CN106010101A - Environment-friendly and waterproof water-borne epoxy coating - Google Patents
Environment-friendly and waterproof water-borne epoxy coating Download PDFInfo
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- CN106010101A CN106010101A CN201610438921.5A CN201610438921A CN106010101A CN 106010101 A CN106010101 A CN 106010101A CN 201610438921 A CN201610438921 A CN 201610438921A CN 106010101 A CN106010101 A CN 106010101A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses an environment-friendly and waterproof water-borne epoxy coating. The environment-friendly and waterproof water-borne epoxy coating is prepared from a first component and a second component in the weight ratio of 10:(3-6). The first component includes, by weight, 20-50 parts of bisphenol-A liquid resin, 40-60 parts of a modified vegetable protein adhesive, 20-40 parts of redispersable rubber powder, 20-30 parts of negative ion powder, 15-35 parts of tourmaline powder, 2-6 parts of silk fibers, 5-15 parts of kaolin, 10-20 parts of weathered coal, 5-15 parts of zeolite powder, 5-15 parts of nano-titania, 2-6 parts of graphene, 1-2 parts of a dispersing agent, 1-2 parts of a defoaming agent and 1-2 parts of a wetting agent. The second component includes, by weight, 20-50 parts of water and 5-15 parts of trimethylhexamethylenediamine. The product is good in adsorbability and elasticity, high in adhesion strength with wall materials, excellent in waterproofness, almost free of formaldehyde release, capable of releasing negative ions for a long time to improve indoor air quality, beneficial to physical and psychological health, long in service life and environmentally friendly.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of environment-friendly waterproof aqueous epoxy coating.
Background technology
Along with science and technology progress and mankind's attention to living environment quality, coatings industry towards environment-friendly type,
Water-borne modification direction is developed, the most just at active development water paint, to adapt to industry and commercial market pair
The demand of aqueous environment protection coating products.The development speed of recent year water paint is very fast, particularly work
Industry is the most urgent by water paint demand, and water paint will have huge potential market, is obtaining significantly
Also huge social benefit can be created while economic benefit.The most urgently exploitation adhesion strength is high, anti-
Aqueous is good, and environmental protection is of value to physically and mentally healthy, service life length aqueous industrial coating.
Summary of the invention
The present invention proposes a kind of environment-friendly waterproof aqueous epoxy coating, goods excellent adsorption, glues with materials for wall
Attached intensity is high, good springiness, and water resistance is excellent, almost without Form aldehyde release, can improve by anion releasing for a long time
IAQ (indoor air quality), useful physical and mental health, service life length and there is the effect of environmental protection.
A kind of environment-friendly waterproof aqueous epoxy coating that the present invention proposes, it includes two kinds of components of first, second, and first,
The weight ratio of second two component is 10:3-6；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 20-50 part, improved plant
Albumen adhesive 40-60 part, re-dispersible glue powder 20-40 part, anion powder 20-30 part, tourmaline powder
15-35 part, silk fiber 2-6 part, Kaolin 5-15 part, weathered coal 10-20 part, zeolite powder 5-15 part,
Nano titanium oxide 5-15 part, Graphene 2-6 part, dispersant 1-2 part, defoamer 1-2 part, wetting agent
1-2 part；
Component B raw material includes by weight: water 20-50 part, trimethylhexamethylenediamine 5-15 part.
Preferably, modified vegetable protein adhesive use following technique prepare: by peanut powder, sodium hydroxide,
Water mix and blend, adds formaldehyde, nano titanium oxide, phenol mix and blend, and whipping temp is 70-80 DEG C；
Nitrogen protection under add soybean protein, sodium sulfite, anion emulsifier, potassium peroxydisulfate, deionized water mix
Close stirring, add ammonia regulation system pH value and stir to 9-9.6, stirring, addition styrene, butyl acrylate
Mixing, whipping temp is 60-70 DEG C；It is sequentially added into silver nitrate, sericine, glycerol, water mixed at room temperature
Uniformly, it is warming up to 50-58 DEG C and continues stirring, obtain modified vegetable protein adhesive.
Preferably, modified vegetable protein adhesive uses following technique to prepare: by weight by 10-20 part flower
Fecula, 1-2 part sodium hydroxide, 40-60 part water mix and blend 40-80min, whipping temp is 50-60 DEG C,
Add 15-20 part formaldehyde, 2-4 part nano titanium oxide, 5-15 part phenol mix and blend 20-50min, stir
Mix temperature and be 70-80 DEG C；Nitrogen protection is lower adds 10-20 part soybean protein, 1-2 part sodium sulfite, 1-3
Part anion emulsifier, 1-2 part potassium peroxydisulfate, 40-80 part deionized water mix and blend 10-20min, add
Ammonia regulation system pH value, to 9-9.6, stirs 20-40min, adds 1-3 part styrene, 2-6 part propylene
Acid butyl ester stirring 20-40min, whipping temp is 60-70 DEG C；It is sequentially added into 0.2-0.8 part silver nitrate, 20-40
Part sericine, 60-80 part glycerol, 100-140 part hydroecium temperature mix homogeneously, be warming up to 50-58 DEG C
Continue stirring 10-30min, obtain modified vegetable protein adhesive.
Preferably, the weight ratio of two kinds of components of first, second is 10:4-5.
Preferably, bisphenol A type liquid resin, the weight ratio of modified vegetable protein adhesive are 30-40:45-50.
Preferably, anion powder, tourmaline powder, the weight ratio of silk fiber are 24-26:25-30:3-4.
Preferably, modified vegetable protein adhesive, Kaolin, weathered coal, zeolite powder, nano titanium oxide,
The weight ratio of Graphene is 45-50:8-12:14-16:8-12:6-8:3-4.
Preferably, described environment-friendly waterproof aqueous epoxy coating, it includes two kinds of components of first, second, and first,
The weight ratio of second two component is 10:4-5；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 30-40 part, improved plant
Albumen adhesive 45-50 part, re-dispersible glue powder 30-34 part, anion powder 24-26 part, tourmaline powder
25-30 part, silk fiber 3-4 part, Kaolin 8-12 part, weathered coal 14-16 part, zeolite powder 8-12 part,
Nano titanium oxide 6-8 part, Graphene 3-4 part, dispersant 1.4-1.6 part, defoamer 1.4-1.6 part,
Wetting agent 1.4-1.6 part；
Component B raw material includes by weight: water 30-40 part, trimethylhexamethylenediamine 8-12 part.
The present invention is with water as diluent, and during reducing coating decoration, VOC (VOC) is to air
In discharge, reduce pollute, protect environment；Bisphenol A type liquid resin, modified vegetable protein adhesive with
Trimethylhexamethylenediamine carries out film forming, and construction is simple, stirs by hand, and construction effect duration is long,
And in modified vegetable protein adhesive, with peanut powder under the effect of nano titanium oxide, use phenol and
Formaldehyde cross-links, and molecular weight is big, and specific surface area is big, and surface can be high, has the skin effect of uniqueness, little
Dimensional effect and macro quanta tunnel effect, add soybean protein further, and use at sodium sulfite scission of link
Reason, anion emulsifier emulsifying, storeroom compatibility is fabulous, add potassium peroxydisulfate, styrene, third
Olefin(e) acid butyl ester effect is cross-linked into graft polymers, adds glycerol, silver nitrate and sericine and can generate and receive
Rice grain, and sericine utilize its coiled structure on the basis of ensureing that nano-particle do not reunites,
Storeroom favorable dispersibility, mutual coating function is fabulous, with bisphenol A type liquid resin, trimethyl six methylene
Base diamidogen effect, on the premise of ensureing goods adhesion strength, goods good springiness, water resistance is excellent, and
Almost without burst size of methanal, free from environmental pollution.
The anion powder that it is possible to additionally incorporate, tourmaline powder, silk fiber can make paint film anion releasing, launch
The harmful gass such as the formaldehyde in far infrared, effectively removal air, can effectively suppress mycete simultaneously, and anti-corrosive properties are good；
Anion powder, tourmaline powder, silk fiber and the Kaolin of addition, weathered coal, zeolite powder, nano-silica
Changing titanium, Graphene mating reaction, adhesion is good, good waterproof performance, and mixing uniformity is excellent, excellent adsorption,
But hardness is high, with the modified vegetable protein adhesive mating reaction added, conservative control ratio, can effectively drop
Low Article Stiffness Determination, good springiness, hardness is moderate.
The present invention is applicable to various environment and temperature, and the epidermis caused because the time is long placed in can be avoided to tilt, take off
The defect such as fall, goods excellent adsorption, high with materials for wall adhesion strength, good springiness, and water resistance is excellent,
Almost without Form aldehyde release, IAQ (indoor air quality), useful physical and mental health can be improved by anion releasing for a long time, use
Life-span length and there is the effect of environmental protection.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of environment-friendly waterproof aqueous epoxy coating, it includes two kinds of components of first, second, and first, second two component
Weight ratio is 10:3；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 50 parts, modified vegetable protein
Adhesive 40 parts, re-dispersible glue powder 40 parts, anion powder 20 parts, tourmaline powder 35 parts, silk fibroin
Tie up 2 parts, Kaolin 15 parts, weathered coal 10 parts, zeolite powder 15 parts, nano titanium oxide 5 parts, graphite
6 parts of alkene, dispersant 1 part, defoamer 2 parts, wetting agent 1 part；
Component B raw material includes by weight: 50 parts of water, trimethylhexamethylenediamine 5 parts.
Embodiment 2
A kind of environment-friendly waterproof aqueous epoxy coating, it includes two kinds of components of first, second, and first, second two component
Weight ratio is 10:6；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 20 parts, modified vegetable protein
Adhesive 60 parts, re-dispersible glue powder 20 parts, anion powder 30 parts, tourmaline powder 15 parts, silk fibroin
Tie up 6 parts, Kaolin 5 parts, weathered coal 20 parts, zeolite powder 5 parts, nano titanium oxide 15 parts, graphite
2 parts of alkene, dispersant 2 parts, defoamer 1 part, wetting agent 2 parts；
Component B raw material includes by weight: 20 parts of water, trimethylhexamethylenediamine 15 parts.
Embodiment 3
A kind of environment-friendly waterproof aqueous epoxy coating, it includes two kinds of components of first, second, and first, second two component
Weight ratio is 10:4；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 40 parts, modified vegetable protein
Adhesive 45 parts, re-dispersible glue powder 34 parts, anion powder 24 parts, tourmaline powder 30 parts, silk fibroin
Tie up 3 parts, Kaolin 12 parts, weathered coal 14 parts, zeolite powder 12 parts, nano titanium oxide 6 parts, graphite
4 parts of alkene, dispersant 1.4 parts, defoamer 1.6 parts, wetting agent 1.4 parts；
Component B raw material includes by weight: 40 parts of water, trimethylhexamethylenediamine 8 parts.
Modified vegetable protein adhesive uses following technique to prepare: by weight by 20 parts of peanut powders, 1 part of hydrogen
Sodium oxide, 60 parts of water mix and blend 40min, whipping temp is 60 DEG C, adds 15 parts of formaldehyde, 4 parts of nanometers
Titanium dioxide, 5 parts of phenol mix and blend 50min, whipping temp is 70 DEG C；Nitrogen protection is lower adds 20 parts
Soybean protein, 1 part of sodium sulfite, 3 parts of anion emulsifiers, 1 part of potassium peroxydisulfate, 80 parts of deionized waters mix
Close stirring 10min, add ammonia regulation system pH value to 9.6, stir 20min, add 3 parts of styrene,
2 parts of butyl acrylate stirring 40min, whipping temp is 60 DEG C；Be sequentially added into 0.8 part of silver nitrate, 20 parts
Sericine, 80 parts of glycerol, 100 parts of hydroecium temperature mix homogeneously, be warming up to 58 DEG C and continue stirring 10min,
Obtain modified vegetable protein adhesive.
Embodiment 4
A kind of environment-friendly waterproof aqueous epoxy coating, it includes two kinds of components of first, second, and first, second two component
Weight ratio is 10:5；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 30 parts, modified vegetable protein
Adhesive 50 parts, re-dispersible glue powder 30 parts, anion powder 26 parts, tourmaline powder 25 parts, silk fibroin
Tie up 4 parts, Kaolin 8 parts, weathered coal 16 parts, zeolite powder 8 parts, nano titanium oxide 8 parts, Graphene
3 parts, dispersant 1.6 parts, defoamer 1.4 parts, wetting agent 1.6 parts；
Component B raw material includes by weight: 30 parts of water, trimethylhexamethylenediamine 12 parts.
Modified vegetable protein adhesive uses following technique to prepare: by weight by 10 parts of peanut powders, 2 parts of hydrogen
Sodium oxide, 40 parts of water mix and blend 80min, whipping temp is 50 DEG C, adds 20 parts of formaldehyde, 2 parts of nanometers
Titanium dioxide, 15 parts of phenol mix and blend 20min, whipping temp is 80 DEG C；Nitrogen protection is lower adds 10 parts
Soybean protein, 2 parts of sodium sulfite, 1 part of anion emulsifier, 2 parts of potassium peroxydisulfates, 40 parts of deionized waters mix
Close stirring 20min, add ammonia regulation system pH value to 9, stir 40min, add 1 part of styrene, 6
Part butyl acrylate stirring 20min, whipping temp is 70 DEG C；It is sequentially added into 0.2 part of silver nitrate, 40 parts of silks
Glue protein matter, 60 parts of glycerol, 140 parts of hydroecium temperature mix homogeneously, be warming up to 50 DEG C and continue stirring 30min,
Obtain modified vegetable protein adhesive.
Embodiment 5
A kind of environment-friendly waterproof aqueous epoxy coating, it includes two kinds of components of first, second, and first, second two component
Weight ratio is 10:4.5；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 36 parts, modified vegetable protein
Adhesive 48 parts, re-dispersible glue powder 32 parts, anion powder 25 parts, tourmaline powder 28 parts, silk fibroin
Tie up 3.5 parts, Kaolin 10 parts, weathered coal 15 parts, zeolite powder 10 parts, nano titanium oxide 7 parts, stone
3.2 parts of alkene of ink, dispersant 1.5 parts, defoamer 1.5 parts, wetting agent 1.5 parts；
Component B raw material includes by weight: 35 parts of water, trimethylhexamethylenediamine 10 parts.
Modified vegetable protein adhesive use following technique prepare: by weight by 16 parts of peanut powders, 1.5 parts
Sodium hydroxide, 50 parts of water mix and blend 60min, whipping temp is 55 DEG C, add 18 parts of formaldehyde, 3 parts receive
Rice titanium dioxide, 12 parts of phenol mix and blend 35min, whipping temp is 75 DEG C；The lower addition 16 of nitrogen protection
Portion soybean protein, 1.5 parts of sodium sulfite, 2 parts of anion emulsifiers, 1.5 parts of potassium peroxydisulfates, 60 parts go from
Sub-water mix and blend 15min, addition ammonia regulation system pH value, to 9.3, stirs 32min, adds 2 parts of benzene
Ethylene, 4 parts of butyl acrylate stirring 28min, whipping temp is 65 DEG C；Be sequentially added into 0.6 part of silver nitrate,
32 parts of sericines, 72 parts of glycerol, 125 parts of hydroecium temperature mix homogeneously, be warming up to 55 DEG C and continue stirring
24min, obtains modified vegetable protein adhesive.
The preparation method of above-mentioned environment-friendly waterproof aqueous epoxy coating comprises the steps: each for first component by proportioning
Raw material mix and blend, control stir speed (S.S.) is 30r/min, and mixing time is 3min, adds component B mixing
Stir, obtain environment-friendly waterproof aqueous epoxy coating.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (8)
1. an environment-friendly waterproof aqueous epoxy coating, it is characterised in that it includes two kinds of components of first, second, and the weight ratio of first, second two component is 10:3-6；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 20-50 part, modified vegetable protein adhesive 40-60 part, re-dispersible glue powder 20-40 part, anion powder 20-30 part, tourmaline powder 15-35 part, silk fiber 2-6 part, Kaolin 5-15 part, weathered coal 10-20 part, zeolite powder 5-15 part, nano titanium oxide 5-15 part, Graphene 2-6 part, dispersant 1-2 part, defoamer 1-2 part, wetting agent 1-2 part；
Component B raw material includes by weight: water 20-50 part, trimethylhexamethylenediamine 5-15 part.
Environment-friendly waterproof aqueous epoxy coating the most according to claim 1, it is characterized in that, modified vegetable protein adhesive uses following technique to prepare: by peanut powder, sodium hydroxide, water mix and blend, adds formaldehyde, nano titanium oxide, phenol mix and blend, and whipping temp is 70-80 DEG C；Adding soybean protein, sodium sulfite, anion emulsifier, potassium peroxydisulfate, deionized water mix and blend under nitrogen protection, add ammonia regulation system pH value and stir to 9-9.6, stirring, addition styrene, butyl acrylate, whipping temp is 60-70 DEG C；It is sequentially added into silver nitrate, sericine, glycerol, hydroecium temperature mix homogeneously, is warming up to 50-58 DEG C and continues stirring, obtain modified vegetable protein adhesive.
Environment-friendly waterproof aqueous epoxy coating the most according to claim 2, it is characterized in that, modified vegetable protein adhesive uses following technique to prepare: by weight by 10-20 part peanut powder, 1-2 part sodium hydroxide, 40-60 part water mix and blend 40-80min, whipping temp is 50-60 DEG C, adding 15-20 part formaldehyde, 2-4 part nano titanium oxide, 5-15 part phenol mix and blend 20-50min, whipping temp is 70-80 DEG C；Nitrogen protection is lower adds 10-20 part soybean protein, 1-2 part sodium sulfite, 1-3 part anion emulsifier, 1-2 part potassium peroxydisulfate, 40-80 part deionized water mix and blend 10-20min; add ammonia regulation system pH value to 9-9.6; stirring 20-40min; adding 1-3 part styrene, 2-6 part butyl acrylate stirring 20-40min, whipping temp is 60-70 DEG C；It is sequentially added into 0.2-0.8 part silver nitrate, 20-40 part sericine, 60-80 part glycerol, 100-140 part hydroecium temperature mix homogeneously, is warming up to 50-58 DEG C and continues stirring 10-30min, obtain modified vegetable protein adhesive.
4. according to the environment-friendly waterproof aqueous epoxy coating described in any one of claim 1-3, it is characterised in that and the weight ratio of first, second two component is 10:4-5.
5. according to the environment-friendly waterproof aqueous epoxy coating described in claim 1-4 any one of any one, it is characterised in that bisphenol A type liquid resin, the weight ratio of modified vegetable protein adhesive are 30-40:45-50.
6. according to the environment-friendly waterproof aqueous epoxy coating described in any one of claim 1-5, it is characterised in that anion powder, tourmaline powder, the weight ratio of silk fiber are 24-26:25-30:3-4.
7. according to the environment-friendly waterproof aqueous epoxy coating described in any one of claim 1-6, it is characterized in that, modified vegetable protein adhesive, Kaolin, weathered coal, zeolite powder, nano titanium oxide, the weight ratio of Graphene are 45-50:8-12:14-16:8-12:6-8:3-4.
8. according to the environment-friendly waterproof aqueous epoxy coating described in any one of claim 1-7, it is characterised in that it includes two kinds of components of first, second, and the weight ratio of first, second two component is 10:4-5；
Wherein first component raw materials by weight portion includes: bisphenol A type liquid resin 30-40 part, modified vegetable protein adhesive 45-50 part, re-dispersible glue powder 30-34 part, anion powder 24-26 part, tourmaline powder 25-30 part, silk fiber 3-4 part, Kaolin 8-12 part, weathered coal 14-16 part, zeolite powder 8-12 part, nano titanium oxide 6-8 part, Graphene 3-4 part, dispersant 1.4-1.6 part, defoamer 1.4-1.6 part, wetting agent 1.4-1.6 part；
Component B raw material includes by weight: water 30-40 part, trimethylhexamethylenediamine 8-12 part.
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| CN201610438921.5A CN106010101A (en) | 2016-06-20 | 2016-06-20 | Environment-friendly and waterproof water-borne epoxy coating |
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| CN107236345A (en) * | 2017-07-26 | 2017-10-10 | 合肥梵腾环保科技有限公司 | A kind of excellent white glue with vinyl of health environment-friendly and preparation method thereof |
| CN107474661A (en) * | 2017-08-24 | 2017-12-15 | 江苏飞亚化学工业有限责任公司 | A kind of water-repellent paint |
| CN107474734A (en) * | 2017-08-24 | 2017-12-15 | 江苏飞亚化学工业有限责任公司 | A kind of mosquito repellent water-repellent paint |
| CN108531051A (en) * | 2018-03-30 | 2018-09-14 | 天长市巨龙车船涂料有限公司 | A kind of high-adhesion waterborne epoxy coatings |
| CN108531036A (en) * | 2018-03-30 | 2018-09-14 | 天长市巨龙车船涂料有限公司 | A kind of bi-component heat preservation waterborne epoxy coatings |
| CN108587392A (en) * | 2018-03-30 | 2018-09-28 | 天长市巨龙车船涂料有限公司 | A kind of waterborne epoxy coatings not easy to crack |
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| CN107236345A (en) * | 2017-07-26 | 2017-10-10 | 合肥梵腾环保科技有限公司 | A kind of excellent white glue with vinyl of health environment-friendly and preparation method thereof |
| CN107474661A (en) * | 2017-08-24 | 2017-12-15 | 江苏飞亚化学工业有限责任公司 | A kind of water-repellent paint |
| CN107474734A (en) * | 2017-08-24 | 2017-12-15 | 江苏飞亚化学工业有限责任公司 | A kind of mosquito repellent water-repellent paint |
| CN108531051A (en) * | 2018-03-30 | 2018-09-14 | 天长市巨龙车船涂料有限公司 | A kind of high-adhesion waterborne epoxy coatings |
| CN108531036A (en) * | 2018-03-30 | 2018-09-14 | 天长市巨龙车船涂料有限公司 | A kind of bi-component heat preservation waterborne epoxy coatings |
| CN108587392A (en) * | 2018-03-30 | 2018-09-28 | 天长市巨龙车船涂料有限公司 | A kind of waterborne epoxy coatings not easy to crack |
| CN110644251A (en) * | 2019-10-08 | 2020-01-03 | 刘国成 | Fabric containing green tea extract |
| CN111837498A (en) * | 2020-08-06 | 2020-10-30 | 乐昌市市政建设工程有限公司 | Garden soil improvement method |
| CN111837498B (en) * | 2020-08-06 | 2022-05-17 | 乐昌市市政建设工程有限公司 | Garden soil improvement method |
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Application publication date: 20161012 |