CN106086653B - It is a kind of to realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness - Google Patents

It is a kind of to realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness Download PDF

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CN106086653B
CN106086653B CN201610668465.3A CN201610668465A CN106086653B CN 106086653 B CN106086653 B CN 106086653B CN 201610668465 A CN201610668465 A CN 201610668465A CN 106086653 B CN106086653 B CN 106086653B
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steel part
medium managese
gradient
equal thickness
warm forming
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CN106086653A (en
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常颖
王存宇
李晓东
韩硕
赵坤民
任大鑫
郑国君
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Dalian University of Technology
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

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  • Physics & Mathematics (AREA)
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Abstract

Present invention offer is a kind of to realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, comprises the following steps:It is stand-by steel plate to choose medium managese steel plate;Stand-by steel plate is heated to complete austenitizing;It is transported in diel and carries out stamping, is quenched to room temperature and obtains warm forming steel part;Steel part after cooling is partly or wholly heated using gradient-heated mode, realize the heat time graded of steel part diverse location, complete steel part after reverse transformation process and be cooled to room temperature, obtaining has capability gradient distribution, high intensity, high-ductility, the medium managese steel part of equal thickness.The medium managese steel part that the present invention is obtained is heterogeneous structure structure, superhigh intensity had not only been realized on same steel part but also the capability gradient distribution of high-ductility is obtained, and the Gradient Features of performance are further realized because of the graded of austenite content in high plastic zone, the demand of lightweight and security is met, with extensive dissemination.

Description

It is a kind of to realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness
Technical field
The invention belongs to automobile steel part forming technique field, more particularly to a kind of realize capability gradient, the temperature of equal thickness Hot forming medium managese steel part preparation method, is suitable for the thin medium managese steel plate that thickness specification is 0.6mm-2mm, obtaining has capability gradient Distribution, with martensite or bainite structure or metastable austenite and the part of ferrite matrix institutional framework.
Background technology
The developing direction of automobile is lightweight, reduction fuel consumption, reduces discharge and improve security, so as to accounting for automobile The automobile steel of weight 70% or so it is also proposed higher requirement, drive the development of automobile steel.In automobile steel making, IF steel, DP steel, TRIP steel and martensite steel etc. are referred to as first generation automobile steel;TWIP steel and full austenite steel are referred to as second generation automobile steel. American scholar (performance and cost) between the first generation and second generation automobile steel proposes third generation automobile steel, i.e. novel steam Automobile-used steel.Q&P steel and medium managese steel are as third generation automobile steel, because of its preferable mechanical property, have been obtained for major steel mill and The production and application of automaker.Medium managese steel has ultra-fine metastable austenite and ferrite matrix institutional framework, its Ovshinsky Being formed by the basis of the martensite of quenching formation or bainite structure for body, new austenite is formed by subsequent annealing With solute element in the enrichment of austenite, the austenite component of ambient-temp-stable is finally given, this technique is referred to as austenite reverse transformation Method.Currently, the reverse transformation technique on medium managese steel is concentrated mainly in the manufacturing process of sheet material, and for warm deep drawing shaping zero In part manufacture, austenite anti-phase political reform how is introduced, to carry out regulation and control design to its performance, there is not yet report.
Technical elements are realized in preparation and the various performances of sheet material on automobile medium managese steel plate, and such as Chinese patent discloses Number it is:CN101638749B《A kind of automobile steel with low cost and high strength ductility balance and preparation method thereof》Described technology, its is original Sheet material has ultra-fine institutional framework, very high strength and ductility product and relatively low production cost.But how to be configured to automobile on sheet material Part and its required various performance requirements are not referred to but.Warm forming medium managese steel result in superelevation tensile strength >= 1000MPa, it might even be possible to reach more than 1400MPa, while the performance characteristic of elongation percentage >=10%.So, how in a temperature Capability gradient is realized on hot forming medium managese steel part, it is difficult the high intensity, high-plastic surmounted its subregion is possessed hot forming boron steel Property mechanical property, subregion possess is realized on the gradient performance feature of elongation percentage >=30%, Same Part capability gradient point Cloth is current urgent problem to be solved.
The content of the invention
According to technical problem set forth above, and provide and a kind of realize capability gradient, the warm forming medium managese steel of equal thickness Part preparation method.Invention introduces the austenite reverse transformation feature of medium managese steel, by warm forming technique and austenite reverse transformation Technique is combined, so as to obtain the medium managese steel part of the high intensity being distributed with capability gradient, high-ductility, equal thickness.
The technological means that the present invention is used is as follows:
It is a kind of to realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, it is characterised in that including as follows Step:
S1, selection medium managese steel plate are stand-by steel plate, and the chemical component weight percentage of the medium managese steel plate is:C:0.01- 0.50%;Mn:4.0-6.0%;P≤0.015%;S≤0.02%, remainder is Fe and inevitable impurity;
S2, stand-by steel plate is heated to complete austenitizing, heating-up temperature is between 750 DEG C -950 DEG C, 1-10 points of insulation Clock;It is transported in diel, in MsMore than temperature carry out stamping, be quenched to room temperature and obtain warm forming steel part, according to The difference of quenching rate, forms martensitic structure structure or bainite structure structure;
S3, the steel part after cooling partly or wholly heated using gradient-heated mode, realize steel part diverse location Heat time graded, heating-up temperature is between 100 DEG C~Ac1 of below Ac1, soaking time -600 minutes 5 minutes, complete Steel part is cooled to room temperature after reverse transformation process, and obtaining has capability gradient distribution, high intensity, high-ductility, the medium managese steel of equal thickness Part.
Further, in the step S1, percentage by weight is added on the basis of the chemical composition of the medium managese steel plate Following one or more elements:Cr:0.2-3.0%;Si:0.3-2.3%;B:0.0005-0.005%;Nb:0.02- 0.10%;[N]:0.002-0.25%;Ti:0.05-0.25%;V:0.02-0.25%;Al:0.015-0.060%;Re: 0.002-0.005%.
Further, in the step S2 stand-by steel plate in martensitic traoformation MsAfter point temperatures above is stamping, pass through Air cooling, oil cooling or water cooling are quenched into room temperature, final to obtain martensite or bainite structure structure.
Further, in the step S3, the steel part after cooling is partly or wholly heated using induction coil, control The Gradient Features of heat time, complete reverse transformation process;Non-heated region is utilized with circulating cooling gas or compressed gas Pre-cooler reduces steel part temperature.
Further, the Gradient Features of the heat time are to set induction coil different heating and thermal insulation time, heating After stopping, the pre-cooler reduction steel part temperature with circulating cooling gas or compressed gas is utilized together with non-heated region.
Further, the medium managese steel part obtained in the step S3 is heterogeneous structure structure, with martensite or bainite Institutional framework and metastable austenite and ferrite matrix institutional framework, wherein metastable austenite content reach 5%-40% it Between graded.I.e. non-heated region is martensitic structure structure or bainite structure structure, and heating region is metastable Ovshinsky Body and ferrite matrix institutional framework.
Further, the medium managese steel part obtained in the step S3 has intensity region:Tensile strength >=1000MPa and prolong Stretch rate >=10%;High plastic zone:The capability gradient distribution of tensile strength >=600MPa and elongation percentage >=30%.
More existing forming technology technology is compared, and invention introduces the austenite reverse transformation feature of medium managese steel, will be warmed into Shape technique is combined with austenite reverse transformation technique.When setting 750 DEG C -950 DEG C of austenitizing temperature and being incubated 1-10 minutes, remove Based on outside warm forming technology characteristics, it is also contemplated that in reverse transformation technique austenitizing heating process need more fully, tissue Regulation and control are more scientific, the gradient formation of metastable austenite and stability during in favor of follow-up reverse transformation.The different anti-phase by setting Become technological parameter, realize the formation of metastable austenite and ferrite matrix, and realize the graded of metastable austenite content, So as to further realize the graded of performance in the tissue regions, while the martensite or bainite group that are obtained with warm forming Structural region matching is knitted, the high intensity being distributed with capability gradient, high-ductility, the medium managese steel part of equal thickness is obtained.
The present invention is to make use of warm forming technique to reduce steel part resilience feature, can form martensite or bainite Institutional framework, combines the tissue modulation technology of third generation automobile medium managese steel again, forms metastable austenite and ferrite matrix tissue Structure, and austenite content can form gradient distribution, and superhigh intensity had not only been realized on same steel part but also the performance of high-ductility is obtained Gradient is distributed, and the Gradient Features of performance are further realized because of the graded of austenite content in high plastic zone, is met Lightweight and the demand of security, with extensive dissemination.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is the accompanying drawing used required in technology description to do simply to introduce, it should be apparent that, drawings in the following description are this hairs Some bright embodiments, for those of ordinary skill in the art, without having to pay creative labor, can be with Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is process chart of the invention.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is A part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
As shown in figure 1, a kind of realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, including it is as follows Step:
S1, selection medium managese steel plate are stand-by steel plate, and the chemical component weight percentage of the medium managese steel plate is:C:0.01- 0.50%;Mn:4.0-6.0%;P≤0.015%;S≤0.02%, remainder is Fe and inevitable impurity;The step S1 In, the following one or more elements of percentage by weight are added on the basis of the chemical composition of the medium managese steel plate:Cr:0.2- 3.0%;Si:0.3-2.3%;B:0.0005-0.005%;Nb:0.02-0.10%;[N]:0.002-0.25%;Ti:0.05- 0.25%;V:0.02-0.25%;Al:0.015-0.060%;Re:0.002-0.005%.
S2, stand-by steel plate is heated to complete austenitizing, heating-up temperature is between 750 DEG C -950 DEG C, 1-10 points of insulation Clock;It is transported in diel, in MsMore than temperature carry out stamping, be quenched to room temperature and obtain warm forming steel part;It is described Stand-by steel plate is in martensitic traoformation M in step S2sAfter point temperatures above is stamping, it is quenched into by air cooling, oil cooling or water cooling Room temperature, it is final to obtain martensite or bainite structure structure.
S3, the steel part after cooling partly or wholly heated using induction coil using gradient-heated mode, controlled The Gradient Features of heat time, that is, set the induction coil different heating and thermal insulation time, when realizing the heating of steel part diverse location Between graded, heating-up temperature is between 100 DEG C~Ac1 of below Ac1, soaking time -600 minutes 5 minutes, complete reverse transformation mistake Cheng Hou, stops heating, and the pre-cooler reduction steel with circulating cooling gas or compressed gas is utilized together with non-heated region Part temperature, obtaining has capability gradient distribution, high intensity, high-ductility, the medium managese steel part of equal thickness.
Obtained medium managese steel part is heterogeneous structure structure, with martensite or bainite structure structure and metastable Ovshinsky Body and ferrite matrix institutional framework, wherein metastable austenite content reach the graded between 5%-40%.Medium managese steel part With intensity region:Tensile strength >=1000MPa and elongation percentage >=10%;High plastic zone:Tensile strength >=600MPa and extension The capability gradient distribution of rate >=30%.
Embodiment 1
Choosing medium managese steel part chemical component weight percentage is:C:0.1%;Mn:4.6%;Nb:0.05%;Ti: 0.05%;P:0.013%;S:0.01%, remainder is Fe and inevitable impurity.
By taking certain vehicle collision prevention girders as an example, by thickness for needed for 1.6mm stand-by steel plate is cut into steel part size, by stand-by steel Part is heated to 850 DEG C, is incubated 5 minutes;It is transported in diel and carries out stamping, is measured after shaping using infrared radiation thermometer Steel part mean temperature is at 450 DEG C or so, and stand-by steel part is air-cooled to room temperature.Steel part is divided into three regions, 1. and 2. region is to add Thermal region, carries out sensing heating, heating-up temperature is at 670 DEG C (this temperature is between 100 DEG C~Ac1 of below Ac1), and heating region is 1. Soaking time is 5 minutes, and 2. soaking time is 1 hour to heating region.3. remaining region, passes through the cooling of compressed gas for region Processing, it is to avoid 3. temperature is too high and occur structural transformation in region.Stand-by steel part is cooled to after above-mentioned successive heating and thermal insulation processing Room temperature.
Three regions after stamping from steel part are separately sampled, and load-deformation curve is obtained by uniaxial tensile test, And then mechanical property is obtained, as shown in table 1, the austenite volume content for heating 1. area (soaking time 5 minutes) is 10.2%, its Mechanical property:Tensile strength 720MPa, elongation percentage 18%, i.e. strength and ductility product are 13GPa% or so;Heating 2. area, (soaking time 1 is small When) austenite volume content be 30%, its mechanical property:Tensile strength 706MPa, elongation percentage 42%, i.e. strength and ductility product are 30GPa% or so, non-heated region (3. area) has martensitic structure structure, its mechanical property:Tensile strength is 1510MPa, Elongation percentage 11.4%, i.e. strength and ductility product are 17GPa% or so.It is achieved thereby that the distribution of same equal thickness steel part capability gradient, high-strength Degree and high-ductility have concurrently.
The mechanical property of certain the vehicle collision prevention girders capability gradient distribution of table 1
Subregion performance Tensile strength (MPa) Elongation percentage (%) Strength and ductility product (GPa%)
1. area 720 18 13
2. area 706 42 30
3. area 1510 11.4 17
Finally it should be noted that:Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations;To the greatest extent The present invention is described in detail with reference to foregoing embodiments for pipe, it will be understood by those within the art that:Its according to The technical scheme described in foregoing embodiments can so be modified, or which part or all technical characteristic are entered Row equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology The scope of scheme.

Claims (7)

1. a kind of realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, it is characterised in that including following step Suddenly:
S1, selection medium managese steel plate are stand-by steel plate, and the chemical component weight percentage of the medium managese steel plate is:C:0.01- 0.50%;Mn:4.0-6.0%;P≤0.015%;S≤0.02%, remainder is Fe and inevitable impurity;
S2, stand-by steel plate is heated to complete austenitizing, heating-up temperature is incubated 1-10 minutes between 750 DEG C -950 DEG C;Turn Transport in diel, in MsMore than temperature carry out stamping, be quenched to room temperature and obtain warm forming steel part;
S3, the steel part after cooling partly or wholly heated using gradient-heated mode, realize steel part diverse location plus Hot time gradient change, heating-up temperature is between 100 DEG C~Ac1 of below Ac1, soaking time -600 minutes 5 minutes, completes anti-phase Steel part is cooled to room temperature after change process, and obtaining has capability gradient distribution, high intensity, high-ductility, the medium managese steel part of equal thickness.
2. according to claim 1 realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, its feature Be, in the step S1, added on the basis of the chemical composition of the medium managese steel plate the following one kind of percentage by weight or Multiple element:Cr:0.2-3.0%;Si:0.3-2.3%;B:0.0005-0.005%;Nb:0.02-0.10%;[N]:0.002- 0.25%;Ti:0.05-0.25%;V:0.02-0.25%;Al:0.015-0.060%;Re:0.002-0.005%.
3. according to claim 1 realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, its feature It is, stand-by steel plate is in martensitic traoformation M in the step S2sAfter point temperatures above is stamping, pass through air cooling, oil cooling or water Cold quenching is final to obtain martensite or bainite structure structure to room temperature.
4. according to claim 1 realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, its feature It is, in the step S3, the steel part after cooling is partly or wholly heated using induction coil, controls the ladder of heat time Feature is spent, reverse transformation process is completed;Non-heated region utilizes the pre-cooler reduction with circulating cooling gas or compressed gas Steel part temperature.
5. according to claim 4 realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, its feature It is, the Gradient Features of the heat time are to set the induction coil different heating and thermal insulation time, after heating stops, and are added with non- Thermal region utilizes the pre-cooler reduction steel part temperature with circulating cooling gas or compressed gas together.
6. capability gradient, the warm forming medium managese steel part preparation method of equal thickness are realized according to claim 3 or 4, its Be characterised by, the medium managese steel part obtained in the step S3 is heterogeneous structure structure, with martensite or bainite structure structure, And metastable austenite and ferrite matrix institutional framework, wherein metastable austenite content reaches that gradient between 5%-40% becomes Change.
7. according to claim 6 realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness, its feature It is, the medium managese steel part obtained in the step S3 has intensity region:Tensile strength >=1000MPa and elongation percentage >=10%; High plastic zone:The capability gradient distribution of tensile strength >=600MPa and elongation percentage >=30%.
CN201610668465.3A 2016-08-15 2016-08-15 It is a kind of to realize capability gradient, the warm forming medium managese steel part preparation method of equal thickness Expired - Fee Related CN106086653B (en)

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