CN106800852A - A kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax and preparation method thereof - Google Patents
A kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax and preparation method thereof Download PDFInfo
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- CN106800852A CN106800852A CN201710091359.8A CN201710091359A CN106800852A CN 106800852 A CN106800852 A CN 106800852A CN 201710091359 A CN201710091359 A CN 201710091359A CN 106800852 A CN106800852 A CN 106800852A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax and preparation method thereof, by to water-based room temperature self-cross linking type polyacrylate dispersion, deionized water, levelling agent, coalescents, wetting agent, thickener, defoamer, delustering agent, PH adjusts liquid, bactericide, mould inhibitor, age resister, sealing compound is matched by certain percentage number, again by grinding, mixing, stirring, add dispensing, the sequence of operations such as emulsification, the sealing wax VOC emission amount being made is extremely low, it is a kind of safety and free of contamination environment-friendly type coating, the infringement polluted to natural environment and to health can to greatest extent be reduced, and with good gas permeability and the row that extends, paint film is difficult to ftracture and comes off, also there is color inhibition in the aspect of performance of paint film, good hand touch, naturally the characteristics of moistening.
Description
Technical field
The present invention relates to chemistry painting industry field, specifically, it is related to a kind of articles made of bamboo wood furniture multi-functional environment-protection matt
Sealing wax and preparation method thereof.
Background technology
Articles made of bamboo woodcare paint includes numerous species, such as PU paints, PE paints, NC paint, water paint, PU paint tools on the market at present
Have the advantages that hardness is good, richness is good, adhesive force is good, good endurance, good hand touch, but less environmental protection, countries in Europe base
This superseded this kind of coating；The combination property of PE paints is high, and phase is painted with PU at the aspect such as wear-resisting, heat-resisting, corrosion-resistant, high glaze
When, but because PE paints are anaerobic type coating, in ingress of air, surface is easily tacky because that can not be fully cured, and is not easy to make
With on the furniture of complex model；Preferably, easy construction is dried rapidly NC paint decoration function, and the requirement to painting environment is not
Height, with preferable hardness and brightness, is less prone to film defect, and repairing is easy, but solid content is relatively low, it is necessary to more applies
Work road number can be only achieved preferable effect, and durability is not so good, especially internal use nitrocellulose lacquer, and its guarantor's light colour retention is bad, uses
Time slightly length is easy for loss of gloss, cracking, the disadvantage such as discoloration occur, and paint film protective effect is bad, not organic solvent-resistant, intolerant to
It is hot, not corrosion-resistant；Although water paint has the advantages that environmentally friendly paint film effect is good, but single-component water-based paint is in the property such as hardness and high temperature resistant
Still there is a certain distance with double-component oil paint on energy.
But, with expanding economy and the raising of environmental consciousness and the progress of water-borne wood coating technology, Waterborne wood
Device paint has become the trend of development, and following home decoration and coatings for furniture market must be the world of water paint, and how
Solve the problems, such as existing aqueous woodware paint to have a certain distance with double-component oil paint in the performance such as hardness and high temperature resistant is mesh
Preceding people need the direction of research.
The content of the invention
The present invention is according to above-mentioned technical background, there is provided a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax and its system
Preparation Method.
To solve the above problems, the technical solution adopted in the present invention is：
A kind of multi-functional environment-protection matt sealing wax, it is characterised in that the constituent of the matt sealing wax includes：Water-based room temperature
Self-cross linking type polyacrylate dispersion, deionized water, levelling agent, coalescents, wetting agent, thickener, defoamer, delustering agent,
PH adjustment liquid, bactericide, mould inhibitor, age resister, sealing compound, wherein the degree of each composition is：Water-based room temperature selfing
Connection type polyacrylate dispersion 65~80%, deionized water 10~20%, levelling agent 0.2~1%, coalescents 0.2~1%,
Wetting agent 0.1~0.5%, thickener 1.2~6%, defoamer 0.1~0.5%, delustering agent 0.2~1%, PH adjustment liquid 0.1~
0.5%th, bactericide 0.05~0.2%, mould inhibitor 0.1~0.5%, age resister 0.7~2.7%, sealing compound 3~10%.
Further, the levelling agent is polyether-modified dimethyl silicone polymer, and coalescents are propandiol butyl ether, wetting
Agent is epoxy-modified polysiloxane, and thickener is hydrophobically modified hydroxyethyl cellulose, the poly- ammonia of nonionic hydrophobically modified oxirane
Ester copolymer and organobentonite, defoamer are the middle temperature high effective antifoaming agents of SXP-106, and delustering agent is organic modification nano-gas-phase
Method silica, PH adjustment liquid is triethylamine solution, and bactericide is silver ion solution, and mould inhibitor is dichloride in anatase type TiO2, is resisted
Aging dose is nano zine oxide and ultraviolet absorbent UV-531, and sealing compound is wood wax oil.
Further, the degree of each constituent is in the thickener：Hydrophobically modified hydroxyethyl cellulose 0.1
~0.5%, nonionic hydrophobically modified ethoxylated urethanes copolymer 0.1~0.5%, organobentonite 1~5%.
Further, the degree of each constituent is in the age resister：Nano zine oxide 0.2~0.7%,
Ultraviolet absorbent UV-531 0.5~2%.
Further, the degree of each composition of matt sealing wax is：Water-based room temperature self-cross linking type polyacrylate
It is emulsion 72%, deionized water 12%, polyether-modified dimethyl silicone polymer 0.7%, propandiol butyl ether 0.7%, epoxide modified poly-
Siloxanes 0.3%, hydrophobically modified hydroxyethyl cellulose 0.5%, nonionic hydrophobically modified ethoxylated urethanes copolymer
0.5%th, the middle temperature high effective antifoaming agent 0.4% of organobentonite 3.2%, SXP-106, organic modification nano-gas-phase method silica
0.8%th, triethylamine solution 0.4%, silver ion solution 0.15%, dichloride in anatase type TiO2 0.35%, nano zine oxide 0.5%,
Ultraviolet absorbent UV-531 1.5%, wood wax oil 6%.
Further, the degree of each composition of matt sealing wax is：Water-based room temperature self-cross linking type polyacrylate
It is emulsion 65%, deionized water 20%, polyether-modified dimethyl silicone polymer 0.5%, propandiol butyl ether 0.5%, epoxide modified poly-
Siloxanes 0.2%, hydrophobically modified hydroxyethyl cellulose 0.25%, nonionic hydrophobically modified ethoxylated urethanes copolymer
0.25%th, the middle temperature high effective antifoaming agent 0.2% of organobentonite 2.5%, SXP-106, organic modification nano-gas-phase method titanium dioxide
Silicon 0.5%, triethylamine solution 0.2%, silver ion solution 0.1%, dichloride in anatase type TiO2 0.2%, nano zine oxide 0.5%,
Ultraviolet absorbent UV-531 1.1%, wood wax oil 8%.
Further, the degree of each composition of matt sealing wax is：Water-based room temperature self-cross linking type polyacrylate
It is emulsion 80%, deionized water 10%, polyether-modified dimethyl silicone polymer 0.5%, propandiol butyl ether 0.5%, epoxide modified poly-
Siloxanes 0.2%, hydrophobically modified hydroxyethyl cellulose 0.25%, nonionic hydrophobically modified ethoxylated urethanes copolymer
0.25%th, the middle temperature high effective antifoaming agent 0.2% of organobentonite 2.5%, SXP-106, organic modification nano-gas-phase method titanium dioxide
Silicon 0.5%, triethylamine solution 0.2%, silver ion solution 0.1%, dichloride in anatase type TiO2 0.2%, nano zine oxide 0.5%,
Ultraviolet absorbent UV-531 1.1%, wood wax oil 3%.
A kind of preparation method of multi-functional environment-protection matt sealing wax, comprises the following steps：
A, by the load weighted organobentonite, organic modification nano-gas-phase method silica, nano zine oxide, sharp
Titanium-type nano TiO 2 is put into grinder after being homogenously mixed together and is ground, and the powder granule degree requirement being ground is 500
It is more than mesh；
B, by the load weighted water-based room temperature self-cross linking type polyacrylate dispersion, polyether-modified polydimethylsiloxanes
Alkane, propandiol butyl ether, epoxy-modified polysiloxane, hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified oxirane gather
The middle temperature high effective antifoaming agent of urethane copolymer, wood wax oil, SXP-106 is put into reactor, is forced into 0.4~0.6MPa, is heated up to
65~80 degree, then stirred 30~60 minutes with the rotating speed of 100~300r/min；
C, the mixture that will be obtained in step A are added in aforesaid reaction vessel, add deionized water, and keeping temperature pressure is not
Become, rotating speed is brought up into 1500~2000r/min, stir 20~40 minutes, obtain mixed solution；
D, solution mixed above is added load weighted ultraviolet absorbent UV-531, silver ion solution do sterilized and anti-ageing
Change is processed, and adds triethylamine solution, and then adjustment solution PH is carried out to 8~8.5 with powerful ultrasonic homogeneous emulsification instrument
Matter is emulsified 15~30 minutes, 4# glasss of viscosity of adjustment 25-35 seconds, that is, make finished product.
Water-based room temperature self-cross linking type polyacrylate dispersion is main film forming matter in the present invention, transparent with film
Property, adhesive force and glossiness it is good, dicoration, against weather, resistance to carbonated drink property and resistance to acids and bases are excellent, and richness and glossiness are high
The advantages of, and it is good in water stability, the safe-use period is long, and the same day is not run out, and next day still can be used, not waste of resource, no
Pollution environment.
Polyether-modified dimethyl silicone polymer has extremely low surface energy, good ground wetting and good anti-shrinkage cavity
Performance, increases surface slip and scratch resistance and adhesion inhibiting properties, it is therefore prevented that the formation of Bei Nade whirlpools, improves levelling and light
Pool, it is adaptable to all solvent-borne types, no-solvent type and water-based paint system.And because it has excellent phase with all binder systems
Dissolubility thus it will not be produced in varnish muddiness problem.
Propandiol butyl ether is environment-friendly type solvent, can soften emulsion polymerization composition granule, these particles is coalesced fusion another
Rise, preferably form film, it can also improve the resistance to of emulsion paint in addition to it can reduce emulsion paint MFT (MFFT)
The paint film properties such as climacteric, washable property, the color developing of coating.
Epoxy-modified polysiloxane can be allowed the water to be deployed in it by reducing solid material surface tension or interfacial tension
On surface, or its surface is penetrated, so as to solid material is soaked.
Hydrophobically modified hydroxyethyl cellulose can also the plyability of reinforcing material and viscous in addition to not influenceing the toning of coating
Knotting strength, does not reduce with splendid thickening property and levelability and the gloss of paint film.
Nonionic hydrophobically modified ethoxylated urethanes copolymer can improve the mobility and levelability of emulsion paint, reduce
Flow coat splashing, raising paint film richness, fungus resistance and glossiness.
Organobentonite has superior temperature stability, in use the limit without highest or minimum operating temperature
System, can improve the storage stability of coating in addition coating, its high temperature anti-sag effect is that other organic thickener rheology agents are difficult to
Reach.
The middle temperature high effective antifoaming agents of SXP-106 be with the dispersing aid of excellent performance, emulsifying agent is refined forms.With consumption
Less, the obvious characteristic of safety non-toxic, defoaming effect.
Organic modification nano-gas-phase method silica has uncommon material characteristic, i.e., minimum particle diameter (is once tied
The particle diameter of structure is 7~40 nanometers), great specific surface area (BET method is detected as 100~400m2/g), purity (dioxy very high
99.8%) SiClx content is not less than, its chaining tendency make it have the reinforcing, thickening property of brilliance, thixotropy, extinction,
The performances such as dispersiveness, insulating properties, antistick characteristic.
Triethylamine solution can mainly play a part of to adjust pH value.
The mechanism that silver ion solution is used refers to during its is used, to slowly release Ag+, because Ag+ is dense
In the case of can destroy bacterial cell membrane or consumingly attract the thin base of zymoprotein in bacterial body, and be combined together rapidly, reduce
The activity of thin plateau bioactive enzyme, with antibacterial action.
Dichloride in anatase type TiO2, with broad-spectrum antiseptic function, can suppress and kill as photocatalytic semiconductor inorganic antiseptic
Microorganism killing, and play the role of deodorant, mould proof, sterilization, itself stable chemical nature and to human body and environmentally friendly, photocatalysis
Persistent.
Nano zine oxide is the preservative and luminous agent in coating in addition to tinting strength, tinting power and covering power, again；Additionally, receiving
The rice excellent ultraviolet screening ability of zinc oxide makes it have the characteristic for more protruding at the aspect such as anti-aging of coating.
Ultraviolet absorbent UV-531 is a kind of remarkable efficient anti-aging auxiliary agent of performance, can absorb 240-340 nanometers
Ultraviolet light, with color it is shallow, nontoxic, compatibility is good, animal migration is small, it is easy to process the features such as.
Wood wax oil has strong, the environmentally friendly advantage of permeability, and it can penetrate into timber, naturally protect timber, play maintenance
Effect.
The of the invention a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax being prepared from using above-mentioned material is being made
Without the addition harmful substance such as organic solvent and formaldehyde, lead, chromium during standby, the film forming of sealing wax is with the volatilization high score of moisture
The final crosslinking of extruding is formed sub- particle mutually, therefore water paint VOC emission amount is extremely low, only accounts for the 0%~10% of oil paint, institute
To be a kind of safety and free of contamination environment-friendly type coating, can to greatest extent reduce and natural environment be polluted and to health
Infringement.And the physical film deposition mode of particle crosslinking also has water paint paint film good gas permeability and to prolong in sealing wax of the present invention
Zhan Hang, paint film is difficult to ftracture and comes off, and is even more prominent compared to oil paint weatherability especially for use on outdoor woodwork, in paint film
Aspect of performance water paint also have color inhibition, good hand touch, naturally moisten paint film feature.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with specific embodiment.
A kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax, the constituent of the matt sealing wax includes：It is aqueous
Room-temperature self crosslinking type polyacrylate dispersion, deionized water, levelling agent, coalescents, wetting agent, thickener, defoamer, delustring
Agent, PH adjustment liquid, bactericide, mould inhibitor, age resister, sealing compound, wherein the degree of each composition is：Water-based room temperature is certainly
Crosslinked polyacrylate emulsion 65~80%, deionized water 10~20%, levelling agent 0.2~1%, coalescents 0.2~
1%th, wetting agent 0.1~0.5%, thickener 1.2~6%, defoamer 0.1~0.5%, delustering agent 0.2~1%, PH adjustment liquid
0.1~0.5%, bactericide 0.05~0.2%, mould inhibitor 0.1~0.5%, age resister 0.7~2.7%, sealing compound 3~
10%.
The levelling agent is polyether-modified dimethyl silicone polymer, and coalescents are propandiol butyl ether, and wetting agent is epoxy
Modified polyorganosiloxane, thickener is hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified ethoxylated urethanes copolymer
And organobentonite, defoamer is the middle temperature high effective antifoaming agents of SXP-106, and delustering agent is organic modification nano-gas-phase method titanium dioxide
Silicon, PH adjustment liquid is triethylamine solution, and bactericide is silver ion solution, and mould inhibitor is dichloride in anatase type TiO2, and age resister is
Nano zine oxide and ultraviolet absorbent UV-531, sealing compound are wood wax oil.
The degree of each constituent is in the thickener：Hydrophobically modified hydroxyethyl cellulose 0.1~0.5%,
Nonionic hydrophobically modified ethoxylated urethanes copolymer 0.1~0.5%, organobentonite 1~5%.
The degree of each constituent is in the age resister：Nano zine oxide 0.2~0.7%, ultraviolet is inhaled
Receive agent UV-531 0.5~2%.
Table 1 is three groups of specific ratio numbers of each component of the present invention
Embodiment 1~3
Each raw material is taken by the material composition composition in table 1, first by the load weighted organobentonite, organic modification
Nano-gas-phase method silica, nano zine oxide, dichloride in anatase type TiO2 are put into grinder after being homogenously mixed together and carry out
Grinding, the powder granule degree requirement being ground obtains mixture standby more than 500 mesh；Then will be load weighted described aqueous
Room-temperature self crosslinking type polyacrylate dispersion, polyether-modified dimethyl silicone polymer, propandiol butyl ether, epoxide modified poly- silica
Alkane, hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified ethoxylated urethanes copolymer, wood wax oil, the middle temperature of SXP-106
High effective antifoaming agent is put into reactor, is forced into 0.4MPa, is heated up to 65 degree, then stirs 30 points with the rotating speed of 100r/min
Clock；The mixture that will be obtained in above-mentioned steps again is added in aforesaid reaction vessel, adds deionized water, and keeping temperature pressure is constant,
Rotating speed is brought up into 1500r/min, is stirred 20 minutes, obtain mixed solution；Finally solution mixed above is added load weighted
Ultraviolet absorbent UV-531, silver ion solution do sterilized and anti-aging treatment, add triethylamine solution, and adjustment solution PH is extremely
8, then carry out emulsifying 15 minutes with powerful ultrasonic homogeneous emulsification instrument, 4# glasss of viscosity of adjustment 25 seconds make finished product.
Embodiment 4~6
Each raw material is taken by the material composition composition in table 1, first by the load weighted organobentonite, organic modification
Nano-gas-phase method silica, nano zine oxide, dichloride in anatase type TiO2 are put into grinder after being homogenously mixed together and carry out
Grinding, the powder granule degree requirement being ground obtains mixture standby more than 500 mesh；Then will be load weighted described aqueous
Room-temperature self crosslinking type polyacrylate dispersion, polyether-modified dimethyl silicone polymer, propandiol butyl ether, epoxide modified poly- silica
Alkane, hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified ethoxylated urethanes copolymer, wood wax oil, the middle temperature of SXP-106
High effective antifoaming agent is put into reactor, is forced into 05MPa, is heated up to 72 degree, is then stirred 45 minutes with the rotating speed of 200r/min；
The mixture that will be obtained in above-mentioned steps again is added in aforesaid reaction vessel, adds deionized water, and keeping temperature pressure is constant, will be turned
Speed brings up to 1800r/min, stirs 30 minutes, obtains mixed solution；Finally solution mixed above is added load weighted ultraviolet
Light absorbers UV-531, silver ion solution do sterilized and anti-aging treatment, add triethylamine solution, adjust solution PH to 8.3,
Then emulsifying is carried out 24 minutes with powerful ultrasonic homogeneous emulsification instrument, 4# glasss of viscosity of adjustment 30 seconds make finished product.
Embodiment 7~9
Each raw material is taken by the material composition composition in table 1, first by the load weighted organobentonite, organic modification
Nano-gas-phase method silica, nano zine oxide, dichloride in anatase type TiO2 are put into grinder after being homogenously mixed together and carry out
Grinding, the powder granule degree requirement being ground obtains mixture standby more than 500 mesh；Then will be load weighted described aqueous
Room-temperature self crosslinking type polyacrylate dispersion, polyether-modified dimethyl silicone polymer, propandiol butyl ether, epoxide modified poly- silica
Alkane, hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified ethoxylated urethanes copolymer, wood wax oil, the middle temperature of SXP-106
High effective antifoaming agent is put into reactor, is forced into 0.6MPa, is heated up to 80 degree, then stirs 60 points with the rotating speed of 300r/min
Clock；The mixture that will be obtained in above-mentioned steps again is added in aforesaid reaction vessel, adds deionized water, and keeping temperature pressure is constant,
Rotating speed is brought up into 2000r/min, is stirred 40 minutes, obtain mixed solution；Finally solution mixed above is added load weighted
Ultraviolet absorbent UV-531, silver ion solution do sterilized and anti-aging treatment, add triethylamine solution, and adjustment solution PH is extremely
8.5, then carry out emulsifying 30 minutes with powerful ultrasonic homogeneous emulsification instrument, 4# glasss of viscosity of adjustment 35 seconds make into
Product.
The present invention is not limited to above-mentioned preferred embodiment, and anyone should learn what is made under enlightenment of the invention
Structure change, it is every with of the invention with technical scheme as same or similar, belong to protection scope of the present invention.
Claims (8)
1. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax, it is characterised in that the constituent of the matt sealing wax
Including：Water-based room temperature self-cross linking type polyacrylate dispersion, deionized water, levelling agent, coalescents, wetting agent, thickener, disappear
Infusion, delustering agent, PH adjustment liquid, bactericide, mould inhibitor, age resister, sealing compound, wherein the degree of each composition is：
Water-based room temperature self-cross linking type polyacrylate dispersion 65~80%, deionized water 10~20%, levelling agent 0.2~1%, film forming are helped
Agent 0.2~1%, wetting agent 0.1~0.5%, thickener 1.2~6%, defoamer 0.1~0.5%, delustering agent 0.2~1%, PH
Adjustment liquid 0.1~0.5%, bactericide 0.05~0.2%, mould inhibitor 0.1~0.5%, age resister 0.7~2.7%, sealing compound
3~10%.
2. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax according to claim 1, it is characterised in that：It is described
Levelling agent is polyether-modified dimethyl silicone polymer, and coalescents are propandiol butyl ether, and wetting agent is epoxy-modified polysiloxane,
Thickener be hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified ethoxylated urethanes copolymer and organobentonite,
Defoamer is the middle temperature high effective antifoaming agents of SXP-106, and delustering agent is organic modification nano-gas-phase method silica, and PH adjustment liquid is
Triethylamine solution, bactericide is silver ion solution, and mould inhibitor is dichloride in anatase type TiO2, and age resister is nano zine oxide and purple
Ultraviolet absorbers UV-531, sealing compound is wood wax oil.
3. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax according to claim 1 and 2, it is characterised in that：
The degree of each constituent is in the thickener：Hydrophobically modified hydroxyethyl cellulose 0.1~0.5%, nonionic is dredged
Water modified ethoxylated urethanes copolymer 0.1~0.5%, organobentonite 1~5%.
4. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax according to claim 1 and 2, it is characterised in that：
The degree of each constituent is in the age resister：Nano zine oxide 0.2~0.7%, ultra-violet absorber UV-
531 0.5~2%.
5. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax according to any one of claim 1-4, it is special
Levy and be：The degree of each composition of matt sealing wax is：Water-based room temperature self-cross linking type polyacrylate dispersion 72%, go
Ionized water 12%, polyether-modified dimethyl silicone polymer 0.7%, propandiol butyl ether 0.7%, epoxy-modified polysiloxane 0.3%,
Hydrophobically modified hydroxyethyl cellulose 0.5%, nonionic hydrophobically modified ethoxylated urethanes copolymer 0.5%, organobentonite
3.2%th, the middle temperature high effective antifoaming agents 0.4% of SXP-106, organic modification nano-gas-phase method silica 0.8%, triethylamine solution
0.4%th, silver ion solution 0.15%, dichloride in anatase type TiO2 0.35%, nano zine oxide 0.5%, ultra-violet absorber UV-
531 1.5%, wood wax oil 6%.
6. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax according to any one of claim 1-4, it is special
Levy and be：The degree of each composition of matt sealing wax is：Water-based room temperature self-cross linking type polyacrylate dispersion 65%, go
Ionized water 20%, polyether-modified dimethyl silicone polymer 0.5%, propandiol butyl ether 0.5%, epoxy-modified polysiloxane 0.2%,
Hydrophobically modified hydroxyethyl cellulose 0.25%, nonionic hydrophobically modified ethoxylated urethanes copolymer 0.25%, organic swelling
Soil 2.5%, the middle temperature high effective antifoaming agents 0.2% of SXP-106, organic modification nano-gas-phase method silica 0.5%, triethylamine are molten
Liquid 0.2%, silver ion solution 0.1%, dichloride in anatase type TiO2 0.2%, nano zine oxide 0.5%, ultra-violet absorber UV-
531 1.1%, wood wax oil 8%.
7. a kind of articles made of bamboo wood furniture multi-functional environment-protection matt sealing wax according to any one of claim 1-4, it is special
Levy and be：The degree of each composition of matt sealing wax is：Water-based room temperature self-cross linking type polyacrylate dispersion 80%, go
Ionized water 10%, polyether-modified dimethyl silicone polymer 0.5%, propandiol butyl ether 0.5%, epoxy-modified polysiloxane 0.2%,
Hydrophobically modified hydroxyethyl cellulose 0.25%, nonionic hydrophobically modified ethoxylated urethanes copolymer 0.25%, organic swelling
Soil 2.5%, the middle temperature high effective antifoaming agents 0.2% of SXP-106, organic modification nano-gas-phase method silica 0.5%, triethylamine are molten
Liquid 0.2%, silver ion solution 0.1%, dichloride in anatase type TiO2 0.2%, nano zine oxide 0.5%, ultra-violet absorber UV-
531 1.1%, wood wax oil 3%.
8. a kind of articles made of bamboo wood furniture preparation method of multi-functional environment-protection matt sealing wax, it is characterised in that：The preparation method
Comprise the following steps：
A, by the load weighted organobentonite, organic modification nano-gas-phase method silica, nano zine oxide, anatase titanium dioxide
Nano TiO 2 is put into grinder after being homogenously mixed together and is ground, the powder granule degree requirement being ground 500 mesh with
On；
B, by the load weighted water-based room temperature self-cross linking type polyacrylate dispersion, polyether-modified dimethyl silicone polymer, third
Glycol butyl ether, epoxy-modified polysiloxane, hydrophobically modified hydroxyethyl cellulose, nonionic hydrophobically modified ethoxylated urethanes are total to
The middle temperature high effective antifoaming agent of polymers, wood wax oil, SXP-106 is put into reactor, is forced into 0.4~0.6MPa, is heated up to 65~80
Degree, is then stirred 30~60 minutes with the rotating speed of 100~300r/min；
C, the mixture that will be obtained in step A are added in aforesaid reaction vessel, add deionized water, and keeping temperature pressure is constant, will
Rotating speed brings up to 1500~2000r/min, stirs 20~40 minutes, obtains mixed solution；
D, solution mixed above is added load weighted ultraviolet absorbent UV-531, silver ion solution do sterilized and anti-aging place
Reason, adds triethylamine solution, and then adjustment solution PH carries out homogenized milk to 8~8.5 with powerful ultrasonic homogeneous emulsification instrument
Change 15~30 minutes, 4# glasss of viscosity of adjustment 25-35 seconds make finished product.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679423A (en) * | 2019-01-22 | 2019-04-26 | 重庆环绿明珠新材料科技有限公司 | A kind of aqueous wood wax oil and preparation method thereof |
| CN109943110A (en) * | 2019-03-21 | 2019-06-28 | 苏州蓝沃奇纳米科技有限公司 | The self-cleaning degerming Essence of plant, preparation method and self-cleaning degerming coating |
| CN110172298A (en) * | 2019-05-20 | 2019-08-27 | 苏州市超邦涂料有限公司 | A kind of high molecular nanometer weather resistance environmental protection coating |
| CN111154365A (en) * | 2020-01-20 | 2020-05-15 | 东莞大宝化工制品有限公司 | Water-based paint suitable for bamboo boards and preparation method thereof |
| CN111393994A (en) * | 2020-04-01 | 2020-07-10 | 郑州熙虎科技有限公司 | Matte wood wax oil |
| CN113480899A (en) * | 2019-11-28 | 2021-10-08 | 河北晨阳工贸集团有限公司 | Yellowing-resistant indoor water-based wood paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614026A (en) * | 2013-11-04 | 2014-03-05 | 三棵树涂料股份有限公司 | Aqueous woodenware matte clean finishing coat and its preparation method |
| CN103881500A (en) * | 2014-03-27 | 2014-06-25 | 中华制漆（深圳）有限公司 | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint |
| CN104592840A (en) * | 2014-12-30 | 2015-05-06 | 三棵树涂料股份有限公司 | Scratch-endurable high-performance aqueous semi-dumb white paint for woodwork and preparation method thereof |
| CN105440835A (en) * | 2015-12-09 | 2016-03-30 | 三棵树涂料股份有限公司 | Waterborne woodware matte white finish with high scratch resistance and high performance |
-
2017
- 2017-02-21 CN CN201710091359.8A patent/CN106800852A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614026A (en) * | 2013-11-04 | 2014-03-05 | 三棵树涂料股份有限公司 | Aqueous woodenware matte clean finishing coat and its preparation method |
| CN103881500A (en) * | 2014-03-27 | 2014-06-25 | 中华制漆（深圳）有限公司 | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint |
| CN104592840A (en) * | 2014-12-30 | 2015-05-06 | 三棵树涂料股份有限公司 | Scratch-endurable high-performance aqueous semi-dumb white paint for woodwork and preparation method thereof |
| CN105440835A (en) * | 2015-12-09 | 2016-03-30 | 三棵树涂料股份有限公司 | Waterborne woodware matte white finish with high scratch resistance and high performance |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679423A (en) * | 2019-01-22 | 2019-04-26 | 重庆环绿明珠新材料科技有限公司 | A kind of aqueous wood wax oil and preparation method thereof |
| CN109943110A (en) * | 2019-03-21 | 2019-06-28 | 苏州蓝沃奇纳米科技有限公司 | The self-cleaning degerming Essence of plant, preparation method and self-cleaning degerming coating |
| CN110172298A (en) * | 2019-05-20 | 2019-08-27 | 苏州市超邦涂料有限公司 | A kind of high molecular nanometer weather resistance environmental protection coating |
| CN113480899A (en) * | 2019-11-28 | 2021-10-08 | 河北晨阳工贸集团有限公司 | Yellowing-resistant indoor water-based wood paint and preparation method thereof |
| CN111154365A (en) * | 2020-01-20 | 2020-05-15 | 东莞大宝化工制品有限公司 | Water-based paint suitable for bamboo boards and preparation method thereof |
| CN111393994A (en) * | 2020-04-01 | 2020-07-10 | 郑州熙虎科技有限公司 | Matte wood wax oil |
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