CN106070232A - Containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M - Google Patents
Containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M Download PDFInfo
- Publication number
- CN106070232A CN106070232A CN201610540017.5A CN201610540017A CN106070232A CN 106070232 A CN106070232 A CN 106070232A CN 201610540017 A CN201610540017 A CN 201610540017A CN 106070232 A CN106070232 A CN 106070232A
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- China
- Prior art keywords
- metalaxyl
- cga
- insect amide
- cyanogen insect
- bromine cyanogen
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
Abstract
The present invention relates to a kind of containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M, effective ingredient is CGA-173506, Metalaxyl-M and bromine cyanogen insect amide, and between CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three, mass ratio is 1～10:1～10:1～20.The present composition for being coated process to peanut seed, and preventing and treating Roots of Peanut maize ear rot and Gryllotalpa have potentiation, improve peanut seeding planting percent.
Description
Technical field
The invention belongs to pesticide combination and applied technical field, be specifically related to a kind of peanut seed treatment compositions, effectively
Composition is CGA-173506, Metalaxyl-M and bromine cyanogen insect amide, and composition for preventing and controlling Roots of Peanut maize ear rot and Gryllotalpa have potentiation, improves
Peanut seed planting percent.
Background technology
In agricultural production, the quality of seed quality directly affects the production of crop, and seed is from germinateing to seedling stage appearance
Easily carried by seed or Pathogen Infection, insecticide in soil gnaws, cause that the sowing time such as rotten, incomplete is sick, insect pest, serious shadow
Ring seeding quality, reduce sowing planting percent.Such as, the peanut seedling phase is contaminated by Fusarium spp. and causes root rot, and Gryllotalpa gnaws seed
And rhizome, cause the Semen arachidis hypogaeae section of being short of seedling ridge, have a strong impact on yield.
CGA-173506 (fludioxonil), pyroles antibacterial, this medicine is broad-spectrum touch-out effect, by suppression glucose phosphorus
Acylated relevant transfer, and suppress the growth of fungal mycelium, ultimately result in pathogen dead；Major part seed-borne fungi can be prevented and treated
And the fungal disease of soil infection, stable in soil, form protection zone at seed and seedling rhizosphere, prevent pathogenic bacteria from invading.
Metalaxyl-M (metalaxyl-M), anilide antibacterial, the main conjunction suppressing pathogenic bacteria mycelium internal protein
Become so that it is malnutrition, it is impossible to normal growth and dead.Protection and therapeutical effect, there is interior absorption, can by the root of plant, stem,
Leaf absorbs, and transfers to each organ of plant with moisture content operating in plant.
Bromine cyanogen insect amide (cyantraniliprole), Benzoylamide insecticides, by activating the fish Buddhist nun of target pest
Fourth receptor and pest control；The calcium ion of storage, result in the releasable striped muscle of activation of ryanodine receptor and smooth muscle cell
Causing damaging muscular movement regulation, paralysis, final insect is dead.
CGA-173506, Metalaxyl-M and bromine cyanogen insect amide are conducted in-depth research by Crinis Carbonisatus of the present invention, in substantial amounts of test
On the basis of, find that CGA-173506, Metalaxyl-M and bromine cyanogen insect amide are combined processing peanut seed, to Semen arachidis hypogaeae root-rot
Sick, Gryllotalpa has potentiation, and expanding prevention is composed, hence it is evident that improve peanut seeding planting percent.After further study, this is completed
Invention.
Summary of the invention
The present invention seeks to solve peanut seeding to be caused harm a difficult problem by sick, worm, it is provided that a kind of containing bromine cyanogen insect amide with cough up bacterium
Nitrile and the seed treatment compositions of Metalaxyl-M, seed treatment compositions significantly improves preventing and treating Roots of Peanut maize ear rot, Gryllotalpa effect
Really, peanut seeding planting percent is improved.
Technical scheme: a kind of containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M, effectively
Composition is CGA-173506, Metalaxyl-M and bromine cyanogen insect amide, mass ratio between CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three
It is 1～10:1～10:1～20, CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three's mass summation quality hundred in the composition
Proportion by subtraction is 2%～40%, and remaining is insecticides adjuvant.
The seed treatment compositions of the present invention, can give the seed treatment dosage form of directly use by pesticide technique, can
To be suspension seed-coating agent.
The seed treatment compositions of the present invention also include solvent, cosolvent, emulsifying agent, dispersant, wetting agent, thickening agent,
Antifreezing agent, cyst material, pH adjusting agent, defoamer, disintegrating agent, stabilizer, penetrating agent, diffusant, preservative, synergist, medicine
The pesticide such as evil palliative, binding agent, density adjuster and filler allow to use and acceptable auxiliary agent, is all pesticidal preparations
In conventional or allow the composition used, be not particularly limited, concrete composition and consumption are determined by test according to recipe requirements.
The production technology of the seed treatment compositions of the present invention all belongs to existing known technology, does not repeats them here.
The seed treatment compositions of the present invention is coated process to peanut seed, and preventing and treating Roots of Peanut maize ear rot and Gryllotalpa have
Potentiation, improves peanut seeding planting percent.
The use frequency of seed treatment compositions of the present invention and amount of application are with seed variety, disease pest occurrence degree, weather feelings
Conditions etc. change and have small variations, can reach, by using suitable adjustment, the purpose effectively prevented and treated.
Compared with prior art, the method have the advantages that:
1, CGA-173506, Metalaxyl-M and the combination of bromine cyanogen insect amide have notable synergistic effect, improve using effect.
2, CGA-173506, Metalaxyl-M and bromine cyanogen insect amide combination expanding prevention spectrum, controlling disease and insect pest simultaneously.
3, CGA-173506, Metalaxyl-M and the combination of bromine cyanogen insect amide process for peanut seed, can effectively prevent and treat Semen arachidis hypogaeae root-rot
Sick, Gryllotalpa, improves peanut seeding planting percent.
4, CGA-173506, Metalaxyl-M and bromine cyanogen insect amide are applied in combination conveniently, reduce single active ingredient processing cost, stream
Logical cost, reduces material and uses, reduce energy resource consumption.
Detailed description of the invention
In order to be more fully understood that the essence of the present invention, below in conjunction with embodiment, present disclosure is described in further detail,
Content not limitation of the invention mentioned in embodiment, the following stated is only used for explaining the present invention, for without departing from this
Amendment that spirit and principle are made, replace or improve, belong to the scope of protection of present invention.
Embodiment 1: Toxicity Determination is tested
Roots of Peanut maize ear rot test method: survey standard method NY/T1156.2-2006 with reference to raw, use pastille medium therapy.
Take the medicinal liquid 6mL of each single dose and mixture series concentration, add in the PDA culture medium of the 54mL being cooled to 45 DEG C, make required
The pastille culture medium flat plate of final concentration.Then 6mm diameter mycelia block is produced from the Semen arachidis hypogaeae pine root fungus colony edge cultivated 7 days,
Moving in each series pastille culture medium, mycelia faces down, and each process repeats for 4 times.It is disposed, is placed in the constant temperature of 25 ± 1 DEG C
Biochemical cultivation case is cultivated.
Gryllotalpa test method: survey standard method NY/T1154.10-2008 with reference to raw, uses soil to mix medicine method.By dry husky earth
Soil crosses 40 mesh stainless steel sifts, weighs 1.0kg/ part after carrying out high-temperature disinfection treatment 7h with freeze-day with constant temperature target and cool down at 210 DEG C
To plastic tub, measure 100mL and stir in soil for reagent liquid, mix thoroughly after Indoor Natural infiltration 2h, then by 50 buds
The peanut seed of long 2～3cm is mixed into wherein, finally choose 50 Gryllotalpas is put into basin, and making it bury voluntarily (can not be voluntarily
The Gryllotalpa buried is changed in time).Every concentration repeats for 4 times and sets the process without medicament (containing solvent for use and emulsifying agent) to make blank
Comparison, being disposed is transferred to artificial climate and raises mutually.
Statistical analysis is carried out, by calculating the LC of each medicament with DPS statistical analysis software50Or EC50Evaluate each medicament
Parasite killing, bactericidal activity, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B medicament the toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of C in the percentage composition+C medicament toxicity index × mixture of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
According to the synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as potentiation；Co-toxicity coefficient (CTC)≤
80 show as antagonism；80 ＜ co-toxicity coefficient (CTC) ＜ 120 show as summation action.
From table 1,2 it can be seen that CGA-173506, Metalaxyl-M and the combination of bromine cyanogen insect amide are common to Semen arachidis hypogaeae pine root fungus, Gryllotalpa
Poison coefficient (CTC) value is all higher than 120, illustrates that the combination of CGA-173506, Metalaxyl-M, bromine cyanogen insect amide is to pine root fungus, Gryllotalpa performance
For potentiation.
Table 1, CGA-173506, Metalaxyl-M and the bromine cyanogen insect amide combination Toxicity Determination result to Semen arachidis hypogaeae pine root fungus
Table 2, CGA-173506, Metalaxyl-M, the bromine cyanogen insect amide combination Toxicity Determination result to Gryllotalpa
Embodiment 2:24% CGA-173506 Metalaxyl-M bromine cyanogen insect amide suspension seed-coating agent
Following material is weight ratio: CGA-173506 2%, Metalaxyl-M 2%, bromine cyanogen insect amide 20%, detergent alkylate sulphur
Hydrochlorate 4%, octyl phosphate 2%, PVA0.2%, azarin 2%, Magnesiumaluminumsilicate 2%, glycerol 2%, potassium sorbate 0.3%, three
Ethamine 0.3%, organosilicon 0.5%, deionized water to 100%.Above-mentioned material is pulverized the most in advance, stirred, adds
Sand mill grinds, after high shear mixing, prepares 24% CGA-173506 Metalaxyl-M bromine cyanogen insect amide suspension seed-coating agent.
Embodiment 3: seed treatment is applied
Selected peanut seed is standby in being placed on bucket, proportionally medicament: water: seed (1:49:200) measures, and medicament is in advance
Fully dilute with water, the medicinal liquid after dilution is stirred with seed, dries under without sunshine shining directly.After drying routinely
Sowing operation, a situation arises and Semen arachidis hypogaeae number of seedling to 4 leaf phases investigation disease pest to treat peanut growth.
From table 3, table 4 it can be seen that 24% CGA-173506 Metalaxyl-M bromine cyanogen insect amide suspension seed-coating agent is to Semen arachidis hypogaeae kind
Son processes, and to Roots of Peanut maize ear rot preventive effect 97.32%, to Gryllotalpa preventive effect 95.15%, improves Semen arachidis hypogaeae seedling more than 59%, to Semen arachidis hypogaeae
Safety.24% CGA-173506 Metalaxyl-M bromine cyanogen insect amide suspension seed-coating agent using effect is substantially better than each single and two tuples
Close using effect.
Table 3,24% CGA-173506 Metalaxyl-M bromine cyanogen insect amide suspension seed-coating agent is to peanut seed treatment effect
Peanut seed security test is tied by table 4,24% CGA-173506 Metalaxyl-M bromine cyanogen insect amide suspension seed-coating agent
Really
Claims (7)
1. one kind contains bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M, it is characterised in that: effectively become
Being divided into CGA-173506, Metalaxyl-M and bromine cyanogen insect amide, between CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three, mass ratio is
1～10:1～10:1～20.
A kind of seed treatment combination containing bromine cyanogen insect amide and CGA-173506 and Metalaxyl-M the most according to claim 1
Thing, it is characterised in that: between CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three, mass ratio is 1:1:10.
A kind of seed treatment combination containing bromine cyanogen insect amide and CGA-173506 and Metalaxyl-M the most according to claim 1
Thing, it is characterised in that: CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three's mass summation mass percent in the composition are
2%～40%.
A kind of seed treatment combination containing bromine cyanogen insect amide and CGA-173506 and Metalaxyl-M the most according to claim 1
Thing, it is characterised in that: CGA-173506, Metalaxyl-M and bromine cyanogen insect amide three's mass summation mass percent in the composition are
24%.
A kind of seed treatment combination containing bromine cyanogen insect amide and CGA-173506 and Metalaxyl-M the most according to claim 1
Thing, it is characterised in that: compositions is to give the seed treatment dosage form directly used by pesticide technique, is suspension seed-coating agent.
A kind of seed treatment combination containing bromine cyanogen insect amide and CGA-173506 and Metalaxyl-M the most according to claim 1
Thing, it is characterised in that: following material is weight ratio: CGA-173506 2%, Metalaxyl-M 2%, bromine cyanogen insect amide 20%, dodecane
Base benzene sulfonate 4%, octyl phosphate 2%, PVA0.2%, azarin 2%, Magnesiumaluminumsilicate 2%, glycerol 2%, potassium sorbate
0.3%, triethylamine 0.3%, organosilicon 0.5%, deionized water to 100%, prepare 24% CGA-173506 Metalaxyl-M bromine cyanogen
Insect amide suspension seed-coating agent.
7. a kind of seed treatment compositions containing bromine cyanogen insect amide and CGA-173506 and Metalaxyl-M described in claim 1 is used for
Peanut seed is coated process, the application in preventing and treating Roots of Peanut maize ear rot and Gryllotalpa.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610540017.5A CN106070232A (en) | 2016-07-08 | 2016-07-08 | Containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M |
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| CN201610540017.5A CN106070232A (en) | 2016-07-08 | 2016-07-08 | Containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M |
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| CN201610540017.5A Withdrawn CN106070232A (en) | 2016-07-08 | 2016-07-08 | Containing bromine cyanogen insect amide and CGA-173506 and the seed treatment compositions of Metalaxyl-M |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107467030A (en) * | 2017-08-30 | 2017-12-15 | 佛山市盈辉作物科学有限公司 | Seed treatment compositions containing fludioxonil, Metalaxyl-M and fluorine pyrrole furanone |
| CN108935477A (en) * | 2018-08-31 | 2018-12-07 | 济南仕邦农化有限公司 | A kind of suspension seed-coating agent and its application |
| CN109601297A (en) * | 2018-07-24 | 2019-04-12 | 先正达参股股份有限公司 | The method for preventing Codonopsis's plant root rot |
| CN114097803A (en) * | 2021-12-25 | 2022-03-01 | 青岛奥迪斯生物科技有限公司 | Prothioconazole-containing pesticide composition and application thereof |
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| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107467030A (en) * | 2017-08-30 | 2017-12-15 | 佛山市盈辉作物科学有限公司 | Seed treatment compositions containing fludioxonil, Metalaxyl-M and fluorine pyrrole furanone |
| CN109601297A (en) * | 2018-07-24 | 2019-04-12 | 先正达参股股份有限公司 | The method for preventing Codonopsis's plant root rot |
| CN108935477A (en) * | 2018-08-31 | 2018-12-07 | 济南仕邦农化有限公司 | A kind of suspension seed-coating agent and its application |
| CN114097803A (en) * | 2021-12-25 | 2022-03-01 | 青岛奥迪斯生物科技有限公司 | Prothioconazole-containing pesticide composition and application thereof |
| CN114097803B (en) * | 2021-12-25 | 2023-07-25 | 青岛奥迪斯生物科技有限公司 | Pesticide composition containing prothioconazole and application thereof |
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Application publication date: 20161109 |