formula nozzle 2 extends along the normal direction on the face of cylinder.
Above-mentioned body 1 can be complete cylindrical structure thus its surface is the face of cylinder, it is also possible to be only one Part has the structure on the face of cylinder.
Have above-mentioned connecting hole, the electrostatic spinning nozzle of needle nozzle track can greatly reduce in each needle nozzle electric field Influence each other so that the most advanced and sophisticated electric field of each needle nozzle is more uniform.
In the triangular trajectory that above-mentioned often group three connecting holes of export structure are constituted, it is parallel to the limit of face of cylinder axis Being positioned on the top line on the face of cylinder, the symmetrical centre of the most adjacent export structure is also on the top line on the face of cylinder.
Preferably, in same group of export structure, the projection in the horizontal plane of each connecting hole is respectively at the end points of equilateral triangle On.The projection of i.e. three connecting holes constitutes the track of an equilateral triangle.This arrangement is more beneficial for ensureing most advanced and sophisticated electric field Uniform.
It is further preferred that the spacing of adjacent sets export structure is actually adjacent equilateral triangle on horizontal plane Distance.As shown in Figure 3, the spacing of adjacent sets export structure is actual is spacing d between subpoint 31 and subpoint 32, and should Spacing d is the most equal with the length of side of equilateral triangle, and this arrangement is more beneficial for ensureing the uniform of most advanced and sophisticated electric field.
The spinning process of above-described embodiment is as follows:
As shown in Figure 4, being evenly applied on each needle nozzle 2 by outside coating unit by spinning liquid, body 1 is relative to receipts Acquisition means 4 is fixed, and needle nozzle 2 is towards collection device 4, and spinning liquid is in needle nozzle 2, collection device 4 institute Producing induced jet under the induction electric field formed, induced jet is induced to collection device 4 and forms fiber.
In other embodiments of electrostatic spinning nozzle, what needle nozzle 2 can have hollow goes out sap cavity, and this goes out sap cavity and passes through Before and after logical needle nozzle 2, having inlet on body 1 surface, body 1 is internal has solution channel, goes out sap cavity by correspondence Connecting hole, solution channel connection inlet.Now, connecting hole may be considered a spray orifice.
The spinning process using the preferred embodiment is as follows:
As shown in Figure 4, body 1 is fixed relative to collection device 4, and needle nozzle 2 is towards collection device 4, will Spinning liquid injects in sap cavity by solution channel and arrives needle nozzle 2 top, and spinning liquid is at needle nozzle 2, collection device 4 Producing induced jet under the induction electric field formed, induced jet is induced to collection device 4 and forms fiber.This spinning process Can continue with spun structure and carry out spinning incessantly.
Below by way of Electric Field Simulation the electrostatic spinning nozzle in embodiment and the most linearly array arranged with And the shower nozzle that in plane, triangle center symmetric array is arranged contrasts.
Simulation parameter is as follows: needle nozzle 2 diameter 2mm, and the height of nozzle-end to the face of cylinder is 15mm, such as Fig. 3 institute In the top view (floor projection) shown, the spacing of adjacent nozzle subpoint is 20mm, and nozzle material is rustless steel, the face of cylinder straight Footpath is 100mm, a length of 220mm, and material is rustless steel.Face of cylinder top line distance collection device distance is 115mm, collection device A width of 180mm, a length of 240mm, thickness is 2mm, and material is aluminum.Simulation software is comsol, and emulation voltage is 50kv.Institute's power taking field It is electric field at nozzle tip 1mm.
The nozzle 61 of contrast simulation becomes three row's arranged in linear arrays in plane 6, as shown in Figure 5.Nozzle 61 diameter 2mm, Nozzle-end is 15mm to the height of plane 6, and adjacent nozzle spacing is 20mm, and material is rustless steel.The top of nozzle 61 is from also Not shown collection device distance is 100mm, a width of 180mm of collection device, a length of 240mm, and thickness is 2mm, and material is aluminum.Emulation Software is comsol, and emulation voltage is 50kv;Institute's power taking field is electric field at nozzle tip 1mm.
As shown in Figure 6, the nozzle 51 of contrast simulation centrosymmetry array triangular in shape in plane 5 is arranged, this layout institute Formed track connecting hole each with this electrostatic spinning nozzle project on horizontal plane on formation figure consistent.Nozzle 51 Diameter 2mm, the height of nozzle-end to plane 5 is 15mm, and adjacent nozzle spacing is 20mm, and material is rustless steel.Nozzle 51 Top from and not shown collection device distance be 100mm, a width of 180mm of collection device, a length of 240mm, thickness is 2mm, material For aluminum.Simulation software is comsol, and emulation voltage is 50kv;Institute's power taking field is electric field at nozzle tip 1mm.
Comparison diagram 7, Fig. 8 and Fig. 9 are simulation result, and in Fig. 9, the electric field intensity difference of adjacent needle nozzle is less, and often The electric field intensity difference in individual region (every three crests are one group of curve formed) is less;And shown in Fig. 7 and Fig. 8, adjacent spray The electric field intensity gap of mouth substantially big than in Fig. 9.Therefore the electric field using the present embodiment electrostatic spinning nozzle to be obtained is more equal Even.
The above is the preferred embodiment of the present invention, and it is not intended that limiting the scope of the invention.

Claims (7)

1. an electrostatic spinning nozzle for face of cylinder triangle center symmetric array, including body (1), it is characterised in that: described Body (1) has the face of cylinder being positioned at top and is provided with at least three group export structures, and each group export structure includes being opened in Three connecting holes on the face of cylinder, each connecting hole is all connected to needle nozzle (2), and each needle nozzle (2) is along the method on the face of cylinder To extending and contour, three connecting holes are positioned on the end points of triangle, and later group export structure is relative to previous group export structure The axis direction on the face of cylinder is centrosymmetric and from a distance, a wherein limit of each triangle is on the same line And the axis each parallel to the face of cylinder.
The electrostatic spinning nozzle of the face of cylinder the most according to claim 1 triangle center symmetric array, it is characterised in that: institute Stating in triangle, the limit being parallel to face of cylinder axis is positioned on the top line on the face of cylinder.
The electrostatic spinning nozzle of the face of cylinder the most according to claim 2 triangle center symmetric array, it is characterised in that: with In one group of export structure, the projection in the horizontal plane of each connecting hole is respectively on the end points of equilateral triangle.
The electrostatic spinning nozzle of the face of cylinder the most according to claim 3 triangle center symmetric array, it is characterised in that: phase The distance that adjacent group export structure separates is equal with the length of side of equilateral triangle.
5., according to the electrostatic spinning nozzle of the face of cylinder triangle center symmetric array described in claim 1 or 2 or 3 or 4, it is special Levying and be: described needle nozzle (2) has the sap cavity that of hollow, described body (1) surface has inlet, and body (1) is internal There is solution channel, described in go out sap cavity by corresponding connecting hole, solution channel connection inlet.
6. a spinning process, it is characterised in that: use the electrostatic spinning nozzle according to any one of claim 1 to 4, will spin Silk liquid is coated on each needle nozzle (2), and spinning liquid produces under the induction electric field that needle nozzle (2), collection device are formed Induced jet, induced jet is induced to collection device and forms fiber.
7. a spinning process, it is characterised in that: use the electrostatic spinning nozzle described in claim 5, by spinning liquid by molten Liquid passage injects in sap cavity and arrives needle nozzle (2) top, and spinning liquid is formed at needle nozzle (2), collection device Producing induced jet under induction electric field, induced jet is induced to collection device and forms fiber.
CN201610657313.3A 2016-08-11 2016-08-11 The electrostatic spinning nozzle of face of cylinder triangle center symmetric array and spinning process Pending CN106119985A (en)

Priority Applications (1)

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CN201610657313.3A CN106119985A (en) 2016-08-11 2016-08-11 The electrostatic spinning nozzle of face of cylinder triangle center symmetric array and spinning process

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690992A (en) * 2019-03-12 2020-09-22 株式会社东芝 Nozzle unit, electric field spinning nozzle and electric field spinning device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007303015A (en) * 2006-05-10 2007-11-22 Univ Of Shiga Prefecture Static spinning apparatus
CN101298724A (en) * 2008-06-20 2008-11-05 东华大学 Method for producing continuous high-efficiency nano fibre nonwoven fabric and production device thereof
CN101484619A (en) * 2006-07-05 2009-07-15 松下电器产业株式会社 Method and apparatus for producing nanofiber and polymeric web
CN103334166A (en) * 2013-06-18 2013-10-02 清华大学 Electrospinning liquid filamentation device and electrostatic spinning machine
CN204570099U (en) * 2015-01-15 2015-08-19 睿金生物科技(苏州)有限公司 A kind of anti-interference electrospinning device easy to assemble

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007303015A (en) * 2006-05-10 2007-11-22 Univ Of Shiga Prefecture Static spinning apparatus
JP4981355B2 (en) * 2006-05-10 2012-07-18 公立大学法人 滋賀県立大学 Electrostatic spinning device
CN101484619A (en) * 2006-07-05 2009-07-15 松下电器产业株式会社 Method and apparatus for producing nanofiber and polymeric web
CN101298724A (en) * 2008-06-20 2008-11-05 东华大学 Method for producing continuous high-efficiency nano fibre nonwoven fabric and production device thereof
CN103334166A (en) * 2013-06-18 2013-10-02 清华大学 Electrospinning liquid filamentation device and electrostatic spinning machine
CN204570099U (en) * 2015-01-15 2015-08-19 睿金生物科技(苏州)有限公司 A kind of anti-interference electrospinning device easy to assemble

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690992A (en) * 2019-03-12 2020-09-22 株式会社东芝 Nozzle unit, electric field spinning nozzle and electric field spinning device
KR20200109248A (en) * 2019-03-12 2020-09-22 가부시끼가이샤 도시바 Head unit, electrospinning head, and electrospinning apparatus
KR102287674B1 (en) * 2019-03-12 2021-08-10 가부시끼가이샤 도시바 Head unit, electrospinning head, and electrospinning apparatus
CN111690992B (en) * 2019-03-12 2022-11-04 株式会社东芝 Nozzle unit, electric field spinning nozzle and electric field spinning device

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