CN106054306A - 导光板、发光单元以及具有发光单元的液晶显示元件 - Google Patents
导光板、发光单元以及具有发光单元的液晶显示元件 Download PDFInfo
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- CN106054306A CN106054306A CN201610223676.6A CN201610223676A CN106054306A CN 106054306 A CN106054306 A CN 106054306A CN 201610223676 A CN201610223676 A CN 201610223676A CN 106054306 A CN106054306 A CN 106054306A
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- 150000002736 metal compounds Chemical class 0.000 description 1
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- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
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- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
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- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical group CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
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- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- HUAZGNHGCJGYNP-UHFFFAOYSA-N propyl butyrate Chemical compound CCCOC(=O)CCC HUAZGNHGCJGYNP-UHFFFAOYSA-N 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
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- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical group CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- ATZHWSYYKQKSSY-UHFFFAOYSA-N tetradecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)=C ATZHWSYYKQKSSY-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0035—Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
- G02B6/004—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles
- G02B6/0043—Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles provided on the surface of the light guide
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
- G02B1/048—Light guides characterised by the cladding material
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133602—Direct backlight
- G02F1/133606—Direct backlight including a specially adapted diffusing, scattering or light controlling members
- G02F1/133607—Direct backlight including a specially adapted diffusing, scattering or light controlling members the light controlling member including light directing or refracting elements, e.g. prisms or lenses
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Planar Illumination Modules (AREA)
- Liquid Crystal (AREA)
Abstract
本发明有关于一种导光板、具有此导光板的发光单元以及具有此发光单元的液晶显示元件。前述的导光板包含导光层,且该导光层是使用图案形成用油墨组合物于导光板底面形成。上述的图案形成用油墨组合物包含丙烯酸酯系树脂(A)、具有特定结构的硬化性树脂(B)、填充材(C)以及溶剂(D)。使用上述导光板可制得高印刷安定性及高辉度的液晶显示元件。
Description
技术领域
本发明是有关于一种液晶显示元件,且特别是有关于一种图案形成用油墨组合物用于形成具有高印刷安定性及高辉度的导光板、具有导光板的发光单元以及具有发光单元的液晶显示元件。
背景技术
液晶显示元件广泛应用于个人电脑、电视、可携式电话等的显示装置中,由于其本身并非发光体,因此必须设置称为背光(backlight)的面光源照射光线以显示影像。近几年来,为应用于轻量化及小型化的笔记型电脑等的薄型液晶显示器,多采用于导光板的一端配置光源,并经由全反射将光线传至远端而形成面光源的侧光型(side light)背光,而不使用于光源前方设置反射板的直下型背光。
上述侧光型背光中,利用导光板底面印刷的图案,可破坏光线的全反射,产生不规则的散射及反射,将光线导引至导光板正面。日本特开2008-095103揭露一种图案形成用油墨,此油墨包含具有丙烯酸系树脂的高分子树脂、具有1,6-己二异氰酸酯的架桥剂及一充填材。然而,前述油墨形成的图案于使用时易造成导光板涂布时的印刷缺陷(mura),而未能让业界所接受,且此缺陷于大尺寸的导光板上更为严重。因此,如何提高导光板的印刷安定性,已成为本技术领域中的一重要课题。
发明内容
因此,本发明的一个方面在于提供一种导光板,此导光板包含入射光线的入光面、出射光线的出光面及相对于出光面且具有导光层的底面,其中导光层是以图案形成用油墨组合物经涂布及干燥处理后,而于导光板底面形成网点图案。上述的图案形成用油墨组合物包含丙烯酸酯系树脂(A)、具有特定结构的硬化性树脂(B)、填充材(C)及溶剂(D)。
本发明的另一方面在于提供一种发光单元,此发光单元包含发光源以及与发光源结合的上述导光板。
本发明的又一方面在于提供一种液晶显示元件,此液晶显示元件包含上述的发光单元,以及设置于发光单元的导光板的出光面上方的液晶面板。使用上述的导光板可制得具有高印刷安定性以及高辉度的液晶显示元件。
本发明的导光层、导光板、发光单元及液晶显示元件的结构与制作方法,以下析述之。
导光层
本发明的导光层是将图案形成用油墨组合物经涂布处理,例如喷墨(inkjet)、网印(screen printing)或转印(imprint)等印刷方式,涂布于导光板的底面上,再经干燥处理后形成网点图案而获得。
上述的图案形成用油墨组合物包含丙烯酸酯系树脂(A)、硬化性树脂(B)、填充材(C)以及溶剂(D),以下依序阐述之。
丙烯酸酯系树脂(A)
本发明的图案形成用油墨组合物所使用的丙烯酸酯系树脂(A)可例如由下述乙烯性不饱和单体聚合而成,其具体例如:丙烯酸、甲基丙烯酸、丁烯酸、α-氯丙烯酸、乙基丙烯酸、肉桂酸、马来酸、马来酸酐、富马酸、衣康酸、衣康酸酐、柠康酸、柠康酸酐等的不饱和羧酸(酐)类;苯乙烯、α-甲基苯乙烯、乙烯基甲苯、对氯苯乙烯、甲氧基苯乙烯等的芳香族乙烯基化合物;N-苯基马来酰亚胺、N-邻-羟基苯基马来酰亚胺、N-间-羟基苯基马来酰亚胺、N-对-羟基苯基马来酰亚胺、N-邻-甲基苯基马来酰亚胺、N-间-甲基苯基马来酰亚胺、N-对-甲基苯基马来酰亚胺、N-邻-甲氧基苯基马来酰亚胺、N-间-甲氧基苯基马来酰亚胺、N-对-甲氧基苯基马来酰亚胺、N-环己基马来酰亚胺等马来酰亚胺类;丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸正丙酯、甲基丙烯酸正丙酯、丙烯酸异丙酯、甲基丙烯酸异丙酯、丙烯酸正丁酯、甲基丙烯酸正丁酯、丙烯酸异丁酯、甲基丙烯酸异丁酯、丙烯酸仲丁酯、甲基丙烯酸仲丁酯、丙烯酸叔丁酯、甲基丙烯酸叔丁酯、丙烯酸2-羟基乙酯、甲基丙烯酸-2-羟基乙酯、丙烯酸-2-羟基丙酯、甲基丙烯酸-2-羟基丙酯、丙烯酸-3-羟基丙酯、甲基丙烯酸-3-羟基丙酯、丙烯酸-2-羟基丁酯、甲基丙烯酸-2-羟基丁酯、丙烯酸-3-羟基丁酯、甲基丙烯酸-3-羟基丁酯、丙烯酸-4-羟基丁酯、甲基丙烯酸-4-羟基丁酯、丙烯酸烯丙酯、甲基丙烯酸烯丙酯、丙烯酸苯甲酯、甲基丙烯酸苯甲酯、丙烯酸苯酯、甲基丙烯酸苯酯、丙烯酸三乙二醇甲氧酯(methoxy triethylene glycol acrylate)、甲基丙烯酸三乙二醇甲氧酯(methoxytriethylene glycol methacrylate)、甲基丙烯酸十二烷基酯(lauryl methacrylate)、甲基丙烯酸十四烷基酯(tertadecyl methacrylate)、甲基丙烯酸十六烷基酯(cetylmethacrylate)、甲基丙烯酸十八烷基酯(octadecylmethacrylate)、甲基丙烯酸二十烷基酯(eicosyl methacrylate)、甲基丙烯酸二十二烷基酯(docosyl methacrylate)等的不饱和羧酸酯类;丙烯酸-2-氨乙酯、甲基丙烯酸-2-氨乙酯、丙烯酸-2-氨丙酯、甲基丙烯酸-2-氨丙酯、丙烯酸-3-氨丙酯、甲基丙烯酸-3-氨丙酯等不饱和羧酸氨烷酯类;丙烯酸环氧丙基酯、甲基丙烯酸环氧丙基酯等不饱和羧酸环氧丙基酯类;乙酸乙烯酯、丙酸乙烯酯、丁酸乙烯酯等的羧酸乙烯酯类;乙烯基甲醚、乙烯基***、烯丙基环氧丙基醚、甲代烯丙基环氧丙基醚等不饱和醚类;丙烯腈、甲基丙烯腈、α-氯丙烯腈、氰化亚乙烯等的氰化乙烯基化合物;丙烯酰胺、甲基丙烯酰胺、α-氯丙烯酰胺、N-羟乙基丙烯酰胺、N-羟乙基甲基丙烯酰胺等的不饱和酰胺;1,3-丁二烯、异丙烯、氯丙烯等的脂肪族共轭二烯类。上述乙烯性不饱和单体可以单独一种使用或者混合多种使用。其中,以丙烯酸、甲基丙烯酸、苯乙烯、N-苯基马来酰亚胺、丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸正丁酯、丙烯酸-2-羟基乙酯、甲基丙烯酸-2-羟基乙酯、丙烯酸苯甲酯、甲基丙烯酸苯甲酯等为较佳。
本发明的丙烯酸酯系树脂(A)可利用各种已知的混合机或分散机将乙烯性不饱和单体均匀混合,并添加0.01wt%至3wt%的聚合起始剂于常温下聚合而得,并可视需要使用有机溶剂。
上述使用的聚合起始剂,其具体例如:过氧化苯甲酰等的过氧化物、偶氮二异丁腈[2,2’-azobis(isobutyronitrile);简称AIBN]、偶氮二异戊腈[2,2’-azobis(methylbutyronitrile);简称AMBN]等的偶氮化合物等。
上述使用的有机溶剂需选用较易和其它有机成分互相溶解者,其具体例如:乙二醇单甲基醚、乙二醇单乙基醚、二乙二醇单乙基醚、二乙二醇单正丙基醚、二乙二醇单正丁基醚、三乙二醇单甲基醚、三乙二醇单乙基醚、丙二醇单甲基醚、丙二醇单乙基醚、二丙二醇单甲基醚、二丙二醇单乙基醚、二丙二醇单正丙基醚、二丙二醇单正丁基醚、三丙二醇单甲基醚、三丙二醇单乙基醚等的(聚)亚烷基二醇单烷醚类;乙二醇单甲基醚醋酸酯、乙二醇单乙基醚醋酸酯、丙二醇单甲基醚醋酸酯、丙二醇单乙基醚醋酸酯等的(聚)亚烷基二醇单烷醚醋酸酯类;二乙二醇二甲基醚、二乙二醇甲基乙基醚、二乙二醇二乙基醚、四氢呋喃等的其它醚类;甲乙酮、环己酮、2-庚酮、3-庚酮等的酮类;2-羟基丙酸甲酯、2-羟基丙酸乙酯(乳酸乙酯)等乳酸烷酯类;2-羟基-2-甲基丙酸甲酯、2-羟基-2-甲基丙酸乙酯、3-甲氧基丙酸甲酯、3-甲氧基丙酸乙酯、3-乙氧基丙酸甲酯、3-乙氧基丙酸乙酯、乙氧基醋酸乙酯、羟基醋酸乙酯、2-羟基-3-甲基丁酸甲酯、3-甲基-3-甲氧基丁基醋酸酯、3-甲基-3-甲氧基丁基丙酸酯、醋酸乙酯、醋酸正丙酯、醋酸异丙酯、醋酸正丁酯、醋酸异丁酯、醋酸正戊酯、醋酸异戊酯、丙酸正丁酯、丁酸乙酯、丁酸正丙酯、丁酸异丙酯、丁酸正丁酯、丙酮酸甲酯、丙酮酸乙酯、丙酮酸正丙酯、乙酰醋酸甲酯、乙酰醋酸乙酯、2-氧基丁酸乙酯等的其它酯类;甲苯、二甲苯、己烷、环己烷、三甲苯、二异丙苯等的芳香族或脂肪族烃类;N-甲基吡咯烷酮、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺等的羧酸胺类。前述溶剂可单独使用一种或混合多种使用。其中,以丙二醇单甲基醚、丙二醇单甲基醚醋酸酯、二乙二醇二甲基醚、乳酸乙酯、3-乙氧基丙酸乙酯为较佳。
硬化性树脂(B)
本案此处所称的硬化性树脂(B)是包含如下式(I)所示结构:
于式(I)中,p、m及n分别为1至500的整数;R1代表氢原子及/或甲基;R2代表碳数为1至6的直链烷基或碳数为3至6的支链烷基;A代表苯环或环己烷;X代表CR2、氧原子、亚磺基(SO2)或硫原子;Y代表环氧基、氧杂环丁烷基或脂环族环氧基的结构;Y’代表环氧基、氧杂环丁烷基或脂环族环氧基的开环结构;以及R代表氢原子及/或甲基。
较佳地,上式(I)的硅氧树脂骨架部分的p的上限值可为200,而m及n的上限值可为50。
在上式(I)中,若硅氧树脂骨架部分的重复单元数「n」、双酚型环氧树脂骨架的重复单元数「m」,以及由硅氧树脂骨架和双酚型环氧树脂骨架所构成的重复单元数「p」落于上述数值范围,即使环境温度变化,导光板的网点图案也可具有高印刷安定性及高辉度。
上式(I)的X的具体结构可包含如下式(i-1-1)至式(i-1-6)所示的结构:
上式(I)的Y的具体结构包含如下式(i-2-1)至式(i-2-3)所示的结构:
其中,上式(i-2-2)与式(i-2-3)的R3、R4及R5可各自代表氢原子或碳数为1至6的直链烷基或碳数为3至6的支链烷基。
上式(I)的Y’的具体结构包含如下式(i-3-1)至式(i-3-3)所示的结构:
其中,上式(i-3-2)与式(i-3-3)的R3、R4及R5可各自代表氢原子或碳数为1至6的直链烷基或碳数为3至6的支链烷基。
举例来说,当上式(I)所示的「A」为苯环,且「X」为CR2时,双酚型环氧树脂和硅氧树脂的缩合反应可利用任何已知的方法进行。
上述的硬化性树脂(B)的重量平均分子量并未特别限制,但较佳地,硬化性树脂(B)的重量平均分子量可为3000至10万。当上述的硬化性树脂(B)的重量平均分子量未达3000时,会产生过多的未反应单体。另一方面,若上述的硬化性树脂(B)的重量平均分子量超过10万,会使得粘度过高而造成与其它成分的相溶性不佳。
上述的硬化性树脂(B)的重量平均分子量又以1万至5万为更佳。
上述的双酚型环氧树脂可为市售品,其具体例可例如为828、1004以及YX8000(三菱化学制)等的双酚A型环氧树脂、806、4004(三菱化学制)的双酚F型环氧树脂或R-710等的双酚E型环氧树脂。
上述的硅氧树脂的具体例可为信越硅氧树脂制造的二乙二醇单***改性的硅氧树脂,其商品名为KF-6001。
若未使用硬化性树脂(B),则液晶显示元件中的网点图案印刷安定性不佳,且所制得的导光板的辉度亦不佳。基于前述的丙烯酸酯系树脂(A)为100重量份,硬化性树脂(B)的使用量通常为2重量份至20重量份,较佳为3重量份至17重量份,更佳为5重量份至15重量份。当硬化性树脂(B)的使用量为上述范围时,则后续可制得印刷安定性较佳的网点图案,更可提升后续所制得的导光板的辉度。
填充材(C)
本发明的填充材(C)可例如为有机填充材及/或无机填充材。其中,有机填充材的具体例如:环氧树脂、三聚氰胺树脂、尿素树脂、丙烯酸树脂、酚醛树脂、聚酰亚胺树脂、聚酰胺树脂、聚酯树脂以及铁氟龙树脂等。至于无机填充材的具体例如:氧化铝、氢氧化铝、二氧化硅〔例如由触媒化成公司所制造的市售品[商品名如OSCAR 1132(粒径12nm;分散剂为甲醇)、OSCAR 1332(粒径12nm;分散剂为正丙醇)、OSCAR 105(粒径60nm;分散剂为γ-丁内酯)、OSCAR106(粒径120nm;分散剂为二丙酮醇)等];由扶桑化学公司所制造的市售品[商品名如Quartron PL-1-IPA(粒径13nm;分散剂为异丙酮)、Quartron PL-1-TOL(粒径13nm;分散剂为甲苯)、Quartron PL-2L-PGME(粒径18nm;分散剂为丙二醇单甲醚)、Quartron PL-2L-MEK(粒径18nm;分散剂为甲乙酮)等];由日产化学公司所制造的市售品[商品名如IPA-ST(粒径12nm;分散剂为异丙醇)、EG-ST(粒径12nm;分散剂为乙二醇)、IPA-ST-L(粒径45nm;分散剂为异丙醇)、IPA-ST-ZL(粒径100nm;分散剂为异丙醇)等]、氧化镁、氢氧化镁、氧化铁、二氧化钛、氧化锌、氧化锡、氮化硅、氮化铝、滑石〔市售品如商品名SG-2000的滑石(平均粒径1μm,日本滑石制)〕、云母、石绵粉、石英粉、高岭土、膨润土(bentonite)、硅藻土、沸石、石膏、玻璃珠、玻璃纤维、硫酸钡、硫酸镁、碳酸钙、碳酸镁、硅酸钙、硅酸铝、硅酸锆、钛酸钾以及富勒烯(fullerene)等。上述填充材可单独一种或混合多种使用。
本发明的填充材(C)的平均粒径并无特别的限制,通常为10μm以下,较佳为5μm以下,更佳为3μm以下。基于前述的丙烯酸酯系树脂(A)为100重量份,填充材(C)的使用量通常为3重量份至70重量份,然以4重量份至60重量份为较佳,又以5重量份至50重量份为更佳。
溶剂(D)
前述的图案形成用油墨组合物所使用的溶剂(D)的种类并没有特别限制,可选自前述丙烯酸酯系树脂(A)聚合过程中所使用的溶剂,在此不赘述。其中,溶剂(D)以丙二醇单甲基醚、丙二醇单甲基醚醋酸酯、二乙二醇二甲基醚、乳酸乙酯、3-乙氧基丙酸乙酯为较佳。该溶剂(D)可单独一种或混合多种使用。
前述的溶剂(D)的使用量没有特别限制。基于前述的丙烯酸酯系树脂(A)为100重量份计,溶剂(C)的使用量通常为100重量份至500重量份,较佳为150重量份至450重量份,更佳为200重量份至400重量份。
金属氧化物(E)
本发明的金属氧化物(E)可例如为金属氧化物、金属络合物等的金属化合物,具体例如:铁、钴、铝、镉、铅、铜、钛、镁、铬、锌、锑等的金属氧化物,以及前述金属的复合氧化物。
前述的金属氧化物(E)的具体例如:二氧化钛粒子,其市售品如商品名NanoTek系列(C.I化成制),OPTOLAKE系列(日挥触媒化成制),MT-05、MT-100W、MT-100SA、MT-100HD、MT-300HD、MT-150A、ND138、ND139、ND140、ND154、ND165、ND177、TS-063、TS-103、TS-159(TAYCA制),NOD-742GTF(NAGASE CHEMTEX制)等;二氧化锆粒子,其市售品如商品名HXU-110JC、HXU-120JC、HXU-210C、NZD-3101(住友大阪水泥制),ID191(TAYCA制),ZRPMA15WT%-E05(C.I化成制),OZ-S30K(日产化学制)等。上述的金属氧化物(E)可单独一种或混合多种使用。
当前述的图案形成用油墨组合物使用金属氧化物(E)时,可进一步提升所制得的液晶显示元件的辉度。
基于丙烯酸酯系树脂(A)为100重量份,金属氧化物(E)的使用量通常为0.05重量份至5重量份,较佳为0.08重量份至4重量份,更佳为0.1重量份至3重量份。
添加剂(F)
本发明的图案形成用油墨组合物可选择性加入添加剂(F),例如:硅烷偶合剂、消泡剂、分散剂等。
上述的硅烷偶合剂的具体例如:乙烯基三氯硅烷、乙烯基三乙氧基硅烷、乙烯基三(β-甲氧基-乙氧基)硅烷、β-(3,4-环氧环己基)乙基三甲氧基硅烷、3-环氧丙氧丙基三甲氧基硅烷、γ-环氧丙氧丙基甲基二乙氧基硅烷、γ-(甲基)丙烯酰氧丙基三甲氧基硅烷、N-(β-氨乙基)-γ-氨丙基三甲氧基硅烷、N-(β-氨乙基)-γ-氨丙基三甲基二甲氧基硅烷、N-苯基-γ-氨丙基三甲氧基硅烷、γ-氯丙基三甲氧基硅烷、γ-硫醇基丙基三甲氧基硅烷、γ-氨丙基三甲氧基硅烷、双-1,2-(三甲氧基硅基)乙烷,商品名SZ 6030(Dow Corning Toray Silicone制)以及商品名KBE-903、KBE-603、KBE-403与KBM-403(信越化学制)。
其中,基于丙烯酸酯系树脂(A)为100重量份,硅烷偶合剂的含量通常为0重量份至30重量份,然以3重量份至25重量份为较佳,又以5重量份至20重量份为更佳。
上述的消泡剂的具体例如:Surfynol MD-20、Surfynol MD-30、Surfynol DF110D、Surfynol 104E、Surfynol 420、Surfynol DF 37、Surfynol DF 58、SurfynolDF 66、Surfynol DF 70与Surfynol DF 210及EnviroGem AD01、EnviroGem AE01与EnviroGem AE02等(Air products制)。其中,基于丙烯酸酯系树脂(A)为100重量份,消泡剂的含量通常为1重量份至10重量份,然以2重量份至9重量份为较佳,又以3重量份至8重量份为更佳。
上述的分散剂可例如为高分子分散剂、聚乙氧基烷基磷酸酯、聚乙氧基烷基胺、烷醇胺、颜料衍生物等。其中,高分子分散剂的具体例如:聚酰胺-胺(盐)、聚羧酸(盐)、具高分子量的不饱和酸酯类、改质的聚氨酯类、改质的聚酯类、改质的聚(甲基)丙烯酸酯、(甲基)丙烯酸是共聚物、萘磺酸甲醛缩合物等。上述高分子分散剂可根据结构进一步分类为直链型高分子、末端改质型高分子、接枝型高分子以及嵌段型高分子。
前述的分散剂亦可使用市售品,其具体例如:商品名DISPERBYK-101、DISPERBYK-107、DISPERBYK-110、DISPERBYK-130、DISPERBYK-161、DISPERBYK-162、DISPERBYK-163、DISPERBYK-164、DISPERBYK-165、DISPERBYK-166、DISPERBYK-170、BYK-P104、BYK-P105等(BYK Chemie制);商品名EFKA 4047、EFKA 4010至4061、EFKA 4330至4340、EFKA 4400至4402、EFKA 5010、EFKA 6220、6745等(EFKA制);商品名AJISPERPB PB-821、AJISPERPB PB-822等(味之素Fine-Techno制);商品名DISPARLON KS-860、DISPARLON KS-873N、DISPARLON 2150、DISPARLON 7004等(楠本化成制);商品名DEMOL RN、DEMOL N、DEMOL MS、DEMOL C、DEMOL SN-B、HOMOGENOL L-18、ACETAMIN 86等(花王制);商品名SOLSPERSE 5000、SOLSPERSE 22000、SOLSPERSE 13240、SOLSPERSE 3000、SOLSPERSE17000、SOLSPERSE 27000、SOLSPERSE 24000、SOLSPERSE 28000、SOLSPERSE 32000、SOLSPERSE 38500等(Lubrizol制),以及商品名HINOACTT-8000E(川研Fine Chemicals制)。
其中,上述的添加剂(F)可单独一种或混合多种使用。
纤维素树脂(G)
本发明的图案形成用油墨组合物可选择性加入纤维素树脂(G)。所述的纤维素树脂(G)是选自于由醋酸丙酸纤维素(Cellulose Acetate Propionate;CAP)以及醋酸丁酸纤维素(Cellulose Acetate Butyrate;CAB)所组成的一族群中的至少一种。上述的纤维素树脂(G)可为市售品,其中CAP的具体例子可为CAP482-20(美国伊士曼化学有限公司制造),CAB的具体例子可为CAB381-20或CAB381-0.5(美国伊士曼化学有限公司制造)等。
基于丙烯酸酯系树脂(A)为100重量份,纤维素树脂(G)的使用量通常为0.1重量份至10重量份,较佳为0.5重量份至8重量份,更佳为1重量份至5重量份。
基于丙烯酸酯系树脂(A)为100重量份,当纤维素树脂(G)的使用量介于0.1重量份至10重量份时,则后续可制得印刷安定性较佳的网点图案。
图案形成用油墨组合物的制备
本发明的图案形成用油墨组合物的制备,一般是将上述丙烯酸酯系树脂(A)、硬化性树脂(B)、填充材(C)以及溶剂(D),并可视需要加入金属氧化物(E)、各种添加剂(F)及/或纤维素树脂(G),于已知的混合机或分散机中均匀混合,即可制得图案形成用油墨组合物。
导光板
请参阅图1,其是绘示根据本发明一实施例的液晶显示元件100的剖面分解示意图。在一实施例中,液晶显示元件100至少包括导光板110、发光单元120以及液晶面板150。
上述的导光板110包含入光面111、出光面113以及相对于出光面113的底面115,其中,入光面111是形成于导光板110的一侧,且底面115与入光面111形成斜角邻接。其次,导光板110由入光面111的一端向相对的另一端形成厚度递减,使光线均一地由该出光面113射出,如图1所示。
前述的导光板110于底面115形成上述的网点图案117,其中上述的网点图案117可使通过入光面111射入导光板110的光线产生散射与反射,亦即均匀地将光线扩散至各种方向,因此网点图案117并没有排列或尺寸大小上的限制。举例而言,上述的网点图案117于印刷时,可选择形成圆形、四角形或六角形等各种不同的形状,而网点图案117的光散射程度及亮度亦可随着油墨中所使用的材质的不同而改变。
发光单元
请再参阅图1,在前述实施例中,前述的发光单元120可包括上述的导光板110以及发光源131,其中导光板110可与发光源131侧向结合,且入光面111与发光源131相对,使发光源131发出的光线(图未绘示)通过入光面111进入导光板110,并藉由导光板110导引光线朝液晶面板150的方向投射,如图1所示。
前述的发光源131包含光源133及设于光源133外侧的反射罩135,其中光源133可为点光源(例如发光二极体)或线光源(例如灯管)。大体上,前述的反射罩135环绕光源133,但反射罩135于邻向导光板110的单一方向设有开口,使光源133发出的光线直接或藉由反射罩135反射后,通过反射罩135的开口以及入光面111而进入导光板110。
另外,前述的发光单元120更可包含光学组140,其中光学组140包含多个光学元件,例如反射片141、扩散片143及棱镜片145等。上述的反射片141与导光板110的底面115相邻,藉此将通过底面115而射出导光板110的光线,反射通过底面115而射入导光板110。上述的扩散片143与导光板110的出光面113相邻,使经由导光板110并通过出光面113射出的光线能均匀扩散。上述的棱镜片145与扩散片143相邻,其中棱镜片145可凝聚光线,以提高光线向液晶面板150投射的正面亮度。
液晶显示元件
请参阅图2,其是绘示根据本发明一实施例的液晶显示元件的立体分解示意图。本发明的液晶显示元件200至少包括上述的发光单元210、液晶面板220、顶部底盘230以及底部底盘240。
上述的液晶面板220可包含薄膜电晶体(TFT)基板221(以下简称为TFT基板)、彩色滤光片(CF)基板223及含有液晶的液晶层(图未绘示),藉此显示外部影像。
其次,印刷电路板225设有驱动晶片(图未绘示),并透过卷带承载封装件(tape carrier package)227连接至TFT基板221。上述显示外部影像所需要的各种讯号,可藉由印刷电路板225及驱动晶片(图未绘示)传递至TFT基板221。
另外,前述的顶部底盘230可与底部底盘240连接。上述的底部底盘240的上方部分形成开放的收纳空间,其中底部底盘240于收纳空间的周围部分可支撑液晶面板220,而收纳空间则可容设上述的发光单元210。上述的发光单元210所提供的光线可通过液晶面板200,而显示外部影像。
上述的顶部底盘230则覆盖并固定液晶面板220的外缘,以防止印刷电路板225曝露于外界。上述的顶部底盘230中间设有开口,藉此曝露出液晶面板220的影像显示区域。
在此补充的是,图1及图2是作为说明之用,且本发明并非限定于此。因此,本发明的发光单元亦能够应用到其它类型的显示设备;本发明的液晶显示元件亦能够使用其它类型的光学元件,例如:偏光片等。
以下利用数个实施方式以说明本发明的应用,然其并非用以限定本发明,本发明技术领域中具有通常知识者,在不脱离本发明的精神和范围内,当可作各种的更动与润饰。
附图说明
为让本发明的上述和其它目的、特征、优点与实施例能更明显易懂,所附图式的说明如下:
图1是绘示根据本发明一实施例的液晶显示元件的剖面分解示意图;
图2是绘示根据本发明一实施例的液晶显示元件的立体分解示意图;
图3是绘示根据本发明一实施例的辉度评价方式的上视图;
其中,符号说明:
100:液晶显示元件 110:导光板
111:入光面 113:出光面
115:底面 117:网点图案
120:发光单元 131:发光源
133:光源 135:反射罩
140:光学组 141:反射片
143:扩散片 145:棱镜片
150:液晶面板 200:液晶显示元件
210:发光单元 220:液晶面板
221:薄膜电晶体基板 223:彩色滤光片基板
225:印刷电路板 227:卷带承载封装件
230:顶部底盘 240:底部底盘
300:导光板 301/302/303/304:边界
310:光源 A1至A9:测定点。
具体实施方式
制备丙烯酸酯系树脂(A)
以下是根据表1制备合成例A-1至A-6的丙烯酸酯系树脂(A)。
合成例A-1
将15重量份的甲基丙烯酸-2-羟基乙酯(以下简称HEMA)、40重量份的甲基丙烯酸甲酯(以下简称MMA)、20重量份的丙烯酸正丁酯(以下简称n-BA)、25重量份的苯乙烯(以下简称SM)及1重量份的偶氮二异戊腈(以下简称AMBN),利用游星式搅拌装置(型号为ARB-310;THINKY制)搅拌均匀,并于80℃下进行热聚合反应,反应24小时后,可得丙烯酸酯系树脂(A-1)。
合成例A-2至A-6
同合成例A-1的丙烯酸酯系树脂的合成方法,不同处在于合成例A-2至A-6是改变丙烯酸酯系树脂(A)中反应物的种类及使用量,其配方如表1所示,此处不另赘述。
制备硬化性树脂(B)
合成例B-1
将120重量份的双酚F型环氧树脂(三菱化学制造;商品名为jER806;环氧基当量为160g/eq)、300重量份的二乙二醇单***改性的硅氧树脂(信越硅氧树脂制造;商品名为KF-6001;羟基当量为62mgKOH/g)、300重量份的丙二醇单丙醚,以及0.2重量百分比的乙基三苯基醋酸膦(以双酚F型环氧树脂与二乙二醇单***改性的硅氧树脂的总固含量为100重量百分比)加入反应容器中,在氮气环境及180℃下进行聚合反应达5小时,以制得氢化双酚F型环氧树脂改性硅氧树脂(B-1)。
合成例B-2
将140重量份的氢化双酚A型环氧树脂(三菱化学制造;商品名为YX8000;环氧基当量为205g/eq)、300重量份的二乙二醇单***改性的硅氧树脂(信越硅氧树脂制造;商品名为KF-6001;羟基当量为62mgKOH/g)、300重量份的丙二醇单丙醚,以及0.2重量百分比的乙基三苯基醋酸膦(以树脂的固含量为100重量百分比)加入反应容器中,在氮气环境及180℃下进行聚合反应达5小时,以制得氢化双酚A型环氧树脂改性硅氧树脂(B-2)。
合成例B-3
将150重量份的双酚F型环氧树脂(三菱化学制造;商品名为jER806;环氧基当量为160g/eq)、300重量份的二乙二醇单***改性的硅氧树脂(信越硅氧树脂制造;商品名为KF-6001;羟基当量为62mgKOH/g)、300重量份的丙二醇单丙醚,以及0.2重量百分比的乙基三苯基醋酸膦(以双酚F型环氧树脂与二乙二醇单***改性的硅氧树脂的总固含量为100重量百分比)加入反应容器中,在氮气环境及180℃下进行聚合反应达5小时,以制得氢化双酚F型环氧树脂改性硅氧树脂(B-3)。
制备图案形成用油墨组合物
以下是根据表2制备实施例1至9及比较例1至3的图案形成用油墨组合物。
实施例1
将100重量份由合成例A-1所得的丙烯酸酯系树脂(A-1)、由合成例B-1所得1重量份的氢化双酚F型环氧树脂改性硅氧树脂(B-1)、3重量份的二氧化硅(商品名:IPA-ST,日产化学制)(C-1)以及100重量份的二乙二醇二甲基醚(diethyleneglycol dimethyl ether,以下简称为D-1),以游星式搅拌装置搅拌均匀后,再以三滚筒机(型号为FC-90mm,繁锠有限公司制)混合3小时,即可制得图案形成用油墨组合物。所得的图案形成用油墨组合物以下列各评价方式进行评价,其结果如表2所述,其中印刷安定性以及辉度的检测方法容后再述。
实施例2至9及比较例1至3
同实施例1的图案形成用油墨组合物的制备方法,不同处在于实施例2至9及比较例1至3是改变图案形成用油墨组合物中原料的种类及使用量,其配方以及评价结果如表2所示,此处不另赘述。
评价方式
1.印刷安定性
使用网印机(型号为PA3-F34,妙印精机制)将图案形成用油墨组合物于32吋的导光板(材料为透明PMMA树脂,厚度为3mm)上印刷300mm2的网点,经下式(II)计算网点印刷的尺寸误差,并依据以下基准进行评价。
◎:网点印刷完全,且尺寸误差大于20%的网点数目低于1%。
○:网点印刷完全,且尺寸误差大于20%的网点数目占于1%至5%。
△:网点印刷完全,且尺寸误差大于20%的网点数目高于5%。
╳:油墨出现漏墨或塞网的现象,造成网点印刷不完全。
2.辉度
请参照图3,其是绘示根据本发明一实施例的辉度评价方式的上视图。首先,利用网印机(型号为PA3-F34;妙印精机制),将实施例1至9以及比较例1至3的图案形成用油墨组合物,于32吋的导光板300(材料为透明PMMA树脂;厚度为3mm)上,自光源端依序印刷上300mm2、400mm2、500mm2、600mm2、700mm2、800mm2及900mm2的网点,如图3所示。
接着,将印刷有图案形成用油墨组合物的导光板于70℃下干燥30分钟后,利用LED 9000K光源310照射导光板300达1小时。之后,利用辉度计(型号为BM-7A;Topcon制)量测辉度,其测定点(A1至A9)亦如图3所示,其中,A1、A2与A8与导光板300的边界301的距离、A2至A4与导光板300的边界304的距离、A4至A6与导光板300的边界303的距离、A6至A8与导光板300的边界302的距离皆为20mm。经下式(III)计算后可得一平均辉度(cd/m2),并依据以下基准进行评价。在式(III)中,L1至L9分别表示A1至A9的辉度。
平均辉度(cd/m2)=(L1+L2+L3+L4+L5+L6+L7+L8+L9)/9 式(III)
◎:平均辉度>800
○:800≧平均辉度>700
△:700≧平均辉度>600
╳:平均辉度≦600
上述实施例与比较例所得的图案形成用油墨组合物,其印刷安定性及辉度的评估结果如表2所示。
如表2实施例1至9的结果可知,当图案形成用油墨组合物含有硬化性树脂(B)时,其印刷安定性及辉度较佳,尤其当硬化性树脂(B)的使用量落于本案所主张的2重量份至20重量份,且含有金属氧化物(E)及/或纤维素树脂(G)时,其可达更高的印刷安定性及辉度。
另一方面,如表2的比较例1至3所示,当图案形成用油墨组合物不含硬化性树脂(B)时,其印刷安定性及辉度不佳。此外,如比较例2所示,虽然添加金属氧化物(E)可稍微提升辉度,但仍无法使图案形成用油墨组合物所制得的导光板达700以上的平均辉度。
需补充的是,本发明虽以特定的化合物、组成、反应条件、制程、分析方法或特定仪器作为例示,说明本发明的导光板、发光单元以及具有该发光单元的液晶显示元件,惟本发明所属技术领域中任何具有通常知识者可知,本发明并不限于此,在不脱离本发明的精神和范围内,本发明的导光板、发光单元以及具有该发光单元的液晶显示元件亦可使用其它的化合物、组成、反应条件、制程、分析方法或仪器进行。
虽然本发明已以实施方式揭露如上,然其并非用以限定本发明,在本发明所属技术领域中任何具有通常知识者,在不脱离本发明的精神和范围内,当可作各种的更动与润饰,因此本发明的保护范围当视后附的权利要求书所界定的范围为准。
Claims (9)
1.一种导光板,其特征在于包含:
入射光线的入光面;
出射光线的出光面;以及
相对于所述出光面的底面,其中所述底面具有导光层,所述导光层是使用图案形成用油墨组合物经涂布处理及干燥处理后,于所述底面形成网点图案,且所述图案形成用油墨组合物包含:
丙烯酸酯系树脂(A);
如下式(I)所示结构的硬化性树脂(B);
填充材(C);以及
溶剂(D);
于式(I)中,p、m及n分别为1至500的整数;R1代表氢原子及/或甲基;R2代表碳数为1至6的直链烷基或碳数为3至6的支链烷基;A代表苯环或环己烷;X代表CR2、氧原子、亚磺基或硫原子;Y代表环氧基、氧杂环丁烷基或脂环族环氧基的结构;Y’代表环氧基、氧杂环丁烷基或脂环族环氧基的开环结构;以及R代表氢原子及/或甲基。
2.如权利要求1所述的导光板,其特征在于其中基于所述丙烯酸酯系树脂(A)为100重量份,所述硬化性树脂(B)的使用量为2重量份至20重量份,所述填充材(C)的使用量为3重量份至70重量份,且所述溶剂(D)的使用量为100重量份至500重量份。
3.如权利要求1所述的导光板,其特征在于其中所述图案形成用油墨组合物更包含金属氧化物(E)。
4.一种发光单元,其特征在于包含:
发光源;以及
与所述发光源结合,且底面具有导光层的导光板;且
其中所述导光层是使用图案形成用油墨组合物经涂布及干燥处理后,以于所述底面上形成网点图案,且所述图案形成用油墨组合物包含:
丙烯酸酯系树脂(A);
如下式(I)所示结构的硬化性树脂(B);
填充材(C);以及
溶剂(D);
于式(I)中,p、m及n分别为1至500的整数;R1代表氢原子及/或甲基;R2代表碳数为1至6的直链烷基或碳数为3至6的支链烷基;A代表苯环或环己烷;X代表CR2、氧原子、亚磺基或硫原子;Y代表环氧基、氧杂环丁烷基或脂环族环氧基的结构;Y’代表环氧基、氧杂环丁烷基或脂环族环氧基的开环结构;以及R代表氢原子及/或甲基。
5.如权利要求4所述的发光单元,其特征在于其中基于所述丙烯酸酯系树脂(A)为100重量份,所述硬化性树脂(B)的使用量为2重量份至20重量份,所述填充材(C)的使用量为3重量份至70重量份,且所述溶剂(D)的使用量为100重量份至500重量份。
6.如权利要求4所述的发光单元,其特征在于其中所述图案形成用油墨组合物更包含金属氧化物(E)。
7.一种液晶显示元件,其特征在于包含:
发光源;
与所述发光源结合,且底面具有导光层的导光板;以及
设置于所述导光板的出光面上方的液晶面板;且
其中所述导光层是使用图案形成用油墨组合物经涂布及干燥处理后,以于所述底面形成网点图案,且所述图案形成用油墨组合物包含:
丙烯酸酯系树脂(A);
如下式(I)所示结构的硬化性树脂(B);
填充材(C);以及
溶剂(D);
于式(I)中,p、m及n分别为1至500的整数;R1代表氢原子及/或甲基;R2代表碳数为1至6的直链烷基或碳数为3至6的支链烷基;A代表苯环或环己烷;X代表CR2、氧原子、亚磺基或硫原子;Y代表环氧基、氧杂环丁烷基或脂环族环氧基的结构;Y’代表环氧基、氧杂环丁烷基或脂环族环氧基的开环结构;以及R代表氢原子及/或甲基。
8.如权利要求7所述的液晶显示元件,其特征在于其中基于所述丙烯酸酯系树脂(A)为100重量份,所述硬化性树脂(B)的使用量为2重量份至20重量份,所述填充材(C)的使用量为3重量份至70重量份,且所述溶剂(D)的使用量为100重量份至500重量份。
9.如权利要求7所述的液晶显示元件,其特征在于其中所述图案形成用油墨组合物更包含金属氧化物(E)。
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