CN106079751A - 一种防雾玻璃 - Google Patents

一种防雾玻璃 Download PDF

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CN106079751A
CN106079751A CN201610638003.7A CN201610638003A CN106079751A CN 106079751 A CN106079751 A CN 106079751A CN 201610638003 A CN201610638003 A CN 201610638003A CN 106079751 A CN106079751 A CN 106079751A
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glass
layer
antifog
thickness
inner layer
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刘杰
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Zhejiang Flying Sanitary Ware Manufacturing Co Ltd
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Zhejiang Flying Sanitary Ware Manufacturing Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10073—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising at least two glass sheets, neither of which being an outer layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10128—Treatment of at least one glass sheet
    • B32B17/10146—Face treatment, e.g. etching, grinding or sand blasting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/225—Nitrides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明涉及玻璃制品技术领域，具体涉及一种防雾玻璃。包括内层玻璃和外层玻璃，内层玻璃和外层玻璃之间设有中间层玻璃，中间层玻璃为偏光玻璃，在外层玻璃表面设有一层氮化硅层，在内层玻璃上设有一层碳化硅层。结构简单，透光性好，外表面透光性好，内表面不易起雾。

Description

一种防雾玻璃
技术领域
本发明涉及玻璃制品技术领域，具体涉及一种防雾玻璃。
背景技术
玻璃是日常生活、工业生产、科学研究和军事应用中必不可少的材料，建筑物窗玻璃、运输工具窗玻璃、挡风玻璃、后视镜、浴室镜子、眼镜镜片、测量仪器的玻璃罩等，当潮湿空气冷凝时，容易在镜面或玻璃表面形成许多微小的水滴而散光，使透明度降低影响视线，还会影响仪器的读数。
发明内容
本发明的目的是为了解决上述存在的问题，提供一种防雾玻璃。
为了达到上述发明目的，本发明采用以下技术方案：
一种防雾玻璃，包括内层玻璃和外层玻璃，内层玻璃和外层玻璃之间设有中间层玻璃，中间层玻璃为偏光玻璃，在外层玻璃表面设有一层氮化硅层，在内层玻璃上设有一层碳化硅层。
作为优选方案，所述内层玻璃、外层玻璃和中间层玻璃之间通过PVB膜连接，PVB膜内设有导电。
作为优选方案，所述内层玻璃的厚度为2-3mm。
作为优选方案，所述外层玻璃的厚度为3-5mm。
作为优选方案，所述氮化硅层的厚度为25-75nm。
作为优选方案，所述碳化硅层的厚度为45-125nm。
作为优选方案，在内层玻璃、外层玻璃和中间层玻璃之间设有一层有机玻璃层，有机玻璃层为导电层。
作为优选方案，所述PVB膜(6)包括以下重量份数的各组分：聚乙烯醇缩丁醛70-75份，聚乙炔3-5份，聚丙二醇缩水甘油醚为4-5份，丙烯酸环己酯为6-7份，氟铝酸钾0.5-1份，聚酰胺蜡微粉0.3-0.5份，二异丙基乙醇胺1-1.5份，聚丁二酸丁二醇酯3-4份，辅助助剂3份。
作为优选方案，所述辅助助剂为将羧甲基纤维素10-13份，钛酸酯偶联剂20-25份，铝酸钙3-5份、偏硼酸钠1-2份，环氧氯丙烷5-8份在45-50℃下加热混合3-5分钟，然后加入聚丙二醇缩水甘油醚1-2份而成。
本发明与现有技术相比，有益效果是：结构简单，透光性好，外表面透光性好，内表面不易起雾。
附图说明
图1是本发明的结构示意图；
图2是本发明的另一种状态的结构示意图。
图中：1内层玻璃，2外层玻璃，3中间层玻璃，4氮化硅层，5碳化硅层，6PVB膜，7有机玻璃层。
具体实施方式
下面通过具体实施例对本发明的技术方案作进一步描述说明。
实施例1：
一种防雾玻璃，如图1所示，包括内层玻璃1和外层玻璃2，内层玻璃1和外层玻璃2之间设有中间层玻璃3，中间层玻璃3为偏光玻璃，在外层玻璃2表面设有一层氮化硅层4，在内层玻璃1上设有一层碳化硅层5，内层玻璃1、外层玻璃2和中间层玻璃3之间通过PVB膜6连接，各层的具体厚度如下：内层玻璃1的厚度为2mm，外层玻璃2的厚度为4mm，氮化硅层4的厚度为75nm，碳化硅层5的厚度为45nm。
实施例2：
一种防雾玻璃，如图1所示，包括内层玻璃1和外层玻璃2，内层玻璃1和外层玻璃2之间设有中间层玻璃3，中间层玻璃3为偏光玻璃，在外层玻璃2表面设有一层氮化硅层4，在内层玻璃1上设有一层碳化硅层5，内层玻璃1、外层玻璃2和中间层玻璃3之间通过PVB膜6连接，各层的具体厚度如下：内层玻璃1的厚度为2.5mm，外层玻璃2的厚度为5mm，氮化硅层4的厚度为25nm，碳化硅层5的厚度为80nm。
实施例3：
一种防雾玻璃，如图1所示，包括内层玻璃1和外层玻璃2，内层玻璃1和外层玻璃2之间设有中间层玻璃3，中间层玻璃3为偏光玻璃，在外层玻璃2表面设有一层氮化硅层4，在内层玻璃1上设有一层碳化硅层5，内层玻璃1、外层玻璃2和中间层玻璃3之间通过PVB膜6连接，各层的具体厚度如下：内层玻璃1的厚度为3mm，外层玻璃2的厚度为3mm，氮化硅层4的厚度为50nm，碳化硅层5的厚度为125nm。
实施例4：
一种防雾玻璃，如图2所示，包括内层玻璃1和外层玻璃2，内层玻璃1和外层玻璃2之间设有中间层玻璃3，中间层玻璃3为偏光玻璃，在外层玻璃2表面设有一层氮化硅层4，在内层玻璃1上设有一层碳化硅层5，内层玻璃1、外层玻璃2和中间层玻璃3之间通过PVB膜6连接，各层的具体厚度如下：内层玻璃1的厚度为2mm，外层玻璃2的厚度为5mm，氮化硅层4的厚度为25nm，碳化硅层5的厚度为125nm。
在内层玻璃1、外层玻璃2和中间层玻璃3之间设有一层有机玻璃层7，有机玻璃层7为导电层，机玻璃层7的厚度为1mm。
实施例5：
一种防雾玻璃，如图2所示，包括内层玻璃1和外层玻璃2，内层玻璃1和外层玻璃2之间设有中间层玻璃3，中间层玻璃3为偏光玻璃，在外层玻璃2表面设有一层氮化硅层4，在内层玻璃1上设有一层碳化硅层5，内层玻璃1、外层玻璃2和中间层玻璃3之间通过PVB膜6连接，各层的具体厚度如下：内层玻璃1的厚度为3mm，外层玻璃2的厚度为3mm，氮化硅层4的厚度为75nm，碳化硅层5的厚度为45nm。
在内层玻璃1、外层玻璃2和中间层玻璃3之间设有一层有机玻璃层7，有机玻璃层7为导电层，机玻璃层7的厚度为3mm。
实施例6：
上述所有实施例中的所用的PVB膜6包括以下重量份数的各组分(每份1kg，并按照该比例混合后进行制备)：聚乙烯醇缩丁醛70份，聚乙炔5份，聚丙二醇缩水甘油醚为4份，丙烯酸环己酯为7份，氟铝酸钾0.5份，聚酰胺蜡微粉0.5份，二异丙基乙醇胺1份，聚丁二酸丁二醇酯4份，辅助助剂3份。辅助助剂为将羧甲基纤维素10份，钛酸酯偶联剂25份，铝酸钙3份、偏硼酸钠1份，环氧氯丙烷5-8份在45-50℃下加热混合3-5分钟，然后加入聚丙二醇缩水甘油醚2份而成。
实施例7：
上述所有实施例中的所用的PVB膜6包括以下重量份数的各组分(每份1kg，并按照该比例混合后进行制备)：聚乙烯醇缩丁醛75份，聚乙炔3份，聚丙二醇缩水甘油醚为5份，丙烯酸环己酯为6份，氟铝酸钾1份，聚酰胺蜡微粉0.3份，二异丙基乙醇胺1.5份，聚丁二酸丁二醇酯3份，辅助助剂3份。
作为优选方案，所述辅助助剂为将羧甲基纤维素13份，钛酸酯偶联剂20份，铝酸钙5份、偏硼酸钠2份，环氧氯丙烷5-8份在45-50℃下加热混合3-5分钟，然后加入聚丙二醇缩水甘油醚1份而成。

Claims (9)

1.一种防雾玻璃，包括内层玻璃(1)和外层玻璃(2)，其特征在于，内层玻璃(1)和外层玻璃(2)之间设有中间层玻璃(3)，中间层玻璃(3)为偏光玻璃，在外层玻璃(2)表面设有一层氮化硅层(4)，在内层玻璃(1)上设有一层碳化硅层(5)。
2.根据权利要求1所述的一种防雾玻璃，其特征在于，所述内层玻璃(1)、外层玻璃(2)和中间层玻璃(3)之间通过PVB膜(6)连接。
3.根据权利要求1所述的一种防雾玻璃，其特征在于，所述内层玻璃(1)的厚度为2-3mm。
4.根据权利要求1所述的一种防雾玻璃，其特征在于，所述外层玻璃(2)的厚度为3-5mm。
5.根据权利要求1所述的一种防雾玻璃，其特征在于，所述氮化硅层(4)的厚度为25-75nm。
6.根据权利要求1所述的一种防雾玻璃，其特征在于，所述碳化硅层(5)的厚度为45-125nm。
7.根据权利要求1所述的一种防雾玻璃，其特征在于，在内层玻璃(1)、外层玻璃(2)和中间层玻璃(3)之间设有一层有机玻璃层(7)，有机玻璃层(7)为导电层。
8.根据权利要求2所述的一种防雾玻璃，其特征在于，所述PVB膜(6)包括以下重量份数的各组分：聚乙烯醇缩丁醛70-75份，聚乙炔3-5份，聚丙二醇缩水甘油醚为4-5份，丙烯酸环己酯为6-7份，氟铝酸钾0.5-1份，聚酰胺蜡微粉0.3-0.5份，二异丙基乙醇胺1-1.5份，聚丁二酸丁二醇酯3-4份，辅助助剂3份。
9.根据权利要求8所述的一种防雾玻璃，其特征在于，所述辅助助剂为将羧甲基纤维素10-13份，钛酸酯偶联剂20-25份，铝酸钙3-5份、偏硼酸钠1-2份，环氧氯丙烷5-8份在45-50℃下加热混合3-5分钟，然后加入聚丙二醇缩水甘油醚1-2份而成。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106863936A (zh) * 2017-02-28 2017-06-20 浙江飞越洁具制造有限公司 一种单向透视玻璃
CN107238875A (zh) * 2017-05-31 2017-10-10 苏州鑫河镜业有限公司 一种电热式抗摔防起雾玻璃镜片

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