CN106011864A - Aerosol type metal decontaminating polishing agent and preparation method thereof - Google Patents
Aerosol type metal decontaminating polishing agent and preparation method thereof Download PDFInfo
- Publication number
- CN106011864A CN106011864A CN201610429355.1A CN201610429355A CN106011864A CN 106011864 A CN106011864 A CN 106011864A CN 201610429355 A CN201610429355 A CN 201610429355A CN 106011864 A CN106011864 A CN 106011864A
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- CN
- China
- Prior art keywords
- type metal
- polisher
- aerial fog
- fog type
- metal decontamination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F3/00—Brightening metals by chemical means
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/024—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing hydrocarbons
Abstract
The invention provides an aerosol type metal decontaminating polishing agent and a preparation method thereof. The aerosol type metal decontaminating polishing agent comprises the following components in percentage by weight: 25.0-35.0% of a fatty hydrocarbon solvent, 1.0-3.0% of limonene, 0.5-1.0% of oleic acid, 0.5-1.5% of triethanolamine, 3-6% of a non-ionic emulsifier, 5-10% of aluminum oxide, 5-10% of diatomite, 5-10% of quartz powder, 0.5-1.5% of modified nano silicon dioxide, 30-40% of deionized water, 5-15% of isopropanol and 5-10% of a propellant. The preparation method for the aerosol type metal decontaminating polishing agent comprises the following steps: preparing a composition of the aerosol type metal decontaminating polishing agent by adopting an emulsifying process; and canning the composition into an aerosol tank; and adding a proper of propellant after sealing the aerosol tank, thereby obtaining the aerosol type metal decontaminating polishing agent. Process operations are simple; and the prepared metal decontaminating polishing agent is safe, is environmentally-friendly, and is convenient to use.
Description
Technical field
The present invention relates to intermetallic composite coating auxiliary agent field, particularly relate to a kind of aerial fog type metal decontamination polisher and
Its preparation method.
Background technology
Metallic article in use, owing to air aoxidizing, moist or contact chemical substance and corrosion
Property the reason such as gas, cause surface of metal product corrosion, adhere to foul greasy dirt situation, in order to increase metal
Product surface is bright and clean, usually uses the metal detergent of chemistry to process.Along with communal facility and life
Applying flexibly the modernization day by day of product, the utilization rate of metallic article is more and more higher, and metal polish is made by people
The most urgent by demand.Metal polish is applicable to the products such as rustless steel, copper, silver, aluminum and plating
Clean wiping light.
Current domestic main use medal polish cream as polish product, but due to tradition antiscuffing paste be by grinding
The raw material compositions such as material, oils and fats and solvent, due to the difference of abrasive material used, the difference of fat type, make
Antiscuffing paste defines multiple different product, uses in various different occasions.So the application of series products
Scope is narrower, and there is poor fluidity, construction inconvenience, and asks the pollution of environment is the most serious etc.
Topic.And liquid metals polisher product typically contains strong acid or phosphate, pollute environment, cleaning efficiency
Relatively low.Along with the raising of environmental requirement, both at home and abroad to volatile organic matter (Volatile Organic
Compounds, VOC) use of solvent limits, therefore, develops the most environmental and price
The most cheap metal decontamination polisher becomes an urgent demand in market.
Summary of the invention
It is an object of the invention to provide a kind of aerial fog type metal decontamination polisher, VOC solvent content is low,
And product stability and mobility are preferably, use aerosol packaging, product is easy to use.
Another object of the present invention is to provide the preparation method of a kind of aerial fog type metal decontamination polisher, work
Skill is simple to operate, prepared metal decontamination polisher safety and environmental protection, easy to use.
For achieving the above object, the present invention provides a kind of aerial fog type metal decontamination polisher, comprise component and
Its percentage by weight is as follows:
Aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine
0.5-1.5%；Nonionic emulsifier 3-6%；Aluminium oxide 5-10%；Kieselguhr 5-10%；Silica flour 5-
10%；Modified manometer silicon dioxide 0.5-1.5%；Deionized water 30-40%；Isopropanol 5-15%；Throw
Penetrate agent 5-10%.
Described aliphatic solvent is Isopars, and boiling range is 190-230 DEG C.
Described nonionic emulsifier is sorbitan fatty ester, and its hydroxyl value is 190-220
MgKOH/g, saponification number is 140-160mgKOH/g, and hydrophile-lipophile balance value is between 4-6.
The particle diameter of described modified manometer silicon dioxide is 0.2-0.3 μm, and specific surface area is 150-250m2/g。
Described propellant is dimethyl ether.
The present invention also provides for the preparation method of a kind of aerial fog type metal decontamination polisher, comprises the steps:
Step 1, on the basis of the gross weight of the anticipated aerial fog type metal decontamination polisher prepared, press respectively
Part by weight weigh aliphatic solvent 25.0-35.0%, limonene 1.0-3.0%, oleic acid 0.5-1.0%, three
Ethanolamine 0.5-1.5%, nonionic emulsifier 3-6%, aluminium oxide 5-10%, kieselguhr 5-10%, quartz
Powder 5-10%, modified manometer silicon dioxide 0.5-1.5%, deionized water 30-40%, isopropanol 5-15%,
Propellant is prepared by the part by weight of 5-10%；
Step 2, aliphatic solvent, limonene, oleic acid, triethanolamine and non-ionic emulsifier by weighing up
Agent mixing and stirring, obtains preliminary mixed solution；
Step 3, aluminium oxide by weighing, kieselguhr and silica flour add in described preliminary mixed liquor,
Under 2000-2500r/min high-speed stirred effect, by the isopropanol weighed and going that a part weighs
Ionized water is slowly added to after mixing by the volume ratio of 1-2:1, then proceed to be slowly added to surplus go from
Sub-water, dispersion and emulsion 10-20min；
Step 4, offer inhalator jar, load after material filtering step 3 obtained in described inhalator jar,
Load onto valve Zha Gai, according to the part by weight of 5-10% in pre-prepared aerial fog type metal decontamination polisher
It is filled with propellant.
Described aliphatic solvent is Isopars, and boiling range is 190-230 DEG C.
Described nonionic emulsifier is sorbitan fatty ester, and its hydroxyl value is 190-220
MgKOH/g, saponification number is 140-160mgKOH/g, and hydrophile-lipophile balance value is between 4-6.
The particle diameter of described modified manometer silicon dioxide is 0.2-0.3 μm, and specific surface area is 150-250m2/g。
Described propellant is dimethyl ether.
Beneficial effects of the present invention: the aerial fog type metal decontamination polisher of the present invention, for oil-in-water
(O/W) type emulsion, have employed substantial amounts of water and replaces volatile solvent, greatly reduce cost, gas
Taste is less, reduces VOC release, improves environmental-protecting performance, and product stability and mobility are preferably,
Use aerosol packaging so that product uses convenient, stable storing, it is not easy to gag somebody, can be rapidly
Remove corrosion material and the greasy dirt of metal surface, can quickly improve the brightness of metal surface, exist simultaneously
Metal surface forms protecting film and alleviates the corrosion of metal surface and oxidation, it is adaptable to rustless steel, copper, silver,
The clean wiping light of the product such as aluminum and plating, improves product serviceability.The aerial fog type of the present invention
The preparation method of metal decontamination polisher, makes a kind of aerial fog type metal decontamination initially with emulsifying process
The compositions of polisher, and by canned for said composition to inhalator jar, after sealing, it is filled with appropriate propellant,
To aerial fog type metal decontamination polisher, technological operation is simple, prepared metal decontamination polisher safety collar
Protect, easy to use.
Accompanying drawing explanation
In order to be able to be further understood that inventive feature and technology contents, refer to below in connection with this
Bright detailed description and accompanying drawing, but accompanying drawing only provides reference and explanation use, is not used for adding the present invention
To limit.
In accompanying drawing,
Fig. 1 is the process chart of the manufacture method of the aerial fog type ceramic tile non-skid coating of the present invention.
Detailed description of the invention
By further illustrating the technological means and effect thereof that the present invention taked, below in conjunction with the present invention's
Preferred embodiment and accompanying drawing thereof are described in detail.
Present invention firstly provides a kind of aerial fog type metal decontamination polisher, comprise component and percentage by weight thereof
As follows:
Aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine
0.5-1.5%；Nonionic emulsifier 3-6%；Aluminium oxide 5-10%；Kieselguhr 5-10%；Silica flour 5-
10%；Modified manometer silicon dioxide 0.5-1.5%；Deionized water 30-40%；Isopropanol 5-15%；Throw
Penetrate agent 5-10%.
Specifically, described aliphatic solvent is Isopars, and boiling range is 190-230 DEG C, described fat
Hydrocarbon solvent is preferably isomery hexadecane hydrocarbon solvent.
Specifically, described nonionic emulsifier is sorbitan fatty ester, and its hydroxyl value is 190-220
MgKOH/g, saponification number is 140-160mgKOH/g, and hydrophile-lipophile balance value is between 4-6.
Specifically, the particle diameter of described modified manometer silicon dioxide is 0.2-0.3 μm, and specific surface area is 150-
250m2/ g, preferably specific surface area are 200m2/g。
Specifically, described propellant is dimethyl ether (DME).
The aerial fog type metal decontamination polisher of the present invention, for oil-in-water emulsion, have employed substantial amounts of water
Replacing volatile solvent, greatly reduce cost, abnormal smells from the patient is less, reduces VOC release, improves ring
Guaranteed cost, and product stability and mobility are preferably, use aerosol packaging so that product uses more
Convenient, stable storing, it is not easy to gag somebody, corrosion material and the greasy dirt of metal surface can be rapidly removed, can
Quickly to improve the brightness of metal surface, form protecting film simultaneously in metal surface and alleviate metal surface
Corrosion and oxidation, it is adaptable to the clean wiping light of the products such as rustless steel, copper, silver, aluminum and plating,
Improve product serviceability.
Referring to Fig. 1, the present invention also provides for the preparation method of a kind of aerial fog type metal decontamination polisher, bag
Include following steps:
Step 1, on the basis of the gross weight of the anticipated aerial fog type metal decontamination polisher prepared, press respectively
Part by weight weigh aliphatic solvent 25.0-35.0%, limonene 1.0-3.0%, oleic acid 0.5-1.0%, three
Ethanolamine 0.5-1.5%, nonionic emulsifier 3-6%, aluminium oxide 5-10%, kieselguhr 5-10%, quartz
Powder 5-10%, modified manometer silicon dioxide 0.5-1.5%, deionized water 30-40%, isopropanol 5-15%,
Propellant is prepared by the part by weight of 5-10%.
Specifically, described aliphatic solvent is Isopars, and boiling range is 190-230 DEG C, described fat
Hydrocarbon solvent is preferably isomery hexadecane hydrocarbon solvent.
Specifically, described nonionic emulsifier is sorbitan fatty ester, and its hydroxyl value is 190-220
MgKOH/g, saponification number is 140-160mgKOH/g, and hydrophile-lipophile balance value is between 4-6.
Specifically, the particle diameter of described modified manometer silicon dioxide is 0.2-0.3 μm, and specific surface area is 150-
250m2/ g, preferably specific surface area are 200m2/g。
Step 2, aliphatic solvent, limonene, oleic acid, triethanolamine and non-ionic emulsifier by weighing up
Agent mixing and stirring, obtains preliminary mixed solution.
Step 3, aluminium oxide by weighing, kieselguhr and silica flour add in described preliminary mixed liquor,
Under 2000-2500r/min high-speed stirred effect, by the isopropanol weighed and going that a part weighs
Ionized water is slowly added to after mixing by the volume ratio of 1-2:1, then proceed to be slowly added to surplus go from
Sub-water, dispersion and emulsion 10-20min.
Step 4, offer inhalator jar, load after material filtering step 3 obtained in described inhalator jar,
Load onto valve Zha Gai, according to the part by weight of 5-10% in pre-prepared aerial fog type metal decontamination polisher
It is filled with propellant.
Concrete, described propellant is dimethyl ether.
In sum, the aerial fog type metal decontamination polisher of the present invention, for oil-in-water (O/W) type emulsifying
Liquid, have employed substantial amounts of water and replaces volatile solvent, greatly reduce cost, and abnormal smells from the patient is less, reduces
VOC discharges, and improves environmental-protecting performance, and product stability and mobility are preferably, use aerosol bag
Dress so that product uses convenient, stable storing, it is not easy to gag somebody can rapidly remove metal surface
Corrosion material and greasy dirt, can quickly improve the brightness of metal surface, be formed in metal surface simultaneously
Protecting film alleviates corrosion and the oxidation of metal surface, it is adaptable to rustless steel, copper, silver, aluminum and plating etc.
The clean wiping light of product, improves product serviceability.The aerial fog type metal decontamination of the present invention is polished
The preparation method of agent, makes the combination of a kind of aerial fog type metal decontamination polisher initially with emulsifying process
Thing, and by canned for said composition to inhalator jar, after sealing, it is filled with appropriate propellant, obtain aerial fog type metal
Decontamination polisher, technological operation is simple, and prepared metal decontamination polisher safety and environmental protection uses just
Prompt.
The above, for the person of ordinary skill of the art, can be according to the technical side of the present invention
Other various corresponding changes and deformation are made in case and technology design, and all these change and deformation are all answered
Belong to the protection domain of appended claims of the present invention.
Claims (10)
1. an aerial fog type metal decontamination polisher, it is characterised in that comprise component and percentage by weight thereof
As follows:
Aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine
0.5-1.5%；Nonionic emulsifier 3-6%；Aluminium oxide 5-10%；Kieselguhr 5-10%；Silica flour 5-
10%；Modified manometer silicon dioxide 0.5-1.5%；Deionized water 30-40%；Isopropanol 5-15%；Throw
Penetrate agent 5-10%.
2. aerial fog type metal decontamination polisher as claimed in claim 1, it is characterised in that described fat
Fat hydrocarbon solvent is Isopars, and boiling range is 190-230 DEG C.
3. aerial fog type metal decontamination polisher as claimed in claim 1, it is characterised in that described non-
Ionic emulsifying agent is sorbitan fatty ester, and its hydroxyl value is 190-220mgKOH/g, saponification number
For 140-160mgKOH/g, hydrophile-lipophile balance value is between 4-6.
4. aerial fog type metal decontamination polisher as claimed in claim 1, it is characterised in that described in change
The particle diameter of property nano silicon is 0.2-0.3 μm, and specific surface area is 150-250m2/g。
5. aerial fog type metal decontamination polisher as claimed in claim 1, it is characterised in that described throwing
Penetrating agent is dimethyl ether.
6. the preparation method of an aerial fog type metal decontamination polisher, it is characterised in that include walking as follows
Rapid:
Step 1, on the basis of the gross weight of the anticipated aerial fog type metal decontamination polisher prepared, press respectively
Part by weight weigh aliphatic solvent 25.0-35.0%, limonene 1.0-3.0%, oleic acid 0.5-1.0%, three
Ethanolamine 0.5-1.5%, nonionic emulsifier 3-6%, aluminium oxide 5-10%, kieselguhr 5-10%, quartz
Powder 5-10%, modified manometer silicon dioxide 0.5-1.5%, deionized water 30-40%, isopropanol 5-15%,
Propellant is prepared by the part by weight of 5-10%；
Step 2, aliphatic solvent, limonene, oleic acid, triethanolamine and non-ionic emulsifier by weighing up
Agent mixing and stirring, obtains preliminary mixed solution；
Step 3, aluminium oxide by weighing, kieselguhr and silica flour add in described preliminary mixed liquor,
Under 2000-2500r/min high-speed stirred effect, by the isopropanol weighed and going that a part weighs
Ionized water is slowly added to after mixing by the volume ratio of 1-2:1, then proceed to be slowly added to surplus go from
Sub-water, dispersion and emulsion 10-20min；
Step 4, offer inhalator jar, load after material filtering step 3 obtained in described inhalator jar,
Load onto valve Zha Gai, according to the part by weight of 5-10% in pre-prepared aerial fog type metal decontamination polisher
It is filled with propellant.
7. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 6, its feature exists
In, described aliphatic solvent is Isopars, and boiling range is 190-230 DEG C.
8. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 6, its feature exists
In, described nonionic emulsifier is sorbitan fatty ester, and its hydroxyl value is 190-220
MgKOH/g, saponification number is 140-160mgKOH/g, and hydrophile-lipophile balance value is between 4-6.
9. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 6, its feature exists
In, the particle diameter of described modified manometer silicon dioxide is 0.2-0.3 μm, and specific surface area is 150-250m2/g。
10. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 6, its feature exists
In, described propellant is dimethyl ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610429355.1A CN106011864B (en) | 2016-06-16 | 2016-06-16 | Aerial fog type metal decontamination polisher and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610429355.1A CN106011864B (en) | 2016-06-16 | 2016-06-16 | Aerial fog type metal decontamination polisher and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106011864A true CN106011864A (en) | 2016-10-12 |
| CN106011864B CN106011864B (en) | 2019-10-08 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674928A (en) * | 2017-10-22 | 2018-02-09 | 吴安婕 | Leather maintaining agent and leather maintaining method |
| CN111304665A (en) * | 2019-10-18 | 2020-06-19 | 广东莱雅新化工科技有限公司 | Rust removing and preventing agent |
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| US3930870A (en) * | 1973-12-28 | 1976-01-06 | International Business Machines Corporation | Silicon polishing solution preparation |
| CN1354214A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Metal polishing agent |
| CN101230310A (en) * | 2007-01-25 | 2008-07-30 | 3M创新有限公司 | Cleaning method and combination |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107674928A (en) * | 2017-10-22 | 2018-02-09 | 吴安婕 | Leather maintaining agent and leather maintaining method |
| CN107674928B (en) * | 2017-10-22 | 2019-10-25 | 三门华迈化工产品有限公司 | Leather maintaining agent and leather maintaining method |
| CN111304665A (en) * | 2019-10-18 | 2020-06-19 | 广东莱雅新化工科技有限公司 | Rust removing and preventing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106011864B (en) | 2019-10-08 |
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