CN106118831A - A kind of rust-proof water-based cutting liquid of high cooling performance - Google Patents
A kind of rust-proof water-based cutting liquid of high cooling performance Download PDFInfo
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- CN106118831A CN106118831A CN201610549692.4A CN201610549692A CN106118831A CN 106118831 A CN106118831 A CN 106118831A CN 201610549692 A CN201610549692 A CN 201610549692A CN 106118831 A CN106118831 A CN 106118831A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/04—Well-defined cycloaliphatic compounds
- C10M2203/045—Well-defined cycloaliphatic compounds used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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Abstract
The invention discloses the rust-proof water-based cutting liquid of a kind of high cooling performance, its raw material includes by weight: cycloalkanes base oil 15 25 parts, polyaniline 28 parts, modified antirust agent 6 12 parts, boric acid 26 parts, castor oil acid 39 parts, diisopropanolamine (DIPA) 16 parts, 2 amino 2 methyl 1 propanol 35 parts, nitrogenous family macromolecule modification slow releasing agent 25 parts, petroleum sodium sulfonate 35 parts, methyl benzotriazole 14 parts, polymerization oleic acid synthetic ester lubricant 24 parts, polynary oleic acid synthetic ester lubricant 36 parts, short carbon chain dicarboxylic acids antirust agent 16 parts, Long carbon chain polybasic carboxylic acid antirust agent 25 parts, maleopimaric acid alkylolamides 34 parts, antibacterial 14 parts, defoamer 26 parts, 14 parts of water.The water-base cutting fluid of the present invention has the cooling performance of excellence, and anti-rust and corrosionproperties is good.
Description
Technical field
The present invention relates to a kind of cutting fluid, particularly relate to the rust-proof water-based cutting liquid of a kind of high cooling performance.
Background technology
Metalworking fluid is a kind of important auxiliary material required for process of metal working, and it primarily serves antirust, profit
Effect sliding, that clean and cool down.Cutting fluid is broadly divided into oil base cutting fluid and water base two big kinds the most both at home and abroad, and
There is the oil type trend to water-base cutting fluid transition, the cutting oil that oil base cutting fluid is the most usually said, its greasy property is good, but
Cooling effect is poor, at a high speed and can produce smog under the conditions of heavy cut, and meeting serious environment pollution, and product uses process
In easily catch fire, cause use dangerous.Just because of disadvantage mentioned above, therefore, oil base cutting fluid can not meet advanced metal and added
The use requirement of work technology.And water-base cutting fluid has series of advantages, such as good cooling results, fire line is good, the dirt to environment
Dye problem is easily solved.Therefore, quickly, water-base cutting fluid includes emulsion, synthetic cutting fluid and microemulsion to development in recent years
Cutting fluid (the most semi-synthetic cutting fluid).The liquid form of synthetic cutting fluid approximates with semi-synthetic cutting fluid, and dilution property is transparent
Shape, is easy in the course of processing observe processing situation, and service life is longer 4～6 times than emulsion；Machine tool slide parts can be played good
Good lubricating and antirust effect.
The synthesis of cutting fluid of the prior art is mainly some lubricants, surfactant, antirust agent, coupling agent, has
Machine silicon type defoamer etc. form, and lubricant mainly applies machine oil, Polyethylene Glycol, fatty acid soaps etc., and antirust agent mainly should
With triethanolamine oleate, borate, nitrite, chromate etc..Surfactant is mainly applied NP series, TX series, is gathered
Ether series etc..
The cooling of cutting fluid of the prior art and rustless property cannot meet the demand in actual production process, the most urgently
The rust-proof water-based cutting liquid of a kind of high cooling performance need to be developed to solve the problems of the prior art.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes the rust-proof water-based cutting of a kind of high cooling performance
Liquid, has the cooling performance of excellence, and anti-rust and corrosionproperties is good.
The rust-proof water-based cutting liquid of a kind of high cooling performance that the present invention proposes, its raw material includes by weight: cycloalkyl
Plinth oil 15-25 part, polyaniline 2-8 part, modified antirust agent 6-12 part, boric acid 2-6 part, castor oil acid 3-9 part, diisopropanolamine (DIPA) 1-
6 parts, 2-amino-2-methyl-1-propanol 3-5 part, nitrogenous family macromolecule modification slow releasing agent 2-5 part, petroleum sodium sulfonate 3-5 part, first
Base benzotriazole 1-4 part, polymerization oleic acid synthetic ester lubricant 2-4 part, polynary oleic acid synthetic ester lubricant 3-6 part, short carbon chain binary
Carboxylic acid antirust agent 1-6 part, Long carbon chain polybasic carboxylic acid antirust agent 2-5 part, maleopimaric acid alkylolamides 3-4 part, antibacterial 1-4 part,
Defoamer 2-6 part, water 1-4 part.
Preferably, modified antirust agent is prepared by following technique: mixed homogeneously with transformer oil by dressing agent, under room temperature
Stirring 20-30min, is subsequently adding butyl titanate and distilled water, stirs 8-12h under room temperature, and then decompression distillation obtains modified anti-
Rust agent.
Preferably, in the preparation technology of modified antirust agent, the weight of dressing agent, transformer oil, butyl titanate and distilled water
Ratio is 2-8:3-6:4-9:12-24.
Preferably, in the preparation technology of modified antirust agent, dressing agent is pressed weight by oleic acid and dodecyltrimethoxysilane
Amount mixes than 1-4:5-15.
Preferably, cycloalkanes base oil, polyaniline, modified antirust agent, boric acid, castor oil acid, diisopropanolamine (DIPA) and 2-amino-
The weight ratio of 2-methyl isophthalic acid-propanol is 18-22:3-7:7-11:3-5:4-8:2-5:3.5-4.5.
Preferably, its raw material includes by weight: cycloalkanes base oil 18-22 part, polyaniline 3-7 part, modified antirust agent 7-
11 parts, boric acid 3-5 part, castor oil acid 4-8 part, diisopropanolamine (DIPA) 2-5 part, 2-amino-2-methyl-1-propanol 3.5-4.5 part, contain
Nitrogen family macromolecule modification slow releasing agent 2.5-4.5 part, petroleum sodium sulfonate 3.5-4.5 part, methyl benzotriazole 2-3 part, polymerization oleic acid close
Become ester lubricant 2.5-3.5 part, polynary oleic acid synthetic ester lubricant 4-5 part, short carbon chain dicarboxylic acids antirust agent 2-5 part, long carbon
Chain polybasic carboxylic acid antirust agent 3-4 part, maleopimaric acid alkylolamides 3.2-3.8 part, antibacterial 2-3 part, defoamer 3-5 part, water 2-3
Part.
Preferably, its raw material includes by weight: cycloalkanes base oil 20 parts, polyaniline 5 parts, modified antirust agent 9 parts, boric acid
4 parts, castor oil acid 6 parts, diisopropanolamine (DIPA) 3.5 parts, 2-amino-2-methyl-1-propanol 4 parts, nitrogenous family macromolecule modification slow release
Agent 3.5 parts, petroleum sodium sulfonate 4 parts, methyl benzotriazole 2.5 parts, polymerization oleic acid synthetic ester lubricant 3 parts, polynary oleic acid synthetic ester
Lubricant 4.5 parts, short carbon chain dicarboxylic acids antirust agent 3.5 parts, Long carbon chain polybasic carboxylic acid antirust agent 3.5 parts, maleopimaric acid alcohol
Amide 3.5 parts, antibacterial 2.5 parts, defoamer 4 parts, 2.5 parts of water.
The rust-proof water-based cutting liquid of a kind of high cooling performance of the present invention, its raw material includes cycloalkanes base oil, polyaniline, changes
Property antirust agent, boric acid, castor oil acid, diisopropanolamine (DIPA), 2-amino-2-methyl-1-propanol, nitrogenous family macromolecule modification slow release
Agent, petroleum sodium sulfonate, methyl benzotriazole, polymerization oleic acid synthetic ester lubricant, polynary oleic acid synthetic ester lubricant, short carbon chain binary
Carboxylic acid antirust agent, Long carbon chain polybasic carboxylic acid antirust agent, maleopimaric acid alkylolamides, antibacterial, defoamer and water.Wherein with cycloalkanes
Base oil is oil phase base material, and auxiliary adds polyaniline, modified antirust agent, boric acid, castor oil acid, diisopropanolamine (DIPA), 2-amino-2-
Methyl isophthalic acid-propanol, nitrogenous family macromolecule modification slow releasing agent, petroleum sodium sulfonate, methyl benzotriazole, polymerization oleic acid synthetic ester lubricate
Agent, polynary oleic acid synthetic ester lubricant, short carbon chain dicarboxylic acids antirust agent, Long carbon chain polybasic carboxylic acid antirust agent, maleopimaric acid
Alkylolamides, antibacterial, defoamer and water, as auxiliary agent, give lubrication, cooling, anticorrosion and rust-preventing characteristic that cutting fluid of the present invention is excellent
Energy.Wherein modified antirust agent is with dressing agent, transformer oil, butyl titanate and distilled water as raw material, the modified antirust agent obtained, outward
Shape is pelletoid, and footpath is evenly distributed, basic soilless sticking phenomenon, and surface exists one layer of organic decoration film, dressing agent and nanoparticle
Between connected by chemical bond, form one layer of sedimentary or passivating film in metal surface, this sedimentary or passivating film are to breakage just
Oil film repair, thus extend the antirust time of oil film, improve rustless property.The water-base cutting fluid of the present invention has
Excellent cooling performance, anti-rust and corrosionproperties is good.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for this is described
Bright rather than be used for limiting the invention, any made on the basis of the present invention amendment, equivalent etc. is all at this
In bright protection domain.
In detailed description of the invention, the weight portion of cycloalkanes base oil can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts,
21 parts, 22 parts, 23 parts, 24 parts, 25 parts；The weight portion of polyaniline can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；Modified
The weight portion of antirust agent can be 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts；The weight portion of boric acid can be 2 parts, 3 parts,
4 parts, 5 parts, 6 parts；The weight portion of castor oil acid can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight of diisopropanolamine (DIPA)
Amount part can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；2-amino-2-first
The weight portion of base-1-propanol can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of nitrogenous family macromolecule modification slow releasing agent
It can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of petroleum sodium sulfonate can be 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The weight portion of methyl benzotriazole can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Godied oil
The weight portion of acid synthetic ester lubricant can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight of polynary oleic acid synthetic ester lubricant
Amount part can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of short carbon chain dicarboxylic acids antirust agent is permissible
It it is 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Long carbon chain polybasic carboxylic acid antirust agent
Weight portion can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of maleopimaric acid alkylolamides is permissible
It it is 3 parts, 3.1 parts, 3.2 parts, 3.3 parts, 3.4 parts, 3.5 parts, 3.6 parts, 3.7 parts, 3.8 parts, 3.9 parts, 4 parts；The weight of antibacterial
Part can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of defoamer can be 2 parts, 2.5 parts, 3 parts,
3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of water can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part.
Embodiment 1
The rust-proof water-based cutting liquid of a kind of high cooling performance that the present invention proposes, its raw material includes by weight: cycloalkyl
Plinth oil 20 parts, polyaniline 5 parts, modified antirust agent 9 parts, boric acid 4 parts, castor oil acid 6 parts, diisopropanolamine (DIPA) 3.5 parts, 2-amino-
2-methyl isophthalic acid-propanol 4 parts, nitrogenous family macromolecule modification slow releasing agent 3.5 parts, petroleum sodium sulfonate 4 parts, methyl benzotriazole 2.5 parts, poly-
Close oleic acid synthetic ester lubricant 3 parts, polynary oleic acid synthetic ester lubricant 4.5 parts, short carbon chain dicarboxylic acids antirust agent 3.5 parts, length
Carbochain polybasic carboxylic acid antirust agent 3.5 parts, maleopimaric acid alkylolamides 3.5 parts, antibacterial 2.5 parts, defoamer 4 parts, 2.5 parts of water.
Modified antirust agent is prepared by following technique: by weight by equal to 5 parts of dressing agents and 4.5 parts of transformer oil mixing
Even, stir 25min under room temperature, be subsequently adding 6.5 parts of butyl titanates and 18 parts of distilled water, under room temperature, stir 10h, steaming of then reducing pressure
Evaporate and obtain modified antirust agent.
In the preparation technology of modified antirust agent, dressing agent is by oleic acid and dodecyltrimethoxysilane by weight 2.5:
10 mix.
Embodiment 2
The rust-proof water-based cutting liquid of a kind of high cooling performance that the present invention proposes, its raw material includes by weight: cycloalkyl
Plinth oil 15 parts, polyaniline 8 parts, modified antirust agent 6 parts, boric acid 6 parts, castor oil acid 3 parts, diisopropanolamine (DIPA) 6 parts, 2-amino-2-
Methyl isophthalic acid-propanol 3 parts, nitrogenous family macromolecule modification slow releasing agent 5 parts, petroleum sodium sulfonate 3 parts, methyl benzotriazole 4 parts, polymerization oleic acid
Synthetic ester lubricant 2 parts, polynary oleic acid synthetic ester lubricant 6 parts, short carbon chain dicarboxylic acids antirust agent 1 part, the polynary carboxylic of Long carbon chain
Acid antirust agent 5 parts, maleopimaric acid alkylolamides 3 parts, antibacterial 4 parts, defoamer 2 parts, 4 parts of water.
Modified antirust agent is prepared by following technique: by weight by equal to 2 parts of dressing agents and 6 parts of transformer oil mixing
Even, stir 20min under room temperature, be subsequently adding 9 parts of butyl titanates and 12 parts of distilled water, under room temperature, stir 12h, distillation of then reducing pressure
Obtain modified antirust agent.
In the preparation technology of modified antirust agent, dressing agent is by oleic acid and dodecyltrimethoxysilane 1:15 by weight
Mix.
Embodiment 3
The rust-proof water-based cutting liquid of a kind of high cooling performance that the present invention proposes, its raw material includes by weight: cycloalkyl
Plinth oil 25 parts, polyaniline 2 parts, modified antirust agent 12 parts, boric acid 2 parts, castor oil acid 9 parts, diisopropanolamine (DIPA) 1 part, 2-amino-2-
Methyl isophthalic acid-propanol 5 parts, nitrogenous family macromolecule modification slow releasing agent 2 parts, petroleum sodium sulfonate 5 parts, methyl benzotriazole 1 part, polymerization oleic acid
Synthetic ester lubricant 4 parts, polynary oleic acid synthetic ester lubricant 3 parts, short carbon chain dicarboxylic acids antirust agent 6 parts, the polynary carboxylic of Long carbon chain
Acid antirust agent 2 parts, maleopimaric acid alkylolamides 4 parts, antibacterial 1 part, defoamer 6 parts, 1 part of water.
Modified antirust agent is prepared by following technique: by weight by equal to 8 parts of dressing agents and 3 parts of transformer oil mixing
Even, stir 30min under room temperature, be subsequently adding 4 parts of butyl titanates and 24 parts of distilled water, under room temperature, stir 8h, distillation of then reducing pressure
Obtain modified antirust agent.
In the preparation technology of modified antirust agent, dressing agent is by oleic acid and dodecyltrimethoxysilane 4:5 by weight
Mix.
Embodiment 4
The rust-proof water-based cutting liquid of a kind of high cooling performance that the present invention proposes, its raw material includes by weight: cycloalkyl
Plinth oil 18 parts, polyaniline 7 parts, modified antirust agent 7 parts, boric acid 5 parts, castor oil acid 4 parts, diisopropanolamine (DIPA) 5 parts, 2-amino-2-
Methyl isophthalic acid-propanol 3.5 parts, nitrogenous family macromolecule modification slow releasing agent 4.5 parts, petroleum sodium sulfonate 3.5 parts, methyl benzotriazole 3 parts, poly-
Close oleic acid synthetic ester lubricant 2.5 parts, polynary oleic acid synthetic ester lubricant 5 parts, short carbon chain dicarboxylic acids antirust agent 2 parts, long carbon
Chain polybasic carboxylic acid antirust agent 4 parts, maleopimaric acid alkylolamides 3.2 parts, antibacterial 3 parts, defoamer 3 parts, 3 parts of water.
Modified antirust agent is prepared by following technique: by weight by equal to 3 parts of dressing agents and 5 parts of transformer oil mixing
Even, stir 22min under room temperature, be subsequently adding 8 parts of butyl titanates and 14 parts of distilled water, under room temperature, stir 11h, distillation of then reducing pressure
Obtain modified antirust agent.
In the preparation technology of modified antirust agent, dressing agent is by oleic acid and dodecyltrimethoxysilane 2:12 by weight
Mix.
Embodiment 5
The rust-proof water-based cutting liquid of a kind of high cooling performance that the present invention proposes, its raw material includes by weight: cycloalkyl
Plinth oil 22 parts, polyaniline 3 parts, modified antirust agent 11 parts, boric acid 3 parts, castor oil acid 8 parts, diisopropanolamine (DIPA) 2 parts, 2-amino-2-
Methyl isophthalic acid-propanol 4.5 parts, nitrogenous family macromolecule modification slow releasing agent 2.5 parts, petroleum sodium sulfonate 4.5 parts, methyl benzotriazole 2 parts, poly-
Close oleic acid synthetic ester lubricant 3.5 parts, polynary oleic acid synthetic ester lubricant 4 parts, short carbon chain dicarboxylic acids antirust agent 5 parts, long carbon
Chain polybasic carboxylic acid antirust agent 3 parts, maleopimaric acid alkylolamides 3.8 parts, antibacterial 2 parts, defoamer 5 parts, 2 parts of water.
Modified antirust agent is prepared by following technique: by weight by equal to 7 parts of dressing agents and 4 parts of transformer oil mixing
Even, stir 28min under room temperature, be subsequently adding 5 parts of butyl titanates and 22 parts of distilled water, under room temperature, stir 9h, distillation of then reducing pressure
Obtain modified antirust agent.
In the preparation technology of modified antirust agent, dressing agent is by oleic acid and dodecyltrimethoxysilane 3:8 by weight
Mix.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. the rust-proof water-based cutting liquid of a high cooling performance, it is characterised in that its raw material includes by weight: cycloalkanes base oil
15-25 part, polyaniline 2-8 part, modified antirust agent 6-12 part, boric acid 2-6 part, castor oil acid 3-9 part, diisopropanolamine (DIPA) 1-6 part,
2-amino-2-methyl-1-propanol 3-5 part, nitrogenous family macromolecule modification slow releasing agent 2-5 part, petroleum sodium sulfonate 3-5 part, methylbenzene
Triazole 1-4 part, polymerization oleic acid synthetic ester lubricant 2-4 part, polynary oleic acid synthetic ester lubricant 3-6 part, short carbon chain dicarboxylic acids
Antirust agent 1-6 part, Long carbon chain polybasic carboxylic acid antirust agent 2-5 part, maleopimaric acid alkylolamides 3-4 part, antibacterial 1-4 part, froth breaking
Agent 2-6 part, water 1-4 part.
The rust-proof water-based cutting liquid of high cooling performance the most according to claim 1, it is characterised in that modified antirust agent is by such as
Lower technique is prepared: mixed homogeneously with transformer oil by dressing agent, stirs 20-30min, be subsequently adding butyl titanate under room temperature
And distilled water, stir 8-12h under room temperature, then decompression distillation obtains modified antirust agent.
The rust-proof water-based cutting liquid of high cooling performance the most according to claim 1 and 2, it is characterised in that modified antirust agent
Preparation technology in, the weight ratio of dressing agent, transformer oil, butyl titanate and distilled water is 2-8:3-6:4-9:12-24.
4. according to the rust-proof water-based cutting liquid of the high cooling performance described in any one of claim 1-3, it is characterised in that modified anti-
In the preparation technology of rust agent, dressing agent is mixed by weight 1-4:5-15 by oleic acid and dodecyltrimethoxysilane.
5. according to the rust-proof water-based cutting liquid of the high cooling performance described in any one of claim 1-4, it is characterised in that cycloalkyl
Plinth oil, polyaniline, modified antirust agent, boric acid, castor oil acid, diisopropanolamine (DIPA) and the weight ratio of 2-amino-2-methyl-1-propanol
For 18-22:3-7:7-11:3-5:4-8:2-5:3.5-4.5.
6. according to the rust-proof water-based cutting liquid of the high cooling performance described in any one of claim 1-5, it is characterised in that its raw material
Include by weight: cycloalkanes base oil 18-22 part, polyaniline 3-7 part, modified antirust agent 7-11 part, boric acid 3-5 part, Oleum Ricini
Acid 4-8 part, diisopropanolamine (DIPA) 2-5 part, 2-amino-2-methyl-1-propanol 3.5-4.5 part, nitrogenous family macromolecule modification slow releasing agent
2.5-4.5 part, petroleum sodium sulfonate 3.5-4.5 part, methyl benzotriazole 2-3 part, polymerization oleic acid synthetic ester lubricant 2.5-3.5 part,
Polynary oleic acid synthetic ester lubricant 4-5 part, short carbon chain dicarboxylic acids antirust agent 2-5 part, Long carbon chain polybasic carboxylic acid antirust agent 3-4
Part, maleopimaric acid alkylolamides 3.2-3.8 part, antibacterial 2-3 part, defoamer 3-5 part, water 2-3 part.
7. according to the rust-proof water-based cutting liquid of the high cooling performance described in any one of claim 1-6, it is characterised in that its raw material
Include by weight: cycloalkanes base oil 20 parts, polyaniline 5 parts, modified antirust agent 9 parts, boric acid 4 parts, castor oil acid 6 parts, two different
Propanolamine 3.5 parts, 2-amino-2-methyl-1-propanol 4 parts, nitrogenous family macromolecule modification slow releasing agent 3.5 parts, petroleum sodium sulfonate 4
Part, methyl benzotriazole 2.5 parts, polymerization oleic acid synthetic ester lubricant 3 parts, polynary oleic acid synthetic ester lubricant 4.5 parts, short carbon chain two
Unit carboxylic acid antirust agent 3.5 parts, Long carbon chain polybasic carboxylic acid antirust agent 3.5 parts, maleopimaric acid alkylolamides 3.5 parts, antibacterial 2.5
Part, defoamer 4 parts, 2.5 parts of water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610549692.4A CN106118831A (en) | 2016-07-13 | 2016-07-13 | A kind of rust-proof water-based cutting liquid of high cooling performance |
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| CN201610549692.4A CN106118831A (en) | 2016-07-13 | 2016-07-13 | A kind of rust-proof water-based cutting liquid of high cooling performance |
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