CN106087421A - Soil-releasing finishing agent and its preparation method and application - Google Patents
Soil-releasing finishing agent and its preparation method and application Download PDFInfo
- Publication number
- CN106087421A CN106087421A CN201610444324.3A CN201610444324A CN106087421A CN 106087421 A CN106087421 A CN 106087421A CN 201610444324 A CN201610444324 A CN 201610444324A CN 106087421 A CN106087421 A CN 106087421A
- Authority
- CN
- China
- Prior art keywords
- soil
- finishing agent
- parts
- releasing finishing
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 43
- 239000002689 soil Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000002148 esters Chemical class 0.000 claims abstract description 24
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 23
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 229910000077 silane Inorganic materials 0.000 claims abstract description 11
- 239000002270 dispersing agent Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims description 29
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 239000004753 textile Substances 0.000 claims description 21
- 235000011090 malic acid Nutrition 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 14
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- -1 silicane alkane Chemical class 0.000 claims description 13
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 12
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 239000001630 malic acid Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004902 Softening Agent Substances 0.000 claims description 3
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 21
- 239000003921 oil Substances 0.000 description 20
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 16
- 235000004883 caffeic acid Nutrition 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- FXMBKAAULHJRKL-UHFFFAOYSA-N [amino(dimethoxy)silyl]oxymethane Chemical compound CO[Si](N)(OC)OC FXMBKAAULHJRKL-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 8
- 239000004744 fabric Substances 0.000 description 8
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 description 5
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 229940074360 caffeic acid Drugs 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 108010059892 Cellulase Proteins 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229940106157 cellulase Drugs 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000011032 tourmaline Substances 0.000 description 3
- 229940070527 tourmaline Drugs 0.000 description 3
- 229910052613 tourmaline Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical class CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- MCGBIXXDQFWVDW-UHFFFAOYSA-N 4,5-dihydro-1h-pyrazole Chemical compound C1CC=NN1 MCGBIXXDQFWVDW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
- D06B23/22—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for heating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of soil-releasing finishing agent, including the component of following weight portion: esters of acrylic acid 20 ~ 30 parts；Containing double bond organosilicon 10 ~ 20 parts；Active organic acid 5 ~ 10 parts；Silane coupler 1 ~ 3 part；Dispersant 3 ~ 5 parts.The soil-releasing finishing agent prepared through the application is widely portable to every field, with low cost, has higher activity, and clean effect is splendid.
Description
Technical field
The present invention relates to the afterfinish method of textile, particularly to a kind of soil-releasing finishing agent and preparation method thereof and should
With.
Background technology
Young father and mother have such worry mostly: when taking to child's laundry every time, and oil stain, spot on clothes need
Will oil stain, spot place the surfactant such as more liquid detergent and in addition cautious rub after, oil stain, spot
Can be cleaned, in particular cases, remain to see sharp trace；Domestic wiping kitchen tools, the rag of dining table, use a period of time
After, it may appear that the greasy feeling on rag substantially increases, and needs often to change, causes the waste of cost；At some special dimensions, than
In oil recovery, drilling well, oil refining industry, the frock of workpeople is inevitably rubbed substantial amounts of oil stain, so, research and develop fuel-displaced
The soil-releasing finishing agent that stain is easily washed, becomes one of present stage scholars problem making earnest efforts research and development.
At present, in existing patent application publication number to be that the Chinese patent of CN105603747A discloses a kind of novel hydrophilic easy
Soil release finishing agent and preparation method thereof, employing esters of acrylic acid is base material, water-soluble silicon oil, carboxymethyl cellulose and tourmaline powder
Etc. being prepared from, the fabric easy-detergency effect after this soil release finishing agent processes is notable, but, tourmaline powder is by Ore mostly
Particle or fiber tourmaline be prepared from, there is heavier color and luster mostly, make the use of this soil release finishing agent have limitation
Property；The Wu Ying of Institutes Of Technology Of Zhejiang have studied the impact using cellulase washing to improving polyester-cotton fabric soil release performance, grinds
Study carefully and show that the color and luster of fabric will not be impacted by the technique through cellulose treatment, and the fabric decontaminating effect after washing is relatively
Good, but, cellulase needs to extract from cellulose, and extraction cost is higher, and washing times is the most, the usage amount of cellulase
The biggest, the cost caused is the highest.
Summary of the invention
It is an object of the invention to provide a kind of with low cost, the suitability is extensive and clean effect is good soil-releasing finishing agent.
The above-mentioned technical purpose of the present invention has the technical scheme that
A kind of soil-releasing finishing agent, including the component of following weight portion:
By using technique scheme, esters of acrylic acid has excellent weatherability, film property and caking property, but it is deposited
In shortcomings such as resistance to water, poisture-penetrability and resistance to soiling differences；Active organic acid is the organic compound that a class is active and acid, will
Esters of acrylic acid mixes with active organic acid, makes esters of acrylic acid surface have higher activity, contributes to and other components
Continue reaction；The organosilicon containing double bond has stronger activity, with esters of acrylic acid generation chemical reaction, the main polymer chain of generation
In containing Si-O-Si key, Si-C key, Si-O key, their bond energy, much larger than the bond energy of C-O key, has the compliance of height, excellent
Different high and low temperature resistance, weatherability, resistance to water and good breathability, substantially increases the solvent resistant of esters of acrylic acid
Property, high and low temperature resistance, durability in oxidative degradation energy, the surface simultaneously having pure propylene acid esters concurrently can low, hydrophobic, pollution resistance and electricity
The good characteristics such as insulating properties and elasticity, the rigidity existed when efficiently solving shortcoming and the Ludox film of acrylate film
By force, glossiness is low, be easily cracked, the cold drying defect such as rapidly, and the two can reach the mutual supplement with each other's advantages in performance；Acrylate
Class, organic acid and containing double bond organosilicon dispersant, silane coupler common effect under the soil-releasing finishing agent that generates be nothing
Color or light-coloured transparent shape liquid, be widely portable to every field, and the raw material price used is cheap, it is adaptable to give birth on a large scale
Producing, and after the soil-releasing finishing agent prepared is coated in textile surface, make textile surface have higher activity, decontamination is imitated
The most splendid.
The present invention is further arranged to: described esters of acrylic acid selects acrylic acid methyl ester., ethyl acrylate and metering system
One in acid hydroxyl ethyl ester.
By using technique scheme, acrylic acid methyl ester. is colourless liquid, is dissolved in ethanol, ether, acetone and benzene, is
A kind of volatile unsaturated methyl ester, is also the conventional monomer of synthesising macromolecule copolymer；Ethyl acrylate is colourless liquid,
It is soluble in ethanol, ether, is easily polymerized, it is possible to other monomer copolymerizations, be the monomer of conventional high molecular synthetic material, and use
In manufacturing coating, binding agent, leather processing auxiliary agent, textile auxiliary, oil paint additive etc.；Hydroxyethyl methylacrylate is colourless
Bright mobile liquid, has higher activity, for resin and the modification of coating, can prepare the propylene that side chain contains activity hydroxy
Acid resin, for manufacturing the adhesive of fabric in textile industry, uses acrylic acid methyl ester., ethyl acrylate or methacrylic acid
A kind of raw material as esters of acrylic acid in hydroxyl ethyl ester, is all conventional synthon, has wide material sources, with low cost
Characteristic, and course of reaction is simple, quick, and efficiency is high.
The present invention is further arranged to: described containing double bond organosilicon selection vinyltrimethoxy silane, vinyl three second
One in TMOS, γ-methacryloxy trimethoxy silane.
By using technique scheme, vinyltrimethoxy silane is colourless transparent liquid, is universal containing double bond
Organosilicon, and acrylic monomers copolymerization, the coating of formation has excellent weatherability, resistant to dust and the advantage such as can clean；Ethylene
Ethyl triethoxy silicane alkane is colourless transparent liquid, can carry out copolymerization with various of monomer, and the coating of preparation has the electrical property of excellence,
Anti-damp and hot, Defend salt fog, mould proof NBC protective performance；γ-methacryloxy trimethoxy silane is colourless transparent liquid, due to
Containing methacryloxy functional groups, can be widely applied to the modification of unsaturated-resin and use as coating, by itself and its
During his monomer copolymerization, prepared coating has stronger activity, impregnated in textile surface and has the characteristic being easier to clean,
Meanwhile, there is weatherability, resistant of high or low temperature and dust-proof, the characteristic of anti-gray of excellence.
The present invention is further arranged to: described active organic acid is malic acid and caffeinic mixture, wherein malic acid
Percentage by weight in malic acid and caffeinic mixture is 40～60%.
By using technique scheme, malic acid has another name called 2-hydroxyl succinic acid, has excellent hydrophilicity, and fourth two
Acid has two carboxyls, and malic acid has polyfunctional group, hydroxyl and carboxyl so that it is have higher activity；Caffeic acid has another name called 3,
4-dihydroxycinnamic acid, polyhydroxy makes it have higher activity, and caffeic acid has the functional groups such as hydroxyl, phenyl, double bond, has
Higher activity, when malic acid and caffeic acid jointly being acted on, can produce synergism, mix with this organic by esters of acrylic acid
When acid carries out being blended, it is favorably improved the surface activity of esters of acrylic acid material, is more beneficial for reacting with other components, and
And, wherein with the percentage by weight of malic acid be 40～60% ratio mix, the activity making the organic acid of mixing is optimal.
The present invention is further arranged to: described silane coupler selects γ aminopropyltriethoxy silane and aminopropan
The mixture of base trimethoxy silane, wherein γ aminopropyltriethoxy silane at γ aminopropyltriethoxy silane and
Percentage by weight in the mixture of TSL 8330 is 40～60%.
By using technique scheme, γ aminopropyltriethoxy silane is colourless transparent liquid, and it is contained within ammonia
Base and ethyoxyl, for coupling organic polymer and inorganic filler, strengthen its caking property, improves the machinery of product, water-fast, anti-ageing
The performances such as change, are usually used in yarn fabric auxiliary agent, insulant, adhesive industry；Amino in TSL 8330
It is respectively intended to coupling organic polymer and inorganic filler with methoxyl group, strengthens organic and inorganic filler compatibility, improve filler
Wettability in the polymer and dispersibility, be usually used in yarn fabric auxiliary agent, insulant, adhesive industry, by gamma-amino third
Ethyl triethoxy silicane alkane and TSL 8330 act on jointly, and the two can produce synergism, makes silane coupler
The activity that has of mixture bigger, beneficially Organic substance and inorganic matter is the most compatible.
The present invention is further arranged to: described dispersant selects triethyl group hexyl phosphoric acid or methyl anyl alcohol.
By using technique scheme, triethyl group hexyl phosphoric acid and methyl anyl alcohol are all the dispersants of excellent performance, energy
Enough reduce the material that solid or liquid particle are assembled in dispersion, the stability in holding system, triethyl group hexyl phosphoric acid or
Person's methyl anyl alcohol adds in reaction system, enables each component in reaction system more uniformly to disperse, and contributes to anti-
Answer ground more fully, thoroughly.
The invention also discloses the preparation method of a kind of soil-releasing finishing agent, comprise the steps:
(1) successively esters of acrylic acid, active organic acid are added in reaction vessel, the temperature in slow increase container to 60～
70℃；
(2) being added in reaction vessel by the organosilicon containing double bond and react, mixing speed is 100～120r/min；
(3) in reaction vessel, silane coupler is added；
(4) adding dispersant in reaction vessel, adding speed is 10～20ml/min, reacts 2～4h.
By using technique scheme, esters of acrylic acid uses active organic acid carry out activation processing, makes acrylic acid
Esters has bigger activity, it is possible to more easily reacts with the organosilicon containing double bond, and is slowly added to dispersant and silicon
Alkane coupling agent, dispersant contributes to more component and more uniformly merges, and makes reaction system homogeneous, stable, and silane coupler can promote
Enter esters of acrylic acid to react with the organosilicon containing double bond, thus ensure to react carry out more fully, thoroughly.
The invention also discloses the application of a kind of soil-releasing finishing agent, use above-mentioned 5～10% soil-releasing finishing agent and
0.3～1% penetrating agent, 1～3% softening agent, 1～3% smooth agent, remaining be water, use and pad or dip finishing technique is to spinning
Fabric arranges.
By using technique scheme, use above-mentioned soil-releasing finishing agent and other auxiliary addition agents, penetrating agent, softening agent
Jointly acting on smooth agent, employing is padded or textile is arranged by dip finishing technique, instead of tradition and uses water, softness
The formula of the soil-releasing finishing agent of agent and smooth agent, the soil-releasing finishing agent of the application processes spot more efficiently, thoroughly, decontamination
Excellent effect.
The present invention is further arranged to: finishing technique parameter: textile liquid carrying rate is 60～80%, 110～120 DEG C of preliminary drying
120～180s, 160～180 DEG C bake 60～100s.
By using technique scheme, controlling above-mentioned technological parameter, textile surface humidity is moderate, to above-mentioned easy decontamination
Finishing agent has stronger adhesive force, makes soil-releasing finishing agent and auxiliary addition agent thereof be attached to textile surface relatively easily, with
Time, use preliminary drying and bake two step heatings, making textile surface have dust and be not easy to adhere in its surface, and wash
Time the oil stain on surface, spot can washes clean easily.
In sum, the method have the advantages that
1, use malic acid and caffeinic blend that esters of acrylic acid is carried out activation processing, make esters of acrylic acid surface have
Bigger activity, beneficially esters of acrylic acid and the reaction containing double bond organosilicon, improve the viscosity of product, make this product more hold
Easily it is attached to product surface；
2, adding the mixture of γ aminopropyltriethoxy silane and amino trimethoxy silane in reaction system, this mixes
Compound fully can react by remaining esters of acrylic acid with in reaction system, considerably improves the soil-releasing finiss of product
Energy；
3, through padding or the textile surface of dip finishing PROCESS FOR TREATMENT and through preliminary drying with after baking two step heat treated, can
Substantially reduce dust and fall in its surface, improve the fungus resistance of textile surface, stain.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
Esters of acrylic acid raw material is bought from Tianjin Jin Heng coating company limited；
Buy from Nanjing through Tian Wei Chemical Co., Ltd. containing double bond organosilicon；
Silane coupler is bought from Nanjing through Tian Wei Chemical Co., Ltd.；
Caffeic acid is bought from Lai Er mattress bio tech ltd, Henan；
Malic acid is bought from Nantong Fei Yu fine chemicals company limited.
Embodiment one:
(1) in there-necked flask, it is sequentially added into 2 parts of malic acids, 3 parts of caffeic acids and 20 parts of acrylic acid methyl ester .s, adds through oil bath under stirring
Heat is to 60 DEG C, and mixing speed is 70r/min；
(2) adding 10 parts of vinyltrimethoxy silanes in there-necked flask, mixing speed is 100r/min, and mixing time is
30min；
(3) in there-necked flask, 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silane are added；
(4) being slowly added to 3 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reaction
2h。
Embodiment two:
(1) in there-necked flask, it is sequentially added into 4 parts of malic acids, 4 parts of caffeic acids and 25 parts of ethyl acrylate, adds through oil bath under stirring
Heat is to 65 DEG C, and mixing speed is 75r/min；
(2) adding 10 parts of acrylic trimethoxy silanes in there-necked flask, mixing speed is 110r/min, stirs 30min；
(3) in there-necked flask, 0.6 part of γ aminopropyltriethoxy silane and 0.9 part of amino trimethoxy silane are added；
(4) being slowly added to 4 parts of methyl anyl alcohols in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reacts 3h.
Embodiment three:
(1) in there-necked flask, 6 parts of malic acids, 4 parts of caffeic acids and 30 parts of hydroxyethyl methylacrylates it are sequentially added into, the lower warp of stirring
Oil bath is heated to 70 DEG C, and mixing speed is 80r/min；
(2) adding 20 parts of γ-metering system phthalein epoxide trimethoxy silanes in there-necked flask, mixing speed is 120r/min,
Mixing time is 30min；
(3) in there-necked flask, 1 part of γ aminopropyltriethoxy silane and 1 part of amino trimethoxy silane are added；
(4) being slowly added to 5 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reaction
4h。
Embodiment four:
(1) in there-necked flask, 5 parts of malic acids, 5 parts of caffeic acids and 25 parts of hydroxyethyl methylacrylates it are sequentially added into, the lower warp of stirring
Oil bath is heated to 66 DEG C, and mixing speed is 72r/min；
(2) adding 16 parts of vinyltrimethoxy silanes in there-necked flask, mixing speed is 115r/min, and mixing time is
30min；
(3) in there-necked flask, 1 part of γ aminopropyltriethoxy silane and 1 part of amino trimethoxy silane are added；
(4) being slowly added to 4.5 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, instead
Answer 3h.
Embodiment five:
(1) in there-necked flask, it is sequentially added into 6 parts of malic acids, 4 parts of caffeic acids and 25 parts of ethyl acrylate, adds through oil bath under stirring
Heat is to 70 DEG C, and mixing speed is 77r/min；
(2) adding 18 parts of γ-metering system phthalein epoxide trimethoxy silanes in there-necked flask, mixing speed is 112r/min,
Mixing time is 30min；
(3) in there-necked flask, 1 part of γ aminopropyltriethoxy silane and 1.5 parts of amino trimethoxy silanes are added；
(4) being slowly added to 3.5 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, instead
Answer 3.5h.
Comparative example one:
(1) 20 parts of acrylic acid methyl ester .s in there-necked flask, are heated to 60 DEG C through oil bath under stirring, and mixing speed is 70r/min；
(2) adding 10 parts of vinyltrimethoxy silanes in there-necked flask, mixing speed is 100r/min, and mixing time is
30min；
(3) in there-necked flask, 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silane are added；
(4) being slowly added to 3 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reaction
2h。
Comparative example two:
(1) in there-necked flask, it is sequentially added into 5 parts of malic acids, 20 parts of acrylic acid methyl ester .s, is heated to 60 DEG C through oil bath under stirring, stirs
Mixing speed is 70r/min；
(2) adding 10 parts of vinyltrimethoxy silanes in there-necked flask, mixing speed is 100r/min, and mixing time is
30min；
(3) in there-necked flask, 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silane are added；
(4) being slowly added to 3 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reaction
2h。
Comparative example three:
(1) in there-necked flask, it is sequentially added into 2 parts of malic acids, 3 parts of caffeic acids and 20 parts of acrylic acid methyl ester .s, adds through oil bath under stirring
Heat is to 60 DEG C, and mixing speed is 70r/min；
(2) adding 10 parts of vinyltrimethoxy silanes in there-necked flask, mixing speed is 100r/min, and mixing time is
30min；
(3) in there-necked flask, 0.5 part of γ aminopropyltriethoxy silane and 0.5 part of amino trimethoxy silane are added；
(4) being slowly added to 3 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reaction
2h。
Comparative example four:
(1) in there-necked flask, it is sequentially added into 2 parts of malic acids, 3 parts of caffeic acids and 20 parts of acrylic acid methyl ester .s, adds through oil bath under stirring
Heat is to 60 DEG C, and mixing speed is 70r/min；
(2) adding 10 parts of vinyltrimethoxy silanes in there-necked flask, mixing speed is 100r/min, and mixing time is
30min；
(3) being slowly added to 3 parts of triethyl group hexyl phosphoric acid in there-necked flask, the flow velocity controlling separatory funnel is 1 part/min, reaction
2h。
Detection method:
(1) viscosity: use rotating cylinder viscometer that leach mill solution is detected；
(2) soil release performance: the textile after padding process washs through aqueous solution soaking, washs feelings under the conditions of observing different time
Condition；
(3) fungus resistance: use VMS300A scientific research level three mesh zoom-stereo microscope to weaving under different time conditions
Product surface is observed, and amplification is 500 times.
The viscosity measurements result of leach mill solution is as shown in the table
| Sample | Viscosity (mpa s) |
| Embodiment one | 78 |
| Embodiment two | 81 |
| Embodiment three | 82 |
| Embodiment four | 80 |
| Embodiment five | 79 |
| Comparative example one | 20 |
| Comparative example two | 32 |
| Comparative example three | 27 |
As seen from the above table, for comparative example, the viscosity of the leach mill solution of embodiment is about 80mpa s, and viscosity carries significantly
Height, can make soil-releasing finishing agent be attached to relatively easily on the surface of textile.
The testing result of soil release performance is as shown in the table
As seen from the above table, the textile that embodiment processed is soaking 1h, and on it, the oil stain of attachment can substantially disappear, and contrasts
Oil stain in example is then not easy to be washed totally.
The testing result of fungus resistance is as shown in the table
As seen from the above table, the textile surface processed through embodiment has the fungus resistance of excellence, stain, is not added with silane even
The textile surface of the comparative example of connection agent is easily adhered antibacterial, and textile surface is the most dirty.
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, people in the art
The present embodiment can be made after reading this specification by member as required does not has the amendment of creative contribution, but as long as at this
All protected by Patent Law in the right of invention.
Claims (9)
1. a soil-releasing finishing agent, it is characterised in that include the component of following weight portion:
Esters of acrylic acid 20 ~ 30 parts
Containing double bond organosilicon 10 ~ 20 parts
Active organic acid 5 ~ 10 parts
Silane coupler 1 ~ 3 part
Dispersant 3 ~ 5 parts.
Soil-releasing finishing agent the most according to claim 1, it is characterised in that: described esters of acrylic acid selects acrylic acid first
One in ester, ethyl acrylate and hydroxyethyl methylacrylate.
Soil-releasing finishing agent the most according to claim 1, it is characterised in that: described containing double bond organosilicon selection vinyl three
One in methoxy silane, VTES, γ-methacryloxy trimethoxy silane.
Soil-releasing finishing agent the most according to claim 1, it is characterised in that: described active organic acid is malic acid and coffee
The mixture of acid, wherein malic acid percentage by weight in malic acid and caffeinic mixture is 40 ~ 60%.
Soil-releasing finishing agent the most according to claim 1, it is characterised in that: described silane coupler selects gamma-amino third
Ethyl triethoxy silicane alkane and the mixture of TSL 8330, wherein γ aminopropyltriethoxy silane γ-
Percentage by weight in the mixture of aminopropyltriethoxywerene werene and TSL 8330 is 40 ~ 60%.
Soil-releasing finishing agent the most according to claim 1, it is characterised in that: described dispersant selects triethyl group hexyl phosphoric acid
Or methyl anyl alcohol.
7. the preparation method of the soil-releasing finishing agent as described in claim 1 ~ 6 any one, it is characterised in that include walking as follows
Rapid:
(1) successively esters of acrylic acid, active organic acid are added in reaction vessel, the temperature in slow increase container to 60 ~
70℃；
(2) being added in reaction vessel by the organosilicon containing double bond and react, mixing speed is 100 ~ 120r/min；
(3) in reaction vessel, silane coupler is added；
(4) adding dispersant in reaction vessel, addition speed is 10 ~ 20ml/min, reacts 2 ~ 4h.
8. the application of the soil-releasing finishing agent as described in claim 1 ~ 6 any one, it is characterised in that: use above-mentioned 5 ~ 10%
Soil-releasing finishing agent and 0.3 ~ 1% penetrating agent, 1 ~ 3% softening agent, 1 ~ 3% smooth agent, remaining be water, use pad or impregnate whole
Textile is arranged by science and engineering skill.
The application of soil-releasing finishing agent the most according to claim 8, it is characterised in that: finishing technique parameter: textile band
Liquid rate is 60 ~ 80%, 110 ~ 120 DEG C of preliminary drying 120 ~ 180s, and 160 ~ 180 DEG C bake 60 ~ 100s.
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