CN106057500A - 一种功能性空心金属微球的制备方法 - Google Patents
一种功能性空心金属微球的制备方法 Download PDFInfo
- Publication number
- CN106057500A CN106057500A CN201610636473.XA CN201610636473A CN106057500A CN 106057500 A CN106057500 A CN 106057500A CN 201610636473 A CN201610636473 A CN 201610636473A CN 106057500 A CN106057500 A CN 106057500A
- Authority
- CN
- China
- Prior art keywords
- cellulose
- mentioned
- liquid
- microballoon
- bamboo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 title abstract description 6
- 239000002184 metal Substances 0.000 title abstract description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 44
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 44
- 241001330002 Bambuseae Species 0.000 claims abstract description 44
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 44
- 239000011425 bamboo Substances 0.000 claims abstract description 44
- 229920002678 cellulose Polymers 0.000 claims abstract description 26
- 239000001913 cellulose Substances 0.000 claims abstract description 26
- 238000004061 bleaching Methods 0.000 claims abstract description 14
- 239000007921 spray Substances 0.000 claims abstract description 14
- 238000001354 calcination Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims description 54
- 239000004005 microsphere Substances 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 24
- 238000001914 filtration Methods 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 12
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 12
- 238000009413 insulation Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000013049 sediment Substances 0.000 claims description 12
- 239000006228 supernatant Substances 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 9
- 238000005342 ion exchange Methods 0.000 claims description 9
- 230000001112 coagulating effect Effects 0.000 claims description 7
- 238000004108 freeze drying Methods 0.000 claims description 7
- UZGKAASZIMOAMU-UHFFFAOYSA-N 124177-85-1 Chemical class NP(=O)=O UZGKAASZIMOAMU-UHFFFAOYSA-N 0.000 claims description 6
- PTHCMJGKKRQCBF-UHFFFAOYSA-N Cellulose, microcrystalline Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC)C(CO)O1 PTHCMJGKKRQCBF-UHFFFAOYSA-N 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- 238000010411 cooking Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 238000001694 spray drying Methods 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- 235000011150 stannous chloride Nutrition 0.000 claims description 6
- 238000010025 steaming Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical class [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- 229960002163 hydrogen peroxide Drugs 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 239000011806 microball Substances 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 235000011091 sodium acetates Nutrition 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000007772 electrode material Substances 0.000 abstract description 10
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 10
- 150000004706 metal oxides Chemical class 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 7
- 238000005341 cation exchange Methods 0.000 abstract description 4
- 229910001432 tin ion Inorganic materials 0.000 abstract description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 2
- 238000009835 boiling Methods 0.000 abstract description 2
- 230000007062 hydrolysis Effects 0.000 abstract description 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 2
- 229910001887 tin oxide Inorganic materials 0.000 abstract 2
- 230000015271 coagulation Effects 0.000 abstract 1
- 238000005345 coagulation Methods 0.000 abstract 1
- 238000010792 warming Methods 0.000 description 4
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000001119 stannous chloride Substances 0.000 description 3
- 239000000052 vinegar Substances 0.000 description 3
- 235000021419 vinegar Nutrition 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- 150000002927 oxygen compounds Chemical class 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- BDKZHNJTLHOSDW-UHFFFAOYSA-N [Na].CC(O)=O Chemical compound [Na].CC(O)=O BDKZHNJTLHOSDW-UHFFFAOYSA-N 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000004758 underpotential deposition Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Manufacturing & Machinery (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610636473.XA CN106057500B (zh) | 2016-08-05 | 2016-08-05 | 一种功能性空心金属微球的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610636473.XA CN106057500B (zh) | 2016-08-05 | 2016-08-05 | 一种功能性空心金属微球的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106057500A true CN106057500A (zh) | 2016-10-26 |
CN106057500B CN106057500B (zh) | 2018-05-22 |
Family
ID=57480914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610636473.XA Active CN106057500B (zh) | 2016-08-05 | 2016-08-05 | 一种功能性空心金属微球的制备方法 |
Country Status (1)
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CN (1) | CN106057500B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114307890A (zh) * | 2022-01-01 | 2022-04-12 | 中国林业科学研究院木材工业研究所 | 一种竹胶囊及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4162914A (en) * | 1977-10-04 | 1979-07-31 | International Harvester Company | Processes for making hollow metal microballoons and the products thereof |
CN101333103A (zh) * | 2008-07-30 | 2008-12-31 | 江苏工业学院 | 一种铁氧体磁性空心微球的合成方法 |
CN101345112A (zh) * | 2008-05-15 | 2009-01-14 | 复旦大学 | 一种磁性无机空心复合微球及其制备方法 |
CN101941076A (zh) * | 2010-08-06 | 2011-01-12 | 华南理工大学 | 用于电磁波吸收材料的多层空心金属微球的制备方法 |
CN104118904A (zh) * | 2014-07-01 | 2014-10-29 | 济南大学 | 三维空心多级结构氧化锡气敏材料的制备方法及其应用 |
-
2016
- 2016-08-05 CN CN201610636473.XA patent/CN106057500B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4162914A (en) * | 1977-10-04 | 1979-07-31 | International Harvester Company | Processes for making hollow metal microballoons and the products thereof |
CN101345112A (zh) * | 2008-05-15 | 2009-01-14 | 复旦大学 | 一种磁性无机空心复合微球及其制备方法 |
CN101333103A (zh) * | 2008-07-30 | 2008-12-31 | 江苏工业学院 | 一种铁氧体磁性空心微球的合成方法 |
CN101941076A (zh) * | 2010-08-06 | 2011-01-12 | 华南理工大学 | 用于电磁波吸收材料的多层空心金属微球的制备方法 |
CN104118904A (zh) * | 2014-07-01 | 2014-10-29 | 济南大学 | 三维空心多级结构氧化锡气敏材料的制备方法及其应用 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114307890A (zh) * | 2022-01-01 | 2022-04-12 | 中国林业科学研究院木材工业研究所 | 一种竹胶囊及其制备方法和应用 |
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Publication number | Publication date |
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CN106057500B (zh) | 2018-05-22 |
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Effective date of registration: 20201214 Address after: 242800 No.10 Donghe Road, Rongcheng Town, Qingyang County, Chizhou City, Anhui Province Patentee after: Chizhou Wisdom Tree Information Technology Service Co.,Ltd. Address before: 315002 room 213-2, business building, 66, academician Road, Ningbo high tech Zone, Zhejiang Patentee before: NINGBO JTX IRON AND STEEL TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20231227 Address after: 247200 Xu village, Yao village, Yao county, Dongzhi County, Chizhou, Anhui Patentee after: DONGZHI WENYUAN CERAMIC TILE PROCESSING FACTORY Address before: 242800 No.10 Donghe Road, Rongcheng Town, Qingyang County, Chizhou City, Anhui Province Patentee before: Chizhou Wisdom Tree Information Technology Service Co.,Ltd. Patentee before: Suzhou new Fang Wei Electronics Co.,Ltd. |
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