CN106010156A - Electric iron antistatic paint and preparation method thereof - Google Patents
Electric iron antistatic paint and preparation method thereof Download PDFInfo
- Publication number
- CN106010156A CN106010156A CN201610663308.3A CN201610663308A CN106010156A CN 106010156 A CN106010156 A CN 106010156A CN 201610663308 A CN201610663308 A CN 201610663308A CN 106010156 A CN106010156 A CN 106010156A
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- Prior art keywords
- parts
- antistatic
- electric iron
- preparation
- catalyst
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses electric iron antistatic paint. The electric iron antistatic paint comprises the following raw materials: organosilicon-modified polyester resin, a pure acrylic emulsion, polyanionic cellulose, epoxy resin, maleate, ferrotitanium powder, isobutanol, propylene glycol monoethyl ether, a proper amount of water, a catalyst, an antistatic auxiliary agent, aluminium hydroxide, n-butyl acetate, and pentaerythritol. A preparation method comprises the following steps: 1) preparing a preliminary mixing solution; 2) preparing an intermediate solution; 3) preparing a mixing solution; and 4) putting the mixing solution obtained in the step 3) in a bowl mill for grinding treatment, and sieving the material to obtain the finished product. The preparation method has the advantages of scientific and reasonable performances, by employing the organic polymer materials with good comprehensive properties and performing optimization and combination, antistatic performance of the composition is increased, cost is low, production period is short, and the antistatic paint is adapted to industrial batch production.
Description
Technical field
The invention belongs to coating industry technical field, particularly relate to a kind of electric iron antistatic coating and preparation method thereof.
Background technology
Coating, at the entitled paint of Chinese tradition, refer to coat body surface can form thin film under certain conditions and rise protection,
One class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Because of coating in early days
Mostly with vegetable oil as primary raw material, therefore also referred to as paint.Now synthetic resin instead of vegetable oil, therefore referred to as coating.It is coated with
Material belongs to organic chemical industry's macromolecular material, and the film formed belongs to macromolecular compound type.The chemical industry current according to the modern times produces
The classification of product, coating belongs to fine chemical product.Modern coating the most progressively becomes a polyfunctional engineering material of class, is
An important industry in chemical industry.At present, the coating industry of China is the most ripe, and market is close to saturated, in addition in green
Under the overall situation of economic globalization, people become more concerned with economy the most flourishing after, environment is by great destruction.Along with new " ring
Guarantor's method " to promulgate, the environmental protection such as country's " environmental protection, beautiful China " advocates the most no longer to stay on slogan, but implements
Perform, implement to promote energetically the development of green science and technology industry.
At present, the covering with paint of household electrical appliance has had bigger change, and traditional thermohardening lacquer is by the water paint of environmental protection
Deng substituting, but different electrical equipment has different requirements due to the difference of the aspects such as function to coating, and more environmentally friendly, more individual character is
Become the pursuit direction of household electrical appliances coating.The market demand huge in the face of household electrical appliances coating and ever-increasing application prospect, strengthen
R&D intensity, updates and improving product performance, accelerates product quality upgrading, develop technically, on cost, performance
On more show the household electrical appliances coating of powerful competitive advantage there is the meaning of reality and the wide market space.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of electric iron antistatic coating and preparation thereof
Method, this coating products excellent performance, there are good antistatic property, and energy-conserving and environment-protective, possess preferable economic benefit and
Social benefit.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of electric iron antistatic coating, is prepared by the raw materials in: silicone modified polyester resin 35～45 parts, pure
Acrylic emulsion 10～15 parts, polyanion cellulose 2～5 parts, epoxy resin 5～12 parts, maleic acid 8～15 parts, ferrotitanium powder
2～6 parts, isobutanol 1～3 parts, propylene-glycol ethyl ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts, antistatic auxiliary 1.5～
2.5 parts, aluminium hydroxide 1～5 parts, butyl acetate 5～10 parts, tetramethylolmethane 5～12 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrotitanium powder, isobutanol, propylene-glycol ethyl ether, aluminium hydroxide and suitable quantity of water are joined in reaction vessel,
It is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of silicone modified polyester resin, pure-acrylic emulsion, polyanion cellulose, epoxy resin and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and season penta 4
Alcohol, mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described antistatic auxiliary is alkyl quaternary ammonium salts.
The beneficial effects of the present invention is:
Preparation method of the present invention is scientific and reasonable, by using combination property preferably high-molecular organic material and carrying out optimum organization,
Improve the antistatic property of compositions, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, draws
Stretching the indexs such as intensity and be superior to common coating, can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, real
Having showed making full use of of resource and the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production, tool
Standby preferable economic benefit and social benefit.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of electric iron antistatic coating, is prepared by the raw materials in: silicone modified polyester resin 35 parts, pure third breast
Liquid 10 parts, polyanion cellulose 2 parts, epoxy resin 5 parts, maleic acid 8 parts, 2 parts of ferrotitanium powder, isobutanol 1 part, third
Glycol ether 6 parts, water are appropriate, catalyst 1.5 parts, antistatic auxiliary 1.5 parts, aluminium hydroxide 1 part, butyl acetate 5 parts,
Tetramethylolmethane 5 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrotitanium powder, isobutanol, propylene-glycol ethyl ether, aluminium hydroxide and suitable quantity of water are joined in reaction vessel,
It is heated to 50～65 DEG C, stirs 20 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of silicone modified polyester resin, pure-acrylic emulsion, polyanion cellulose, epoxy resin and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and season penta 4
Alcohol, mix and blend 50 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
Embodiment 2:
A kind of electric iron antistatic coating, is prepared by the raw materials in: silicone modified polyester resin 45 parts, pure third breast
Liquid 15 parts, polyanion cellulose 5 parts, epoxy resin 12 parts, maleic acid 15 parts, 6 parts of ferrotitanium powder, isobutanol 3 parts,
Propylene-glycol ethyl ether 12 parts, water are appropriate, catalyst 3 parts, antistatic auxiliary 2.5 parts, aluminium hydroxide 5 parts, butyl acetate 10
Part, tetramethylolmethane 12 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrotitanium powder, isobutanol, propylene-glycol ethyl ether, aluminium hydroxide and suitable quantity of water are joined in reaction vessel,
It is heated to 50～65 DEG C, stirs 30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of silicone modified polyester resin, pure-acrylic emulsion, polyanion cellulose, epoxy resin and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and season penta 4
Alcohol, mix and blend 80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
In the above embodiment of the present invention:
Described catalyst is sulfonic acid zinc；
Described antistatic auxiliary is alkyl quaternary ammonium salts.
During the present invention implements, by using combination property preferably high-molecular organic material and carrying out optimum organization, improve combination
The antistatic property of thing, the coating surface using the present invention to obtain is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength etc. refers to
Mark is superior to common coating, and can meet coated-body the most comprehensively uses requirement；Cost of the present invention is relatively low, it is achieved that resource and
Making full use of of the energy, production process is environment friendly and pollution-free, with short production cycle, is suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although with reference to above-mentioned reality
Execute example the present invention has been described in detail, it will be appreciated by those skilled in the art that still the present invention can be modified or
Equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should contain the power in the present invention
In profit claimed range.
Claims (3)
1. an electric iron antistatic coating, it is characterised in that be prepared by the raw materials in: organosilicon modified polyester tree
Fat 35～45 parts, pure-acrylic emulsion 10～15 parts, polyanion cellulose 2～5 parts, epoxy resin 5～12 parts, maleic acid 8～
15 parts, ferrotitanium powder 2～6 parts, isobutanol 1～3 parts, propylene-glycol ethyl ether 6～12 parts, water are appropriate, catalyst 1.5～3 parts,
Antistatic auxiliary 1.5～2.5 parts, aluminium hydroxide 1～5 parts, butyl acetate 5～10 parts, tetramethylolmethane 5～12 parts；
Its preparation method in turn includes the following steps:
(1) maleic acid, ferrotitanium powder, isobutanol, propylene-glycol ethyl ether, aluminium hydroxide and suitable quantity of water are joined in reaction vessel,
It is heated to 50～65 DEG C, stirs 20～30 minutes under 900～1200 revs/min, after mix homogeneously, obtain the most mixed liquid；
(2) mixing of silicone modified polyester resin, pure-acrylic emulsion, polyanion cellulose, epoxy resin and butyl acetate is added
Enter to step (1) in the first mixed liquid obtained, be heated to 65～80 DEG C, continue stirring 30～40 minutes, obtain intermediate liquid；
(3) intermediate liquid that step (2) obtains is cooled to 40～50 DEG C, adds catalyst, antistatic auxiliary and season penta 4
Alcohol, mix and blend 50～80 minutes, obtain mixed liquor；
(4) mixed liquor step (3) obtained puts into grinding in ball grinder and processes, and sieves and gets product.
A kind of electric iron antistatic coating the most according to claim 1, it is characterised in that described catalyst is sulfonic acid zinc.
A kind of electric iron antistatic coating the most according to claim 1, it is characterised in that described antistatic auxiliary is alkyl
Quaternary ammonium salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610663308.3A CN106010156A (en) | 2016-08-12 | 2016-08-12 | Electric iron antistatic paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610663308.3A CN106010156A (en) | 2016-08-12 | 2016-08-12 | Electric iron antistatic paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010156A true CN106010156A (en) | 2016-10-12 |
Family
ID=57135100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610663308.3A Pending CN106010156A (en) | 2016-08-12 | 2016-08-12 | Electric iron antistatic paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106010156A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899248A (en) * | 2010-07-05 | 2010-12-01 | 江门市制漆厂有限公司 | Environment-friendly rust inhibiting primer |
| CN104140743A (en) * | 2014-08-12 | 2014-11-12 | 广州亮豹涂料科技有限公司 | Functional anti-static wall surface paint and preparation method thereof |
| CN105647319A (en) * | 2016-01-20 | 2016-06-08 | 赵东星 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
| CN105647356A (en) * | 2016-01-19 | 2016-06-08 | 杭州吉华高分子材料股份有限公司 | High-temperature-resistant anticorrosive paint |
-
2016
- 2016-08-12 CN CN201610663308.3A patent/CN106010156A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899248A (en) * | 2010-07-05 | 2010-12-01 | 江门市制漆厂有限公司 | Environment-friendly rust inhibiting primer |
| CN104140743A (en) * | 2014-08-12 | 2014-11-12 | 广州亮豹涂料科技有限公司 | Functional anti-static wall surface paint and preparation method thereof |
| CN105647356A (en) * | 2016-01-19 | 2016-06-08 | 杭州吉华高分子材料股份有限公司 | High-temperature-resistant anticorrosive paint |
| CN105647319A (en) * | 2016-01-20 | 2016-06-08 | 赵东星 | Anti-static nano water-based anticorrosive paint and preparation method thereof |
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Application publication date: 20161012 |
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