CN106116157A - A kind of preparation method of Suzhou soil low grade fever's terracotta glaze - Google Patents
A kind of preparation method of Suzhou soil low grade fever's terracotta glaze Download PDFInfo
- Publication number
- CN106116157A CN106116157A CN201610475607.4A CN201610475607A CN106116157A CN 106116157 A CN106116157 A CN 106116157A CN 201610475607 A CN201610475607 A CN 201610475607A CN 106116157 A CN106116157 A CN 106116157A
- Authority
- CN
- China
- Prior art keywords
- glaze
- parts
- terracotta
- low grade
- grade fever
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002689 soil Substances 0.000 title claims abstract description 56
- 208000030208 low-grade fever Diseases 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 94
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 76
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 40
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000010433 feldspar Substances 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 33
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 33
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 claims abstract description 32
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims abstract description 32
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 32
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 32
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 31
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 31
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 31
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 28
- 239000001923 methylcellulose Substances 0.000 claims abstract description 28
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000001055 blue pigment Substances 0.000 claims abstract description 24
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims description 74
- 238000003756 stirring Methods 0.000 claims description 59
- 238000002156 mixing Methods 0.000 claims description 29
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 26
- 239000002253 acid Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 230000036571 hydration Effects 0.000 claims description 3
- 238000006703 hydration reaction Methods 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 238000004534 enameling Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229940035429 isobutyl alcohol Drugs 0.000 claims 1
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical compound [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 claims 1
- 235000010981 methylcellulose Nutrition 0.000 abstract description 24
- 239000000463 material Substances 0.000 abstract description 16
- 238000005245 sintering Methods 0.000 abstract description 15
- 239000002904 solvent Substances 0.000 abstract description 8
- 230000032683 aging Effects 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract description 5
- 230000000996 additive effect Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003674 animal food additive Substances 0.000 abstract description 3
- 238000002425 crystallisation Methods 0.000 abstract description 3
- 230000008025 crystallization Effects 0.000 abstract description 3
- 229910052573 porcelain Inorganic materials 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 description 9
- PSUYMGPLEJLSPA-UHFFFAOYSA-N vanadium zirconium Chemical compound [V].[V].[Zr] PSUYMGPLEJLSPA-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910007735 Zr—Si Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052656 albite Inorganic materials 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052839 forsterite Inorganic materials 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229950000845 politef Drugs 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Cosmetics (AREA)
- Dental Preparations (AREA)
Abstract
The present invention relates to the preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, using zircon-vanadium blue pigment, feldspar powder, Brown Alundum is glaze main material, uses the identical glaze feed additives that can reduce sintering temperature, Pulvis Talci, nano titanium oxide, Ca3(VO4)2, zinc phosphate, lithium carbonate, sodium borate decahydrate and glaze hydrophobicity and aging resistance and the solvent of anti-brush and additive thereof can be improved, oxalic acid, isobutanol, ethanol, Zirconium orthosilicate., Methyl cellulose and water, the sintering temperature of this terracotta is 700 755 DEG C, can become glaze, obtain terracotta, meanwhile, prepared terracotta crystallization effect is good, pressure physical and chemical performance of Denging meets use requirement, this glaze is glittering and translucent, third dimension is strong, bright-colored, low burns till porcelain；Meanwhile, by optimizing solvent so that it is good that it has reasonable hydrophobicity, aging resistance and scour resistance.
Description
Technical field
The invention belongs to terracotta glaze preparation field, particularly to the preparation side of a kind of Suzhou soil low grade fever's terracotta glaze
Method.
Background technology
Terracotta is one ancient, traditional ceramic material of China.Along with the development of tourist industry, people are for terracotta
Demand is also more and more, is also more and more higher to its requirement.
Existing terracotta is the most all to use multiple pug mixed sintering to form, and its glaze layer is the thickest and produces and answers
Power, quality weight, it is easily caused product glaze and be full of cracks occurs, collapses the defect of stripping.The most smooth, and pug is the easiest
Producing and pollute, cost and energy consumption are high, and the quality of product is not sufficiently stable, and its glaze glossiness is inadequate, and colour generation is abundant not, stable,
Easily fade under climate variability area or long sunlight are irradiated.At present, glaze sintering temperature is often higher than 1000 DEG C.As
CN201510289465.8 discloses a kind of glazed tiles utilizing Suzhou soil to prepare, this glazed tiles base substrate by Suzhou soil, schmigel,
Albite, quartz, fused magnesite, organic fiber, phenolic resin, starch and rice husk composition；This glazed tiles glaze by iron oxide yellow,
Yttrium stable zirconium oxide, feldspar powder, nano zine oxide, carborundum, carbon fiber, tin ash, TEOS, politef form, should
Terracotta smooth surface is clean and tidy, bright in colour beautiful, has excellent resistance to compression, the fire-resistant and performance of acid and alkali-resistance, and light weight, inhales
Water rate is low, good permeability, low cost, but its sintering temperature is 1450 degrees Celsius, belongs to highly energy-consuming, pollutes again environment, uncomfortable
Close future economy strategy development, therefore, consider from energy-conservation and national angle, following development inevitable toward low-temperature sintering, energy-conservation
Environmental protection develops.The reduction of sintering temperature, can reduce energy consumption, reduces the cost of glaze goods, meets the needs of social development.Ultralow burning
The research of knot technique so that it is purposes is more extensive, can be used in the reparation of terracotta product defect, reduces the secondary of terracotta goods
Product, reduce the waste of resource.Suzhou soil is medium-low temperature fluid alteration remnants type Kaolin.Originate in Yangshan, Suzhou, Jiangsu Province, China one
Band, hence obtains one's name, but the research that use Suzhou soil prepares terracotta is rather seldom.
Present invention mainly solves technical problem is that: for the deficiencies in the prior art, it is provided that a kind of Suzhou soil low grade fever's coloured glaze
The preparation method of brick glaze material, using zircon-vanadium blue pigment, feldspar powder, Brown Alundum is glaze main material, uses identical can reducing
The glaze feed additives of sintering temperature, Pulvis Talci, nano titanium oxide, Ca3(VO4)2, zinc phosphate, lithium carbonate, ten hydration tetraboric acids
Sodium and glaze hydrophobicity and aging resistance and the solvent of anti-brush and additive thereof can be improved, oxalic acid, isobutanol, ethanol,
Zirconium orthosilicate., Methyl cellulose and water, the sintering temperature of this terracotta is 700-755 DEG C, can become glaze, it is thus achieved that terracotta, meanwhile, institute
The terracotta crystallization effect of preparation is good, pressure grade for physical and chemical performance meets use requirement, and this glaze is glittering and translucent, and third dimension is strong, face
Color is bright-coloured, low burns till porcelain；Meanwhile, by optimizing solvent so that it has reasonable hydrophobicity, aging resistance and scour resistance
Good.
Summary of the invention
It is an object of the invention to, for the problems referred to above, develop the preparation method of a kind of Suzhou soil low grade fever's terracotta glaze,
Using zircon-vanadium blue pigment, feldspar powder, Brown Alundum is glaze main material, uses the identical glaze that can reduce sintering temperature to add
Agent, Pulvis Talci, nano titanium oxide, Ca3(VO4)2, zinc phosphate, lithium carbonate, sodium borate decahydrate and glaze can be improved
Hydrophobicity and aging resistance and the solvent of anti-brush and additive thereof, oxalic acid, isobutanol, ethanol, Zirconium orthosilicate., Methyl cellulose and
Water, the sintering temperature of this terracotta is 700-755 DEG C, can become glaze, it is thus achieved that terracotta, meanwhile, prepared terracotta crystallization
Effective, pressure wait physical and chemical performance to meet use requirement, this glaze is glittering and translucent, and third dimension is strong, bright-colored, low burns till porcelain；
Meanwhile, by optimizing solvent so that it is good that it has reasonable hydrophobicity, aging resistance and scour resistance.
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 40-50 part；Feldspar powder 8-10 part；Brown Alundum 8-10 part；Pulvis Talci 1-7 part；Nano titanium oxide
1-7 part；Ca3 (VO4) 2 1-7 part；Zinc phosphate 1-7 part；Lithium carbonate 1-7 part；Sodium borate decahydrate 1-7 part；Oxalic acid 1-2 part；
Isobutanol 100-200 part；Ethanol 100-200 part；Zirconium orthosilicate. 1-2 part；Methylcellulose 1-2 part；Water 200-300 part；
(2) raw material mixing: first isopropanol and ethanol are mixed, form mixed alcohol, be subsequently added zircon-vanadium blue pigment, stir 5-
10min, adds feldspar powder, Brown Alundum after stirring mixing, adds Pulvis Talci, nano titanium oxide, Ca3 (VO4) 2, phosphorus subsequently
Acid zinc, lithium carbonate, sodium borate decahydrate, stir 5-10min, add oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently,
Stirring 5-10h, finally seals old by the solution stirred, can obtain Suzhou soil low grade fever's terracotta glaze.
As preferably, this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Silicon
Acid zirconium 2 parts；Methylcellulose 2 parts；270 parts of water.
As preferably, raw material mixes, and first isopropanol and ethanol is mixed, forms mixed alcohol, be subsequently added zircon-vanadium blue pigment,
Stirring 7min, adds feldspar powder, Brown Alundum after stirring mixing, adds Pulvis Talci subsequently, nano titanium oxide, Ca3 (VO4) 2,
Zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stir
Mix 7h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
A kind of Suzhou soil low grade fever's terracotta glaze, uses the preparation method of above-mentioned Suzhou soil low grade fever's terracotta glaze to prepare institute
, the fineness (250 mesh sieve margin %) of this glaze is 0.6-0.7, and flow velocity is 32-35s, and proportion is 1.79-1.85.
A kind of enameling method of above-mentioned Suzhou soil low grade fever's terracotta glaze, it is characterised in that: at Suzhou soil low grade fever's terracotta
Dry body on directly glazing, the mode of glazing is for drenching glaze or glaze spraying.
Beneficial effects of the present invention:
(1) generally speaking, by optimizing the composition of terracotta glaze, prepare the terracotta of low grade fever, specifically, use
Zircon-vanadium blue pigment, feldspar powder, Brown Alundum are glaze main material, use the identical glaze feed additives that can reduce sintering temperature,
Pulvis Talci；Nano titanium oxide；Ca3(VO4)2；Zinc phosphate；Lithium carbonate；Sodium borate decahydrate, reduces the sintering of this terracotta
Temperature is 700-755 DEG C, can become glaze, it is thus achieved that terracotta, meanwhile, use the solvent of double alcohol and water mixing as mixed solvent,
It has the solvent polarity of more diversification, is possible not only to the various compositions preferably dissolving in glaze, also makes prepared
The hydrophobicity of terracotta is more preferable；And the addition of Zirconium orthosilicate., it is possible not only to play the effect of binding agent, meanwhile, gluing of Zr-Si system
Knot network so that prepared glaze has more preferable anti-wear performance；And oxalic acid is as weak acid, on the one hand can mix at glaze
During play the effect of binding agent, form the complex of oxalic acid class, and the glaze after peracidity oxalic acid optimizes, it will make
The glaze terracotta of final preparation possesses more preferable acid and alkali-resistance ability.
(2) Suzhou soil terracotta, is the first primary raw material with Suzhou soil, and its quality is softer, it is easy to molding, and in order to improve
The intensity of terracotta, in addition to strengthening on base substrate, also need to carry out further physical and chemical performance in the selection of glaze
Strengthening, and in the selection of glaze, in addition to selecting there is the zircon-vanadium blue pigment of certain materialization intensity, it is also added with feldspar powder, palm fibre
Corundum, as main component, on the one hand can strengthen the stability of this glaze further, the most also improves this glaze and base substrate group
The concordance become；
(3) present invention is in order to realize low grade fever's terracotta, unified selection low grade fever's additive in the composition of glaze, including
Pulvis Talci；Nano titanium oxide；Ca3(VO4)2；Zinc phosphate；Lithium carbonate and sodium borate decahydrate, be the two of raw material at Suzhou soil
In the system of silicon oxide and aluminium oxide, sodium borate decahydrate, as eutectic, i.e. starts to melt at 500 DEG C, and adds carbon
Acid lithium, in low temperature melting process, the most releasable carbon dioxide, by adding titanium dioxide and Pulvis Talci, may pass through meanwhile
Forming low melting point with raw material, in conjunction with the alum salts of positive 5 valencys, and owing to there is PO4-network structure in zinc phosphate so that sintering
Auxiliary agent can preferably enter the binary system of silicon dioxide and aluminium oxide, low one-tenth glaze network is integrally formed, can obtain realization
The low grade fever of terracotta, meanwhile, the concordance of the two additive, not only make glaze and base substrate more stable on combining, meanwhile,
Also ensure that the concordance of sintering process.
(4) preparation technology of the present invention is simple, and raw material sources are extensive, is suitable for industrialized production.
Detailed description of the invention
Below in conjunction with specific embodiment, and with reference to data, the present invention is described in further detail.Should be understood that these embodiments
The present invention solely for the purpose of illustration, rather than limit the scope of the present invention by any way.
Preparation method with Suzhou soil low grade fever's terracotta prepared by the Suzhou soil low grade fever's terracotta glaze prepared by the present invention
As follows:
The preparation method of a kind of Suzhou soil low grade fever's terracotta, comprises the steps:
(1) get the raw materials ready: prepare the blank raw material of this terracotta and the raw material of glaze:
This terracotta base substrate is made up of following raw material:
120 parts of Suzhou soil；Forsterite 23 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Titanium dioxide 3 parts；Ca3(VO4)2 3
Part；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；3 parts of phenolic resin；
(2) base substrate material mixing, molding, drying: weigh blank raw material according to formula, by blank raw material wet ball grinding to 200 mesh
Sieve, screen over-size is 0.3wt%；Slurry after sieving is through being dehydrated into mud cake, and old mud 5 days；Carry out under 15MPa pressure subsequently
Cold isostatic compaction, keeps 1h, dries subsequently；
(3) glaze batch mixing, pouring glaze, microwave drying: weigh glaze raw material according to formula, by glaze raw material wet ball grinding extremely
200 mesh sieves, screen over-size is 0.3wt%；Glaze slurry after sieving uses the mode of spray to impose on the base substrate being dried, glaze
The thickness of material is 0.7mm；Drenching the base substrate after glaze and carry out microwave drying, microwave wavelength is 9 millimeters, and drying time is 6min；It is dried
The water content of the base substrate after rear pouring glaze is less than 1.1wt%；
(4) burn till in kiln, polishing: burning till in kiln, firing period is 80 minutes；To terracotta table after burning till
Face uses sand paper to carry out surface finish process, to surface smoothness less than 0.1 μm, can obtain the low grade fever utilizing Suzhou soil to prepare
Terracotta.
The chemical composition of Suzhou soil is: SiO2 47wt%, Al2O3 38wt%, CaO 10wt%, other compositions 5wt%.
Embodiment 1:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Silicon
Acid zirconium 2 parts；Methylcellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose subsequently
And water, stir 7h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Embodiment 2:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 50 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Silicon
Acid zirconium 2 parts；Methylcellulose 2 parts；300 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 8min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 8min, add oxalic acid, Zirconium orthosilicate., methylcellulose subsequently
And water, stir 8h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Embodiment 3:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 40 parts；Feldspar powder 8 parts；Brown Alundum 8 parts；Pulvis Talci 5 parts；Nano titanium oxide 5 parts；Ca3(VO4)
23 parts；Zinc phosphate 5 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Silicon
Acid zirconium 2 parts；Methylcellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose subsequently
And water, stir 7h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Embodiment 4:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 1 part；Isobutanol 100 parts；Ethanol 100 parts；Silicon
Acid zirconium 1 part；Methylcellulose 1 part；220 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose subsequently
And water, stir 7h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Embodiment 5:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 50 parts；Feldspar powder 10 parts；Brown Alundum 10 parts；Pulvis Talci 7 parts；Nano titanium oxide 7 parts；Ca3
(VO4) 23 parts；Zinc phosphate 3 parts；Lithium carbonate 1 part；Sodium borate decahydrate 3 parts；Oxalic acid 1 part；Isobutanol 150 parts；Ethanol 150
Part；Zirconium orthosilicate. 2 parts；Methylcellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose subsequently
And water, stir 7h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Comparative example 1
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Nano titanium oxide 3 parts；Ca3 (VO4) 23 parts；Phosphoric acid
3 parts of zinc；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Zirconium orthosilicate. 2 parts；First
Base cellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add nano titanium oxide, Ca3 (VO4) 2, phosphoric acid subsequently after stirring mixing
Zinc, lithium carbonate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stirring
7h, finally seals old by the solution stirred, can obtain Suzhou soil low grade fever's terracotta glaze.
Comparative example 2:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Zinc phosphate 3
Part；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Zirconium orthosilicate. 2 parts；Methyl is fine
Dimension element 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci subsequently after stirring mixing, nano titanium oxide, zinc phosphate,
Lithium carbonate, sodium borate decahydrate, stir 7min, adds oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stirs 7h,
After the solution that stirs is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Comparative example 3:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Zirconium orthosilicate. 2 parts；First
Base cellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, sodium borate decahydrate, stir 7min, add oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stir
Mix 7h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
Comparative example 4:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Isobutanol 150 parts；Ethanol 150 parts；Zirconium orthosilicate. 2 parts；
Methylcellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added vanadium zirconium blue
Material, stirs 7min, adds feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca3 subsequently after stirring mixing
2 (VO4), zinc phosphate, lithium carbonate, sodium borate decahydrate, stir 7min, add Zirconium orthosilicate., methylcellulose and water subsequently,
Stirring 7h, finally seals old by the solution stirred, can obtain Suzhou soil low grade fever's terracotta glaze.
Comparative example 5:
The preparation method of a kind of Suzhou soil low grade fever's terracotta glaze, comprises the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)
23 parts；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Ethanol 150 parts；Zirconium orthosilicate. 2 parts；Methyl
Cellulose 2 parts；270 parts of water；
(2) raw material mixing: raw material mixes, and is initially charged ethanol, is subsequently added zircon-vanadium blue pigment, stirs 7min, stirring mixing
Rear addition feldspar powder, Brown Alundum, add Pulvis Talci subsequently, nano titanium oxide, Ca3 (VO4) 2, zinc phosphate, lithium carbonate, ten
Hydration sodium tetraborate, stirs 7min, adds oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stirs 7h, finally will stirring
Uniform solution seals old, can obtain Suzhou soil low grade fever's terracotta glaze.
Being applied to by prepared glaze in the preparation process of Suzhou soil low grade fever's terracotta, its sintering temperature (DEG C) is as follows:
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of the spirit or essential attributes of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter
From the point of view of which point, all should regard embodiment as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all by fall in the implication of equivalency and scope of claim
Change is included in the present invention.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps
Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should
Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment
May be appreciated other embodiments.
Claims (5)
1. the preparation method of Suzhou soil low grade fever's terracotta glaze, it is characterised in that: comprise the steps:
(1) get the raw materials ready: prepare the raw material of the glaze of this terracotta: this terracotta glaze is made up of following raw material:
Zircon-vanadium blue pigment 40-50 part；Feldspar powder 8-10 part；Brown Alundum 8-10 part；Pulvis Talci 1-7 part；Nano titanium oxide 1-7
Part；Ca3(VO4)21-7 part；Zinc phosphate 1-7 part；Lithium carbonate 1-7 part；Sodium borate decahydrate 1-7 part；Oxalic acid 1-2 part；Isobutyl
Alcohol 100-200 part；Ethanol 100-200 part；Zirconium orthosilicate. 1-2 part；Methylcellulose 1-2 part；Water 200-300 part；
(2) raw material mixing, first mixes isopropanol and ethanol, forms mixed alcohol, be subsequently added zircon-vanadium blue pigment, stir 5-
10min, adds feldspar powder, Brown Alundum after stirring mixing, adds Pulvis Talci, nano titanium oxide, Ca subsequently3(VO4)2, phosphoric acid
Zinc, lithium carbonate, sodium borate decahydrate, stir 5-10min, add oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stir
Mix 5-10h, finally the solution stirred is sealed old, Suzhou soil low grade fever's terracotta glaze can be obtained.
2. the preparation method of Suzhou as claimed in claim 2 soil low grade fever's terracotta glaze, it is characterised in that this terracotta
Glaze is made up of following raw material:
Zircon-vanadium blue pigment 43 parts；Feldspar powder 9 parts；Brown Alundum 9 parts；Pulvis Talci 3 parts；Nano titanium oxide 3 parts；Ca3(VO4)2 3
Part；Zinc phosphate 3 parts；Lithium carbonate 3 parts；Sodium borate decahydrate 3 parts；Oxalic acid 2 parts；Isobutanol 150 parts；Ethanol 150 parts；Zirconium orthosilicate.
2 parts；Methylcellulose 2 parts；270 parts of water.
3. the preparation method of Suzhou as claimed in claim 1 soil low grade fever's terracotta glaze, it is characterised in that raw material mixes
Close, first isopropanol and ethanol are mixed, form mixed alcohol, be subsequently added zircon-vanadium blue pigment, stir 7min, add after stirring mixing
Feldspar powder, Brown Alundum, add Pulvis Talci, nano titanium oxide, Ca subsequently3(VO4)2, zinc phosphate, lithium carbonate, ten hydration four boron
Acid sodium, stirs 7min, adds oxalic acid, Zirconium orthosilicate., methylcellulose and water subsequently, stirs 7h, finally molten by stir
Liquid-tight envelope is old, can obtain Suzhou soil low grade fever's terracotta glaze.
4. Suzhou soil low grade fever's terracotta glaze, it is characterised in that use the Suzhou soil described in any one of claim 1-3 low
The preparation method burning terracotta glaze prepares gained, and the fineness (250 mesh sieve margin %) of this glaze is 0.6-0.7, and flow velocity is 32-
35s, proportion is 1.79-1.85.
5. the enameling method of Suzhou as claimed in claim 4 soil low grade fever's terracotta glaze, it is characterised in that: at Suzhou soil
Direct glazing on the dry body of low grade fever's terracotta, the mode of glazing is for drenching glaze or glaze spraying.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114105475A (en) * | 2021-11-30 | 2022-03-01 | 汕头职业技术学院 | Nano titanium dioxide glaze and preparation method thereof |
| CN115073163A (en) * | 2022-07-01 | 2022-09-20 | 深圳振华富电子有限公司 | Chip varistor and preparation method and application thereof |
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| CN102134167A (en) * | 2010-01-21 | 2011-07-27 | 江苏拜富科技有限公司 | Low-temperature melting block finished glaze and preparation method thereof |
| CN102992813A (en) * | 2012-12-17 | 2013-03-27 | 四川科达节能技术有限公司 | High-temperature glaze coating, preparation method thereof, binder and using method of coating |
| CN103183527A (en) * | 2011-12-29 | 2013-07-03 | 湖南省明丰达陶瓷琉璃瓦业有限公司 | Blue gray glaze for glazed tiles and its firing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102134167A (en) * | 2010-01-21 | 2011-07-27 | 江苏拜富科技有限公司 | Low-temperature melting block finished glaze and preparation method thereof |
| CN103183527A (en) * | 2011-12-29 | 2013-07-03 | 湖南省明丰达陶瓷琉璃瓦业有限公司 | Blue gray glaze for glazed tiles and its firing method |
| CN102992813A (en) * | 2012-12-17 | 2013-03-27 | 四川科达节能技术有限公司 | High-temperature glaze coating, preparation method thereof, binder and using method of coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114105475A (en) * | 2021-11-30 | 2022-03-01 | 汕头职业技术学院 | Nano titanium dioxide glaze and preparation method thereof |
| CN115073163A (en) * | 2022-07-01 | 2022-09-20 | 深圳振华富电子有限公司 | Chip varistor and preparation method and application thereof |
| CN115073163B (en) * | 2022-07-01 | 2023-09-01 | 深圳振华富电子有限公司 | Chip piezoresistor and preparation method and application thereof |
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Denomination of invention: A preparation method for Suzhou low firing glazed brick glaze Effective date of registration: 20231114 Granted publication date: 20190521 Pledgee: Industrial Park Branch of Jiangxi Yifeng Rural Commercial Bank Co.,Ltd. Pledgor: Jiangxi Guanli Ceramics Co.,Ltd. Registration number: Y2023980065735 |