CN106075799A - A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons - Google Patents

A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons Download PDF

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Publication number
CN106075799A
CN106075799A CN201610533877.6A CN201610533877A CN106075799A CN 106075799 A CN106075799 A CN 106075799A CN 201610533877 A CN201610533877 A CN 201610533877A CN 106075799 A CN106075799 A CN 106075799A
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parts
chinese medicine
medicine composition
polycyclic aromatic
radix
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CN201610533877.6A
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CN106075799B (en
Inventor
龙明华
巫桂芬
梁勇生
申海燕
龙彪
唐璇
李朋欣
张慧娜
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Guangxi University
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Guangxi University
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • A01N65/42Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20Organic substances

Abstract

The invention discloses a kind of Chinese medicine composition, be specifically related to a kind of degrading polycyclic aromatic hydrocarbons Chinese medicine composition.The present invention answers described degrading polycyclic aromatic hydrocarbons Chinese medicine composition, is made up of following Chinese medicinal plant raw material: Radix Isatidis, Folium Isatidis, Herba Epimedii, Folium Ginkgo, Radix Ophiopogonis, the Radix Astragali;Degrading polycyclic aromatic hydrocarbons Traditional Chinese medicine composition formula of the present invention is reasonable, and preparation technology is simple, and said composition can effectively be degraded the various polycyclic aromatic hydrocarbons in vegetable, improves the nutrition content in vegetable.

Description

A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons
Technical field
The present invention relates to field of traditional Chinese, particularly relate to the Chinese medicine composition of a kind of degrading polycyclic aromatic hydrocarbons.
Background technology
Polycyclic aromatic hydrocarbon (Polycyclic Aromatic Hydrocarbons, PAHs) is also known as polycyclic aromatic Or polycyclic aromatic hydrocarbons, it is a special case of aromatic hydrocarbons, by the virtue not comprising heterocycle or substituent group Fragrant ring is formed.Wherein having is much all known or potential carcinogen, mainly by carbon-containing fuel (firewood, wood carbon, oil Fat) and the imperfect combustion of Nicotiana tabacum L. etc. produced by.At present, the PAHs found at nature has kind more than 100, can be generally divided into Low ring (2~4 ring) PAHs and epipodium (5 rings and more than) PAHs, low ring PAHs can be distributed in gaseous environment, but most of PAHs can only be gathered in inhalable particles surface, especially on the granule less than 5 μm.
1961, since Blumer finds PAHs in soil for the first time, PAHs just caused the extensive pass of people Note.In recent years, most countries was by one of PAHs important content being classified as environmental monitoring work.PAHs is that a class is the most serious Pollutant, be widely present in soil, air and water body, there is extremely strong carcinogenic, teratogenesis and mutagenic action.Most PAHs Compounds is difficult to be degraded, and environment is caused severe contamination.And be present in PAHs in environment and be easily absorbed by plants and in vivo Accumulation, thus affect agricultural product security, it is possible to endanger the healthy of people by food chain.At present, PAHs is at soil, heavy The aspects such as various physics, chemistry and the Biology seed coating in the long-pending environment such as thing, water have caused the very big attention of environmentalist.
The problem such as polycyclic aromatic hydrocarbons contaminated is day by day serious, and in crops, the pollution of PAHs the most gradually is in the news out, and vegetable makees Closely bound up with the health of people for food materials requisite in people's daily life.At present, most scholars are in environment The environmental behaviour of the source of PAHs, distribution, toxicity and generation has had the most deep systematic Study.Meanwhile, plant pair PAHs uptake and accumulation rule, affect plant the physiological ecological of PAHs is rung by the various internal and external factors of PAHs assimilation effect, plant Should also there is relevant report.But, the quality safety of the PAHs residue problem serious threat in farmland, water body and air to vegetable And residents ' health.But the fewest in the research of vegetable field related fields, especially for the PAHs impact on quality of vegetable, as What is the need subtract vegetable to features of pollution on vegetable of the absorption of polycyclic aromatic hydrocarbon and accumulation, various polycyclic aromatic hydrocarbon and residue criterion and The problems such as Prevention Technique are seldom studied, and more do not formulate relevant Prevention Technique standard.Therefore, in terms of vegetable production, grind Study carefully PAHs pollution and Prevention Technique has important practical significance.
Summary of the invention
The technical problem to be solved is to provide the Chinese medicine composition of a kind of degrading polycyclic aromatic hydrocarbons, it is possible to effectively Degraded vegetable in polycyclic aromatic hydrocarbon, improve vegetable quality.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons, it is characterised in that: described Chinese medicine composition includes the group of following weight portion Point: Radix Isatidis 20-300 part, Folium Isatidis 20-300 part, Herba Epimedii 20-300 part, Folium Ginkgo 20-200 part, 15-200 part Radix Ophiopogonis, Radix Astragali 20-300 part.
Preferably technical scheme is: described Chinese medicine composition includes the component of following weight portion: Radix Isatidis 50 parts, Folium Isatidis 150 parts, Herba Epimedii 100 parts, Folium Ginkgo 50 parts, Radix Ophiopogonis 50 parts, the Radix Astragali 50 parts.
Preferably technical scheme is: described Chinese medicine composition includes the component of following weight portion: Radix Isatidis 150 parts, Folium Isatidis 50 parts of leaf, Herba Epimedii 100 parts, Folium Ginkgo 200 parts, Radix Ophiopogonis 100 parts, the Radix Astragali 150 parts.
Preferably technical scheme is: described Chinese medicine composition includes the component of following weight portion: Radix Isatidis 200 parts, Folium Isatidis 200 parts of leaf, Herba Epimedii 200 parts, Folium Ginkgo 150 parts, Radix Ophiopogonis 200 parts, the Radix Astragali 200 parts.
The preparation method of the Chinese medicine composition of above-described a kind of polycyclic aromatic hydrocarbon of degrading, comprises the following steps: by Baphicacanthus cusia Decoction vessel put into by root, Folium Isatidis, Herba Epimedii, Folium Ginkgo, Radix Ophiopogonis, the Radix Astragali, adds the water of 1000 ~ 6000 weight portions, soaks 10-15 After hour, decoct and maintain and boil 30-60 minute, stop heating and filtered while hot collects medicinal liquid.
Compared with prior art, effective effect that the present invention has is:
1, the Chinese medicine composition of the present invention is sprayed onto on plant, can reduce various polycyclic aromatic hydrocarbons in vegetable, particularly naphthalene, Phenanthrene, fluoranthene, benzo (a) anthracene, benzo (a) pyrene;
2, the Chinese medicine composition of the present invention can improve the plant qualities such as vegetable, its Determination of Chlorophyll, soluble sugar, solubility egg In vain, the content of the composition such as crude fiber content improves more apparent.
Detailed description of the invention
By specific examples below, the invention will be further described, not as limitation of the present invention.
Preparation embodiment 1.
A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons, composed of the following components: Radix Isatidis 50g, Folium Isatidis 150g, excessive sheep The leaves of pulse plants 100 g, Folium Ginkgo 50 g, g Radix Ophiopogonis 50, the Radix Astragali 50 g;
Put into decoction vessel by the Radix Isatidis of above-mentioned deal, Folium Isatidis, Herba Epimedii, Folium Ginkgo, Radix Ophiopogonis, the Radix Astragali, add 6kg water soaking 10 hours, room temperature decocted and maintains and boils 30 minutes, stops heating and filtered while hot collects medicinal liquid, i.e. obtain degrading polycyclic aromatic hydrocarbons Traditional Chinese medicine composition extract liquid.
Preparation embodiment 2.
A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons, composed of the following components: Radix Isatidis 150g, Folium Isatidis 50g, excessive sheep The leaves of pulse plants 100 g, Folium Ginkgo 200 g, g Radix Ophiopogonis 100, the Radix Astragali 150;
Put into decoction vessel by the Radix Isatidis of above-mentioned deal, Folium Isatidis, Herba Epimedii, Folium Ginkgo, Radix Ophiopogonis, the Radix Astragali, add 6kg water soaking 12 hours, room temperature decocted and maintains and boils 40 minutes, stops heating and filtered while hot collects medicinal liquid, i.e. obtain degrading polycyclic aromatic hydrocarbons Traditional Chinese medicine composition extract liquid.
Preparation embodiment 3.
A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons, composed of the following components: Radix Isatidis 200 g, Folium Isatidis 200 g, Herba Epimedii 200 g, Folium Ginkgo 150 g, g Radix Ophiopogonis 200, the Radix Astragali 200 g;
Put into decoction vessel by the Radix Isatidis of above-mentioned deal, Folium Isatidis, Herba Epimedii, Folium Ginkgo, Radix Ophiopogonis, the Radix Astragali, add 6kg water soaking 15 hours, room temperature decocted and maintains and boils 60 minutes, stops heating and filtered while hot collects medicinal liquid, i.e. obtain degrading polycyclic aromatic hydrocarbons Chinese medicine composition 3.
Compliance test result embodiment.
Prepare PAHs mixed liquor: the compound method of 1L10mg/L PAHs mixed liquor: with the electronics sky being accurate to 0.0001 Put down and weigh naphthalene NAP, luxuriant and rich with fragrance PHE, fluoranthene FLT, benzo (a) anthracene BaA and each 0.0020g of benzo (a) pyrene BaP, add acetone and be settled to 1L fully dissolves, and loads sealing of labelling in brown bottle, and it is standby to put into 4 DEG C of Refrigerator stores after preparing.
With above-mentioned 10mg/L PAHs mixed liquor, dilution, constant volume configure 600 μ g L-1PAHs mixed solution.
This compliance test result embodiment is as a example by Chinese medicine composition is to the Degradation of PAHs in the minds of four or nine sweet CUICAI: 2015 Four or the nine sweet CUICAI hearts are seeded in agricultural college of Guangxi University Vegetable Base warmhouse booth by July 20, use hole plate seedling growth, treat bud Brassica campestris L. ssp.chinensis Seedling to two leaves wholeheartedly, is moved in bubble chamber on August 8th, 2015 by length, the strain of every case 6, and seeding row spacing is 0.1m × 0.1m, and 3 Secondary repetition.
On August 18th, 2015, is 600 μ g L by concentration-1PAHs mixed liquor Brassica campestris leaves is carried out spraying treatment, even Continuous process 3 days.August 22, Brassica campestris L. ssp.chinensis is gathered the last week, with watering can by the Chinese medicine extraction liquid of above-described embodiment 1 ~ 3 to Brassica campestris leaves Uniformly spray, with clear water for comparison, repeat for 3 times.On August 29th, 2015, gather in the crops Brassica campestris L. ssp.chinensis, detect its ground edible portion many Cyclic aromatics content and quality of vegetable.
By to the assay method of product quality and the mensuration of polycyclic aromatic hydrocarbon content, test result information slip is as follows:
Table 1: decocting for Chinese herbal medicine liquid is on the impact of polycyclic aromatic hydrocarbon content in vegetable
Table 2: the impact of Chinese medicine composition decoction liquor Brassica campestris L. ssp.chinensis nutritional quality
As seen from the above table, traditional Chinese medicine composition extract liquid prepared by the embodiment of the present invention can be degraded multiple polycyclic aromatic hydrocarbon in vegetable, Improving the nutritional labeling in vegetable, the decoction liquor formula of said composition is reasonable, and decocting process is simple, is free from side effects, is simultaneously The formula of effective degrading carcinogen in it matter.

Claims (5)

1. the Chinese medicine composition of a degrading polycyclic aromatic hydrocarbons, it is characterised in that: described Chinese medicine composition includes following weight portion Component: Radix Isatidis 20-300 part, Folium Isatidis 20-300 part, Herba Epimedii 20-300 part, Folium Ginkgo 20-200 part, 15-200 Radix Ophiopogonis Part, Radix Astragali 20-300 part.
The Chinese medicine composition of degrading polycyclic aromatic hydrocarbons the most according to claim 1, it is characterised in that: described Chinese medicine composition includes The component of following weight portion: Radix Isatidis 50 parts, Folium Isatidis 150 parts, Herba Epimedii 100 parts, Folium Ginkgo 50 parts, Radix Ophiopogonis 50 parts, the Radix Astragali 50 parts.
The Chinese medicine composition of degrading polycyclic aromatic hydrocarbons the most according to claim 1, it is characterised in that: described Chinese medicine composition includes The component of following weight portion: Radix Isatidis 150 parts, Folium Isatidis 50 parts, Herba Epimedii 100 parts, Folium Ginkgo 200 parts, Radix Ophiopogonis 100 parts, Huang Stilbene 150 parts.
The Chinese medicine composition of degrading polycyclic aromatic hydrocarbons the most according to claim 1, it is characterised in that: described Chinese medicine composition includes The component of following weight portion: Radix Isatidis 200 parts, Folium Isatidis 200 parts, Herba Epimedii 200 parts, Folium Ginkgo 150 parts, Radix Ophiopogonis 200 parts, Huang Stilbene 200 parts.
5. degrading according to any one of Claims 1-4 the preparation method of Chinese medicine composition of polycyclic aromatic hydrocarbon, its feature exists In comprising the following steps: Radix Isatidis, Folium Isatidis, Herba Epimedii, Folium Ginkgo, Radix Ophiopogonis, the Radix Astragali are put into decoction vessel, add 1000 ~ The water of 6000 weight portions, after soaking 10-15 hour, decocts and maintains and boil 30-60 minute, stops heating and filtered while hot is collected Medicinal liquid.
CN201610533877.6A 2016-07-08 2016-07-08 A kind of Chinese medicine composition of degrading polycyclic aromatic hydrocarbons Active CN106075799B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111170848A (en) * 2020-02-06 2020-05-19 山西中医药大学 Method for preparing benzene carboxylic acid by using traditional Chinese medicine waste residues as raw materials

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111170848A (en) * 2020-02-06 2020-05-19 山西中医药大学 Method for preparing benzene carboxylic acid by using traditional Chinese medicine waste residues as raw materials

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