CN106070279A - One plant growth regulators Thidiazuron diuron electrostatic liquor and making, purposes and using method - Google Patents
One plant growth regulators Thidiazuron diuron electrostatic liquor and making, purposes and using method Download PDFInfo
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- CN106070279A CN106070279A CN201610385584.8A CN201610385584A CN106070279A CN 106070279 A CN106070279 A CN 106070279A CN 201610385584 A CN201610385584 A CN 201610385584A CN 106070279 A CN106070279 A CN 106070279A
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- thidiazuron
- diuron
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Forests & Forestry (AREA)
- Toxicology (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to technical field of pesticide, more particularly relate to a kind of Thidiazuron diuron electrostatic liquor, it is characterised in that be made up of active component Thidiazuron, diuron, dispersant, conductive agent, cosolvent and solvent；The mass fraction of aforementioned each component is as follows, wherein Thidiazuron 0.1%～40.0%, diuron 0.1%～20.0%, cosolvent 1.0%～10.0%, dispersant 1.0%～10.0%, and conductive agent 1.0%～8.0%, solvent complements to 100%.Thidiazuron and diuron i.e. for the practical problem in producing, are compounded by the present invention, develop, drug effect high for environmentally friendly, crop utilization rate rapidly, the electrostatic liquor using conveniently, to operator safely, save labor.If using unmanned plane to spray Thidiazuron diuron electrostatic liquor, can reduce the frequency of taking off of unmanned plane, that improves unmanned planes in a large number sprays efficiency.
Description
Technical field
The present invention relates to technical field of pesticide, more particularly relate to a plant growth regulators Thidiazuron diuron quiet
Electro-hydraulic dose and making, purposes and using method.
Background technology
Due to industrialization and the development of urbanization, rural area person between twenty and fifty's labor transfer is gone out, the aging of rear personnel
And be willing to be intended to rural area and be engaged in the number of hard working and drastically reduce, poor efficiency, arduous pest and disease damage existing plant protection prevention and treatment method are
Through becoming the weak link of agricultural modernization, therefore, the modern agricultural technology system of exploitation " efficiently, saving of labor, laborsaving " also becomes
Agricultural development emphasis direction, promotes machinery cotton picking and is liberation agricultural productive force, improves the Important Action of Cotton Production efficiency.In cotton
Flower, Fructus Capsici plantation in, mainly use machine harvest, but owing to the cotton boll bell phase on cotton plant differs greatly.Chang Youyi
A little cotton bolls before fall frost can not normal mature, and flower or do not open bell after becoming frost, thus affect machine and gather the product of Cotton Gossypii, Fructus Capsici
Amount and grade.To this end, at Cotton Gossypii, Fructus Capsici late growth stage, take to accelerate the ripening and disleave process be the weight in modern cotton, pepper planting
Want link, be also the key link of machinery cotton picking supporting technology.
Mainly with Thidiazuron as defoliant, Thidiazuron (thidiazuron, TDZ) be 1976 by
The cytokinin plant growth regulator of Schering company synthesis, belongs to phenyl urea derivatives, and chemical name is N-
Phenyl-N '-1,2,3-thiadiazoles-5-ureas (N-phenyl-N '-1,2,3-thiadiazol-5-ylurea).Thidiazuron is in cotton
The seeds of flowering plants is planted and makees defoliant use, after being absorbed by cotton plant, can promote that the chorista self-assembling formation between petiole and stem comes off,
It is applicable to cotton growth later stage mechanical harvesting and manually adopts soon.
The preparation major part commonly using Thidiazuron in the market is wettable powder and aqueous suspension agent, the most often
Mu ground needs about 50 kg of water, and water wasting amount is big.It addition, in the case of Daily minimum temperature continues 2 weeks for more than 12 DEG C, Thidiazuron
Could normally play drug effect, due to the uncertainty of weather, if frost season is relatively early, defoliation effect is the most undesirable, accordingly, it would be desirable to
Shorten Thidiazuron and play the time of drug effect.
Summary of the invention
The present invention is to overcome at least one defect (not enough) described in above-mentioned prior art, it is provided that a kind of Thidiazuron enemy's grass
Grand electrostatic liquor and making, purposes and using method.
For solving above-mentioned technical problem, technical scheme is as follows:
A kind of Thidiazuron diuron electrostatic liquor, by active component Thidiazuron, diuron, dispersant, conductive agent, cosolvent and
Solvent forms；The mass fraction of aforementioned each component is as follows, wherein Thidiazuron 0.1 %～40.0 %, diuron 0.1 %～20.0
%, cosolvent 1.0 %～10.0 %, dispersant 1.0 %～10.0 %, conductive agent 1.0 %～8.0 %, solvent complements to 100
%。
Further, described dispersant is sodium lauryl sulphate, fatty acid polyethylene glycol ester, waterglass, trimerization phosphorus
Acid sodium, agriculture breast 600# series, dialkyl benzene sulfonic acids sodium, sodium butylnaphthalenesulfonate, nekal, triethyl group hexyl phosphoric acid,
Calcium lignosulfonate, sodium lignin sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products or detergent；
Further, described conductive agent is pyrroles, polypyrrole, thiophene, dodecylbenzene sodium sulfonate or DBSA
Calcium；
Further, described cosolvent is epoxy resin, polyacrylamide, aliphatic diamine and polyamines, aromatic polyamine, stone
Wax, organic acid, anhydride and boron trifluoride, N,N-dimethylformamide or N-Methyl pyrrolidone；
Further, described solvent is esterification soybean oil, esterification rapeseed oil, esterification Oleum Helianthi, esterification flower
Oil generation, esterification Semen Maydis oil, esterification Oleum Gossypii semen, esterification Semen Lini oil, esterification Oleum Ricini, solvent naphtha 150#, solvent naphtha
200#, two wires oil or more than C10 aromatic hydrocarbons.
The present invention also provides for a kind of method making Thidiazuron diuron electrostatic liquor, described Thidiazuron enemy's grass further
The component of grand electrostatic liquor is as it was previously stated, described electrostatic liquor uses following steps to prepare:
(1) component as described in claim 1 weighs Thidiazuron and diuron, is then completely dissolved with cosolvent, solvent；
(2) adding dispersant, stirring and dissolving is complete；
(3) adding conductive agent, stirring makes fully to dissolve, and obtains transparent solution.
The present invention also provides for a kind of purposes making Thidiazuron diuron electrostatic liquor, described Thidiazuron enemy's grass further
The component of grand electrostatic liquor is as it was previously stated, the purposes of described Thidiazuron diuron electrostatic liquor is for promoting that Cotton Gossypii, Fructus Capsici take off
Leaf.
The present invention also provides for a kind of using method making Thidiazuron diuron electrostatic liquor, described Thidiazuron further
The component of diuron electrostatic liquor as it was previously stated, Cotton Gossypii, Fructus Capsici will ripe time, use electrostatic spray shower nozzle to Cotton Gossypii, peppery
Green pepper sprays described Thidiazuron diuron electrostatic liquor.
Further, spray described in as using aviation to spray.
Compared with prior art, technical solution of the present invention provides the benefit that:
The present invention i.e. for produce in practical problem, Thidiazuron and diuron are compounded, develop into environmentally friendly, crop is sharp
With the electrostatic liquor that rate is high, drug effect is rapid, uses conveniently, to operator safely, save labor.If using unmanned plane to spray thiophene
Benzene grand diuron electrostatic liquor, can reduce the frequency of taking off of unmanned plane, and that improves unmanned planes in a large number sprays efficiency.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is described further.
Embodiment 1:
Prepare 1.5% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 1%
Diuron 0.5%
Paraffin 2.0%
Calcium dodecyl benzene sulfonate 3%
Two wires oil complements to 100%.
Weigh Thidiazuron diuron, be then completely dissolved with cosolvent, solvent；Adding other compositions, stirring and dissolving is complete
Entirely；Stirring makes fully to dissolve, and obtains transparent Thidiazuron diuron electrostatic spray liquor.
Embodiment 2:
Prepare 0.75% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 0.5%
Diuron 0.25%
Dimethyl sulfoxide 2.0%
Dodecylbenzene sodium sulfonate 3%
C10 aromatic hydrocarbons complements to 100%.
Embodiment 3:
Prepare 3% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 2%
Diuron 1%
N,N-dimethylformamide 2.0%
Calcium dodecyl benzene sulfonate 3%
Esterification soybean oil 10%
Two wires oil complements to 100%.
Embodiment 4:
Prepare 0.6 % Thidiazuron diuron electrostatic spray liquor
Thidiazuron 0.4%
Diuron 0.2%
Pyrroles 0.5%
Alkylphenol-polyethenoxy base ether formaldehyde condensation products 4%
Two wires oil complements to 100%.
Embodiment 5:
Prepare 4.5% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 3%
Diuron 1.5%
Polyacrylamide 0.50%
Nekal 3%
Esterification Oleum Ricini 5%
More than C10 aromatic hydrocarbons complements to 100%.
Embodiment 6:
Prepare 1.5% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 1%
Diuron 0.5%
Paraffin 2.0%
Esterification Semen Lini oil 5%
Fatty acid polyethylene glycol ester 3%
Solvent naphtha 150# complements to 100%.
Embodiment 7:
Prepare 3% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 2%
Diuron 1%
Paraffin 2.0%
N-Methyl pyrrolidone 2%
Calcium lignosulfonate 2%
Two wires oil complements to 100%.
Embodiment 8:
Prepare 9% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 6%
Diuron 3%
Paraffin 1.0%
N-Methyl pyrrolidone 2%
Sodium lignin sulfonate 3%
Esterification Semen Lini oil 5%
Two wires oil complements to 100%.
Embodiment 9:
Prepare 15% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 10%
Diuron 5%
Paraffin 2.0%
Dimethyl sulfoxide 2%
Calcium dodecyl benzene sulfonate 3%
Pyrroles 0.5%
Solvent naphtha 200# complements to 100%.
Embodiment 10:
Prepare 9% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 6%
Diuron 3%
Paraffin 2.0%
Dimethyl sulfoxide 1%
Detergent 3%
Pyrroles 0.5%
Esterification soybean oil 5%
Two wires oil complements to 100%.
Embodiment 11:
Prepare 0.9 % Thidiazuron diuron electrostatic spray liquor
Thidiazuron 0.6%
Diuron 0.3%
Paraffin 1.0%
Calcium dodecyl benzene sulfonate 3 %
Esterification Oleum Ricini 5%
Two wires oil complements to 100%.
Embodiment 12:
Prepare 15% Thidiazuron diuron electrostatic spray liquor
Thidiazuron 10%
Diuron 5%
Epoxy resin 0.50%
Pyrroles 0.5%
Calcium dodecyl benzene sulfonate 3%
N,N-dimethylformamide 3%
Two wires oil complements to 100%.
Embodiment 13 field test effect
Within 2015, carry out 1.5% Thidiazuron diuron electrostatic spray liquor at Changji the field efficacy of cotton defoliation is tried
Test.After processing 7 days with the dosage of every mu of 1000ML, experimental plot randomly selects three fields (area is 1 square metre), observe
The cotton defoliation of each field, blow-of-cottons situation, survey result such as table 1.
Table 1 1.5% Thidiazuron diuron electrostatic spray liquor field defoliation effect
1:1.5% Thidiazuron diuron electrostatic spray liquor 800ML/ mu；2:1.5% Thidiazuron diuron electrostatic spray liquor
1000ML/ mu；3:1.5% Thidiazuron diuron electrostatic spray liquor 1200ML/ mu；4:540g/L is de-tells grand 10ML/ mu.
Embodiment 14 field test effect
Within 2015, carry out 2% Thidiazuron diuron electrostatic spray liquor at Changji the field efficacy of cotton defoliation is tried
Test.After processing 7 days with the dosage of every mu of 1000ML, experimental plot randomly selects three fields (area is 1 square metre), observe
The cotton defoliation of each field, blow-of-cottons situation, survey result such as table 1.
Table 2 2% Thidiazuron diuron electrostatic spray liquor field defoliation effect
1:1.5% Thidiazuron diuron electrostatic spray liquor 800ML/ mu；2:1.5% Thidiazuron diuron electrostatic spray liquor
1000ML/ mu；3:1.5% Thidiazuron diuron electrostatic spray liquor 1200ML/ mu；4:540g/L is de-tells grand 10ML/ mu.
Obviously, the above embodiment of the present invention is only for clearly demonstrating example of the present invention, and is not right
The restriction of embodiments of the present invention.For those of ordinary skill in the field, the most also may be used
To make other changes in different forms.Here without also cannot all of embodiment be given exhaustive.All at this
Any amendment, equivalent and the improvement etc. made within the spirit of invention and principle, should be included in the claims in the present invention
Protection domain within.
Claims (9)
1. a Thidiazuron diuron electrostatic liquor, it is characterised in that by active component Thidiazuron, diuron, dispersant, lead
Electricity agent, cosolvent and solvent composition；The mass fraction of aforementioned each component is as follows, wherein Thidiazuron 0.1 %～40.0 %, diuron
0.1 %～20.0 %, cosolvent 1.0 %～10.0 %, dispersant 1.0 %～10.0 %, conductive agent 1.0 %～8.0 %, molten
Agent complements to 100 %.
Thidiazuron diuron electrostatic liquor the most according to claim 1, it is characterised in that described dispersant is 12
Alkyl sodium sulfate, fatty acid polyethylene glycol ester, waterglass, sodium tripolyphosphate, agriculture breast 600# series, dialkyl benzene sulfonic acids sodium, fourth
Base sodium naphthalene sulfonate, nekal, triethyl group hexyl phosphoric acid, calcium lignosulfonate, sodium lignin sulfonate, alkyl phenol polyoxy
Vinyl ethers formaldehyde condensation products or detergent.
Thidiazuron diuron electrostatic liquor the most according to claim 1 and 2, it is characterised in that described conductive agent is pyrrole
Cough up, polypyrrole, thiophene, dodecylbenzene sodium sulfonate or calcium dodecyl benzene sulfonate.
Thidiazuron diuron electrostatic liquor the most according to claim 3, it is characterised in that described cosolvent is epoxy
Resin, polyacrylamide, aliphatic diamine and polyamines, aromatic polyamine, paraffin, organic acid, anhydride and boron trifluoride, N, N-bis-
Methylformamide or N-Methyl pyrrolidone.
Thidiazuron diuron electrostatic liquor the most according to claim 4, it is characterised in that described solvent is esterification
Soybean oil, esterification rapeseed oil, esterification Oleum Helianthi, esterification Oleum Arachidis hypogaeae semen, esterification Semen Maydis oil, esterification Oleum Gossypii semen,
Esterification Semen Lini oil, esterification Oleum Ricini, solvent naphtha 150#, solvent naphtha 200#, two wires oil or more than C10 aromatic hydrocarbons.
6. the method making Thidiazuron diuron electrostatic liquor, it is characterised in that described Thidiazuron diuron electrostatic liquid
The component of agent is as claimed in claim 1, and described electrostatic liquor uses following steps to prepare:
(1) component as described in claim 1 weighs Thidiazuron and diuron, is then completely dissolved with cosolvent, solvent；
(2) adding dispersant, stirring and dissolving is complete；
(3) adding conductive agent, stirring makes fully to dissolve, and obtains transparent solution.
7. make a purposes for Thidiazuron diuron electrostatic liquor, the component of described Thidiazuron diuron electrostatic liquor such as power
Profit requires described in 1, it is characterised in that the purposes of described Thidiazuron diuron electrostatic liquor is for promoting that Cotton Gossypii, Fructus Capsici take off
Leaf.
8. make a using method for Thidiazuron diuron electrostatic liquor, the component of described Thidiazuron diuron electrostatic liquor
As claimed in claim 1, it is characterised in that Cotton Gossypii, Fructus Capsici will ripe time, use electrostatic spray shower nozzle to Cotton Gossypii, Fructus Capsici
Spray described Thidiazuron diuron electrostatic liquor.
The using method of making Thidiazuron diuron electrostatic liquor the most according to claim 8, it is characterised in that described
Spray as using aviation to spray.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106717509A (en) * | 2016-11-22 | 2017-05-31 | 宜昌市农业科学研究院 | Rape disposable machine uniformly harvests detraction method |
| CN107343502A (en) * | 2017-06-13 | 2017-11-14 | 中国农业科学院棉花研究所 | A kind of defoliant composition and its production and use |
| CN107787998A (en) * | 2017-11-07 | 2018-03-13 | 江苏辉丰生物农业股份有限公司 | A kind of cotton growth regulator composition |
| WO2018090072A1 (en) * | 2016-11-18 | 2018-05-24 | Huntsman Corporation Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
| WO2018176895A1 (en) * | 2017-03-31 | 2018-10-04 | 江苏辉丰生物农业股份有限公司 | Pesticide composition containing thiocarbamate compound and thidiazuron |
| CN109362764A (en) * | 2018-12-07 | 2019-02-22 | 安阳全丰生物科技有限公司 | Thidiazuron defoliant composition containing diquat dibromide |
| CN111972425A (en) * | 2020-09-07 | 2020-11-24 | 安徽省四达农药化工有限公司 | Thidiazuron single agent, thidiazuron and brassinolide compound composition and preparation process thereof |
| US12004509B2 (en) | 2016-11-18 | 2024-06-11 | Indorama Ventures Oxides Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018090072A1 (en) * | 2016-11-18 | 2018-05-24 | Huntsman Corporation Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
| CN109068629A (en) * | 2016-11-18 | 2018-12-21 | 胡茨曼澳大利亚股份有限公司 | Total preparation comprising plant growth regulator and oil and the method for making and using the preparation altogether |
| JP2019535638A (en) * | 2016-11-18 | 2019-12-12 | ハンツマン・コーポレーシヨン・オーストラリア・ピーテイワイ・リミテツド | Mixed formulations containing plant growth regulators and oils and methods of blending and using the blended formulations |
| EP3541183A4 (en) * | 2016-11-18 | 2020-05-20 | Huntsman Corporation Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
| JP7015787B2 (en) | 2016-11-18 | 2022-02-03 | インドラマ・ベンチャーズ・オキサイズ・オーストラリア・ピーティーワイ・リミテッド | A mixed formulation containing a plant growth regulator and oil, and a formulation method and usage method of the mixed formulation. |
| US12004509B2 (en) | 2016-11-18 | 2024-06-11 | Indorama Ventures Oxides Australia Pty Limited | Co-formulation comprising a plant growth regulator and an oil, and methods of preparing and using said co-formulation |
| CN106717509A (en) * | 2016-11-22 | 2017-05-31 | 宜昌市农业科学研究院 | Rape disposable machine uniformly harvests detraction method |
| WO2018176895A1 (en) * | 2017-03-31 | 2018-10-04 | 江苏辉丰生物农业股份有限公司 | Pesticide composition containing thiocarbamate compound and thidiazuron |
| CN107343502A (en) * | 2017-06-13 | 2017-11-14 | 中国农业科学院棉花研究所 | A kind of defoliant composition and its production and use |
| CN107787998A (en) * | 2017-11-07 | 2018-03-13 | 江苏辉丰生物农业股份有限公司 | A kind of cotton growth regulator composition |
| CN109362764A (en) * | 2018-12-07 | 2019-02-22 | 安阳全丰生物科技有限公司 | Thidiazuron defoliant composition containing diquat dibromide |
| CN111972425A (en) * | 2020-09-07 | 2020-11-24 | 安徽省四达农药化工有限公司 | Thidiazuron single agent, thidiazuron and brassinolide compound composition and preparation process thereof |
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